PRESENTATION OUTLINE 1. Definition and Significance 3. Food Sources and Classification of Starches 2. Structure of Starches STARCH: DEFINITION AND SIGNIFICANCE
• A complex carbohydrate consisting
of a large number of glucose units joined together by glycosidic bonds. • Produced by all green plants as a storage of energy. • Most consumed carbohydrate by humans. STARCH: DEFINITION AND SIGNIFICANCE
• The word starch originated in the
Middle East from the word “Sterchen” meaning “to stiffen” • Also known as “Amylum” in Latin • Starch is an end product of photosynthesis. STARCH: DEFINITION AND SIGNIFICANCE
• Starch exists in nature as the main
component of cereals and tubers. • In manufactured and processed foods, it plays and obvious role in achieving the desired viscosity. • In Non-food products, plays as an adhesive. • Pure Starch is a white, tasteless and odorless powder that is insoluble in water and alcohol. STARCH: DEFINITION AND SIGNIFICANCE
• Starch is the second most abundant organic
substance on Earth, surpassed only by cellulose. • Serves the plant as food for energy during dormancy and subsequent germination. • Source of 80% of calories worldwide. STRUCTURE OF STARCHES STRUCTURE OF STARCHES
• A starch molecule is composed
of glucose as its building unit linked by alpha linkage. • Two types of glucose residues: 1. Amylose 2. Amylopectin • Amylose and Amylopectin are both polymers of alpha D glucose unit. STRUCTURE OF STARCHES: AMYLOSE
• In amylose, the glucose units are
linked through the C1 of one glucose unit to the C4 of the next glucose unit with the ring oxygen all on the same side. • At least 200 glucose units aligned in a straight by alpha 1,4 linkages with molecules weights from 40,000 – 30,000 STRUCTURE OF STARCHES: AMYLOSE
• Also called the A-fraction of the
starch molecules • More soluble than amylopectin • It has the ability to thicken, gel, and retrograde • Content starch is 20% STRUCTURE OF STARCHES: AMYLOPECTIN • A branched chain polymer of D-glucose unit , besides the C1 to C4 linkage there’s a branching C1 to C6 linkage • Amylopectin is the major polymer in most starches, representing 70 to 85% in non-waxy starches and up to 100% in waxy varieties. • Have 500 to 2000 glucose unit with molecular weight from 4 to 6 million • When branching occurs every 20-25 glucose units with alpha 1,6 linkages as the branching points , also called B-fraction of starch STRUCTURE OF STARCHES: AMYLOPECTIN
• Larger molecules than A fraction
• Less soluble in H2O • Forms paste that is opaque • Thickens more readily than amylose and is responsible for cohesiveness of a paste • Does not gel unless the concentration is 30% • Content starch is 80% AMYLOSE AMYLOPECTIN
• Very soluble • Less Soluble
• Opaque • Less Opaque • Very adhesive due to linear • Less Adhesive configuration • Greatly responsible for viscosity • Less Viscous and not Cohesive and cohesiveness • Easily thickens and gels at 5% • Can thicken but will not gel until concentration is 30% concentration • Retrogradates easily • Less likely to retrogradate Figure 1: Structure of Amylose and Amylopectin Figure 2: Molecular Configuration of Amylose and Amylopectin
Figure 2: Molecular Configuration of Amylose and Amylopectin
FOOD SOURCES AND
CLASSIFICATION OF STARCHES FOOD SOURCES AND CLASSIFICATION OF STARCH
Food Sources:
1. Root crops are high in Starch: Arrowroot or
Uraro, Cassava , Sweet Potato, Taro or Gabi, White Potato or Patatas, Gao Yam and Purple Yam or Ubi. 2. Dried Legumes: Mungbean or Monggo, Cowpea or paayap and soybean or Utaw. 3. Sago also Called Tree Starch FOOD SOURCES AND CLASSIFICATION OF STARCH
Kinds of Starch:
1. Natural Starch or Unmodified – They are
Isolated and derived from plants. 2. Modified Starch – oxidized, pregelatinized, acidified, cross – linked or chemically altered. FOOD SOURCES AND CLASSIFICATION OF STARCH Steps on Starch Separation from Flour : Flour is derived by grinding the 1. Dehulled Cereal dehulled grain into particles of 2. Grounded into Meal powdery fineness. 3. Mixed with water 4. Strained 5. Milky Starch Suspension 6. Supernatant Liquid is Decanted 7. SEDIMENT STARCH 7.1. Impurities Removed 7.2. Dried Sifted 8. CRUDE STARCH (Treated with sulfate and other Chemicals 9. REFINED CORNSTARCH CONCLUSION • Starch – storage form of carbohydrate consisting of glucose deposited as granules or aggregates of granule in the cells of plants. • Kind of Starch 1. Natural Starch 2. Modified Starch • Two types of glucose residues: 1. Amylose 2. Amylopectin THANK YOU FOR LISTENING! Don't hesitate to ask any questions!