hoc vo Think:

Bat 3, 1:

0,2(moties) When G 1 motle

-
=

r
=
-

assume reaction has n-th order

-> -

K.CR
= 0.2
=

with G 1 motle
=

clt
-> 12(1 moese) 0,2
=

(motif.sec) -> 1 0,2(5-1)

=

testwith i order model:

log)-r)=fogls m.foqCA +

tog (0,2) log(0,2) n.log1

initially 5 =
+

finatly -> fog(0,2 10")

x

log0,2
=

log10w (*n)
+

-> 10 phl three vao bazi

rate G
at 10 motle -> FA K. CAR
=
-

0,2
=

10
+
2
=

motle
Bar 3.2
first order: -
1n11-XA)=12t
5
cit minutes:
-

(n(1-0,51 k.5
=
-7k 0,1387 (min-1)
=

If 1 0,75
x =

- (n(1 0,75)
-
-

0,1357.t
=

-> A 10 =

mins

tlonger= 5mins
B 3. 3
-

kC0(1 -
4 A)
-

A =
=

->
I
- E
kt
=

0.5C t0 vait 5mins

Thay C1 =
=

-> 1 -
=5k
1

0,5C Ho Cto

->
c k =

er = c
co:
t.

-> t 15mins
=
Bat 3.4

d gic ri
B3.5
We have:

C-r
1 -
R
-

0 = Dm AD. 1.t
=

(R [(1 -X1)1-n -

1] ( 1)kt
=
-

XA 0,20
=
t 34mins
=

20:0,04motle
XA 0,10
= t 34 mins
=

270 0.8
=
motle
BA, 3.6
after 8 minutes -> 210:1 mol II

XA 0,8 =

18 mins -> XA 0,9 =

have: 1x1(1 0,531 1] (n 1).8K

n
We
-

-
- -
=

E 4 I(1 0,471
x -
-

4
-

17 ( 1).18k
=
-

>
!=
- M 2 =

-> k 0,5 =

= 0.5C
-

-> -

A =
⑲38 2H2
280
2NO
+

- N2 +
2H2O

emety
a
200 240

I as 186115

we have:PNo=PH2 Atal =

2
->
④
+ m

Fe-1])Prtue)
-

+y =

k (n -

1) (2Re)1
-
m

log(Ania)
logication] '-nilog (Protal]
=

chay bling
-1 -

n -
=
2,271

-> n 3,271
=
E 3.9
B
Ac> R, CA0 0,5 mol/l
=

0
CRO =

after

3*st
8 minutes ->

rA kCA = -

k2CR

XAe Emre
=
0,667 -
=
CAe 0,1665
=
moele

to
Cro+GoXA
k
1 oot066in
E
=

2toXAe
- -

31 81
((1 ) m(1 )
+ -

= -

- -

-
E lam roi
Bai 3. 10
A > R C0 2,03 mot /t

E
-

at t 1
= min
second order:
91 1,97 motle
-> 0.015(12
=

rA kC+
=
-

r =

- 1
CA
-
1
Co
=
kt
az =
=> k 0,015
=

Bal 3.11

CAo=1 Mor Il A
-
R
second order:

I
asslime

A
10 200 300400
1 -
1 kt
=

CA Sto 1 1 1 1

t CA 1000 500 333250 N0

dat es =

y 1 5
-

k 10
=

->
=

50
-
2
CA -> -

r1 10 =

-> 1. 1 10
=
-

5(300) -> XA 0,6 =

50 1- XA
Bai 3. 14
Bai 3. 17

en(r)
-
kt
=

0.521

in)- I
-- 76k
=

CA0

k 9,12 18 3/min-1)
-

=
x
=>

k
XA with t 1
day
-

1 e
=

-
=

-> x 1 0,99
=
Ba 3. 14
1

2A0=1
-

moell
-

k 3.95
=

mo
M 0,5
=

C
1 - G-* =

(n- 1).kt

> 985 -

2 -

=
05.k.t 3.(105=

->
985 -

(1-YA) 3.985 =

-> 1 -

(1 -
xx) 3=

-> xA 3> 1
=

so we can confuse thatxt=1 before I he

Bal 3.22 B 3. 23

I
A-TR second order A ->R, C10 =1 mot Iliter
if 210 1
=

modle, XA 0,5
=

XA 0,75 =

=
kG kG0(1 =
-
x1) at t 2 =
hrs -> XA 1=

28 [(1 0,7551
-
4
17 k(n- 1)

