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Neha Waxes
Neha Waxes
A dental wax is a low molecular weight ester of fatty acid derived from
natural and synthetic components such as petroleum derivatives that
soften to a plastic state at a relatively low temperature.
FATS:
They are substances similar to wax but characterized as being soft
and greasy to touch
GUMS:
Gums are various substances from plant or animal sources that
harden in air. Gums combine with water to form sticky, viscous liquids.
NATURAL RESINS:
They are mixtures of high molecular weight organic substances
obtained directly from plants or trees as exudates.
CLASSIFICATION OF WAXES
NATURAL WAXES
MINERAL WAXES
PARAFFIN WAXES
1) It is named paraffin because of its little chemical affinity to
other substances.
2) They are straight – chain hydrocarbons with 26 to 30 carbon
atoms obtained principally from high boiling fractions of
petroleum.
3) Paraffin waxes soften in the temperature range 37 to 55°C and
melt in the range 48 to 70°C. Lower the molecular weight,
lower will be the melting temperature.
4) During solidification and cooling, there is a volumetric
contraction that varies from 11 to 15%. This contraction is not
uniform throughout the temperature range from melting
temperature to room temperature, because the wax is a mixture
of hydrocarbons and the wax passes through transition points
accompanied by changes in physical properties.
5) Paraffin waxes used in dentistry are refined waxes and have less
than 0.5% oils.
6) Flow is 50% at 31.50 C
7) It is likely to flake when trimmed.
8) It does not present a smooth, glossy surface.
MICROCRYSTALLINE WAX
1) They are branched – chain hydrocarbons with 41-50 carbon
atoms.
2) They are similar to paraffin waxes, except that they are obtained
from the heavier oil fractions in the petroleum industry and, as a
result, have higher melting points in the range of 60 – 91°C.
3) These waxes are tougher and more flexible than paraffin waxes.
4) They have an affinity for oil, and their hardness and tackiness
may be altered by adding oil.
5) Microcrystalline waxes have less volumetric change during
solidification than paraffin waxes.
6) They are added to modify the softening and melting ranges of
wax blends.
7) They also serve to reduce the stresses that occur on cooling.
BARNSDAHL
1) Barnsdahl is a microcrystalline wax used to
Increase the melting range
Hardness
Reduce the flow of paraffin waxes.
2) The melting range of Barnsdahl wax is 70 to 74°C
OZOKERITE
1) It is similar to microcrystalline wax.
2) It also has great affinity for oil.
3) In quantities of 5 to 15%, it greatly improves the physical
characteristics of paraffins in the melting range of 54°C.
CERESIN
1) Like microcrystalline waxes, they are straight and branched
chained paraffins, but have higher molecular weights and
greater hardness than hydrocarbon waxes distilled from the
crude products.
2) These waxes may also increase the melting range of paraffin
waxes.
3) The melting range of these waxes is 85 to 95°C.
MONTAN
1) They are hard, brittle and lustrous; they blend well with other
waxes.
2) Therefore, they are often substituted for plant waxes to improve
the hardness and the melting range of paraffin waxes.
PLANT WAXES
CANDELILLA
1) It is derived from Candelilla plant which grows in hot, dry
places.
2) They consist of 40 to 60% of paraffin hydrocarbons containing
29 to 33 carbon atoms.
3) Like Carnauba and Ouricury wax, they harden paraffin waxes
but are not so effective for increasing the melting range.
4) It is added to paraffin to partially or entirely replace carnauba
wax.
5) Its melting point is lower, and it is not as hard as carnauba wax.
6) Their melting range is 68 to 75°C.
JAPAN WAX
1) Japan wax is not a true wax; they are chiefly fats.
2) It is tough, malleable, and sticky material that melts at about
51°C.
3) Japan wax may be mixed with paraffin to improve tackiness
and emulsifying ability.
COCOA BUTTER
1) Cocoa butter is not a true wax either.
2) It is brittle at room temperature.
3) It is used to protect against dehydration of soft tissues and to
protect glass ionomer products temporarily from moisture
during setting or from dehydrating after they set.
INSECT WAXES
BEESWAX
1) It is the primary insect wax used in dentistry.
2) It is derived from honeycombs and consists of partially
crystalline natural polyester and is often blended with paraffin
wax to modify the properties of the latter.
3) It varies in color from yellow to black.
4) Their melting range is 63 - 700C.
