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bài tập KTPU giữa kì
bài tập KTPU giữa kì
Bat 3, 1:
r
=
-
-> -
K.CR
= 0.2
=
with G 1 motle
=
clt
-> 12(1 moese) 0,2
=
log0,2
=
log10w (*n)
+
0,2
=
10
+
2
=
motle
Bar 3.2
first order: -
1n11-XA)=12t
5
cit minutes:
-
(n(1-0,51 k.5
=
-7k 0,1387 (min-1)
=
If 1 0,75
x =
- (n(1 0,75)
-
-
0,1357.t
=
-> A 10 =
mins
tlonger= 5mins
B 3. 3
-
kC0(1 -
4 A)
-
A =
=
->
I
- E
kt
=
-> 1 -
=5k
1
0,5C Ho Cto
->
c k =
er = c
co:
t.
-> t 15mins
=
Bat 3.4
d gic ri
B3.5
We have:
C-r
1 -
R
-
0 = Dm AD. 1.t
=
(R [(1 -X1)1-n -
1] ( 1)kt
=
-
XA 0,20
=
t 34mins
=
20:0,04motle
XA 0,10
= t 34 mins
=
270 0.8
=
motle
BA, 3.6
after 8 minutes -> 210:1 mol II
XA 0,8 =
-
- -
=
E 4 I(1 0,471
x -
-
4
-
17 ( 1).18k
=
-
>
!=
- M 2 =
-> k 0,5 =
= 0.5C
-
-> -
A =
⑲38 2H2
280
2NO
+
- N2 +
2H2O
emety
a
200 240
I as 186115
we have:PNo=PH2 Atal =
2
->
④
+ m
Fe-1])Prtue)
-
+y =
k (n -
1) (2Re)1
-
m
log(Ania)
logication] '-nilog (Protal]
=
chay bling
-1 -
n -
=
2,271
-> n 3,271
=
E 3.9
B
Ac> R, CA0 0,5 mol/l
=
0
CRO =
after
3*st
8 minutes ->
rA kCA = -
k2CR
XAe Emre
=
0,667 -
=
CAe 0,1665
=
moele
to
Cro+GoXA
k
1 oot066in
E
=
2toXAe
- -
31 81
((1 ) m(1 )
+ -
= -
- -
-
E lam roi
Bai 3. 10
A > R C0 2,03 mot /t
E
-
at t 1
= min
second order:
91 1,97 motle
-> 0.015(12
=
rA kC+
=
-
r =
- 1
CA
-
1
Co
=
kt
az =
=> k 0,015
=
Bal 3.11
CAo=1 Mor Il A
-
R
second order:
I
asslime
A
10 200 300400
1 -
1 kt
=
CA Sto 1 1 1 1
y 1 5
-
k 10
=
->
=
50
-
2
CA -> -
r1 10 =
-> 1. 1 10
=
-
50 1- XA
Bai 3. 14
Bai 3. 17
en(r)
-
kt
=
0.521
in)- I
-- 76k
=
CA0
k 9,12 18 3/min-1)
-
=
x
=>
k
XA with t 1
day
-
1 e
=
-
=
-> x 1 0,99
=
Ba 3. 14
1
2A0=1
-
moell
-
k 3.95
=
mo
M 0,5
=
C
1 - G-* =
(n- 1).kt
> 985 -
2 -
=
05.k.t 3.(105=
->
985 -
(1-YA) 3.985 =
-> 1 -
(1 -
xx) 3=
-> xA 3> 1
=
I
A-TR second order A ->R, C10 =1 mot Iliter
if 210 1
=
modle, XA 0,5
=
XA 0,75 =
=
kG kG0(1 =
-
x1) at t 2 =
hrs -> XA 1=
28 [(1 0,7551
-
4
17 k(n- 1)
E 21I(1
-
= -
1.A k.t
=
-> =
CA0 1 -
*A 4
191 1] 2k(n 1)
-
- - -
-> k 1(hr 1)
=
-are***
60
If CA0 =
10 moell
