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NORTHERN MINDANAO COLLEGES, INC.

Atega Street, Barangay 11 Poblacion, Cabadbaran City


GENERAL CHEMISTRY-2
9th UNIT EXAMINATION
SECOND SEMESTER (S.Y. 2022-2023)

Name: _______________________________ Grade & Section: ________________


Teacher: _______________________________ Score: ________________

I. IDENTIFICATION (15pts)
Direction: Identify the following processes. Write your answers on the space provided. Strictly no erasures!

Write S = Spontaneous and NS = Nonspontaneous Write P = Positive and N = Negative


_____1. Diffusion of gas from low pressure to a high _____9. Sugar dissolving in tea
pressure
_____2. Ice melting in lukewarm water _____10. Frost forms on a window pane
_____3. Salt dissolving in water _____11. Air pumped into a tire
_____4. Combination of nitric oxide and oxygen to _____12. Acetone evaporates from nail polish
form nitrogen dioxide remover
_____5. Iron rusting _____13. A gas condenses
_____6. A ball rolling down a slide _____14. A chocolate melt
_____7. Ethanol combusts in the presence of oxygen _____15. Water vapor condenses into water
_____8. Boiling water into steam

II. MULTIPLE CHOICE (10pts)


Direction: Write the letter of the correct answer in each item in the space provided before the number.
Use small/lowercase letters only.

_____16. In a spontaneous process, which of the following always increases?


a. the entropy of the system c. the entropy of the universe
b. the entropy of the surroundings d. the entropy of the system and the universe   
_____17.  The dissolution of ammonium nitrate in water is a spontaneous endothermic process. It is spontaneous
because the system undergoes _________.
a. a decrease in enthalpy. c. a decrease in entropy.
b. an increase in entropy. d. an increase in free energy
_____18.  Which one of the following thermodynamic quantities is not a state function?
a. enthalpy b. entropy c. internal energy d. work
_____19.  Which statement is incorrect?
a. At constant pressure, H = E + PV
b. The thermodynamic symbol for entropy is S.
c. Gibbs free energy is a state function.
d. For an endothermic process, H is negative.
_____20.  What is the unit of entropy?
a. J mol-1 b. J K mol-1 c. J-1 K-1 mol-1 d. J K-1 mol-1
_____21.  Which of the following is true for the entropy of an isolated system?
a. It can never increase c. It can never be zero
b. It can never decrease d. None of the above
_____22.  It is natural for systems in the universe to _____ spontaneously.
a. become disordered c. produce heat
b. become ordered d. do work
_____23.  Why does entropy increase during a spontaneous process?
a. Entropy increases because energy always transfers spontaneously from a dispersed state to a
concentrated state.
b. Entropy increases because energy always transfers spontaneously from a concentrated state to a
dispersed state.
c. Entropy increases because pressure always increases spontaneously.
d. Entropy increases because temperature of any system always increases spontaneously.
_____24.  Which of the following processes will lead to a decrease in the entropy of the system?
a. Salt crystals dissolve in water. c. Iron and oxygen react to form rust.
b. Air escapes from a hole in a balloon. d. Ice melts in your hand.
_____25.  The __________ law of thermodynamics states that entropy is always increasing.
a. First b. second c. third d. zeroth
III. CALCULATION
Direction: Calculate the following chemical thermodynamics problem. Show your complete solution on the
space provided. No solution means wrong answer!
1. Consider the first ionization of sulfurous acid:

H2SO3(aq) + H+(aq) →HSO3-


ΔHf˚
-145.5 0 -151.9
(kJ/mol)

56 0 26
(J/K.mol)
(a) Calculate the ΔH˚rxn
(b) Calculate the ΔS˚rxn
(c) Calculate the ΔG at 4962˚C
(d) Analyze the spontaneity of the reaction

"Honesty is the best policy!