5) It is brittle at room temperature, but becomes plastic at body
temperature.
6) It is the main component of sticky wax.
7) The effect of adding bees wax to paraffin wax is
To render the material less brittle.
To reduce the extent to which it will flow under stress at
temperatures just below the melting point.
ANIMAL WAXES
SPERMACETI WAX
1) It is obtained from the sperm whale.
2) They are not used extensively in dentistry.
3) They are mainly ester waxes.
4) It is liquid at room temperature.
5) Spermaceti wax has been used as a coating in the manufacture
of dental floss.
I. SYNTHETIC WAXES
1) Melting range
2) Thermal expansion
3) Mechanical properties
4) Flow
5) Residual stress
6) Ductility
Melting range
Thermal expansion
Mechanical properties
Residual stress
Ductility
1) Like flow, ductility increases as the temperature of a wax specimen
is increased.
2) In general, waxes with lower melting temperatures have a greater
ductility at any given temperature than those with higher melting
temperatures.
3) A blended wax with components that have wide melting ranges
generally has greater ductility than blended waxes that have a
narrow range.
4) Generally, highly refined waxes are quite brittle.
INLAY WAX
CLASSIFICATION
DESIRABLE PROPERTIES
COMPOSITION
PARAFFIN
1) It is the main ingredient of inlay waxes.
2) Concentration: - 40 to 60%
3) It is likely to flake when it is trimmed
4) It does not present a smooth, glossy surface; hence other waxes
and natural resins are added as modifying agents.
5) Paraffin can be produced with a wide range of melting points.
Paraffin used for Type I wax is required to have a higher
melting point than does paraffin used for Type II waxes.
CARNAUBA WAX
1) Concentration: - 25%
2) It is quite hard, and it has relatively high melting point.
3) It is combined with paraffin to decrease the flow at mouth
temperature.
4) Carnauba wax has an agreeable odor, and it contributes to the
glossiness of the wax surface even more than does dammar
resin.
CANDELILLA WAX
1) Candelilla wax can also be added to paraffin wax to partially or
entirely replace the carnauba wax.
2) It provides the same general qualities as the carnauba wax, but
its melting point is lower, and it is not as hard as carnauba wax.
CERESIN
1) Concentration: - 10%
2) Ceresin may replace part of the paraffin to modify the toughness
and carving characteristics of the wax.
BEESWAX
1) Concentration :- 5%
2) It improves plasticity and cohesiveness.
3) It makes the wax easier to mold.
SYNTHETIC WAXES
1) Carnauba wax is often replaced in part with certain synthetic
waxes that are compatible with paraffin wax.
2) One is a complex nitrogen derivative of the higher fatty acids;
the other is composed of esters of acids derived from Montan
wax, a petroleum derivative.
3) Because of high melting point of the synthetic waxes, more
paraffin can be incorporated to improve the general working
qualities of the product.
MANIPULATION
1) Dry heat is generally preferred to the use of a water bath. The latter
can result in the inclusion of water droplets, which could splatter
on flaming, smear the wax surface during polishing, and distort the
pattern during thermal changes.
2) When the stick is softened over a flame, care should be taken not
to overheat it.
3) The wax should be cooled gradually at the mouth temperature and
not by cold water and then removed carefully
4) After removal, avoid touching the wax pattern with the fingers as
much as possible to prevent any temperature changes.
INDIRECT WAX PATTERN
PROPERTIES
FLOW
1) When forming a wax pattern in the mouth, the wax must be
heated to a temperature at which it has sufficient flow under
compression to reproduce the prepared cavity walls in great
detail.
2) Insufficient flow of the wax caused by insufficient heating
results in the lack of cavity detail and introduces excess stress
within the pattern.
3) An overabundant amount of flow resulting from excessive
heating makes compression of the wax difficult because of a
lack of “body” in the material.
4) Type I inlay wax should exhibit a marked plasticity, or flow, at
a temperature slightly above that of the mouth
5) The wax begins to harden at approximately 58°C (136°F), the
point at which the curve first departs from a straight line, and it
is solid below approximately 40°C (104°F), when it cools again
at a constant rate.
6) ANSI/ADA Specification no.4 provides certain requirements for
the flow properties of inlay waxes at specific temperatures, as
indicated in the following table.
7) The maximum flow permitted for Type I waxes at 37°C is 1%.
