JEE Main PYQs Atomic Structure 28399275

InfinIITy Academy
Subject : Chemistry Paper Set : 1
Standard : 11 JEE Main_ PYQs _Mole concept Date : 19-07-2023
Total Mark : 800 Time : 0H:0M

Chemistry - Section A - MCQ

[1] Which transition in the hydrogen spectrum would have the same wavelength (A) 1s orbital (B) 3s orbital
as the Balmer type transition from n = 4 to n = 2 of He+ spectrum
(C) 2s orbital (D) 2p orbital
(A) n = 2 to n = 1 (B) n = 1 to n = 3
(C) n = 1 to n = 2 (D) n = 3 to n = 4 [7] If p is the momentum of the fastest electron ejected from a metal surface after
the irradiation of light having wavelength λ, then for 1.5 p momentum of the
photoelectron, the wavelength of the light should be: (Assume kinetic energy
[2] The shortest wavelength of hydrogen atom in Lyman series is λ. The longest of ejected photoelectron to be very high in comparison to work function)
wavelength in Balmer series of He+ is
(A) 34 λ (B) 12 λ
(A) 5
(B) 9λ
9λ 5 (C) 4
9
λ (D) 2
3
λ
(C) 36λ
5
(D) 5λ
9
[8] Given below are two statements:
Statement I : According to Bohr's model of hydrogen atom, the angular mo-
[3] Consider the following pairs of electrons mentum of an electron in a given stationary state is quantised.
(A) (a) n = 3, 1 = 1, ml = 1, ms = + 12 Statement II : The concept of electron in Bohr's orbit, violates the Heisenberg
(b) n = 3, 1 = 2, ml = 1, ms = + 12 uncertainty principle.
(B) (a) n = 3, 1 = 2, ml = −2, ms = − 21 In the light of the above statements, choose the most appropriate answer from
the options given below:
(b) n = 3, 1 = 2, ml = −1, ms = − 12
(C) (a) n = 4, 1 = 2, ml = 2, ms = + 12 (A) Both Statement I and Statement II are correct.
(b) n = 3, 1 = 2, ml = 2, ms = + 12 (B) Statement I is correct but Statement II is incorrect.
The pairs of electron present in degenerate orbitals is/are...... .
(C) Statement I is incorrect but Statement II is correct
(A) Only A (B) Only B
(D) Both Statement I and Statement II are incorrect.
(C) Only C (D) (B) and (C) [9] The shortest wavelength of H atom is the Lyman series is λ1 . The longest wave-
length in the Balmer series of He+ is :
[4] The pair, in which ions are isoelectronic with Al3+ is ..... . (A) 5λ1
(B) 27λ1
9 5
(A) Br − and Be2+ (B) Cl− and Li+ (C) 9λ1

5
(D) 36λ1
5
(C) S 2− and K + (D) O2− and M g 2+

[10] Based on the equation ( )
∆E = −2.0 × 10−18 J n12 − 1
[5] Given 2 n21
(A) n = 5, ml = +1 the wavelength of the light that must be absorbed to excite hydrogen electron
(B) n = 2, l = 1, ml = −1, ms = −1/2 from level n = 1 to level n = 2 will be: (h = 6.625 × 10−34 J s, C =
The maximum number of electron(s) in an atom that can have the quantum 3 × 108 m s−1 )
numbers as given in (A) and (B) are respectively
(A) 1.325 × 10−7 m (B) 1.325 × 10−10 m
(A) 25 and 1 (B) 8 and 1
(C) 2.650 × 10−7 m (D) 5.300 × 10−10 m
(C) 2 and 4 (D) 4 and 1
( 2)
[11] Energy of an electron is given by E = −2.178 × 10−18 J Z . Wavelength
[6] The graph between |ψ| and r(radial distance) is shown below. This represents
2 n2
of light required to excite an electron in an hydrogen atom from level n = 1 to
n = 2 will be :
(h = 6.62 × 10−34 Js and c = 3.0 × 108 ms−1 )
(A) 1.214 × 10−7 m (B) 2.816 × 10−7 m
(C) 6.500 × 10−7 m (D) 8.500 × 10−7 m
[12] Excited hydrogen atom emits light in the ultraviolet region at 2.47 × 1015 Hz.
With this frequency, the energy of a single photon is (h = 6.63 × 10−34 Js)
(A) 8.041 × 10−40 J (B) 2.680 × 10−19 J
(C) 1.640 × 10−18 J (D) 6.111 × 10−17 J
[13] Which of the following is the correct plot for the probability density ψ 2 (r) as a
function of distance ' r ' of the electron form the nucleus for 2s orbital?
Page No : 1
{ }
[21] For the Balmer series in the spectrum of H atom, v̄ = RH 1
n2
− 1
n2
,
(A) (B) 1 2
the correct statements among (I) to (IV ) are
(I) As wavelength decreases, the lines in the series converge
(II) The integer n1 is equal to 2
(III) The lines of longest wavelength corresponds to n2 = 3
(IV ) The ionization energy of hydrogen can be calculated from wave number
of these lines
(A) (II), (III), (IV ) (B) (I), (II), (III)
(C) (I), (III), (IV ) (D) (I), (II), (IV )
(C) (D)
[22] For any given series of spectral lines of atomic hydrogen, let ∆V̄ = ∆V̄max −
∆V̄min be the difference in maximum and minimum frequencies in cm−1 . the
ration ∆V̄Lymann / ∆V̄Balmer is
(A) 5 : 4 (B) 4 : 1
(C) 9 : 4 (D) 27 : 5
[23] Which one of the following about an electron occupying the 1 s orbital in a
hydrogen atom is incorrect? (The Bohr radius is represented by a0
[14] The orbital having two radial as well as two angular nodes is (A) The electron can be found at a distance 2a0 from the nucleus
(B) The probability density of finding the electron is maximum at the nucleus
(A) 3p (B) 4f
(C) The magnitude of potential energy is double that of its kinetic energy on
(C) 4d (D) 5d an average
(D) The total energy of the electron is maximum when it is at a distance a0
from the nucleus
[15] The radius of the second Bohr orbit, in terms of the Bohr radius, a0 , in Li2+ is
[24] A stream of electrons from a heated filaments was passed two charged plates
(A) 4a0
(B) 2a0 kept at a potential difference V esu. If e and m are charge and mass of an elec-
9 9 tron, respectively, then the value of h/λ, (where λ is wavelength associated
with electron wave) is given by :
(C) 2a0
(D) 4a0
3 3 √ √
(A) meV (B) 2meV
[16] In the sixth period, the orbitals that are filled are
(C) meV (D) 2meV
(A) 6s, 5f, 6d, 6p (B) 6s, 6p, 6d, 6f
[25] The ratio of the shortest wavelength of two spectral series of hydrogen spec-
(C) 6s, 5d, 5f, 6p (D) 6s, 4f, 5d, 6p trum is found to be about 9. The spectral series are
(A) Lyman and Paschen (B) Brackett and Pfund

[17] Given below are two statements. One is labelled as Assertion A and the other
is labelled as Reason R. (C) Paschen and Pfund (D) Balmer and Brackett
Assertion A : Energy of 2s orbital of hydrogen atom is greater than that of 2 s
orbital of lithium.
Reason R : Energies of the orbitals in the same subshell decrease with increase
in the atomic number. [26] If the shortest wavelength in Lyman series of hydrogen atom is A, then the
In the light of the above statements, choose the correct answer from the op- longest wavelength in Paschen series of He+ is
tions given below.
(A) 5A9
(B) 9A
5
(A) Both A and R are true and R is the correct explanation of A.
(C) 36A (D) 36A
(B) Both A and R are true but R is NOT the correct explanation of A. 5 7
(C) A is true but R is false.

[27] The region in the electromagnetic spectrum where the Balmer series lines ap-
(D) A is false but R is true. pear is
[18] The de-Broglie wavelength of a particle of mass 6.63 g moving with a velocity (A) Visible (B) Microwave
of 100 ms−1 is
(C) Ultraviolet (D) Infrared
(A) 10−33 m (B) 10−35 m
(C) 10−31 m (D) 10−25 m [28] Heat treatment of muscular pain involves radiation of wavelength of about
900 nm. Which spectral line of H− atom is suitable for this purpose?
[RH = 1 × 105 cm−1 , h = 6.6 × 10−34 Js c = 3 × 108 ms−1 ]
[19] The de Broglie wavelength of an electron in the 4th Bohr orbit is
(A) Paschen, ∞ → 3 (B) Paschen, 5 → 3
(A) 8πa0 (B) 2πa0
(C) Balmer, ∞ → 2 (D) Lyman, ∞ → 1
(C) 4πa0 (D) 6πa0
[29] The number of radial and angular nodes in 4d orbital are, respectively ........ .
[20] The electron in the hydrogen atom undergoes transition from higher orbitals
to orbital of radius 211.6 pm. This transition is associated with (A) 1 and 2
(A) Lyman series (B) Balmer series (B) 3 and 2

(C) 1 and 0
(C) Paschen series (D) Brackett series
(D) 2 and 1
Page No : 2
[30] Given below are two statements: one is labelled as Assertion (A) and the other
is labelled as Reason(R) : (A) (A), (B) and (C) (B) (A), (C), (D) and (E)
Assertion (A) : The ionic radii of O2− and M g 2+ are same.
Reason (R) : Both O2− and M g 2+ are isoelectronic species. (C) (A), (C) and (D) (D) (A), (B), (C) and (D)
In the light of the above statements, choose the correct answer from the op-
tions given below
[37] A certain orbital has no angular nodes and two radial nodes. The orbital is
(A) Both (A) and (R) are true and (R) is the correct explanation of (A)
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A) (A) 2 s (B) 3 s
(C) (A) is true but (R) is false (C) 3 p (D) 2 p
(D) (A) is false but (R) is true