YA 0,91
->
-> k 1
=
At
-
Bal 3. 24
GA, Mol II 1 2 6 7 I 12
I
4
↑A kG=
mloqCA
+
logk = -
1,224
I n 1,26
=
2I* E
-
M
=
(n
=
-
11kt
-> A 8,13 hr
=
Bai at0 "C
3.25 A 2,5B
-
0
Aime (min) ⑧ 2 4 6 81012 14 *
partial pressure of A
760600475390320275240215150
(mmHy)
CA 8,0458,0350,U289,0230,4190060,014 00130,009
e[E2) (, 12)t
- -
=
[11, 123
(M
-> 0,12725
chay bing R2 0,9999 ky R2 0.1591(1)
=
-> =
-> +
=
12 0.03152
lacceptable) =
k
4 E Ecar
=
↓
=
CAC
0,045 0,009
1 4(2) rate
-
4 ->
=
-ron
=
Bai 3.29
first order
10
2A -> R 9 0,4
=
-
=
amount of
reactant 0.5 0,4
inerts dang
wayand varyingthe
-ence)
0,2
1,0
We have:
t
-
can
c5 if the volume of reactant
Mixtre
Akay si
((-y-08) 13min)k
=
12
-> k =
0.231
=
min-1
BC 3.30
Using R 0,088
=
L.atm. 12-1 mol-1
A
-> 1,6R
A 0.5 0.5
inents
-i
0,5 -> Ex
1
=
5 16
=
Ardaincreased
by
totul
I 113
firstorder volume:
varying
- -
(1 -
g) kt
=
-
14min)k2 -> 1 0.45 (min-1)
()1 )
=
-
-
=
Bai 3.31
&HI I H2
Ahermal
decomposition: -> +
knadi
second order reaction:
ching
-
A kCA =
2
koe
=
-
FIRT. 2A nhying
this i
-> k
.T
stenk= euko
(I)
-
1
enk
↳
+12 =
T
va
y
=
22400x 26,291
y
- +
=
E = 22400
->
-
=
=
=>
rate of
equation: -
VA 7,48
=
x 1023 2-
x 224007.G
2.7
dpA
a) We are given: = k P . p2A
dt
b) ideal gas: pA . V = nA . R. T or pA = CA . R. T
d(CA RT)
− = 3,66. (CA RT)2
dt
dCA 1
− = 3,66. (CA RT)2 .
dt R. T
1 1 (𝑎𝑡𝑚) . 22,4 (𝑙) 𝑚𝑜𝑙 −1
k’= 3,66 ( ). . (400 𝐾) = 120 (ℎ𝑟)−1 ( )
atm.hr 1 (𝑚𝑜𝑙) . 273 (𝐾) 𝑙
3.5
dC
First order reaction: − = kC
dt
Co
=> ln ( ) = kt
C
Co
Replacing data: ln ( ) = k. (2040 s) => 𝑘 ≈ 1.1 × 10−4 (𝑠 −1 )
0.8Co
dC
Rate equation: − = (1.1 × 10−4 𝑠 −1 ). C
dt
3.6
We know that;
About equation shows that plot of log(𝑡1/2 ) us log(𝐶𝐴0 ) will result in a straight lire with
slope (1-n) [and some intercept ! ]
We are given data in terms of total pressure, so we will modify equation to suit the
situation
* given, equimolar mixture => 𝑃𝐻 = 𝑃𝑁0 ( partial pressures)
For this equation (E) also; log(𝑡1/2 ) vs log(𝑃𝑡 ) will give straight line with stope (1-
n)* [but now intereept has chauged !]