The low flow at this temperature permits carving and removal of
the pattern from the prepared cavity at oral temperature without
distortion.
8) Type I wax shows greater flow than Type II wax at
temperatures both below and above mouth temperature.
9) In addition, both Type I and Type II waxes must have a minimal
flow of 70% and a maximum flow of 90% at 45°C.
THERMAL PROPERTIES
I. Thermal conductivity
1) The thermal conductivity of these waxes is low.
2) Time is required both to heat them uniformly throughout
and to cool them to body or room temperature.
II. Coefficient of thermal expansion
1) The coefficient of thermal expansion of waxes is high
when compared to other dental materials.
2) As shown in the figure, the wax may expand as much as
0.7% with an increase in temperature of 20°C, or it may
contract as much as 0.35% when it is cooled from 37°C to
25°C.
3) The average linear coefficient of thermal expansion over
such a temperature range is 350 x 10-6/°C.
4) This is one of the inherent disadvantages of waxes when
they are used in the direct technique.
5) This property is less significant when the wax is used in the
indirect technique because the pattern is not subjected to
change from mouth to room temperature.
AVAILABLE PRODUCTS
The following products have been evaluated and certified by the Council
on Dental Materials, Instruments and equipment under ANSI/ADA
Specification No. 4 for Dental Inlay Casting Wax:-
MDL Company manufactures 4 types of inlay wax, green, blue, red and
violet. These waxes differ in their hardness.
CASTING WAX
SUPPLIED AS
COMPOSITION
1) Paraffin
2) Ceresin
3) Beeswax
4) Resins and other waxes
TYPES
1) Class A – 28 Gauge – Pink in color.
2) Class B – 30 Gauge – Green in color.
3) Class C – Ready shape – Blue in color.
PROPERTIES
BASEPLATE WAX
1) Baseplate wax derives its name from its use on the baseplate tray
to establish the vertical dimension, plane of occlusion, and initial
arch form in the technique for the complete denture restoration.
2) It is also referred to as modeling wax.
COMPOSITION
Baseplate wax may contain
1) Paraffin based waxes or commercial ceresin.
2) Small quantities of other waxes, resins and other additives to
develop specific qualities desired in the wax.
A typical composition may include:
1) Ceresin – 80%
2) Beeswax- 12%
3) Carnauba- 2.5%
4) Natural or synthetic resins- 3%
5) Microcrystalline waxes- 2.5%
USES
1) They are used to make occlusion rims.
2) Baseplate wax is the material used to produce the desired contour
of the denture after the teeth are set in position. As a result, the
contour wax establishes the pattern for the final plastic denture.
3) Patterns for orthodontic appliances and prostheses other than
complete dentures, which are to be constructed of plastics, also are
made of baseplate wax.
4) It has also been widely used in many phases of dentistry to check
the various articulating relations in the mouth and to transfer them
to the articulator.
TYPES
Three types of waxes are included in ANSI/ADA Specification no. 24
for baseplate wax:
1) Type 1 – Soft wax for building contours and veneers
2) Type 2 – Hard wax for patterns to be tried in the mouth in
temperate climate
3) Type 3 – Extra hard wax for patterns to be tried in the mouth
in tropical climate
PROPERTIES
FLOW
1) The maximum flow allowed at room temperature decreases
rapidly from Type 1 to Type 3.
2) The harder the wax, the less the flow at a given temperature.
DIMENSIONAL CHANGES
1) The linear thermal expansion from 26°C to 40°C should be less
than 0.8%.
OTHER PROPERTIES
1) Baseplate waxes should be easily trimmed with a sharp instrument
at 23°C and should yield a smooth surface after gentle flaming.
2) These waxes should not leave any residue on porcelain or plastic
teeth
3) They should not adhere to other sheets of wax or separating paper
on storage.
4) There is residual stress within the baseplate wax that holds and
surrounds the teeth of a wax denture pattern. This stress results
from differential cooling, “pooling” the wax with a hot spatula,
and physically manipulating the wax below its most desirable
working temperature.
5) The waxed denture should be flasked soon after completion to
maintain the greatest accuracy of tooth relations.
