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    LOAN PHẠM THỊ PHƯƠNG
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    This document discusses organic chemistry topics related to conjugated alkadienes including their nomenclature, preparation through dehydrogenation and elimination reactions, electrophilic addition reactions and their reaction mechanisms, Diels-Alder reactions including reactivity based on electron-withdrawing groups on the dienophile and stereochemistry, and polymerization reactions of alkadienes. It is authored by Dr. Nam T.S. Phan of HCMC University of Technology and covers chapters on conjugated alkadienes, their properties as non-polar molecules, and reactions similar to alkenes, with sections on various preparation methods, reaction types, and controlling factors in Diels-Alder reactions like stereochemistry and diene

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    This document discusses organic chemistry topics related to conjugated alkadienes including their nomenclature, preparation through dehydrogenation and elimination reactions, electrophilic addition reactions and their reaction mechanisms, Diels-Alder reactions including reactivity based on electron-withdrawing groups on the dienophile and stereochemistry, and polymerization reactions of alkadienes. It is authored by Dr. Nam T.S. Phan of HCMC University of Technology and covers chapters on conjugated alkadienes, their properties as non-polar molecules, and reactions similar to alkenes, with sections on various preparation methods, reaction types, and controlling factors in Diels-Alder reactions like stereochemistry and diene

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    © All Rights Reserved
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    4 views18 pages

    Chapter 6

    Uploaded by

    LOAN PHẠM THỊ PHƯƠNG
    This document discusses organic chemistry topics related to conjugated alkadienes including their nomenclature, preparation through dehydrogenation and elimination reactions, electrophilic addition reactions and their reaction mechanisms, Diels-Alder reactions including reactivity based on electron-withdrawing groups on the dienophile and stereochemistry, and polymerization reactions of alkadienes. It is authored by Dr. Nam T.S. Phan of HCMC University of Technology and covers chapters on conjugated alkadienes, their properties as non-polar molecules, and reactions similar to alkenes, with sections on various preparation methods, reaction types, and controlling factors in Diels-Alder reactions like stereochemistry and diene

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 18

    ORGANIC CHEMISTRY

    Dr Nam T. S. Phan
    Faculty of Chemical Engineering
    HCMC University of Technology
    Office: room 211, B2 Building
    Phone: 38647256 ext. 5681
    Email: ptsnam@hcmut.edu.vn
    1
    Chapter 6:
    CONJUGATED
    ALKADIENES

    A non-polar molecule

    2
    Reactions of isolated dienes are just like
    those of alkenes
    3
    4
    NOMENCLATURE OF
    ALKADIENES

    5
    6
    PREPARATION OF 1,3-ALKADIENE
    Dehydrogenations

    Eliminations of unsaturated alcohols & alkyl halides

    7
    ELECTROPHILIC ADDITION
    REACTIONS

    8
    9
    Reaction mechanism:

    10
    11
    12
    DIELS-ALDER REACTIONS

    13
    Reactivity of the dienophile is increased if 1 or
    more electron-withdrawing groups are present

    Partial positive charge 14


    Stereochemistry

    Racemic
    mixture

    15
    In order to participate in a Diels-Alder reaction,
    the diene must be in an s-cis conformation

    C1 & C4 are too far apart


    to react with the
    dienophile

    16
    17
    Polymerizations

    18

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