Here,
n = 3.271
[ *You can use the nature of graphs; applying logarithm on both side of eqn (E);
[(0.5)1−𝑛 −1](𝑃𝑡𝑜𝑡𝑎𝑙 )1−𝑛
log(𝑡1/2 ) = log[ ̃ (𝑛−1)(2𝑅𝑇)1−𝑛
]
𝐾
(0.5)1−𝑛 −1
log (𝑡1 ) = log[ ̃ ] ) + (1
⏟ − 𝑛) log[(𝑃
⏟ 𝑡𝑜𝑡𝑎𝑙 ) ])
⏟ 2 ⏟ 𝐾(𝑛−1)(2𝑅𝑇)1−𝑛
−𝑟𝐴 = 𝑘𝐶𝐴𝑚
𝑑𝐶𝐴 𝑑𝑋𝐴
= 𝐶𝐴0 = 𝑘𝐶𝐴𝑚 ……(1)
𝑑𝑡 𝑑𝑡
If calculated rate constant is same for the both condition then assumed rate constant is
correct.
2
= 𝑘𝐶𝐴0 (1- 𝑥𝐴 )2 ( 𝐶𝐴 = 𝐶𝐴0 (1 − 𝑥𝐴 ))
Case 1:
= 0.5 Lmol-1min-1
Case 2:
therefore, order of the reaction is 2 and rate constant (k) is 0.5 Lmol-1min-1
−𝑟𝐴 = 0.5𝐶𝐴2
3.7
𝑡 = 0 … $0 = ?
After his raise we have } …. from this final
𝑡 = 3 $ = 135
$0
3.8
This
3.9
S
+
XA
10
XA 0
=
* 1
=
0
100 100 100
(A 0 =
100A
= + 200B 300
=
roo
EA
e
=
->G mile e
=>
0,8
=
=
20
=
-> xB a
=
1x0, 0,4
=
cB
co(x) 2004)
=
=
10 modle
=
BC 4.5
To 400K,
=
CB0=200
A B
+
)
-
Ex 0
=
?
EB 0
=
A =
xB
Y0
=
=
0,
=
Bai 5. 1
we have:
T
5 imin-= 1 min
=
&
BC5.2
Ba 5.3 for mixed flow
live y
-i.
mins
- >1
-
198) min-1)
=
0,01
F k.(
1,98(n)
rate: -
=
1,95
=
+(90) =
k(z) w
e
=
k 2(min-1)
=> =
0.0004)
-
rw k.(w
=
1(0,0002)
=
=
Bat 5.4
present:
115 CA0=10 mot It
A
-
R -
PA k.CA
=
XA 0,7
=
kT
4 -a
=
=
->
(1 xA)
kT
-
XA
---
!(11) AY
115
k4 =1,347
=
7
-
10015(d -
0,77115
double the volume -> new KT 2x1,347 2,69
=
=
B
2,69:
T-x12,69 -
=
x45
-
XA 0,794 =
BG5.5 XA 0,999
=
Vo = 400t 1 min
M
A B +
-
R -
rA 200
= CA. 2B
2A0 100 mmolle
1
I
2
EA
=
-
-
min
order plug
=
kT (t0 ( M -
1) =
en
[*] where
M -
1
Ahls M 2
=
= 2 b210
200+ 10,1772-17:
=>
=>
T 0.31
=
min
Inanys] 6,2156
=
v Yvo (400)(0,31)
=>
=
=
1241
=
Bas 5.6:
k1
*
R A (0,04 min-1) 27-10.01 min->) CR
n
-
v 2000 2
=
vo 100
=
e/min
min-1
EA 0
=
have:
312
we
0.01
=
min-1
woxte=4
20 Min-1
we have:
Xe
100 -
100Xte
-> XA 0,506
=
Bal 5.8
5.6
M-M
type?
y chang reaction
Bai 5.9
a min
enzyme
A -
Ri -
r =
Vo 2591min
=
XA 0,95
Mot Il
↳
can
may
=
20 2
=
k (n k2(40 C)
= +
0,11] 9861
v
2I1 +
-> =
0,512- =
Bal 5.10
->
A 2.5) products)
-
VA 40min-1)
=
CA
FAo NO
=
moe min
V 221
=
Co 2 Mot =
It XA =?
firstorder:
FAO vo. CAr -> 100 mot / min=
= (2 motle) vo
5 (min
=>
vo =
kT (n =
= 11
1 -
XA
n.(2) en-
=) =
XA 0,988
=
B1 5.11
y chary
Bai 5.12
xi5.5
y
Ba 5.13 -
I phos:213,
4Pt -> Py(q) GH2
+
inerts: 113
It 10
=
mollhi
for 1storder reaction.