[38] The correct set of four quantum numbers for the valence electrons of rubidium
[31] The wave function (Ψ) of 2s is given by atom (Z = 37) is :
( )1/2 ( )
Ψ2s = √1 a
1
2 − ar e−r/2a0 (A) 5, 0, 0, + 12 (B) 5, 1, 0, + 12
2 2π 0 0
At r = r0 , radial node is formed. Thus, r0 in terms of a0
(C) 5, 1, 1, + 12 (D) 5, 0, 1, + 12
(A) r0 = a0 (B) r0 = 4a0
(C) r0 = a0
(D) r0 = 2a0 [39] According to molecular theory, the species among the following that does not
exist is
2
[32] Given below are two statements: One is labelled as Assertion A and the other (A) He+ 2 (B) He−2
is labelled as Reason R
Assertion A : Zero orbital overlap is an out of phase overlap. (C) Be2 (D) O22−
Reason R : It results due to different orientation/ direction of approach of or-
bitals.
In the light of the above statements. Choose the correct answer from the op- [40] Given below are two statements : one is labelled as Assertion A and the other
tions given below. is labelled as Reason R:
Assertion A: In the photoelectric effect, the electrons are ejected from the
(A) Both A and R are true and R is the correct explanation of A metal surface as soon as the beam of light of frequency greater than thresh-
old frequency strikes the surface.
(B) Both A and R are true but R is N OT the correct explanation of A Reason R : When the photon of any energy strikes an electron in the atom,
transfer of energy from the photon to the electron takes place.
(C) A is true but R is false In the light of the above statements, choose the most appropriate answer from
(D) A is false but R is true the options given below :
[33] According to Bohr's atomic theory :- (A) Both A and R are correct but R is NOT the correct explanation of A
2
(A) Kinetic energy of electron is ∝ Z
n2
. (B) A is correct but R is not correct
(B) The product of velocity (v) of electron and principal quantum number (n),
'vn' ∝ Z 2 . (C) Both A and R are correct and R is the correct explanation of A
3
(C) Frequency of revolution of electron in an orbit is ∝ Z
n3
. (D) A is not correct but R is correct
3
(D) Coulombic force of attraction on the electron is ∝ Z .
n4 [41] The heat of atomization of methane and ethane are 360 kJ/mol and
Choose the most appropriate answer from the options given below :
620 kJ/mol, respectively. The longest wavelength of light capable of break-
(A) (C) Only (B) (A) Only ing the C − C bond is (Avogadro number = 6.02 × 1023 , h = 6.62 × 10−34 Js
)
(C) (A), (C) and (D) only (D) (A) and (D) only (A) 2.48 × 104 nm (B) 1.49 × 103 nm
[34] For emission line of(atomic (C) 2.48 × 103 nm (D) 1.49 × 104 nm
) hydrogen from n1 = 8 to nf = n, the plot of wave
number (v̄) against 1
n2
will be(The Rydberg constant, RH is in wave number
unit) [42] Given below are the quantum numbers for 4 electrons.
A. n = 3, l = 2, m1 = 1, ms = +1/2
(A) Linear with intercept −RH (B) Non linear B. n = 4, l = 1, m1 = 0, ms = +1/2
C. n = 4, l = 2, m1 = −2, ms = −1/2
D. n = 3, l = 1, m1 = −1, ms = +1/2
(C) Linear with slope RH (D) Linear with slope −RH
The correct order of increasing energy is
[35] Given below are two statement: one is labelled as Assertion A and the other (A) D < B < A < C (B) D < A < B < C
is labelled as Reason R
Assertion A : 5f electrons can participate in bonding to a far greater extent (C) B < D < A < C (D) B < D < C < A
than 4f electrons
Reason R : 5f orbitals are not as buried as 4f orbitals
In the light of the above statements, choose the correct answer from the op- [43] In an atom how many orbital (s) will have the quantum numbers; n = 3, l = 2
tions given below and ml = +2 ?
(A) Both A and R are true but R is NOT the correct explanation of A (A) 5 (B) 3
(B) Both A and R are true and R is the correct explanation of A
(C) 1 (D) 7
(C) A is false but R is true
(D) A is true but R is false [44] Arrange the following orbitals in decreasing order of energy ?
(A) n = 3, 1 = 0, m = 0
[36] Consider the following statements: (B) n = 4, l = 0, m = 0
(A) The principal quantum number n is a positive integer with values of
′ ′
(C) n = 3, l = 1, m = 0
′ n′ = 1, 2, 3, . . ..
(D) n = 3, l = 2, m = 1
(B) The azimuthal quantum number ′ l′ for a given ′ n′ (principal quantum num- The correct option for the order is :
ber) can have values as l = 0, 1, 2, . . . n
′ ′
(C) Magnetic orbital quantum number ml for a particular l (azimuthal quan-
′ ′ ′ ′
(A) B > D > C > A (B) D > B > C > A
tum number) has (2l + 1) values.
(D) ±1/2 are the two possible orientations of electron spin. (C) A > C > B > D (D) D > B > A > C
(E) For l = 5, there will be a total of 9 orbital.
Which of the above statements are correct?
[45] The de Broglie wavelength of a car of mass 1000 kg and velocity 36 km/hr is
Page No : 3
(A) 6.626 × 10−34 m (B) 6.626 × 10−38 m (A) (B)
(C) 6.626 × 10−31 m (D) 6.626 × 10−30 m

Statement I : Rutherford's gold foil experiment cannot explain the line spec-
trum of hydrogen atom.
Statement II : Bohr'smodel of hydrogen atom contradicts Heisenberg's uncer-
tainty principle.
In the light of the above statements, choose the most appropriate answer from
the options given below :
(A) Statement I is false but statement II is true.

(B) Both statement I and statement II are false.
(C) (D)
(C) Statement I is true but statement II is false.
(D) Both statement I and statement II are true.
[47] Which one of the following sets of ions represents a collection of isoelectronic
species?
(Given : Atomic Number: F :9, Cl : 17, N a = 11, M g = 12, Al = 13, K =
19, Ca = 20, Sc = 21 )
(A) Ci+ , N a+ , M g 2+ , Ca2+ (B) Ba2+ , Sr 2+ , K+, Ca2+
(C) N 3− , O 2− , F, S 2− (D) K + , Cl− , Ca2+ , Sc3+
[48] Identify the incorrect statement from the following.

[53] If λ0 and λ be threshold wavelength and wavelength of incident light, the ve-
(A) A circular path around the nucleus in which an electron moves is proposed locity of photoelectron ejected from the metal surface is
as Bohr's orbit. √ √
(A) 2h
(λ0 − λ) (B) 2hc
(λ0 − λ)
(B) An orbital is the one electron wave function (Ψ) in an atom.
m m
√ ( ) √ ( )
2hc λ0 −λ
(C) (D) 2h 1
−λ 1
(C) The existence of Bohr's orbits is supported by hydrogen spectrum. m λλ
0 m λ0
(D) Atomic orbital is characterised by the quantum numbers n and l only

[54] Match List − I with List − II.
[49] The difference between the radii of 3rd and 4th orbits of Li2+ is ∆R1 . The List − I List − II
difference between the radii of 3rd and 4th orbits of He+ is ∆R2 . Ratio (A) ΨM O = ΨA − ΨB (I) Dipole moment
∆R1 : ∆R2 is : (B) µ = Q × I (II) Bonding molecular
orbital
(A) 8 : 3 (B) 3 : 2
Nb −Na
(C) 2
(III) Anti-bonding
(C) 3 : 8 (D) 2 : 3 molecualr orbital
(D) ΨM O = ΨA +ΨB (IV ) Bond order
[50] The radius of the 2nd orbit of Li2+ is x. The expected radius of the 3rd orbit
of Be3+ is (A) (A) − (II), (B) − (I), (C) − (IV ), (D) − (III)
(A) 9
x (B) 4
x (B) (A) − (III), (B) − (IV ), (C) − (I), (D) − (II)
4 9
(C) 27
x (D) 16
x (C) (A) − (III), (B) − (I), (C) − (IV ), (D) − (II)
16 27
(D) (A) − (III), (B) − (IV ), (C) − (II), (D) − (I)
[51] The correct decreasing order of energy, for the orbitals having, following set of
quantum numbers. [55] Consider the hypothetical situation where the azimuthal quantum number, l,
(A) n = 3, 1 = 0, m = 0 takes values 0 , 1, 2, . . . . . . n + 1, where n is the principal quantum number.
Then, the element with atomic number
(B) n = 4, 1 = 0, m = 0
(C) n = 3, 1 = 1, m = 0 (A) 13 has a half−filled valence subshell
(D) n = 3, 1 = 2, m = 1
(B) 9 is the first alkali metal
(A) (D) > (B) > (C) > (A) (B) (B) > (D) > (C) > (A)
(C) 8 is the first noble gas
(C) (C) > (B) > (D) > (A) (D) (B) > (C) > (D) > (A) (D) 6 has a 2p− valence subshell
[56] If the Thomson model of the atom was correct, then the result of Rutherford's
[52] Which of the graphs shown below does not represent the relationship between gold foil experiment would have been:
incident light and the electron ejected from metal surface?
(A) α-Particles pass through the gold foil deflected by small angles and with
reduced speed.
(B) All α-particles get bounced back by 180◦ .
(C) α-Particles are deflected over a wide range of angles.
(D) All of the α-particles pass through the gold foil without decrease in speed
[57] Which of the following combination of statements is true regarding the inter-
pretation of the atomic orbitals?
(1) An electron in an orbital of high angular momentum stays away from the
nucleus than an electron in the orbital of lower angular momentum.
(2) For a given value of the principal quantum number, the size of the orbit is
inversely proportional to the azimuthal quantum number
(3) According to wave mechanics, the ground state angular momentum is equal
to 2π
h
(4) The plot of Ψ V s r for various azimuthal quantum numbers, shows peak
shifting towards higher r value
Page No : 4
(A) (1), (3) (B) (1), (2) (A) Splitting of spectral lines in electrical field is called Stark effect
(B) Frequency of emitted radiation from a black body goes from a lower wave-
(C) (1), (4) (D) (2), (3) length to higher wavelength as the temperature increases
(C) Photon has momentum as well as wavelength
Statement I : Bohr's theory accounts for the stability and line spectrum of Li+ (D) Rydberg constant has unit of energy
ion.
Statement II : Bohr's theory was unable to explain the splitting of spectral lines [61] Given below are two statements.
in the presence of a magnetic field. Statement I : According to Bohr's model of an atom, qualitatively the magni-
In the light of the above statements, choose the most appropriate answer from tude of velocity of electron increases with decrease in positive charges on the
the options given below: nucleus as there is no strong hold on the electron by the nucleus.
Statement II : According to Bohr's model of an atom, qualitatively the magni-
(A) Both statement I and statement II are true. tude of velocity of electron increases with decrease in principal quantum num-
ber.
(B) Statement I is false but statement II is true. In the light of the above statements, choose the most appropriate answer from
(C) Both statement I and statement II are false.
(A) Both Statement I and Statement II are false
(D) Statement I is true but statement II is false.
(B) Both Statement I and Statement II are true
[59] The plots of radial distribution functions for various orbitals of hydrogen atom
against r are given below
′ ′
(C) Statement I is false but Statement II is true
image
The correct plot for 3 s orbital is (D) Statement I is true but Statement II is false
[62] The de Broglie wavelength (λ) associated with a photoelectron varies with the
frequency (v) of the incident radiation as, [v0 is threshold frequency]:
(A) λ ∝ 1
(v−v0 )
(B) λ ∝ 1
1
(v−v0 ) 4
(C) λ ∝ 1
3 (D) λ ∝ 1
1
(v−v0 ) 2 (v−v0 ) 2
[63] The de-Broglie's wavelength of electron present in first Bohr orbit of ′ H ′ atom
is
o o
(A) 4 × 0.529 A (B) 2π × 0.529 A
o o
(C) 0.529
2π A (D) 0.529 A
[64] The number of orbitals with n = 5, ml = +2 is ...... . (Round off to the Nearest
Integer)
(A) 3 (B) 2
(C) 1 (D) 0
[65] If m and e are the mass and charge of the revolving electron in the orbit of
radius r for hydrogen atom, the total energy of the revolving electron will be
1 e2 2
(A) 2 r
(B) − er
me2 e2
(C) r
(D) − 12 r
[66] Which of the following sets of quantum numbers is not allowed?
(A) n = 3, 1 = 2, m1 = 0, s = + 12
(B) n = 3, 1 = 2, m1 = −2, s = + 12
(C) n = 3, 1 = 3, m1 = −3, s = − 12
(D) n = 3, 1 = 0, m1 = 0, s = − 12
[67] A metal surface is exposed to 500 nm radiation. The threshold frequency of

the metal for photoelectric current is 4.3 × 1014 Hz. The velocity of ejected
electron is ....... × 105 ms−1 (Nearest integer) ]
[Use : h = 6.63 × 10−34 Js, me = 9.0 × 10−31 kg
(A) 7 (B) 5
(C) 1 (D) 500