E 21I(1
-

= -

1.A k.t
=

-> =

CA0 1 -

*A 4
191 1] 2k(n 1)
-

- - -

-> k 1(hr 1)
=

-are***
60
If CA0 =
10 moell

YA 0,91
->
-> k 1
=

At

-
 Bal 3. 24

GA, Mol II 1 2 6 7 I 12

I
4

0,10,25 1,0 2,0 1,0 0,5

0,06
-A
CA0 10
=
monle -> EAf=a motle

↑A kG=

-> log(r) logK =

mloqCA
+

logk = -

1,224

I n 1,26
=

2I* E
-

M
=

(n
=
-

11kt

-> A 8,13 hr
=
Bai at0 "C
3.25 A 2,5B
-

0
Aime (min) ⑧ 2 4 6 81012 14 *

partial pressure of A
760600475390320275240215150
(mmHy)
CA 8,0458,0350,U289,0230,4190060,014 00130,009

assume first-order reversible: ↓

at (B

e[E2) (, 12)t
- -
=

[11, 123

(M
-> 0,12725
chay bing R2 0,9999 ky R2 0.1591(1)
=

-> =
-> +
=

12 0.03152
lacceptable) =
k
4 E Ecar
=

↓
=

CAC

0,045 0,009
1 4(2) rate
-

4 ->
=

-ron
=
 Bai 3.29
first order

10
2A -> R 9 0,4
=
-
=

amount of
reactant 0.5 0,4

inerts dang
wayand varyingthe

-ence)
0,2

1,0
We have:
t
-

can
c5 if the volume of reactant

Mixtre

Akay si

((-y-08) 13min)k
=

12
-> k =
0.231
=
min-1
 BC 3.30
Using R 0,088
=
L.atm. 12-1 mol-1
A
-> 1,6R
A 0.5 0.5
inents
-i
0,5 -> Ex
1
=

5 16
=
Ardaincreased
by
totul
I 113

firstorder volume:
varying
- -

(1 -

g) kt
=

-
14min)k2 -> 1 0.45 (min-1)
()1 )
=
-
-

=
Bai 3.31

&HI I H2
Ahermal
decomposition: -> +

knadi
second order reaction:
ching
-

A kCA =
2
koe
=
-

FIRT. 2A nhying
this i

-> k
.T
stenk= euko
(I)
-

1
enk
↳

+12 =

T
va
y
=

22400x 26,291
y
- +
=

chay bang trong excel:

54,972
vaenk 26,291 Ko e

E = 22400
->
-
=

=
=>

rate of
equation: -
VA 7,48
=
x 1023 2-
x 224007.G
2.7
dpA
a) We are given: = k P . p2A
dt

Balancing dimensions we find: k P = 3.66 (atm)−1 (hr)−1

b) ideal gas: pA . V = nA . R. T or pA = CA . R. T

from (a) we have:

dpA
− = 3,66. p2A
dt

d(CA RT)
− = 3,66. (CA RT)2
dt

dCA 1
− = 3,66. (CA RT)2 .
dt R. T
1 1 (𝑎𝑡𝑚) . 22,4 (𝑙) 𝑚𝑜𝑙 −1
 k’= 3,66 ( ). . (400 𝐾) = 120 (ℎ𝑟)−1 ( )
atm.hr 1 (𝑚𝑜𝑙) . 273 (𝐾) 𝑙

3.5
dC
First order reaction: − = kC
dt

Co
=> ln ( ) = kt
C
Co
Replacing data: ln ( ) = k. (2040 s) => 𝑘 ≈ 1.1 × 10−4 (𝑠 −1 )
0.8Co

dC
Rate equation: − = (1.1 × 10−4 𝑠 −1 ). C
dt

3.6

We know that;

(0.5)1−𝑛 −1 .1−𝑛 Octave reuirepiel. pg4𝑠1

𝑡1/2 = 𝐶𝐴0 _______(A) [ ]
̃ (𝑛−1)
𝐾 𝑒𝑞𝑛 33(𝑎)

We will be using this so solve the given question.

About equation shows that plot of log(𝑡1/2 ) us log(𝐶𝐴0 ) will result in a straight lire with
slope (1-n) [and some intercept ! ]

We are given data in terms of total pressure, so we will modify equation to suit the
situation
* given, equimolar mixture => 𝑃𝐻 = 𝑃𝑁0 ( partial pressures)

and 𝑃𝐻2 + 𝑃𝑁0 = 𝑃𝑡𝑜𝑡𝑎𝑙

𝑃𝑡𝑜𝑡𝑎𝑙
𝑃𝐻2 = 𝑃𝑁0 = ____(B)
2

Since stoichiometric ratio is 1 here, so either of H2 and NO can be treken as = A A

comperuse

Lit 𝐶𝐴0 = (𝐶𝐻2 )0 [taking 𝐻2 as A compouid]

As 𝑃𝐴0 = 𝐶𝐴0 . 𝑅. 𝑇 (ideal gas eqn) ___________(c)

𝑃𝑐𝑜𝑡𝑥
Using equation (B) in (c) => 𝐶𝐴0 = _________(𝐷)
2𝑅𝑡

Putting (D) in equation (A) ;

[(0.5)1−𝑛 −1(𝑃𝑡𝑜𝑡𝑎𝑙 )1−𝑛
𝑡1/2 = ̃ (𝑛−1)(2𝑅𝑇)1−𝑛
_____________(E)
𝐾

For this equation (E) also; log(𝑡1/2 ) vs log(𝑃𝑡 ) will give straight line with stope (1-
n)* [but now intereept has chauged !]