XA 0,75 =
z (1 4)(n 1 * 11,4
atm
k
3
=
91XA
+
-
=
1 -
xA
FAo (1) abac 1
bas1 vi saw
Also,
Go:
Fousts, a more
ty
12 10 hr-1 4A - 7R
=
201 ki
FAo 10
=
inents 20
31
-60. I
=
0,5
=
60
[(1
v
+0.57 en
-19510,751]
=
=17 lit
0.66 moe (l 0,33 mol/L
Bat 5.14 ↑ ↑
2A0 660 = monot le if (Af =330 mmol II
BA - R FAo 54U
= mmot / min ↓
V ?
may ko hien
=
Bai
91
2=
=
⑯
gi then
we have: -
rA 0,054
=
= e
st
c =
miner
5 X =
-> YA 0,75
=
equation== Jc8 8
Jol
-
"nas)
(x)
rass"
x
-> V Fo*
=
-> v 8,55l
=
B 5.15
0.0542
resea
2A -
> R -
r =
Go =1 mol/l
kY(0 =A
- 9054(1moele)
5
=
->
2 =
CA 1 -
x =
-> T 10(sec
=
-
-)
x1 moele
Fao
A (mot/sec)
=
-
0.2
=
10(sec 1)
-
Ba 5.16
A -
> 3R1 -
r (0,6min-1) 2A
=
50% No=1801 / min
A
-
50% inerts
A
- 3R
reactants
115 90 =300 mmol/l =0,3 mor ll
0,5
inents v 1m3 10002
=
-
0.5
An
=
Autul 2 -
1
Ex 1
=
F
=
for first
order -> kT (1 2A) (n
=
+
1 -
EAXA
1 -
xA
->
0.68= 13((x) x1 +
xA
I 2(n)fx1) xA
-> -
=
-> XA 0,88 =
B 5.17
I
20 302
- ms)
rozone= 0.05
Cozone
-
20, - 302
recictunts
0.2 0,3
inents
0,8 Af
-
total 1 1,1
-> 21 1=01
=
D =
vo 1 =
liter Is
kT(n EXA (9
22(1 31)((1 x1)
1)?x
+
+ -
= + +
->
0,057.005 2.0,1(1 0,14n(1
=
+
-
0,5 0,12 6,5+
x
(0,1
+ 1)x5
+
1 -
0.5
- V 381
= liter
BCL 5.18
27 -> R -
r 0,05C12 (mol/l.s)
=
V =
2 liter
(2
+
4
+
1 -
XA
-> 0.05. 240.1 21-0,5)(1-0,5)(n(1
=
-
x1) -
0,5xA # 8,25
*A
-
1 xA
12 0,5(n(1 a
-
=
-
-
xA) -
0,5XA +
1 -
YA
->
t
x1 0,98=
1
=XA 0,98 motle
-> a 0.02
- =
=
=
Bal 5.19 (gial ich khas Think) A
-
3R
(e/min) 0,06 8,45 8,1
No 1,5
Pha Ank 2
2(mmot (e) 30 60 SO 105
1 1 aqueous thi 0
I 1 1
gas
yo
0,06 8,1
(molle)
It
CA
is
8,08 0.143
S 0,105 0,045
k21N
T
A
-
↳-> log( -
NA) logR m.