(A) (B) (B) (A)
[68] Ionization energy of gaseous N a atoms is 495.5 kJ mol−1 . The lowest
(C) (D) (D) (C) possible frequency of light that ionizes a sodium atom is (h = 6.626 ×
10−34 Js, NA = 6.022 × 1023 mol−1 )
[60] Which of the following statements is false?
(A) 7.50 × 104 s−1 (B) 4.76 × 1014 s−1
(C) 3.15 × 1015 s−1 (D) 1.24 × 1015 s−1
Page No : 5
[69] When light of wavelength 248 nm falls on a metal of threshold energy 3.0 eV , [76] The electrons are more likely to be found
the de-Broglie wavelength of emitted electrons is ............. Å
(Round √
off to the Nearest Integer).
[Use : 3 = 1.73, h = 6.63 × 10]−34 Js me = 9.1 × 10−31 kg; c =
3.0 × 108 ms−1 1eV = 1.6 × 10−19 J
(A) 7 (B) 9
(C) 12 (D) 18
[70] At temperature T , the average kinetic energy of any particle is 3

2
KT . The de
Broglie wavelength follows the order
(A) in the region a and b (B) in the region a and c
(A) Visible photon > Thermal neutron > Thermal electron
(C) only in the region a (D) only in the region c
(B) Thermal proton > Thermal electron > Visible photon
(C) Thermal proton > Visible photon > Thermal electron [77] Consider the following set of quantum numbers
(D) Visible photon > Thermal electron > Thermal neutron n l ml
A 3 3 −3
[71] The most abundant elements by mass in the body of a healthy human adult are B 3 2 −2
:
Oxygen (61.4%); Carbon (22.9%), Hydrogen (10.0%); and Nitrogen (2.6%). C 2 1 +1
The weight which a 75 kg person would gain if all 1 H atoms are replaced by D 2 2 +2
2 H atoms is ....... kg
The number of correct sets of quantum numbers is ..... .
(A) 15 (B) 37.5
(A) 4 (B) 1
(C) 7.5 (D) 10
(C) 2 (D) 3
[72] Which of the following pair is not isoelectronic species? (At. no.
Sm, 62; Er, 68 : Y b, 70 : Lu, 71; Eu, 63 : T b, 65; Tm, 69) [78] If the radius of the 3rd Bohr's orbit of hydrogen atom is r3 and the radius of 4th
Bohr's orbit is r4 . Then ....
(A) Sm2+ and Er3+ (B) Y b2+ and Lu3+
(A) r4 = 9
r
16 3
(B) r4 = 16
r
9 3
(C) Eu2+ and T b4+ (D) T b2+ and T m4+ (C) r4 = 3

r (D) r4 = 4
r
4 3 3 3
[73] The energy of an electron in the first Bohr orbit of hydrogen atom is −2.18 × [79] The number of atomic orbitals from the following having 5 radial nodes is ........
10−18 J. Its energy in the third Bohr orbit is ......... 7s, 7p, 6s, 8p, 8d
(A) 1
27
of this value (B) One third of this value (A) 3 (B) 2
(C) Three times of this value (D) 1

9
th of this value (C) 1 (D) 4
[74] The quantum number of four electrons are given below [80] The ground state energy of hydrogen atom is −13.6 eV . The energy of second
I.n = 4, l = 2, ml = −2, ms = −1/2 excited state of He+ ion in eV is
II.n = 3, l = 2, ml = 1, ms = +1/2
III.n = 4, l = 1, ml = 0, ms = +1/2 (A) −54.4 (B) −3.4
IV.n = 3, l = 1, ml = 1; ms = −1/2
The correct order of their increasing energies will be (C) −6.04 (D) −27.2
(A) I < III < II < IV (B) I < II < III < IV
[81] Outermost electronic configurations of four elements A, B, C, D are given be-
(C) IV < II < III < I (D) IV < III < II < I low.
3s2
3s2 3p1
[75] The wave number of the first emission line in the Balmer series of H− Spectrum 3s2 3p3
is ( R = Rydberg constant) 3s2 3p4
The correct order of first ionization enthalpy for them is.
(A) 365
R (B) 400
9
R
(A) (A) < (B) < (C) < (D) (B) (B) < (A) < (D) < (C)
(C) 76 R (D) 34 R
(C) (B) < (D) < (A) < (C) (D) (B) < (A) < (C) < (D)

Chemistry - Section B - NUMERIC

[85] A certain orbital has n = 4 and mL = −3. The number of radial nodes in this
[82] A proton and a Li3+ nucleus are accelerated by the same potential. If λLi and orbital is .......... (Round off to the Nearest Integer).
λP denote the de Broglie wavelengths of Li3+ and proton respectively, then [86] The minimum uncertainty in the speed of an electron in an one dimensional
the value of λλLi is x × 10−1 .The value of x is ............ region of length 2ao
P (Where a0 = Bohr radius 52.9pm ) is kms−1
(Rounded off to the nearest integer)
(Given : Mass of electron = 9.1 × 10−31 kg, Planck's constant h = 6.63 ×
(Mass of Li 3+ = 8.3 mass of proton)
10−34 Js )
o
[83] The radius of the second Bohr orbit for hydrogen atom is .......... A [87] The number of subshells associated with n = 4 and m = −2 quantum numbers
(Plank's const. h = 6. × 10−34 Js ; mass of electron = 9.1091 × 10−31 kg ; is :
charge of electron e = 1.60210 × 10−19 C ; permittivity of vaccum ϵ0 = [88] An accelerated electron has a speed of 5 × 106 ms−1 with an uncertainty of
8.854185 × 10−12 kg −1 m−3 A2 ) 0.02 %. The uncertainty in finding its location while in motion is x × 10−9 m.
[84] Consider an imaginary ion 48 X 3− . The nucleus contains 'a'% more neutrons The value of x is ...... (Nearest integer) ]
[Use mass of electron = 9.1 × 10−31 kg, h = 6.63 × 10−34 J s, π = 3.14
22
than the number of electrons in the ion. The value of 'a' is ..... [nearest integer]
Page No : 6
[89] A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The [109] The number of incorrect statement /s about the black body from the follow-
number of photons emitted per second by the bulb is x × 1020 . The value of x ing is .........
is ...... . ] (A) Emit or absorb energy in the form of electromagnetic radiation
[ Given : h = 6.63 × 10 −34 Js and c = 3.0 × 10 ms
8 −1
(B) Frequency distribution of the emitted radiation depends on temperature
(C) At a given temperature, intensity vs frequency curve passes through a max-
[90] The total number of isoelectronic species from the given set is .......
2− − 2+ + + 3+ imum value
O , F , Al, M g , N a , O , M g, Al , F (D) The maximum of the intensity vs frequency curve is at a higher frequency
[91] If the work function of a metal is 6.63 × 10−19 J, the maximum wavelength at higher temperature compared to that at lower temperature
of the photon required to remove a photoelectron from the metal is .... nm. [110] The longest wavelength of light that can be used for the ionisation of lithium
(Nearest integer) atom (Li) in its ground state is x × 10−8 m. The value of x is ..... (Nearest In-
[Given : h = 6.63 × 10−34 J s, and c = 3 × 108 m s−1 ] teger)
[92] The total number of orbitals associated with the principal quantum number 5 (Given : Energy of the electron in the first shell of the hydrogen atom is
is −2.2 × 10−18 J; h = 6.63 × 10−34 Js and c = 3 × 108 ms−1 )
[93] The minimum energy that must be possessed by photons in order to produce [111] Following figure shows spectrum of an ideal black body at four different tem-
the photoelectric effect with platinum metal is .... × 10−19 J peratures. The number of correct statement/s from the following is ...............
[Given: The threshold frequency of platinum is 1.3 ×1015 s−1 and h = 6.6 × A. T4 > T3 > T2 > T1
10−34 J s.] B. The black body consists of particles performing simple harmonic motion.
C. The peak of the spectrum shifts to shorter wavelength as temperature in-
[94] Ejection of the photoelectron from metal in the photoelectric effect experi- creases.
ment can be stopped by applying 0.5 V when the radiation of 250 nm is used. D. T 1
v1
= Tv2
2
= T3
v3
̸= constant
The work function of the metal is ................ eV E. The given spectrum could be explained using quantisation of energy.
[95] If the uncertainty
( in)velocity and position of a minute particle in space are,
2.4 × 10−26 m s−1 and 10−7 (m) respectively. The mass of the particle in g
is .... (Nearest integer)
(Given : h = 6.626 × 10−34 Js )
o
[96] What is the work function of the metal if the light of wavelength 4000 A gen-
erates photoelectrons of velocity 6 × 105 ms−1 from it? ............. eV (Mass of
electron = 9 × 10−31 kg Velocity of light = 3 × 108 ms−1 Planck's constant
= 6.626 × 10−34 Js Charge of electron = 1.6 × 10−19 J eV −1 )
[97] The wavelength of electrons accelerated from rest through a potential differ-
ence of 40 kV is X × 10−12 m. The value of x is ....... (Nearest integer)
Given : Mass of electrons = 9.1 × 10−31 kg
Charge on an electron = 1.6 × 10−19 C
Planck's constant = 6.63 × 10−34 Js
[98] The energy of one mole of photons of radiation of frequency 2 × 1012 Hz
in Jmol−1 is .....(Nearest) integer) (Given: h = 6.626 × 10−34 JS
NA = 6.022 × 1023 mol−1 [112] The orbital angular momentum of an electron in 3s orbital is xh . The value of.x
2π
[99] The number of significant figures in 0.00340 is ...... is ...........
[113] The energy of one mole of photons of radiation of wavelength 300nm is ......
[100] Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6Å. The kJ mol−1 .
radius of the third Bohr orbit of He is .................. picometer. (Nearest Integer)
+
(Given : h = 6.63 × 10−34 Js, NA = 6.02 × 1023 mol−1 , c = 3 × 108 ms−1 )
[101] If the de Brogile wavelength of the electron in nth Bohr orbit in a hydrogenic [114] A source of monochromatic radiation of wavelength 400 nm provides 1000 J
atom is equal to 1.5 πa0 ( a0 is Bohr radius), then the value of n/z is of energy in 10 seconds. When this radiation falls on the surface of sodium,
[102] Maximum number of electrons that can be accommodated in shell with n = 4 x × 1020 electrons are ejected per second. Assume that wavelength 400 nm is
are: sufficient for ejection of electron ( from the surface of) sodium metal. The value
of x is ....... (Nearest integer) h = 6.626 × 10−34 Js
[103] If the wavelength for an electron emitted from H atom is 3.3 × 10 −10 m, then
energy absorbed by the electron in its ground state compared to minimum en- [115] The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom
ergy required for its escape from the atom, is .......times. (Nearest integer). h2
is equal to xma 2 . The value of 10x is ........ . (a0 is radius of Bohr's orbit) (Nearest
[Given : h = 6.626 × 10−34 Js,Mass of electron = 9.1 × 10−31 ] 0
integer) [Given : π = 3.14]
[104] The electron in the nth orbit of Li2+ is excited to (n + 1) orbit using the ra-
diation of energy 1.47 × 10−17 J (as shown in the diagram). The value of n is [116] The value of magnetic quantum number of the outermost electron of Zn ion
+
.....Given RH = 2.18 × 10 −18 J is ..... .