6) During dewaxing procedure, to ensure complete elimination of the
modeling wax, soap solution is added to the hot water. This
reduces the surface tension of the wax, a process known as
“emulsification”, which helps in complete elimination
AVAILABLE PRODUCTS
The following products have been evaluated and certified by the Council
on Dental Materials, Instruments and equipment under ANSI/ADA
Specification No. 24 for Dental Inlay Casting Wax:-
COMPOSITION
1) The modeling pastes are based on diurethane dimethacrylate
oligomers with 40% to 55% polyurethane dimethacrylate or poly
(methyl methacryalte) fillers.
2) The liquid consistency is mostly urethane dimethacrylate.
3) These resins have a camphorquinone activator.
PROPERTIES
PROCESSING WAXES
BOXING WAX
PROPERTIES
1) This wax should be pliable at 21°C and should retain its shape at
35°C.
2) Because the impression may be made from a viscoelastic material
that is easily distorted, a boxing wax that is readily adaptable to
the impression at room temperature is desirable.
3) In general, boxing wax should be slightly tacky and have
sufficient strength and toughness for convenient manipulation.
UTILITY WAX
COMPOSITION
It mainly consists of beeswax, petroleum and other soft waxes in
varying proportions.The utility wax is usually supplied in both stick and
sheet form in dark red or orange
USES
1) It is used to adjust contour of perforated tray for use with
hydrocolloids
To raise flange height
To extend the tray posteriorly
To raise palatal portion of the tray in cases of deep palate.
PROPERTIES
1) The ductility and flow of utility waxes are the highest of any of the
dental waxes.
2) The utility wax should be pliable at a temperature of 21°C to 24°C,
which makes it workable and easily adaptable at room temperature.
3) The flow of this wax should not be less than 65% or more than
80% at 37.5°C.
4) Because building one layer on top of another is often desirable, the
specification requires a sufficient adhesiveness at 21°C to 24°C.
STICKY WAX
COMPOSITION
1) Yellow bees wax – brittle in nature with intermediate melting
range and can flow better.
2) Rosin – gives stickiness to adhere to materials.
3) Natural resins like gum dammar – increase toughness, smoothness
and shine to wax.
USES
1) Sticky wax is used for joining or assembling metal parts before
soldering.
2) It is also used for joining fragments of broken dentures before
repair procedure.
PROPERTIES
1) Sticky wax should have a dark or vivid color so that it is readily
distinguishable from the light colored gypsum products.
2) The flow should be maximum 5% at 30°C and 90% at 43°C.
3) The shrinkage of sticky wax should be 0.5% at temperatures
between 43°C and 28°C
4) There should not be more than 0.2% residue after burnout.
IMPRESSION WAXES
COMPOSITION
1) Impression waxes consist typically of a mixture of low melting
paraffin wax and base wax in ratio of about 3:1. This composition
ensures a very high degree of flow at mouth temperature.
2) In addition it may contain other wax like ceresin and also metal
particles e.g. aluminum or copper particles.
PROPERTIES
USES
USES
It is used to articulate accurately certain models of opposing quadrants
COMPOSITION
1) They are composed of beeswax, or hydrocarbon waxes such as
paraffin or ceresin.
2) Some bite registration waxes also contain aluminum or copper
particles.
MODE OF SUPPLY
They are supplied as U – shaped rods on wafers. One side of the
wax is usually covered with foil. Used for checking occlusal
relationships.
Blockout Wax
1) It is bright red for high visibility
2) It has excellent carvability for smooth contouring on die
surfaces.
3) Its hardness holds carved edges and high fusing temperature
prevents adhesion to coping wax
4) It is mainly co posed of paraffins, micro waxes, natural polymer
carbonic acid resins of high molecular weight
5) It fills undercuts, covers sharp edges and corrects draw on dies
with non parallel walls
Esthetic wax
1) It produces naturally esthetic diagnostic wax-ups, patterns for cast
crown inlays and onlay.
2) Ivory Opaque Sculpturing Wax provides maximum visibility and
the characterizing colors create gingival dentinal tones, translucent
enamel, unique coloring and incisal effects.
RECENT ADVANCES
SUMMARY
Although waxes are not used as the final restoration in dentistry, they are
critical to the success of many dental restorations. The physical
properties of waxes are diverse, but all waxes share the properties of
having a melting range, the tendency to flow, the ability to harbor
stresses, and the largest thermal expansion of any dental material. The
proper manipulation of waxes is critical to ensure that these properties
do not interfere with the success of the final dental restoration.
3. Soft No. 3 (red): Used for minor tray correction and as an initial
lining to stabilize the tray.