Prepared by: Submitted to: Noted by:

MEA-ANN OSCIANAS, LPT JEVANH A. EUGENIO, MATF HERMIE LIZA D. SASIS, MACDDS
Subject Teacher Senior High Coordinator Basic Education Principal
NORTHERN MINDANAO COLLEGES, INC.
Atega Street, Barangay 11 Poblacion, Cabadbaran City
GENERAL CHEMISTRY-2
9th UNIT EXAMINATION
SECOND SEMESTER (S.Y. 2022-2023)

Name: _______________________________ Grade & Section: ________________


Teacher: _______________________________ Score: ________________

I. IDENTIFICATION (15pts)
Direction: Identify the following processes. Write your answers on the space provided.

Write S = Spontaneous and NS = Nonspontaneous Write P = Positive and N = Negative


_____1. Diffusion of gas from low pressure to a high _____9. Sugar dissolving in tea P
pressure NS
_____2. Ice melting in lukewarm water S _____10. Frost forms on a window pane N
_____3. Salt dissolving in water S _____11. Air pumped into a tire N
_____4. Combination of nitric oxide and oxygen to _____12. Acetone evaporates from nail polish
form nitrogen dioxide NS remover P
_____5. Iron rusting S _____13. A gas condenses N
_____6. A ball rolling down a slide S _____14. A chocolate melt P
_____7. Ethanol combusts in the presence of oxygen S _____15. Water vapor condenses into water N
_____8. Boiling water into steam NS

II. MULTIPLE CHOICE (10pts)


Direction: Write the letter of the correct answer in each item in the space provided before the number.
Use small/lowercase letters only.

_____16. In a spontaneous process, which of the following always increases?


a. the entropy of the system c. the entropy of the universe
b. the entropy of the surroundings d. the entropy of the system and the universe   
_____17.  The dissolution of ammonium nitrate in water is a spontaneous endothermic process. It is spontaneous
because the system undergoes _________.
a. a decrease in enthalpy. c. a decrease in entropy.
b. an increase in entropy. d. an increase in free energy
_____18.  Which one of the following thermodynamic quantities is not a state function?
a. enthalpy b. entropy c. internal energy d. work
_____19.  Which statement is incorrect?
a. At constant pressure, H = E + PV
b. The thermodynamic symbol for entropy is S.
c. Gibbs free energy is a state function.
d. For an endothermic process, H is negative.
_____20.  What is the unit of entropy?
a. J mol-1 b. J K mol-1 c. J-1 K-1 mol-1 d. J K-1 mol-1
_____21.  Which of the following is true for the entropy of an isolated system?
c.It can never increase c. It can never be zero
d. It can never decrease d. None of the above
_____22.  It is natural for systems in the universe to _____ spontaneously.
c. become disordered c. produce heat
d. become ordered d. do work
_____23.  Why does entropy increase during a spontaneous process?
e. Entropy increases because energy always transfers spontaneously from a dispersed state to a
concentrated state.
f. Entropy increases because energy always transfers spontaneously from a concentrated state to a
dispersed state.
g. Entropy increases because pressure always increases spontaneously.
h. Entropy increases because temperature of any system always increases spontaneously.
_____24.  Which of the following processes will lead to a decrease in the entropy of the system?
b. Salt crystals dissolve in water. c. Iron and oxygen react to form rust.
b. Air escapes from a hole in a balloon. d. Ice melts in your hand.
_____25.  The __________ law of thermodynamics states that entropy is always increasing.
b. First b. second c. third d. zeroth
IV. CALCULATION
Direction: Calculate the following chemical thermodynamics problem. Show your complete solution.
No solution means wrong answer!
1. Consider the first ionization of sulfurous acid:
H2SO3(aq) + H+(aq) →HSO3-
ΔHf˚
-145.5 0 -151.9
(kJ/mol)

56 0 26
(J/K.mol)
(a) Calculate the ΔH˚rxn
(b) Calculate the ΔS˚rxn
(c) Calculate the ΔG at 4962˚C
(d) Analyze the spontaneity of the reaction

"Honesty is the best policy!

Prepared by: Submitted to: Noted by:

MEA-ANN OSCIANAS, LPT JEVANH A. EUGENIO, MATF HERMIE LIZA D. SASIS, MACDDS
Subject Teacher Senior High Coordinator Basic Education Principal

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