[117] The number of photons emitted by a monochromatic (single frequency) in-
frared range finder of power 1 mW and wavelength of 1000 nm, in 0.1 second
is x × 1013 . The value of x is ..... .
(Nearest
( integer) )
h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1
[118] The number of orbitals associated with quantum numbers n = 5, ms = + 21
is
[119] The wavelength of an electron of kinetic energy 4.50 × 10−29 J is . . . .. ×
[105] The number of s-electrons present in an ion with 55 protons in its unipositive 10−5 m. (Nearest integer)Given : mass of electron is 9 × 10−31 kg, h = 6.6×
state is
10−34 Js
[106] Electromagnetic radiation of wavelength 663 nm is just sufficient to ionise
[120] The number of following statement/s which is/are incorrect is
the atom of metal A. The ionization energy of metal A in kJ mol−1 is ...... . (A) Line emission spectra are used to study the electronic structure
(Rounded-off to the nearest integer)
[ ] (B) The emission spectra of atoms in the gas phase show a continuous spread
h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1 , NA = 6.02 × 1023 mol−1 of wavelength from red to violet
[107] The wavelength of an electron and a neutron will become equal when the ve- (C) An absorption spectrum is like the photographic negative of an emission
locity of the electron is x times the velocity of neutron. The value of x is (Nearest spectrum
Integer)(Mass of electron is 9.1×10−31 kg and mass of neutron is 1.6×10−27 kg (D) The element helium was discovered in the sun by spectroscopic method
) [121] Which of the following is the energy of a possible excited state of hydrogen ?
[108] The number of correct statements from the following ............ eV
A. For 1 s orbital, the probability density is maximum at the nucleus.
B. For 2s orbital, the probability density first increases to maximum and then
decreases sharply to zero.
C. Boundary surface diagrams of the orbitals encloses a region of 100% proba-
bility of finding the electron.
D. p and d-orbitals have 1 and 2 angular nodes respectively.
E. Probability density of p-orbital is zero at the nucleus.
Page No : 7
InfinIITy Academy
Subject : Che Paper Set : 1
Standard : 11 JEE Main_ PYQs _Mole concept (Answer Key) Date : 19-07-2023


1-A 2-B 3-B 4-D 5-B 6-C 7-C 8-A 9-C 10 - A
11 - A 12 - C 13 - B 14 - D 15 - D 16 - D 17 - A 18 - A 19 - A 20 - B
21 - B 22 - C 23 - D 24 - B 25 - A 26 - D 27 - A 28 - A 29 - A 30 - D
31 - D 32 - A 33 - C 34 - D 35 - B 36 - C 37 - B 38 - A 39 - C 40 - B
41 - B 42 - B 43 - C 44 - B 45 - B 46 - D 47 - D 48 - D 49 - D 50 - C
51 - A 52 - C 53 - C 54 - C 55 - C 56 - A 57 - A 58 - B 59 - C 60 - B
61 - C 62 - D 63 - B 64 - A 65 - D 66 - C 67 - B 68 - D 69 - B 70 - D
71 - C 72 - D 73 - D 74 - C 75 - A 76 - B 77 - C 78 - B 79 - A 80 - C
81 - B


82 - 2 83 - 2.12 84 - 4 85 - 0 86 - 548 87 - 2 88 - 58 89 - 2 90 - 5 91 - 300
92 - 25 93 - 8.58 94 - 4.5 95 - 22 96 - 2.1 97 - 6 98 - 798 99 - 3 100 - 270 101 - 0.75
102 - 32 103 - 2 104 - 1 105 - 10 106 - 180 107 - 1758 108 - 3 109 - 0 110 - 4 111 - 2
112 - 0 113 - 399 114 - 2 115 - 3155 116 - 0 117 - 50 118 - 25 119 - 7 120 - 1 121 - −3.4
Page No : 8
InfinIITy Academy
Subject : Che Paper Set : 1
Standard : 11 JEE Main_ PYQs _Mole concept (Solutions) Date : 19-07-2023


[1] Which transition in the hydrogen spectrum would have the same wavelength (A) Br − and Be2+ (B) Cl− and Li+
as the Balmer type transition from n = 4 to n = 2 of He+ spectrum
[ JEE MAIN 2023 ] (C) S 2− and K + (D) O2− and M g 2+
(A) n = 2 to n = 1 (B) n = 1 to n = 3
Solution:[ Correct Answer : D ]
(C) n = 1 to n = 2 (D) n = 3 to n = 4
Isoelectronic species have same no. of electrons Al+3 , O 2− , M g +2 all
have 10 electrons.
Solution:[ Correct Answer : A ]
[5] Given
He+ ion : [ ] (A) n = 5, ml = +1
(B) n = 2, l = 1, ml = −1, ms = −1/2
1
= R(1)2 1
− 1
λ(H) n2 n2 The maximum number of electron(s) in an atom that can have the quantum
] [1 2
numbers as given in (A) and (B) are respectively
1
= R(2)2 212 − 412 [ JEE MAIN 2013 ]
λ(He+ )
( )
Given λ(H) = λ He+
[ ] [ ] (A) 25 and 1 (B) 8 and 1
R(1)2 n12 − n12 = R(4) 212 − 1
42
1 2
(C) 2 and 4 (D) 4 and 1
1
n2
− 1
n2
= 1
12
− 1
22
1 2
On comparing n1 = 1 and n2 = 2
Solution:[ Correct Answer : B ]
[2] The shortest wavelength of hydrogen atom in Lyman series is λ. The longest
wavelength in Balmer series of He+ is (i) n = 5 means l = 0, 1, 2, 3, 4
[ JEE MAIN 2023 ]
since m = +1
(A) 5
(B) 9λ hence total no. of electrons will be = 0 (from s) +2 (from p) +2 (fron d) +2
9λ 5
(from f ) +2 (from g)
(C) 36λ
(D) 5λ =0+2+2+2+2=8
5 9
(ii) n = 2, l = 1, ml = −1, ms = −1/2 represent 2p orbital with one
electron
( ) [6] The graph between |ψ|2 and r(radial distance) is shown below. This represents
[ JEE MAIN 2019 ]
For H : λ
1
= RH × 12 112 − ∞12
( )
λ
1
= RH × 22 × 14 − 19
He+
λHe+
From (1) and (2) λ
= 9
5
λHe+ = λ × 95
λHe+ = 9λ 5
[3] Consider the following pairs of electrons

(A) (a) n = 3, 1 = 1, ml = 1, ms = + 12
(b) n = 3, 1 = 2, ml = 1, ms = + 12
(B) (a) n = 3, 1 = 2, ml = −2, ms = − 21
(b) n = 3, 1 = 2, ml = −1, ms = − 12
(C) (a) n = 4, 1 = 2, ml = 2, ms = + 12
(b) n = 3, 1 = 2, ml = 2, ms = + 12 (A) 1s orbital (B) 3s orbital
The pairs of electron present in degenerate orbitals is/are...... .
[ JEE MAIN 2022 ] (C) 2s orbital (D) 2p orbital
(A) Only A (B) Only B
(C) Only C (D) (B) and (C)
Based on ′ n + 1′ rule only (B) has pair of electron in degenerate or-

bitals
[4] The pair, in which ions are isoelectronic with Al3+ is ..... .
[ JEE MAIN 2022 ]
Page No : 9
Solution:[ Correct Answer : C ] Solution:[ Correct Answer : C ]
As we know ∆E = hc λ
So λ = ∆E hc
for λ minimum i.e.
shortest; ∆E = maximum
for Lyman series n = 1& for ∆Emax
Transition must be(form n = ∞
) to n = 1
So 1
λ
= RH Z 2 1
n2
− 1
n2
3
1 2
1
λ
= RH − 0)
Z 2 (1
1
λ
= R × (1)2 ⇒ λ1 = R 1
For longest wavelength ∆E = minimum for Balmer series n = 3 to n = 2 will

have ∆E minimum
As we know that for s− orbital graph start from top and no. of radial node for He+ Z = 2 ( )
= n − l − 1 For 2s orbital it will = 2 − 0 − 1 = 1 So λ1 = RH × Z 2 n12 − n12
∴ The graph is of 2s 2
( )1 2
1
= RH × 4 41 − 91
[7] If p is the momentum of the fastest electron ejected from a metal surface after
λ2
the irradiation of light having wavelength λ, then for 1.5 p momentum of the
1
λ2
= RH × 5
9
photoelectron, the wavelength of the light should be: (Assume kinetic energy λ2 = λ1 × 9
of ejected photoelectron to be very high in comparison to work function)
5
[ JEE MAIN 2019 ] [10] Based on the equation ( )
(A) 3
4
λ (B) 1
2
λ ∆E = −2.0 × 10−18 J n12 − 1
n2
2 1
the wavelength of the light that must be absorbed to excite hydrogen electron
(C) 4
λ (D) 2
λ
9 3 from level n = 1 to level n = 2 will be: (h = 6.625 × 10−34 J s, C =
3 × 108 m s−1 )
[ JEE MAIN 2014 ]
Solution:[ Correct Answer : C ]
(A) 1.325 × 10−7 m (B) 1.325 × 10−10 m
1 1 m2 u2 1 P2
K.E = 2
mu2 = 2 m
= 2 m
(C) 2.650 × 10−7 m (D) 5.300 × 10−10 m
2
hc
λ1
= W o + (K.E)1 = W o + 12 Pm
hc (1.5P )2
λ2
= W o + (K.E)2 = W o + 12 m
On solving Solution:[ Correct Answer : A ]
λ2 = 94 λ1 ( )
Since the K.E is very high is comparison to work function, then we can assume ∆E = −2.0 × 10−18 × 212 − 1
12
that K.E + W o = K.E = −2.0 × 10−18 × −3
4
[8] Given below are two statements: = 1.5 × 10−18
Statement I : According to Bohr's model of hydrogen atom, the angular mo- ∆E = hcλ
mentum of an electron in a given stationary state is quantised. hc 6.6×10−34 ×3×108
Statement II : The concept of electron in Bohr's orbit, violates the Heisenberg λ= ∆E
= 1.5×10−18
uncertainty principle. = 1.325 × 10−7 m
In the light of the above statements, choose the most appropriate answer from ( 2)
the options given below: [11] Energy of an electron is given by E = −2.178 × 10−18 J Z . Wavelength
[ JEE MAIN 2023 ] n2
of light required to excite an electron in an hydrogen atom from level n = 1 to
(A) Both Statement I and Statement II are correct. n = 2 will be :
(h = 6.62 × 10−34 Js and c = 3.0 × 108 ms−1 )
(B) Statement I is correct but Statement II is incorrect. [ JEE MAIN 2013 ]
(C) Statement I is incorrect but Statement II is correct (A) 1.214 × 10−7 m (B) 2.816 × 10−7 m
(D) Both Statement I and Statement II are incorrect.
(C) 6.500 × 10−7 m (D) 8.500 × 10−7 m
According to Bohr's model the angular momentum is quantised and equal to
nh
.
2π Let λ is the wavelength of that photon then
Heisenberg uncertainty principle explains orbital concept, which is based on
hc/λ = E2 − E1 [ ]
probability of finding electron.
and using value of given E, E = hc
λ
= 2.178 × 10−18 × z 2 1
12
− 1
22
(z = 1)
[9] The shortest wavelength of H atom is the Lyman series is λ1 . The longest wave- 6.62×10−34 ×3×108
length in the Balmer series of He+ is : ∴λ= 2.178×10−18
× 4
3
= 1.214 × 10−7 m
[ JEE MAIN 2020 ]
[12] Excited hydrogen atom emits light in the ultraviolet region at 2.47 × 1015 Hz.
(A) 5λ1
9
(B) 27λ1
5
With this frequency, the energy of a single photon is (h = 6.63 × 10−34 Js)
[ JEE MAIN 2014 ]
(C) 9λ1
(D) 36λ1
5 5 (A) 8.041 × 10−40 J (B) 2.680 × 10−19 J
(C) 1.640 × 10−18 J (D) 6.111 × 10−17 J
E = hv
= 6.63 × 10−34 × 2.47 × 1015
= 1.640 × 10−18 J
[13] Which of the following is the correct plot for the probability density ψ 2 (r) as a
function of distance ' r ' of the electron form the nucleus for 2s orbital?
[ JEE MAIN 2022 ]
Page No : 10
(A) (B)
Energy of orbitals decreases on increasing the atomic number.
[18] The de-Broglie wavelength of a particle of mass 6.63 g moving with a velocity
of 100 ms−1 is
[ JEE MAIN 2014 ]
(A) 10−33 m (B) 10−35 m
(C) 10−31 m (D) 10−25 m