So we plot log(𝑡1/2 ) and log(𝑃𝑡 ) from data given

Attached screenshot of spreadsheet with plot;

R2 = 0.9769 is almost good (ideally R2 = 1 for perfect)

Here,

Stope = -2.271 = 1-n

n = 3.271

[ *You can use the nature of graphs; applying logarithm on both side of eqn (E);
[(0.5)1−𝑛 −1](𝑃𝑡𝑜𝑡𝑎𝑙 )1−𝑛
log(𝑡1/2 ) = log[ ̃ (𝑛−1)(2𝑅𝑇)1−𝑛
]
𝐾

as; log 𝐴𝐵 = log 𝐴 + log 𝐵

(0.5)1−𝑛
 log(𝑡1/2 ) = log[ ̃ ] + log[(𝑃𝑡𝑜𝑡𝑎𝑙 )1−𝑛 ]
𝐾 (𝑛−1)(2𝑅𝑇)1−𝑛
as; log 𝐴𝑚 = m. log 𝐴

(0.5)1−𝑛 −1
 log (𝑡1 ) = log[ ̃ ] ) + (1
⏟ − 𝑛) log[(𝑃
⏟ 𝑡𝑜𝑡𝑎𝑙 ) ])
⏟ 2 ⏟ 𝐾(𝑛−1)(2𝑅𝑇)1−𝑛

Y axis intercept stope x-axis

The rate expression is as follows:

−𝑟𝐴 = 𝑘𝐶𝐴𝑚
𝑑𝐶𝐴 𝑑𝑋𝐴
= 𝐶𝐴0 = 𝑘𝐶𝐴𝑚 ……(1)
𝑑𝑡 𝑑𝑡

n: is the order of the reaction

Assume order of reaction and find out the rate constant

If calculated rate constant is same for the both condition then assumed rate constant is
correct.

Assume 2nd order reaction:

𝑑𝑋𝐴
𝐶𝐴0 = 𝑘𝐶𝐴2
𝑑𝑡

2
= 𝑘𝐶𝐴0 (1- 𝑥𝐴 )2 ( 𝐶𝐴 = 𝐶𝐴0 (1 − 𝑥𝐴 ))

Integrate the above equation and obtain the following result:

1 𝑥𝐴
k= [( )]
𝑡𝐶𝐴0 1−𝑥𝐴

Case 1:

For t = 8 min, xA = 0.8, and 𝐶𝐴0 = 1𝑚𝑜𝑙/𝐿

1 0.8
k= [( )]
8 min x 1𝑚𝑜𝑙/𝐿 1−0.8

= 0.5 Lmol-1min-1

Case 2:

For t = 18 min, xA = 0.9, and 𝐶𝐴0 = 1𝑚𝑜𝑙/𝐿

1 0.9
k= [( )]
18 min x 1𝑚𝑜𝑙/𝐿 1−0.9
= 0.5 Lmol-1min-1

therefore, order of the reaction is 2 and rate constant (k) is 0.5 Lmol-1min-1

Rate equation for this reaction is:

−𝑟𝐴 = 0.5𝐶𝐴2

3.7

𝑡 = 0 … $0 = ?
After his raise we have } …. from this final
𝑡 = 3 $ = 135

$0

For unchanged betting habits

$0
ln = (0.144)(3)… or $0 = 208
135

3.8

From the table of data

at 𝐶𝐴 = 500 𝑡 = 100 𝑚𝑖𝑛

This

at 𝑡 = 5 ℎ𝑟𝑠 + 100 min = 400 𝑚𝑖𝑛

mol
CA = 200 ….. or XA = 0,6
𝑚3

3.9

For a first order reversible reaction

𝑘1
→
𝐶 = 0.5 𝑚𝑜𝑙/𝐿
A <−
R { 𝐴0 …..𝑋𝐴𝑅 = 0.667
𝑘2 𝐶𝑅0 = 0

The integrated conversion equation in a batch reactor (constant volume because it is a

liquid) is given by
𝑋𝐴
−ln(1 − ) = (k1 + k2) t
𝑋𝐴𝑒

Replacing values we then find

 1
𝑙𝑛2
−ln(1 − ) = (k1 + k2) 8 min …….. k1 + k2
3
2 = = 0,086625 min-1 …(i)
8
3

Now from thermodynamics we know that

2
𝐶𝑅𝑒 𝑘1 0.5 𝑥
k= = = 3
1 =2
𝐶𝐴𝑒 𝑘2 0.5 𝑥
3

This…. k1 = 2k2 ……………………(ii)