log2A
=
+
↓
chay bang n 2
I
=
-
dring may de
k4
=
fink -
rA
r 42
-
=
-
Bai 5.20 Co 100
=
mmol/e-
A -> R
v 1e =
-
~, liter/min 1 6 24
A -> R
C, mmot lt 4 20 50
EA =
11 0
=
assume that
firstorder-> KT
=
= A
1 -
YA
t
↓ Tc
=
-> k 24
=get
=
=> 2427
124
to
the
BC 5.21
->
A R time to
CA0=1,3 mol Ib
↓
CA 0,3
=
mol ll
-
1 k(1
=
->
log) -rx) logk magCA
+
↑
Bat 5.23
FA0 1000
=
mol A I hn
XAf) 1,2(1
=
-
0,75) 0.3
=
moe le
F-
CSR:
e,
applying
r=5en
1,2
b) me 10.5in 60 min
canb va 2
tiring on wher
Bar 5.24
V 0,12
the rate
=
asslime expression:
-
A - > 5R 21 4 =
5
EA =
= 4
->
fin i
i
for MFR: T
4 -
= cho
may
+
-Frg(1
V 0,12
=
--rA 10 FanYA
m
=
A 100
=
②
x)
(1 2)
- =
->
1
- Y
=
B
Ex
1 +
FAo
Immoe/hr)
CA
Immol/eS
x= -
A 10FtoXA
=
E=
1 +
3000 50 5001
0.1667
5000 60 0,1176 5888
]e?
chay bring 96,274x2110105
1,0106 rA
E
=
n =
->
Ink 4,5672 ->
=
k 96,274
=
Ba5.25
time to obtain Co 8
=
XA 0,75
=
Motle - -
T So-2A
-
HA)=IaK +
mInCAf - A =
⑧ ⑳
-
Rating
Bài 5.24:
−ℽa = 𝐾. 𝐶 𝑛 a
A 5R : Given reaction
5−1
Hence €A = =4
1
𝑋𝐴 .𝐹𝐴0 𝑋𝐴 .𝐹𝐴0
(−𝑅𝐴 ) = = V = 0.1 (𝑙𝑖𝑡)
𝑉 0.1
𝑚𝑖𝑙𝑖𝑚𝑒𝑡
(−𝑅𝐴 ) = 10. 𝐹𝐴0 . 𝑋𝐴 𝐶𝐴 = 100.
𝑙𝑖𝑡
𝐶𝐴0 . (1 − 𝑋𝐴 ) 𝐶
1− 𝐴
𝐶𝐴 = 𝐶𝐴0
= 𝑋𝐴
(1 +∈𝐴 . 𝑋𝐴 ) 𝐶
1− 𝐴
𝐶𝐴0
Solution :
Given that
2A -> R + S
P0 = 1 atm , T = 100°C
Given Po = 1 atm
80
Mole fraction of A = x.A= =0.80
100
-total pressure
For ∈ 𝐴 = 𝐵, 𝐶𝐴 = 𝐶𝐴𝑜 . (1 − 𝑋𝐴 )
𝜏𝑝𝑙𝑢𝑔 = 𝑡𝑏𝑎𝑡𝑐ℎ
𝑃.𝐴0
𝐶𝐴0 =
𝑅𝑇
= 0.0261 mol/l
FA0 = 0.0278
310 𝑥 0.0278
=
0.0261
V = 330 (l)
Hence volume of the plug flow required for that is 95% convestion
Bài 5.30:
AR
𝐶𝐴0 = 2, 𝐶𝐴𝑘 = 1
𝐶𝐴0 .𝑥𝐴
𝜏= 𝐶𝐴 = 𝐶𝐴0 − 𝐶𝐴0 . 𝑥𝐴
𝑘.𝐶 𝑛 a
𝐶𝐴0 −𝐶𝐴
𝜏= 𝐶𝐴0 . 𝑥𝐴 = 𝐶𝐴0 − 𝐶𝐴
𝐶 𝑛a
1
𝑇0 =
𝑘
1
𝑘= . 0.02
50
2−0.65
60 = 2
𝑘.(0.65)𝑛
𝟏 16 1.2 − 0.8 𝑘. (0.65)𝑛
= = .