(C) (D)
De Broglie wavelength (λ) = h

mv
6.63×10−34
6.63×10−3 ×100
= 10−33 m
[19] The de Broglie wavelength of an electron in the 4th Bohr orbit is

[ JEE MAIN 2020 ]
(A) 8πa0 (B) 2πa0
(C) 4πa0 (D) 6πa0

For 2s, number of radial nodes = 2 − 0 − 1 = 1 and value of ψ 2 is al- Solution:[ Correct Answer : A ]
ways positive.
2πr = nλ
[14] The orbital having two radial as well as two angular nodes is
[ JEE MAIN 2021 ] for n = 1, r = a0
n = 4, r = 16a0
(A) 3p (B) 4f So, 2π × 16a0 = 4 × λ
λ = 8πa0
(C) 4d (D) 5d
[20] The electron in the hydrogen atom undergoes transition from higher orbitals
to orbital of radius 211.6 pm. This transition is associated with
[ JEE MAIN 2017 ]
(A) Lyman series (B) Balmer series
n−l−1=2
1=2 (C) Paschen series (D) Brackett series
n−2−1=2
n=5
[15] The radius of the second Bohr orbit, in terms of the Bohr radius, a0 , in Li2+ is
[ JEE MAIN 2020 ] n2
r = 0.529 × Z
(A) (B)
4a0 2a0 o
9 9 r = 211.6 pm = 2.11 A
2 o
(C) 2a0
(D) 4a0 ⇒ 0.529 × nZ = 2.11 A
3 3 n = 2 (Balmer series)
{ }
Solution:[ Correct Answer : D ] [21] For the Balmer series in the spectrum of H atom, v̄ = RH 1
− 1
,
n21 n22
rn = n ×a
2
0 the correct statements among (I) to (IV ) are
z (I) As wavelength decreases, the lines in the series converge
For 2nd Bohr orbit of Li+2 (II) The integer n1 is equal to 2
n=2 (III) The lines of longest wavelength corresponds to n2 = 3
z=3 2 (IV ) The ionization energy of hydrogen can be calculated from wave number
⇒ rn = 2 ×a 3
0
= 4a30 of these lines
[ JEE MAIN 2020 ]
[16] In the sixth period, the orbitals that are filled are
[ JEE MAIN 2020 ] (A) (II), (III), (IV ) (B) (I), (II), (III)
(A) 6s, 5f, 6d, 6p (B) 6s, 6p, 6d, 6f (C) (I), (III), (IV ) (D) (I), (II), (IV )
(C) 6s, 5d, 5f, 6p (D) 6s, 4f, 5d, 6p

Solution:[ Correct Answer : D ] For balmer : n1[ = 2, n2 =] 3, 4, 5, . . . ∞
As per (n + ℓ) rule in 6th period, order of orbitals filling is 6s, 4f, 5d, 6p v̄ = λ1
= RH 212 − n12
[ ]
2
[17] Given below are two statements. One is labelled as Assertion A and the other λ
1
= RH 212 − 312
longest
is labelled as Reason R.
Assertion A : Energy of 2s orbital of hydrogen atom is greater than that of 2 s [22] For any given series of spectral lines of atomic hydrogen, let ∆V̄ = ∆V̄max −
orbital of lithium. ∆V̄min be the difference in maximum and minimum frequencies in cm−1 . the
Reason R : Energies of the orbitals in the same subshell decrease with increase
in the atomic number. ration ∆V̄Lymann / ∆V̄Balmer is
In the light of the above statements, choose the correct answer from the op- [ JEE MAIN 2019 ]
tions given below.
[ JEE MAIN 2022 ] (A) 5 : 4 (B) 4 : 1
(A) Both A and R are true and R is the correct explanation of A. (C) 9 : 4 (D) 27 : 5
(B) Both A and R are true but R is NOT the correct explanation of A.
(C) A is true but R is false.
(D) A is false but R is true.
Page No : 11
Solution:[ Correct Answer : C ] Solution:[ Correct Answer : D ]
∆V̄Lymann = RH
4
For Lyman series (short wavelength)
∆V̄Balmer = 9 RH 2 =∞
n1 = 1, n( )
∆V̄
⇒ ∆V̄Lymann = 94
1
λ
= Rz 2 − n12
1
n2
Balmer ( 1 2
)
Formula [ ] ⇒ A1
= 12 R 11 − ∞ 1
⇒ A1
=R
V̄ = RH n12 − 1 Longest wavelength = 1st line
1 n22
n1 = 3, n(2 =4 )
[23] Which one of the following about an electron occupying the 1 s orbital in a hy-
drogen atom is incorrect? (The Bohr radius is represented by a0
1
λ
= Rz 2 1
32
− 412 ⇒ λ 1
= R7
36
[ JEE MAIN 2019 ] R= 1
A
1 ×7
(A) The electron can be found at a distance 2a0 from the nucleus 1
= A
⇒ 1
= 7
⇒λ= 36 A
λ 36 λ 36 A 7
(B) The probability density of finding the electron is maximum at the nucleus [27] The region in the electromagnetic spectrum where the Balmer series lines ap-
pear is
(C) The magnitude of potential energy is double that of its kinetic energy on [ JEE MAIN 2020 ]
an average
(A) Visible (B) Microwave
(D) The total energy of the electron is maximum when it is at a distance a0
from the nucleus
(C) Ultraviolet (D) Infrared
T.E = −K.E = P2E Solution:[ Correct Answer : A ]

The energy of electrons increases as they are away from the nucleus. The
probability of finding the 1s electron may be higher at a0 but the energy is not. Balmer series give visible lines For H−atom
The probability density of finding the electron is not zero at any place in the
atom. So, the energy may be higher when it is far from a0 [28] Heat treatment of muscular pain involves radiation of wavelength of about
900 nm. Which spectral line of H− atom is suitable for this purpose?
[24] A stream of electrons from a heated filaments was passed two charged plates [RH = 1 × 105 cm−1 , h = 6.6 × 10−34 Js c = 3 × 108 ms−1 ]
kept at a potential difference V esu. If e and m are charge and mass of an elec- [ JEE MAIN 2019 ]
tron, respectively, then the value of h/λ, (where λ is wavelength associated
with electron wave) is given by : (A) Paschen, ∞ → 3 (B) Paschen, 5 → 3
[ JEE MAIN 2016 ]
√ √ (C) Balmer, ∞ → 2 (D) Lyman, ∞ → 1
(A) meV (B) 2meV
(C) meV (D) 2meV Solution:[ Correct Answer : A ]

o
[i] 900 nm = 9000 A
Solution:[ Correct Answer : B ] It is in far infra red region hence paschen.
Kinetic energy = eV = 12 mu2 [29] The number of radial and angular nodes in 4d orbital are, respectively ........ .
√ [ JEE MAIN 2022 ]
2eV
u= m
Here, u is the velocity of the electron. (A) 1 and 2
The de broglie wavelength is λ = mu h
(B) 3 and 2
h
= mu
(C) 1 and 0
λ
Substitute
√ equation (1) in equation (2)
√
(D) 2 and 1
h 2eV
λ
=m m
= 2meV
[25] The ratio of the shortest wavelength of two spectral series of hydrogen spec- Solution:[ Correct Answer : A ]
trum is found to be about 9. The spectral series are
[ JEE MAIN 2019 ]
Radial node = n − l − 1
(A) Lyman and Paschen (B) Brackett and Pfund =4−2−1
=1
(C) Paschen and Pfund (D) Balmer and Brackett Angular node (l) = 2
[30] Given below are two statements: one is labelled as Assertion (A) and the other
Solution:[ Correct Answer : A ] is labelled as Reason(R) :
Assertion (A) : The ionic radii of O2− and M g 2+ are same.
( )
1 =RH 1 − 12 Z2
Reason (R) : Both O2− and M g 2+ are isoelectronic species.
λ2 n2
( 1
n2
) In the light of the above statements, choose the correct answer from the op-
1 =R 1 − 12 Z2 tions given below
[ JEE MAIN 2022 ]
H
λ1 n21 n2
As for shortest wavelength both n1 and n12 are ∞

λ1 n1 (A) Both (A) and (R) are true and (R) is the correct explanation of (A)
∴ λ2
= 9
1
= 1
n2
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A)
1
Now if = 3 and n1 is 1 it will justify the statement hence Lyman and
n11
Paschen is correct.
(C) (A) is true but (R) is false
[26] If the shortest wavelength in Lyman series of hydrogen atom is A, then the
(D) (A) is false but (R) is true
longest wavelength in Paschen series of He+ is
[ JEE MAIN 2017 ]
(A) 5A
9
(B) 9A
5
Ionic radius of O2− is more than that of M g 2+
(C) 36A
5
(D) 36A
7
Both O 2− and M g 2+ are isoelectronic with 10 electrons
[31] The wave function (Ψ) of 2s is given by

( )1/2 ( )
Ψ2s = √1 1
a0
2 − ar e−r/2a0
2 2π 0
At r = r0 , radial node is formed. Thus, r0 in terms of a0
[ JEE MAIN 2023 ]
Page No : 12
(A) r0 = a0 (B) r0 = 4a0
(C) r0 = a0
(D) r0 = 2a0
2
For emission [line nf < n ]i [ ]
∴ v̄ = RZ 2 1
− 1
= R 812 − 1
Solution:[ Correct Answer : D ] ( i
n2 n 2
f
)
n2
or, v̄ = RH 64 1
− n12
At node Ψ2s = 0
RH RH
∴ 2 − ar0 = 0 = −
0
64 (2 )
n
∴ r0 = 2a0 v̄ = −RH n12 + RH
64
[32] Given below are two statements: One is labelled as Assertion A and the other ∴ y = mx + c
is labelled as Reason R Slope = −RH
Assertion A : Zero orbital overlap is an out of phase overlap.
Reason R : It results due to different orientation/ direction of approach of or- [35] Given below are two statement: one is labelled as Assertion A and the other
bitals. is labelled as Reason R
In the light of the above statements. Choose the correct answer from the op- Assertion A : 5f electrons can participate in bonding to a far greater extent
tions given below. than 4f electrons
[ JEE MAIN 2022 ] Reason R : 5f orbitals are not as buried as 4f orbitals
In the light of the above statements, choose the correct answer from the op-
(A) Both A and R are true and R is the correct explanation of A tions given below
[ JEE MAIN 2023 ]
(B) Both A and R are true but R is N OT the correct explanation of A
(A) Both A and R are true but R is NOT the correct explanation of A
(C) A is true but R is false
(B) Both A and R are true and R is the correct explanation of A
(D) A is false but R is true
(C) A is false but R is true
(D) A is true but R is false
5f orbital not buried as 4f orbitals so e− present in 5f orbital experi-

ence less nuclear attraction than e− present in 4f orbital. Hence electrons of 5
f orbital can take part in bonding to a far greater extent.
[36] Consider the following statements:

(A) The principal quantum number ′ n′ is a positive integer with values of
′ n′ = 1, 2, 3, . . ..
(B) The azimuthal quantum number ′ l′ for a given ′ n′ (principal quantum num-
ber) can have values as ′ l′ = 0, 1, 2, . . . n
(C) Magnetic orbital quantum number ′ m′l for a particular ′ l′ (azimuthal quan-
tum number) has (2l + 1) values.
(D) ±1/2 are the two possible orientations of electron spin.
[33] According to Bohr's atomic theory :- (E) For l = 5, there will be a total of 9 orbital.
2
(A) Kinetic energy of electron is ∝ Z . Which of the above statements are correct?
n2 [ JEE MAIN 2022 ]
(B) The product of velocity (v) of electron and principal quantum number (n),
'vn' ∝ Z 2 . (A) (A), (B) and (C) (B) (A), (C), (D) and (E)
3
(C) Frequency of revolution of electron in an orbit is ∝ Z
n3
.
(D) Coulombic force of attraction on the electron is ∝ Z .
3
(C) (A), (C) and (D) (D) (A), (B), (C) and (D)
n4
Choose the most appropriate answer from the options given below :
[ JEE MAIN 2021 ]
(A) (C) Only (B) (A) Only
(A) Number of values of n = 1, 2, 3 . . . ∞
(C) (A), (C) and (D) only (D) (A) and (D) only (B) Number of values of ℓ = 0 to (n − 1)
(C) Number of values of m = −ℓ to +ℓ
Total values = 2ℓ + 1
Solution:[ Correct Answer : C ] (D) Values of spin = ± 12
(E) For ℓ = 5 number of orbitals = 2ℓ + 1 = 11
According to Bohr's theory :
z 2 eV z2 [37] A certain orbital has no angular nodes and two radial nodes. The orbital is
(A) KE = 13.6 n 2 atom ⇒ KEα n2 [ JEE MAIN 2021 ]
(B) speed of e α n
− z
∴ v × nαz (A) 2 s (B) 3 s

(C) Frequency of revolution of e− = v
2πr
∴ frequency α n
z 2
(C) 3 p (D) 2 p
3
2
{ 2
(D) F = kqr12q2 = kze
r2
rα nz
⇒ Fα( Z )
2 2
n
Z
3 1 = 0 ⇒ ′ s′ orbital
⇒ Fαn
z
4
n−l−1=2
[34] For emission line of(atomic n−1=2
) hydrogen from n1 = 8 to nf = n, the plot of wave n=3
number (v̄) against 1
n2
will be(The Rydberg constant, RH is in wave number
unit) [38] The correct set of four quantum numbers for the valence electrons of rubidium
[ JEE MAIN 2019 ] atom (Z = 37) is :
[ JEE MAIN 2014 ]
(A) Linear with intercept −RH (B) Non linear
(A) 5, 0, 0, + 12 (B) 5, 1, 0, + 12
(C) Linear with slope RH (D) Linear with slope −RH
(C) 5, 1, 1, + 12 (D) 5, 0, 1, + 12
Page No : 13
(A) D < B < A < C (B) D < A < B < C
(C) B < D < A < C (D) B < D < C < A
E.C. of Rubidium is (Z = 37) = 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s1
The valence electron is in 5s orbital.
Its 4 quantum numbers are- n = 5, l = 0, m = 0, s = + 12 Solution:[ Correct Answer : B ]
[39] According to molecular theory, the species among the following that does not Energy order of subshell decided by (n + λ) rule.
exist is
[ JEE MAIN 2021 ] A ⇒ 3d ⇒ n + 1 = 5
B ⇒ 4p ⇒ n + λ = 5
(A) He+
2 (B) He−
2 C ⇒ 4d ⇒ n + ℓ ⇒ 6
D ⇒ 3s ⇒ (n + ℓ) = 4
(C) Be2 (D) O22− D<A<B<C
[43] In an atom how many orbital (s) will have the quantum numbers; n = 3, l = 2
Solution:[ Correct Answer : C ] and ml = +2 ?
[ JEE MAIN 2013 ]
Chemical Species Bond Order (A) 5 (B) 3

He+ 0.5
2
(C) 1 (D) 7
He−
2 0.5
Be2 0 Solution:[ Correct Answer : C ]
O22− 1
According to M.O.T. If bond order of chemical species is zero then that
chemical species does not exist.
[40] Given below are two statements : one is labelled as Assertion A and the other
is labelled as Reason R:
Assertion A: In the photoelectric effect, the electrons are ejected from the n = 3, l = 2 means 3d orbital
metal surface as soon as the beam of light of frequency greater than thresh- i.e. in an atom only one orbital can have the value ml = +2
old frequency strikes the surface.
Reason R : When the photon of any energy strikes an electron in the atom, [44] Arrange the following orbitals in decreasing order of energy ?
transfer of energy from the photon to the electron takes place. (A) n = 3, 1 = 0, m = 0
In the light of the above statements, choose the most appropriate answer from (B) n = 4, l = 0, m = 0
the options given below : (C) n = 3, l = 1, m = 0
[ JEE MAIN 2023 ] (D) n = 3, l = 2, m = 1
The correct option for the order is :
(A) Both A and R are correct but R is NOT the correct explanation of A [ JEE MAIN 2023 ]
(B) A is correct but R is not correct (A) B > D > C > A (B) D > B > C > A
(C) Both A and R are correct and R is the correct explanation of A
(C) A > C > B > D (D) D > B > A > C
(D) A is not correct but R is correct
Solution:[ Correct Answer : B ] Solution:[ Correct Answer : B ]
There is a characteristic minimum frequency, or 'threshold frequency,' for (A) n = 3; 1 = 0; m = 0; 3s orbital

each metal below which the photoelectric effect is not seen. The ejected (B) n = 4; 1 = 0; m = 0; 4s orbital
electrons leave with a specific amount of kinetic energy at a frequency v > v0 (C) n = 3; 1 = 1; m = 0; 3p orbital
with an increase in light frequency of these electron kinetic energies also rise. (D) n = 3; 1 = 2; m = 0; 3d orbital
As per Hund's rule energy is given by (n + l) value.
[41] The heat of atomization of methane and ethane are 360 kJ/mol and If value of (n + l) remains same then energy is given by n only.
620 kJ/mol, respectively. The longest wavelength of light capable of break-
ing the C − C bond is (Avogadro number = 6.02 × 1023 , h = 6.62 × 10−34 Js [45] The de Broglie wavelength of a car of mass 1000 kg and velocity 36 km/hr is
) [ JEE MAIN 2013 ]
[ JEE MAIN 2015 ]
(A) 6.626 × 10−34 m (B) 6.626 × 10−38 m
(A) 2.48 × 104 nm (B) 1.49 × 103 nm
(C) 6.626 × 10−31 m (D) 6.626 × 10−30 m
(C) 2.48 × 103 nm (D) 1.49 × 104 nm

h
λ = mv
In CH4 , 4 × BE(C−H) = 360 kJ/mol
h = 6.6 × 10−34 J − s
∴ BE(C−H) = 90 kJ/mol
m = 1000 kg
In C2 H6 , BE(C−C) + 6 × BE(C−H) = 620 kJ/mol 3
∴ BE(C−C) = 80 kJ/mol v = 36 km/hr = 36×10
60×60
m/ sec = 10 m/ sec
6.6×10−34
∴ BE(C−C) = 80×103
J/molecule λ= 103 ×10
= 6.6 × 10−38 m
6.023×1023
Now, E = hc
λ [46] Given below are two statements:
−34
×3×108 ×6.023×1023 Statement I : Rutherford's gold foil experiment cannot explain the line spec-
∴ λ = 6.626×10 80×103 trum of hydrogen atom.
∴ λ = 1.419 × 103 nm Statement II : Bohr'smodel of hydrogen atom contradicts Heisenberg's uncer-
tainty principle.
[42] Given below are the quantum numbers for 4 electrons. In the light of the above statements, choose the most appropriate answer from
A. n = 3, l = 2, m1 = 1, ms = +1/2 the options given below :
B. n = 4, l = 1, m1 = 0, ms = +1/2 [ JEE MAIN 2021 ]
C. n = 4, l = 2, m1 = −2, ms = −1/2
D. n = 3, l = 1, m1 = −1, ms = +1/2 (A) Statement I is false but statement II is true.
The correct order of increasing energy is (B) Both statement I and statement II are false.
[ JEE MAIN 2022 ]
(C) Statement I is true but statement II is false.
(D) Both statement I and statement II are true.
Page No : 14
Solution:[ Correct Answer : D ] Solution:[ Correct Answer : A ]
Rutherford's gold foil experiment only proved that electrons are held to- (A) n + ℓ = 3 + 0 = 3
wards nucleus by electrostatic forces of attraction and move in circular orbits (B) n + ℓ = 4 + 0 = 4
with very high speeds. (C) n + ℓ = 3 + 1 = 4
Bohr's model gave exact formula for simultaneous calculation of speed & dis- (D) n + ℓ = 3 + 2 = 5
tance of electron from the nucleus, something which was deemed impossible Higher n + ℓ value, higher the energy & if same n + ℓ value, then higher n
according to Heisenberg. value, higher the energy.Thus: D > B > C > A.
[47] Which one of the following sets of ions represents a collection of isoelectronic [52] Which of the graphs shown below does not represent the relationship between
species? incident light and the electron ejected from metal surface?
(Given : Atomic Number: F :9, Cl : 17, N a = 11, M g = 12, Al = 13, K = [ JEE MAIN 2019 ]
19, Ca = 20, Sc = 21 )
[ JEE MAIN 2023 ] (A) (B)
(A) Ci+ , N a+ , M g 2+ , Ca2+ (B) Ba2+ , Sr 2+ , K+, Ca2+
(C) N 3− , O 2− , F, S 2− (D) K + , Cl− , Ca2+ , Sc3+
K + Cl1 Ca2+ Sc3+

18 18 18 18
[48] Identify the incorrect statement from the following.

[ JEE MAIN 2022 ]
(A) A circular path around the nucleus in which an electron moves is proposed
as Bohr's orbit. (C) (D)
(B) An orbital is the one electron wave function (Ψ) in an atom.
(C) The existence of Bohr's orbits is supported by hydrogen spectrum.