0,086625
k2 = = 0,028875
(i) & (ii) give { 3
k1 = 0.057750

This the rate expression for the disappearance of A

−𝑟𝐴 = 0.05775𝐶𝐴 - 0,028875 CR

Bas 4. A R find
Go ?
B
+
-

S
+

XA
10
XA 0
=

= 100 200 CA?

CB0 200
CB!
=

100 100 100 100

*A 0,8=

* 1
=
0
100 100 100

(A 0 =
100A
= + 200B 300
=

OA +100B 100R 1005 300

VXA 1
=
= + +

roo
EA

e
=

->G mile e
=>
0,8
=

=
20

=
-> xB a
=

1x0, 0,4
=

cB
co(x) 2004)
=
=

10 modle
=
BC 4.5

To 400K,
=

Ro=4 atm, CAg 100,

=

CB0=200
A B
+
)
-

2R find XA, XB, 2B

T
300R,
= R 3atm, CA 20
=
=

Ex 0
=

?
EB 0
=

A =

xB
Y0
=
=
0,
=
Bai 5. 1

space velocity=1 (min--

21
- R S +

plug flow reactor X

=0,9

we have:

T
5 imin-= 1 min
=

&
BC5.2
Ba 5.3 for mixed flow

chota base landi:kT=

=x -

live y

-i.
mins

- >1
-
198) min-1)
=

0,01
F k.(
1,98(n)
rate: -

=
1,95
=
+(90) =

k(z) w
e
=

k 2(min-1)
=> =

0.0004)
-

rw k.(w
=

1(0,0002)
=
=
Bat 5.4

present:
115 CA0=10 mot It
A
-
R -

PA k.CA
=

XA 0,7
=

kT
4 -a
=
=

->
(1 xA)
kT
-

XA
---

!(11) AY
115

k4 =1,347
=

7
-
10015(d -
0,77115
double the volume -> new KT 2x1,347 2,69
=
=

B
2,69:
T-x12,69 -
=

x45
-
XA 0,794 =
 BG5.5 XA 0,999
=

Vo = 400t 1 min

M
A B +
-

R -

rA 200
= CA. 2B
2A0 100 mmolle
1
I
2
EA
=
-
-

min

order plug
=

flow reactor [B0 200

= mmol/l
second

kT (t0 ( M -

1) =
en
[*] where
M -

1
Ahls M 2
=

= 2 b210
200+ 10,1772-17:
=>

=>
T 0.31
=
min
Inanys] 6,2156
=

v Yvo (400)(0,31)
=>
=
=

1241
=
Bas 5.6:
k1
*
R A (0,04 min-1) 27-10.01 min->) CR
n
-

v 2000 2
=
vo 100
=

e/min

Cto -100 mol/h

k1 0.04
=

min-1
EA 0
=

have:
312
we

0.01
=

min-1

woxte=4
20 Min-1

we have:

Xe
100 -

100Xte

-> XA 0,506
=
 Bal 5.8
5.6
M-M
type?
y chang reaction

Bai 5.9

a min
enzyme
A -
Ri -

r =

Vo 2591min
=

XA 0,95
Mot Il
↳
can
may
=

20 2
=

for this M-M type reaction:

k (n k2(40 C)
= +

0,11] 9861
v
2I1 +
-> =

0,512- =
 Bal 5.10

->
A 2.5) products)
-

VA 40min-1)
=
CA

FAo NO
=
moe min
V 221
=

Co 2 Mot =

It XA =?
firstorder:
FAO vo. CAr -> 100 mot / min=
= (2 motle) vo

5 (min
=>
vo =

kT (n =

= 11
1 -
XA

n.(2) en-
=) =
XA 0,988
=

B1 5.11

y chary
Bai 5.12
xi5.5
y
Ba 5.13 -

rphos=(10 fr-1) < phos

I phos:213,
4Pt -> Py(q) GH2
+

inerts: 113
It 10
=
mollhi
for 1storder reaction.
XA 0,75 =

z (1 4)(n 1 * 11,4
atm
k
3
=

91XA
+
-
=

1 -

xA
FAo (1) abac 1
bas1 vi saw
Also,
Go:
Fousts, a more

ty
12 10 hr-1 4A - 7R
=

201 ki
FAo 10
=

Mot Ihn reactants 40

inents 20
31
-60. I
=

0,5
=

60
 [(1
v
+0.57 en
-19510,751]
=

=17 lit
0.66 moe (l 0,33 mol/L

Bat 5.14 ↑ ↑
2A0 660 = monot le if (Af =330 mmol II

BA - R FAo 54U
= mmot / min ↓
V ?
may ko hien
=

Bai
91
2=
=

⑯
gi then
we have: -

rA 0,054
=

= e
st
c =
miner

5 X =

-> YA 0,75
=
 equation== Jc8 8

Jol
-

"nas)
(x)
rass"
x
-> V Fo*
=

-> v 8,55l
=
 B 5.15
0.0542
resea
2A -

> R -

r =

Go =1 mol/l

for second order mixed flow reactor CAf 0,5moe

=
/l

kY(0 =A
- 9054(1moele)
5
=

->
2 =

CA 1 -

x =

-> T 10(sec
=
-

-)

x1 moele
Fao
A (mot/sec)
=

-
0.2
=

10(sec 1)
-

Ba 5.16
A -

> 3R1 -

r (0,6min-1) 2A
=
50% No=1801 / min
A
-
50% inerts
A
- 3R
reactants
115 90 =300 mmol/l =0,3 mor ll
0,5
inents v 1m3 10002
=

-
0.5

An
=

Autul 2 -
1
Ex 1
=

F
=
for first
order -> kT (1 2A) (n
=
+
1 -

EAXA
1 -

xA
->
0.68= 13((x) x1 +

xA

I 2(n)fx1) xA
-> -
=

-> XA 0,88 =

B 5.17

I
20 302
- ms)
rozone= 0.05
Cozone
-

20, - 302
recictunts
0.2 0,3
inents
0,8 Af
-

total 1 1,1

-> 21 1=01
=
 D =

CAORT (=1,5 atm40(0,082)(93 2737

=
+

-> CA0 (molle/ XA

2
=
0,85 0.5 =

vo 1 =
liter Is

for second order:

kT(n EXA (9
22(1 31)((1 x1)
1)?x
+
+ -
= + +

->
0,057.005 2.0,1(1 0,14n(1
=
+
-
0,5 0,12 6,5+

x
(0,1
+ 1)x5
+

1 -

0.5

- V 381
= liter

BCL 5.18
27 -> R -

r 0,05C12 (mol/l.s)
=

12 - CA0 mot /liter

->
2f =
=
=
1

V =
2 liter

vo 0,51/min 0,0083 eIs

=
=

for second order:

kT(A 231)1 (1)(n)1

-
7
- =
+ -
x =) 91XA
+

(2
+
4
+

1 -

XA
-> 0.05. 240.1 21-0,5)(1-0,5)(n(1
=
-
x1) -

0,5xA # 8,25
*A
-

1 xA
12 0,5(n(1 a
-

=
-
-

xA) -

0,5XA +

1 -

YA
->
t
x1 0,98=

1
=XA 0,98 motle
-> a 0.02
- =
=

=
Bal 5.19 (gial ich khas Think) A
-
3R
(e/min) 0,06 8,45 8,1
No 1,5
Pha Ank 2
2(mmot (e) 30 60 SO 105

1 1 aqueous thi 0
I 1 1
gas

yo
0,06 8,1

(molle)

It
CA

is
8,08 0.143

S 0,105 0,045
 k21N
T
A
-

↳-> log( -

NA) logR m.
log2A
=
+

↓
chay bang n 2

I
=

-
dring may de
k4
=

fink -

rA

r 42
-
=

-
Bai 5.20 Co 100
=
mmol/e-
A -> R
v 1e =
-

~, liter/min 1 6 24
A -> R
C, mmot lt 4 20 50

EA =
11 0
=

assume that
firstorder-> KT
=
= A
1 -

YA
t
↓ Tc
=

-> k 24

=get
=

=> 2427
124

to
the
BC 5.21
->
A R time to
CA0=1,3 mol Ib

↓
CA 0,3
=
mol ll
-

1 k(1
=

->
log) -rx) logk magCA
+

↑
 Bat 5.23

a) XA 0,75 Go=1,2 Moele E 0 so

1 xA
=
=

FA0 1000
=

mol A I hn

FAG CA0. 11hr

vo -> vo
20
=
=

-> 2Af 2Ar(1

=
-

XAf) 1,2(1
=
-

0,75) 0.3
=

moe le

F-
CSR:

e,
applying

r=5en
1,2
b) me 10.5in 60 min

canb va 2
tiring on wher
Bar 5.24
V 0,12
the rate
=

asslime expression:
-

rA k.2A 20 100 mmol/2

①
=

fr) -rA) enk

=
+
m. InCA

A - > 5R 21 4 =

5
EA =
= 4
->
fin i
i
for MFR: T
4 -
= cho
may
+

-Frg(1
V 0,12
=

--rA 10 FanYA
m
=

A 100
=

②
x)
(1 2)
- =

->
1
- Y
=

B
Ex
1 +
 FAo
Immoe/hr)
CA
Immol/eS
x= -
A 10FtoXA
=

E=
1 +

300 16 0,5122 1536,6

100 30 0,31815 3161,5

3000 50 5001
0.1667
5000 60 0,1176 5888

calculate value of (n)-rA) and InCA

corresponding

]e?
 chay bring 96,274x2110105
1,0106 rA

E
=

n =

->
Ink 4,5672 ->
=

k 96,274
=
Ba5.25

time to obtain Co 8
=

XA 0,75
=
Motle - -

T So-2A
-
HA)=IaK +
mInCAf - A =

⑧ ⑳
-
Rating
Bài 5.24:

Let’s assume rate expression is:

−ℽa = 𝐾. 𝐶 𝑛 a

A  5R : Given reaction
5−1
Hence €A = =4
1

For MFR (performance 𝑐𝑞𝑛 )

𝐶𝐴0 𝑋𝐴 𝑉.𝐶𝐴0 𝐶𝐴0 .𝑋𝐴
𝜏= => =
(−𝑅𝐴 ) 𝐹𝐴0 (−𝑅𝐴 )

𝑋𝐴 .𝐹𝐴0 𝑋𝐴 .𝐹𝐴0
 (−𝑅𝐴 ) = = V = 0.1 (𝑙𝑖𝑡)
𝑉 0.1
𝑚𝑖𝑙𝑖𝑚𝑒𝑡
 (−𝑅𝐴 ) = 10. 𝐹𝐴0 . 𝑋𝐴 𝐶𝐴 = 100.
𝑙𝑖𝑡

For varying volume system

𝐶𝐴0 . (1 − 𝑋𝐴 ) 𝐶
1− 𝐴
𝐶𝐴 = 𝐶𝐴0
= 𝑋𝐴
(1 +∈𝐴 . 𝑋𝐴 ) 𝐶
1− 𝐴
𝐶𝐴0

𝐹𝐴0 𝐶𝐴 𝐶𝐴 −ℽa = 10. 𝐹𝐴0 . 𝑋𝐴

1−
𝐶𝐴0
= 𝑋𝐴
𝐶𝐴
1−
𝐶𝐴0

300 16 0.5122 1536.6

1000 30 0.31818 3121.8

3000 50 0.1667 5001

5000 60 0.1176 5880

Calculate corresponding value ln(−ℽa) and ln𝐶𝐴

ln(−ℽa) 7.3373 8.0652 8.517 8.679

ln𝐶𝐴 2.772 3.4011 3.912 4.094

From 𝑐𝑞𝑛 draw graph ln(−ℽa) vs ln(𝐶𝐴 )

From the graph we find that the slope

n= 1.0106 & ln k = 4.5672 => K = 96.274

Hence rate expression: −ℽa = 96.274 . 𝐶𝐴 1.0106

Bài 5.28

Solution :

To the given problem the solution is follow as below that

Given that

2A -> R + S

P0 = 1 atm , T = 100°C

Feed containing 20Y-In and 80% mole

For this reaction and feed : 5vol off reacfant

Mixture yield 5 vol of product mixture on complete conversion

5.5
𝑃. 𝐴 = =0 A = 0
5

For Plug Flow :

𝑇 𝑉 𝑋𝑎 ⅆ𝑥𝐴
= = ∫𝐵
𝐶𝐴 𝐹𝐴0 (−𝑟𝐴)

Given Po = 1 atm
80
Mole fraction of A = x.A= =0.80
100

Partial pressure of Ax = Mole fraction of Ax

-total pressure

PA0 = 0.8N = 0.8 atm

For ∈ 𝐴 = 𝐵, 𝐶𝐴 = 𝐶𝐴𝑜 . (1 − 𝑋𝐴 )

For gaseous : 𝐶𝐴 < 𝑃𝐴 ; 𝑃𝐴 = 𝑃𝐴 . (1 − 𝑋𝐴 )

Given that 𝑋𝐴 = 0.95

𝑃𝐴 = 0.8. (1 − 0.95) = 0.04 𝑎𝑡𝑚

The portal required time for change in the partial pressure of a from 𝑃. 𝐴0 = 0.8𝑎𝑡𝑚, to
𝑃. 𝐴0 = 0.04𝑎𝑡𝑚 in a batch reactor is obtained directly from data