𝟐 20 2 − 0.65 𝑘. (0.8)𝑛
16 1.35 0.65𝑛
𝑥 =
60 60 0.8
9 13𝑛
=
10 16
0.9 = (0.8125)𝑛
log(0.9) = 𝑛. log(0.8125)
log(0.9)
𝑛=
log(0.8125)
𝑛 = 0.50
1
𝑛=
2
So we know order 2 𝑘 value
𝜏 𝑥𝐴
=
𝐶𝐴0 (−𝛾𝐴 )
𝑋𝐴 = 0.75
𝐶𝐴0 .𝑥𝐴
𝜏= 𝐶𝐴 = 𝐶𝐴0 . (1 − 𝑋𝐴 )
𝑘.𝐶 𝑛 a
(0.8).(0.75)
𝜏 = (0.02).(0.2)0.5 𝐶𝐴 = 0.8. (1 − 0.75)
𝐶𝐴 = 0.2
𝑉
We know 𝜏 =
𝑣0
So v = 𝜏. 𝑣0
=67.08x1
=67.08
𝑌𝑎 𝐶𝐴0 .ⅆ𝑋𝑎
𝜏 = ∫0 𝐶𝐴 = 𝐶𝐴0 − 𝐶𝐴0 . 𝑋𝐴
(−𝛾𝐴 )
0.2
𝑑𝑋𝑎
𝜏 = −∫
0.8 (0.02). (0.2)𝑛
𝜏 = 67.08 𝑠𝑒𝑐
𝑣
So 𝜏 =
𝑣0
v = 𝜏. 𝑣0
= 67.08 vt
Reactants Products
100 100
100 100
Products − Reactants
∈𝐴 =
Reactants
∈𝐴 = 0
𝑋𝑎
𝑉 𝑑𝑋𝑎 (1 +∈𝐴 . 𝑋𝑎)
=∫
𝑉𝐴0 . 𝐶𝐴0 0 𝑘. 𝐶𝐴0 (1 − 𝑋𝑎)
Since ∈𝐴 = 0
𝑘 𝑋𝑎 ⅆ𝑋𝑎
V.( ) = ∫0
𝑉0 (1−𝑋𝑎)
𝑘 𝑘
. 𝑉 = −ln(1 − 𝑋𝑎) . 32 = −ln(1 − 0.99)
𝑉0 𝑉0
𝑘
= 0.144
𝑉0
With the connected stoichiometry:
A 3R
Reactants Products
100 300
𝑋𝑎 ⅆ𝑋𝑎 𝑋𝑎 𝑋𝑎
∫0 + ∈𝐴 ∫0 . 𝑑𝑋𝑎
(1−𝑋𝑎) (1−𝑋𝑎)
𝑅
V. = −ln(1 − 𝑋𝑎) - ∈𝐴 . 𝑋𝑎 − ∈𝐴 ln(1 − 𝑋𝑎)
𝑉0
𝑅
From Er = 0.144
𝑉0
𝑋𝑎 = 0.99
∈𝐴 = 2
0.144V = 11.835
*
Question A B ) R S
1:
Go 1 motle XA 0,5
-
+ +
=
=
irreversible
elementary liquid phase CB0 1,5moe
=
/2
gia
->
applying second order reaction:
the
be
-
->
A KCA.CB,
=
fr =(CBo-2A0kt
we denote that: M =
1
=
1,5
=
k
#
M(1 -
XA)
thay so:
In 195=(1,5-1).
Smer)
-> 12. (1hr) -> k 0,575
=
1,5(1 -
0.57
- 0.575 x
Bm
L
-
=
x
b) IfCAr CBO
=
1 mot
=
Ihr
t 1hr
-> Pr
=
Because to:CBO =
1 muy/hr -> so we
assump that.2A S
+
rA kC
=
tiny can may
->
( ) 4
=
F()-575/1hr)
-> XA 0,365 =
Question 2: 21 R
->
2S
+
2nd order
P1 =
8
atm
P 40,3 in 3 minutes
system
as we have:
PA Pto
f(P -k0) < PA
1am
1(P0 0,3-Po)
-
- +
=
t
=
increased by30% PA 1a m
-(0,3) 0.4(c+ m)
+
-
=>
=
=
X1
14A 10,4
=>
0,6
=
=
because volume
constant reactor ->
2p =
0
Applying:1TGo:
O ***
*
*=
* 05
↓
do ko
bit
dia
fai bao which.
2A R 2S
+
+
XA 0
=
015 O 0
*A 1
=
2A *yR 15
+
0