(D) Atomic orbital is characterised by the quantum numbers n and l only
Atomic orbital is characterised by n, l, m.
[49] The difference between the radii of 3rd and 4th orbits of Li2+ is ∆R1 . The
difference between the radii of 3rd and 4th orbits of He+ is ∆R2 . Ratio
∆R1 : ∆R2 is :
[ JEE MAIN 2020 ]
(A) 8 : 3 (B) 3 : 2
K.E = hv − hv0 , So (B) is not correct.
(C) 3 : 8 (D) 2 : 3
[53] If λ0 and λ be threshold wavelength and wavelength of incident light, the ve-
locity of photoelectron ejected from the metal surface is
Solution:[ Correct Answer : D ] [ JEE MAIN 2014 ]
√ √
42 2 (A) 2h
(λ0 − λ) (B) 2hc
(λ0 − λ)
(r4 −r3 )42+ − 33 m m
∆R1
= = 3
=
7/3
= 2 √ ( ) √ ( )
∆R2 (r4 −r3 )He+ 42 2
− 32 7/2 3
λ0 −λ
2 (C) 2hc
(D) 2h 1
−λ1
[50] The radius of the 2nd orbit of Li2+ is x. The expected radius of the 3rd orbit
m λλ0 m λ
0
of Be3+ is
[ JEE MAIN 2023 ]
(A) 9
4
x (B) 4
9
x
The kinetic enegry of the ejected electron is given by the equation
(C) 27
16
x (D) 16
27
x hv = hv0 + 12 mv 2 ∵ v = λc
or hc
λ
= λhc
+ 12 mv 2
0

1
mv 2 = hc − hc
2 ( λ ) λ0
λ0 −λ
= hc λλ
0 ( )
Li2+ 2 λ0 −λ
r2 = x = k × 23 = 4k ∴ v 2 = 2hc
m λλ0
2 √ ( )
Be3+ λ0 −λ
r3 = y = k × 34
2
or v = 2hc
m λλ0
y
x
= 94 × 34 = 27
16 [54] Match List − I with List − II.
y = 27
16
x List − I List − II
(A) ΨM O = ΨA − ΨB (I) Dipole moment
[51] The correct decreasing order of energy, for the orbitals having, following set of
quantum numbers. (B) µ = Q × I (II) Bonding molecular
(A) n = 3, 1 = 0, m = 0 orbital
(B) n = 4, 1 = 0, m = 0 (C) Nb −N
2
a
(III) Anti-bonding
(C) n = 3, 1 = 1, m = 0 molecualr orbital
(D) n = 3, 1 = 2, m = 1
[ JEE MAIN 2022 ] (D) ΨM O = ΨA +ΨB (IV ) Bond order
[ JEE MAIN 2022 ]
(A) (D) > (B) > (C) > (A) (B) (B) > (D) > (C) > (A)
(C) (C) > (B) > (D) > (A) (D) (B) > (C) > (D) > (A)
Page No : 15
(A) (A) − (II), (B) − (I), (C) − (IV ), (D) − (III) Statement I : Bohr's theory accounts for the stability and line spectrum of Li+
ion.
(B) (A) − (III), (B) − (IV ), (C) − (I), (D) − (II) Statement II : Bohr's theory was unable to explain the splitting of spectral lines
in the presence of a magnetic field.
(C) (A) − (III), (B) − (I), (C) − (IV ), (D) − (II) In the light of the above statements, choose the most appropriate answer from
[ JEE MAIN 2021 ]
(D) (A) − (III), (B) − (IV ), (C) − (II), (D) − (I)
(A) Both statement I and statement II are true.
(B) Statement I is false but statement II is true.
(A) ψM O = ψA − ψB (III) ABM O
(B) µ = Q × r (I) Dipole moment (C) Both statement I and statement II are false.
(C) Nb −N
2
2
(IV ) Bond order (D) Statement I is true but statement II is false.
(D) ψM O = ψA + ψB (II) BM O
[55] Consider the hypothetical situation where the azimuthal quantum number, l,
takes values 0 , 1, 2, . . . . . . n + 1, where n is the principal quantum number. Statement−I is false since Bohr's (theory accounts for the stability and
Then, the element with atomic number
[ JEE MAIN 2020 ] spectrum of single electronic species eg : He+ , Li2+ etc )
Statement−II is true.
(A) 13 has a half−filled valence subshell
[59] The plots of radial distribution functions for various orbitals of hydrogen atom
(B) 9 is the first alkali metal against ′ r′ are given below
image
(C) 8 is the first noble gas The correct plot for 3 s orbital is
[ JEE MAIN 2021 ]
(D) 6 has a 2p− valence subshell
l = 0 to (n + 1)
n=1 n=2
l = 0, 1, 2 l = 0, 1, 2, 3
1p 1d 2s 2p 2d 2f
(n + l) ⇒ 1s 1 2 3 2 3 4 5
n=3
l = 0, 1, 2, 3, 4
3s 3p 3d 3f 3g
3 4 5 6 7
Now, in order to write electronic configuration, we need to apply (n + l) rule
Energy order : 1s < 1p < 2s < 1d < 2p < 3s < 2d
Option 1) 13 : 1s2 1p6 2s2 1d3 is not half filled
Option 2) 9 : 1s2 1p6 2s1 is the first alkali metal because after losing one
electron, it will achieve first noble gas configuration
Option 3) 8 : 1s2 1p6 is the first noble gas because after 1p6 e− will
Option 4) 6 : 1s2 1p4 has 1p valence subshell.
[56] If the Thomson model of the atom was correct, then the result of Rutherford's
gold foil experiment would have been:
[ JEE MAIN 2021 ]
(A) α-Particles pass through the gold foil deflected by small angles and with
reduced speed.
(B) All α-particles get bounced back by 180◦ .
(C) α-Particles are deflected over a wide range of angles.
(D) All of the α-particles pass through the gold foil without decrease in speed
As in Thomson model, protons are diffused (charge is not centered) α-

particles deviate by small angles and due to repulsion from protons, their
speeddecreases.
[57] Which of the following combination of statements is true regarding the inter-
pretation of the atomic orbitals?
(1) An electron in an orbital of high angular momentum stays away from the
nucleus than an electron in the orbital of lower angular momentum.
(2) For a given value of the principal quantum number, the size of the orbit is
inversely proportional to the azimuthal quantum number
(3) According to wave mechanics, the ground state angular momentum is equal
to 2π
h
(4) The plot of Ψ V s r for various azimuthal quantum numbers, shows peak
shifting towards higher r value
[ JEE MAIN 2019 ]
(A) (1), (3) (B) (1), (2)
(C) (1), (4) (D) (2), (3)

(A) (B) (B) (A)
(C) (D) (D) (C)
An electron in an orbital of high angular momentum stays away from
the nucleus than an electron in the orbital of lower angular momentum.
According to Bohr's theory, angular momentum is an integral multiple of 2π
h
.
Hence,the ground state angular momentum is h equal to 2π . h
Statements a and c are incorrect. As we know the principal quantum number

depends on size whereas azimuthal quantum number doesn't depend on size.
Page No : 16
Solution:[ Correct Answer : C ] Solution:[ Correct Answer : B ]
Number of radial nodes = n − ℓ − 1 First Bohr orbit of H atom has radius

o
=3−0−1=2 r = 0.529 A
Therefor corresponding graph is (D) Also, the angular momentum is quantised.
Hence answer is (3) mvr = 2π h
h
[60] Which of the following statements is false? 2πr = mv = λ
[ JEE MAIN 2018 ] λ = 2π × 0.529 A
o
(A) Splitting of spectral lines in electrical field is called Stark effect [64] The number of orbitals with n = 5, ml = +2 is ...... . (Round off to the Nearest
(B) Frequency of emitted radiation from a black body goes from a lower wave- Integer)
[ JEE MAIN 2021 ]
length to higher wavelength as the temperature increases
(C) Photon has momentum as well as wavelength (A) 3 (B) 2
(D) Rydberg constant has unit of energy (C) 1 (D) 0

When temperature is increased, black bodyemit high energy radiation,
from higher wavelength to lower wavelength . Rydberg constant has unit of For, n = 5
length i.e. cm−1 ℓ = (0, 1, 2, 3, 4)
If ℓ = 0, m = 0
[61] Given below are two statements. ℓ = 1, m = {−1, 0, +1}
Statement I : According to Bohr's model of an atom, qualitatively the magni-
tude of velocity of electron increases with decrease in positive charges on the ℓ = 2, m = {−2, −1, 0, +1, +2}
nucleus as there is no strong hold on the electron by the nucleus. ℓ = 3, m = {−3, −2, −1, 0, +1, +2, +3}
Statement II : According to Bohr's model of an atom, qualitatively the magni- ℓ = 4, m = {−4, −3, −2, −1, 0, +1, +2, +3, +4}
tude of velocity of electron increases with decrease in principal quantum num- 5d, 5f and 5g subshell contain one-one orbital having mℓ = +2
ber.
In the light of the above statements, choose the most appropriate answer from [65] If m and e are the mass and charge of the revolving electron in the orbit of
the options given below: radius r for hydrogen atom, the total energy of the revolving electron will be
[ JEE MAIN 2021 ] [ JEE MAIN 2014 ]
(A) Both Statement I and Statement II are false 1 e2 2

(A) 2 r
(B) − er
(B) Both Statement I and Statement II are true me2 e2
(C) r
(D) − 12 r
(C) Statement I is false but Statement II is true
(D) Statement I is true but Statement II is false Solution:[ Correct Answer : D ]
Solution:[ Correct Answer : C ] Total energy of a revolving electron is the sum of its kinetic and poten-
tial energy.
( Total
) energy = K.E. + P.E.
Velocity of electron in Bohr's atom is given by 2 2
= e2r + − er = − e2r
2
V ∝ Zn
Z = atomic number of atom, corresponds to +ve charge so as Z increase [66] Which of the following sets of quantum numbers is not allowed?
velocity increases so statement−I is wrong. [ JEE MAIN 2022 ]
and as ′ n′ decreases velocity increases so statement−II is correct.
(A) n = 3, 1 = 2, m1 = 0, s = + 12
[62] The de Broglie wavelength (λ) associated with a photoelectron varies with the
frequency (v) of the incident radiation as, [v0 is threshold frequency]: (B) n = 3, 1 = 2, m1 = −2, s = + 12
[ JEE MAIN 2019 ]
(C) n = 3, 1 = 3, m1 = −3, s = − 12
(A) λ ∝ 1
(v−v0 )
(B) λ ∝ 1
1
(v−v0 ) 4
(D) n = 3, 1 = 0, m1 = 0, s = − 12
(C) λ ∝ 1
3 (D) λ ∝ 1
1
(v−v0 ) 2 (v−v0 ) 2
Solution:[ Correct Answer : D ] 1 = 0, 1, 2 . . . (n − 1)