At t = 3305 => 𝑃. 𝐴0 = 0.04𝑎𝑡𝑚

At t = 201 => 𝑃. 𝐴0 = 0.08𝑎𝑡𝑚

𝑡𝑏𝑎𝑡𝑐ℎ = 330 − 20 = 310 𝑠𝑒𝑐

As that ∈= 0 we have constant density system then

𝜏𝑝𝑙𝑢𝑔 = 𝑡𝑏𝑎𝑡𝑐ℎ

Therefore; T for the plug flow = 310 sec

𝜏 𝑈
=
𝐶𝐴0 𝐼.𝐴0

𝑃.𝐴0
 𝐶𝐴0 =
𝑅𝑇

PA0 = 0.8 atm, T = 373K, R=0.08206 atm/mol.k

0.80
𝐶𝐴0 =
0.08206 .373

= 0.0261 mol/l

FA0 = 0.0278

Now, the volume of reactor is

𝜏.𝐹𝐴0
𝑉=
𝐶𝐴0

310 𝑥 0.0278
=
0.0261

V = 330 (l)

Hence volume of the plug flow required for that is 95% convestion
Bài 5.30:

Given & reaction

AR

Let the rate equation be (−𝛾𝐴 = 𝑘. 𝐶 𝑛 a)

And from the data given

𝐶𝐴0 = 2, 𝐶𝐴𝑘 = 1

basic equation of mixed how reactor

𝜏 𝑥𝐴
= as 𝐶𝐴 = 𝐶𝐴0 . (1 − 𝑥𝐴 )
𝐶𝐴0 (−𝛾𝐴 )

𝐶𝐴0 .𝑥𝐴
𝜏= 𝐶𝐴 = 𝐶𝐴0 − 𝐶𝐴0 . 𝑥𝐴
𝑘.𝐶 𝑛 a

𝐶𝐴0 −𝐶𝐴
𝜏= 𝐶𝐴0 . 𝑥𝐴 = 𝐶𝐴0 − 𝐶𝐴
𝐶 𝑛a

From experiment 𝜏 = 50 𝑠𝑒𝑐, 𝐶𝐴0 = 2, 𝐶𝐴𝑘 = 1

2−1
𝑇0 =
𝑘.(1)𝑛

1
𝑇0 =
𝑘

1
𝑘= . 0.02
50

Now from 2nd experimental data

𝜏 = 16, 𝐶𝐴0 = 2, 𝐶𝐴𝑘 = 0.8

𝐶𝐴0 −𝐶𝐴 1.2−0.8
𝜏= 16 = 1
𝑘.𝐶 𝑛 a 𝑘.(0.8)𝑛

As from 3rd experimental data

𝐶𝐴0 −𝐶𝐴
𝜏=
𝑘.𝐶 𝑛 a

2−0.65
60 = 2
𝑘.(0.65)𝑛
𝟏 16 1.2 − 0.8 𝑘. (0.65)𝑛
= = .
𝟐 20 2 − 0.65 𝑘. (0.8)𝑛

16 1.35 0.65𝑛
𝑥 =
60 60 0.8
9 13𝑛
=
10 16
0.9 = (0.8125)𝑛

Apply log on both sides

log(0.9) = 𝑛. log(0.8125)

log(0.9)
𝑛=
log(0.8125)

𝑛 = 0.50

1
𝑛=
2
So we know order 2 𝑘 value
𝜏 𝑥𝐴
=
𝐶𝐴0 (−𝛾𝐴 )

Given 𝐶𝐴 = 0.8 𝑚𝑜𝑙, V0 = 1 Ut/sec

𝑋𝐴 = 0.75
𝐶𝐴0 .𝑥𝐴
𝜏= 𝐶𝐴 = 𝐶𝐴0 . (1 − 𝑋𝐴 )
𝑘.𝐶 𝑛 a

(0.8).(0.75)
𝜏 = (0.02).(0.2)0.5 𝐶𝐴 = 0.8. (1 − 0.75)

𝜏 = 67.08 𝑠𝑒𝑐 𝐶𝐴 = 0.8. (0.25)

𝐶𝐴 = 0.2
𝑉
We know 𝜏 =
𝑣0
 So v = 𝜏. 𝑣0

=67.08x1

=67.08

Size of CSTR is 67.08 sec

Now for PFR

𝜏 𝑋𝑎 ⅆ𝑋𝑎
= ∫0
𝐶𝐴0 (−𝛾𝐴 )

𝑌𝑎 𝐶𝐴0 .ⅆ𝑋𝑎
𝜏 = ∫0 𝐶𝐴 = 𝐶𝐴0 − 𝐶𝐴0 . 𝑋𝐴
(−𝛾𝐴 )

And limit changes from 𝐶𝐴0 𝑡𝑜 𝐶𝐴

𝐶 ⅆ𝑋𝑎
𝜏 = − ∫𝐶 𝐴
𝐴0 𝑘.𝐶 𝑛 a

0.2
𝑑𝑋𝑎
𝜏 = −∫
0.8 (0.02). (0.2)𝑛

𝜏 = 67.08 𝑠𝑒𝑐
𝑣
So 𝜏 =
𝑣0

v = 𝜏. 𝑣0

= 67.08 vt

So the volume of reactor required in 67.08 vt

Slide example:

Since reactants phase reaction “∈𝐴 ” should be calculated

Reactants Products
100 100
100 100

Products − Reactants
∈𝐴 =
Reactants

∈𝐴 = 0

Design equation of PFR

𝑋𝑎
𝑉 𝑑𝑋𝑎
=∫
𝑉𝐴0 . 𝐶𝐴0 0 (−𝑅𝐴 )

𝑋𝑎
𝑉 𝑑𝑋𝑎 (1 +∈𝐴 . 𝑋𝑎)
=∫
𝑉𝐴0 . 𝐶𝐴0 0 𝑘. 𝐶𝐴0 (1 − 𝑋𝑎)

Since ∈𝐴 = 0
𝑘 𝑋𝑎 ⅆ𝑋𝑎
V.( ) = ∫0
𝑉0 (1−𝑋𝑎)

𝑘 𝑘
. 𝑉 = −ln(1 − 𝑋𝑎) . 32 = −ln(1 − 0.99)
𝑉0 𝑉0

𝑘
= 0.144
𝑉0
With the connected stoichiometry:

A  3R

Reactants Products

100 300

Products − Reactants 300 − 100

∈𝐴 = = =2
Reactants 100
For PFR
𝑋𝑎
𝑉 𝑑𝑋𝑎 (1 +∈𝐴 . 𝑋𝑎)
= ∫
𝑉𝐴0 . 𝐶𝐴0 0 𝑅. 𝐶𝐴0 (1 − 𝑋𝑎)
𝑅 𝑋𝑎 (1+∈𝐴 .𝑋𝑎)
V. = ∫0 . 𝑑𝑋𝑎
𝑉0 (1−𝑋𝑎)

𝑋𝑎 ⅆ𝑋𝑎 𝑋𝑎 𝑋𝑎
∫0 + ∈𝐴 ∫0 . 𝑑𝑋𝑎
(1−𝑋𝑎) (1−𝑋𝑎)

𝑋𝑎 ⅆ𝑋𝑎 𝑋𝑎 (1−𝑋𝑎) 𝑋𝑎 ⅆ𝑋𝑎

∫0 + ∈𝐴 − ∫0 . 𝑑𝑋𝑎 + ∈𝐴 − ∫0
(1−𝑋𝑎) (1−𝑋𝑎) (1−𝑋𝑎)

𝑅
V. = −ln(1 − 𝑋𝑎) - ∈𝐴 . 𝑋𝑎 − ∈𝐴 ln(1 − 𝑋𝑎)
𝑉0

𝑅
From Er = 0.144
𝑉0

𝑋𝑎 = 0.99

∈𝐴 = 2

V.0144 = −ln(1 − 0.99) − (2 𝑥 0.99) - 2ln(1 − 0.99)

0.144V = 4.605 – 1.98 + 9210

0.144V = 11.835

=> V = 82.187 (L)

The required reaction volume is 82.187 L

 -

*
Question A B ) R S
1:
Go 1 motle XA 0,5
-
+ +

=
=

irreversible
elementary liquid phase CB0 1,5moe
=

/2

gia
->
applying second order reaction:
the
be
-

->
A KCA.CB,
=

fr =(CBo-2A0kt
we denote that: M =

1
=
1,5
=

k
#

M(1 -

XA)

thay so:

In 195=(1,5-1).
Smer)
-> 12. (1hr) -> k 0,575
=

1,5(1 -

0.57

- 0.575 x
Bm
L
-

=
x

b) IfCAr CBO
=
1 mot
=
Ihr
t 1hr
-> Pr
=

Because to:CBO =
1 muy/hr -> so we
assump that.2A S
+

rA kC
=
tiny can may

->
( ) 4
=

F()-575/1hr)
-> XA 0,365 =
 Question 2: 21 R
->

2S
+
2nd order

P1 =

8
atm

P 40,3 in 3 minutes
system
as we have:

PA Pto
f(P -k0) < PA
1am
1(P0 0,3-Po)
-

- +
=

t
=

increased by30% PA 1a m
-(0,3) 0.4(c+ m)
+
-

=>
=
=

X1
14A 10,4
=>

0,6
=
=

because volume
constant reactor ->
2p =
0

Applying:1TGo:
O ***
*
*=
* 05

↓
do ko
bit
dia
fai bao which.
2A R 2S
+
+

XA 0
=
015 O 0

*A 1
=
2A *yR 15
+
0