∴ for n = 3
h
λ= mv 1 = 0, 1, 2
According to Einstein's theory of photoelectric effect: 1 = 3,
hv = hv0 + KE not possible for n = 3
hv = hv0 + 12 mv 2
2h(v − v0 ) = mv 2 [67] A metal surface is exposed to 500 nm radiation. The threshold frequency of
2h(v−v0 ) the metal for photoelectric current is 4.3 × 1014 Hz. The velocity of ejected
= v2
m
1 electron is ....... × 105 ms−1 (Nearest integer) ]
v ∝ (v − v0 ) 2 [Use : h = 6.63 × 10−34 Js, me = 9.0 × 10−31 kg
λ∝ h
1 [ JEE MAIN 2021 ]
m(v−v0 ) 2
λ∝ 1
1 (A) 7 (B) 5
(v−v0 ) 2
[63] The de-Broglie's wavelength of electron present in first Bohr orbit of ′ H ′ atom (C) 1 (D) 500
is
[ JEE MAIN 2018 ]
o o
(A) 4 × 0.529 A (B) 2π × 0.529 A
o o
(C) 0.529
2π A (D) 0.529 A
Page No : 17
Solution:[ Correct Answer : B ] Solution:[ Correct Answer : D ]
Kinetic energy of any particle = 3

2
KT
Also K.E. = 12 mv 2
1
mv 2 = 32 KT ⇒ v 2 = 3KT
2 √ m
3KT
v= m
De-broglie wavelength
= λ = mv = √h3KT
h
m m
λ= √ h λ ∝ √1m
v : speed of electron having max. K.E. 3KT m
⇒ from Einstein equation : E = ϕ + K · E· max Mass of electron < mass of neutron
⇒ hc = hv0 + 12 mv2 λ (electron) > λ (neutron)
λ
6.63×10−34 ×3×108
⇒ = 6.63 × 10−34 × 4.3 × 1014 + 12 mv2 [71] The most abundant elements by mass in the body of a healthy human adult are
500×10−9
−20
:
⇒ 6.63×30×10
= 6.63 × 4.3 × 10−20 + 12 mv2 Oxygen (61.4%); Carbon (22.9%), Hydrogen (10.0%); and Nitrogen (2.6%).
5
⇒ 11.271 × 10−20 J = 12 × 9 × 10−31 × v2 The weight which a 75 kg person would gain if all 1 H atoms are replaced by
2 H atoms is ....... kg
⇒ v = 5 × 105 m/sec [ JEE MAIN 2017 ]
[68] Ionization energy of gaseous N a atoms is 495.5 kJ mol−1 . The lowest (A) 15 (B) 37.5
possible frequency of light that ionizes a sodium atom is (h = 6.626 ×
10−34 Js, NA = 6.022 × 1023 mol−1 ) (C) 7.5 (D) 10
[ JEE MAIN 2014 ]
(A) 7.50 × 104 s−1 (B) 4.76 × 1014 s−1

(C) 3.15 × 1015 s−1 (D) 1.24 × 1015 s−1
Mass of hydrogen in human body = 100 10
× 75 = 7.5 kg
If all H atoms are replaced by H atoms, then, the mass will become
1 2
Solution:[ Correct Answer : D ] 7.5 × 2 = 15 kg. Therefore, the weight gain will be 7.5 kg
Energy = NA hv [72] Which of the following pair is not isoelectronic species? (At. no.
Sm, 62; Er, 68 : Y b, 70 : Lu, 71; Eu, 63 : T b, 65; Tm, 69)
495.5 = 6.023 × 1023 × 6.6 × 10−34 × v [ JEE MAIN 2022 ]
495.5×103 J
23 ×6.6×10−34 = 12.4 × 10
v = 6.023×10 14
= 1.24 × 1015 s−1 (A) Sm2+ and Er3+ (B) Y b2+ and Lu3+
[69] When light of wavelength 248 nm falls on a metal of threshold energy 3.0 eV , (C) Eu2+ and T b4+ (D) T b2+ and T m4+
the de-Broglie wavelength of emitted electrons is ............. Å
(Round √
off to the Nearest Integer).
[Use : 3 = 1.73, h = 6.63 × 10]−34 Js me = 9.1 × 10−31 kg; c = Solution:[ Correct Answer : D ]
3.0 × 108 ms−1 1eV = 1.6 × 10−19 J
[ JEE MAIN 2021 ] Sm2+ → electron = 60
Er3+ → electron = 65
(A) 7 (B) 9 T b2+ → electron = 63
T m4+ → electron = 65
(C) 12 (D) 18 all are (not isoelectronic)
[73] The energy of an electron in the first Bohr orbit of hydrogen atom is −2.18 ×
Solution:[ Correct Answer : B ] 10−18 J. Its energy in the third Bohr orbit is .........
[ JEE MAIN 2023 ]
Energy incident = hc
−34
λ (A) 1
27
of this value (B) One third of this value
6.63×10 ×3.0×108
= 248×10−9 ×1.6×10−19
eV
= 6.63×3×100 (C) Three times of this value (D) 1
9
th of this value
248×1.6
= 0.05eV × 100 = 5eV
Now using E = ϕ + K.E
5 = 3 + K.E
K.E. = 2eV = 3.2 × 10−19 J −18
Z2
En = −2.18×10
for debroglie wavelength λ = mv
h n2
i.e. En ∝ n12
K.E = 12 mv 2
√
so v = 2KE [74] The quantum number of four electrons are given below
m
I.n = 4, l = 2, ml = −2, ms = −1/2
hence λ = √2KE×m
h
II.n = 3, l = 2, ml = 1, ms = +1/2
6.63×10−34 III.n = 4, l = 1, ml = 0, ms = +1/2
= √
2×3.2×10−19 ×9.1×10−31 IV.n = 3, l = 1, ml = 1; ms = −1/2
= 6.63 10−34
× 10 66.3×10−10 m The correct order of their increasing energies will be
7.6 −25 = 7.6 [ JEE MAIN 2019 ]
= 8.72 × 10 −10 m
≈ 9 × 10−10 m (A) I < III < II < IV (B) I < II < III < IV
= 9o
(C) IV < II < III < I (D) IV < III < II < I
[70] At temperature T , the average kinetic energy of any particle is 3
2
KT . The de
Broglie wavelength follows the order
[ JEE MAIN 2015 ] Solution:[ Correct Answer : C ]
(A) Visible photon > Thermal neutron > Thermal electron
According to Aufbau principle, the energy sequence is
(B) Thermal proton > Thermal electron > Visible photon 3p < 3d < 4p < 4d
(C) Thermal proton > Visible photon > Thermal electron [75] The wave number of the first emission line in the Balmer series of H− Spec-
trum is ( R = Rydberg constant)
(D) Visible photon > Thermal electron > Thermal neutron [ JEE MAIN 2013 ]
Page No : 18
(A) 5
36
R (B) 9
400
R (A) r4 = 9
r
16 3
(B) r4 = 16
r
9 3
(C) 7
6
R (D) 3
4
R (C) r4 = 3
r
4 3
(D) r4 = 4
r
3 3
Solution:[ Correct Answer : A ] Solution:[ Correct Answer : B ]

( )
n2
v̄ = RZ 2 212 − 312 r = 0.529 × Z
( ) 2
= R 14 − 19 r3 = 0.529 × 31
5R 2
= 36 r4 = 0.529 × 41
r4 2
[76] The electrons are more likely to be found r3
= 342 = 16
9
[ JEE MAIN 2019 ]
r4 = 16r
9
3
[79] The number of atomic orbitals from the following having 5 radial nodes is ........
7s, 7p, 6s, 8p, 8d
[ JEE MAIN 2023 ]
(A) 3 (B) 2
(C) 1 (D) 4
(A) in the region a and b (B) in the region a and c Radial node = n − ℓ − 1
7s ⇒ R · N = 7 − 0 − 1 = 6
(C) only in the region a (D) only in the region c 7p ⇒ R · N = 7 − 1 − 1 = 5
6s ⇒ R · N = 6 − 0 − 1 = 5
8p ⇒ R · N = 8 − 1 − 1 = 6
Solution:[ Correct Answer : B ] 8d ⇒ R · N = 8 − 2 − 1 = 5
So, Answer is 3
[80] The ground state energy of hydrogen atom is −13.6 eV . The energy of second
excited state of He+ ion in eV is
[ JEE MAIN 2019 ]
(A) −54.4 (B) −3.4
(C) −6.04 (D) −27.2

At a & c, probability of finding electron is maximum 2
E = −13.6 n eV
[77] Consider the following set of quantum numbers +
z2
EHe = −13.6 49
n l ml
A 3 3 −3 [81] Outermost electronic configurations of four elements A, B, C, D are given be-
B 3 2 −2 low.
C 2 1 +1 3s2
3s2 3p1
D 2 2 +2 3s2 3p3
The number of correct sets of quantum numbers is ..... . 3s2 3p4
[ JEE MAIN 2022 ] The correct order of first ionization enthalpy for them is.
[ JEE MAIN 2022 ]
(A) 4 (B) 1
(A) (A) < (B) < (C) < (D) (B) (B) < (A) < (D) < (C)
(C) 2 (D) 3
(C) (B) < (D) < (A) < (C) (D) (B) < (A) < (C) < (D)

Quantum no. of set (B) and (C) can be correct.
(A) and (D) are wrong as n = ℓ is not possible. 3s2 → M g
3s2 3p1 → Al
[78] If the radius of the 3rd Bohr's orbit of hydrogen atom is r3 and the radius of 4th 3s2 3p3 → P
Bohr's orbit is r4 . Then .... 3s2 3p4 → S
[ JEE MAIN 2022 ] C>D>A>B


[82] A proton and a Li3+ nucleus are accelerated by the same potential. If λLi and
Solution:
λP denote the de Broglie wavelengths of Li3+ and proton respectively, then h
λ = √2mqV
the value of λλLi is x × 10−1 .The value of x is ............ √
P
(Rounded off to the nearest integer) λLi
=
mp (e)V
mLi = 8.3mp
(Mass of Li = 8.3 mass of proton)
3+ λp mLi (3e)(V )
√
[ JEE MAIN 2021 ] λLi
= 1
= 5 = 0.2 = 2 × 10−1
1
λp 8.3×3
Page No : 19
o
[83] The radius of the second Bohr orbit for hydrogen atom is .......... A
(Plank's const. h = 6. × 10−34 Js ; mass of electron = 9.1091 × 10−31 kg ;
charge of electron e = 1.60210 × 10−19 C ; permittivity of vaccum ϵ0 = Solution:
8.854185 × 10−12 kg −1 m−3 A2 ) Total energy per sec. = 50 J
[ JEE MAIN 2017 ] 50 = n×6.63×10
−34
×3×108
795×10−9
Solution: n = 1998.49 × 1017 [n = no. of photons per second ]
According to Bohr's theory = 1.998 × 1020
o
n2 ≃ 2 × 1020
r = 0.529 × Z A
2 o = x × 1020
= 0.529 × 2
1
= 2.116 A x=2
[84] Consider an imaginary ion 48
22 X
3− . The nucleus contains 'a'% more neutrons
[90] The total number of isoelectronic species from the given set is .......
than the number of electrons in the ion. The value of 'a' is ..... [nearest integer] O2− , F − , Al, M g 2+ , N a+ , O + , M g, Al3+ , F
Solution: Solution:
48 X 3−
22 Isoelectronic species O2Θ , F Θ , M g 2+ , N a⊕ , Al3+
No. of neutrons = 26
No. of electrons = 25 [91] If the work function of a metal is 6.63 × 10−19 J, the maximum wavelength
% of extra neutrons of the photon required to remove a photoelectron from the metal is .... nm.
than electrons = 26−25 × 100 = 4 (Nearest integer)
25
[Given : h = 6.63 × 10−34 J s, and c = 3 × 108 m s−1 ]
[85] A certain orbital has n = 4 and mL = −3. The number of radial nodes in this [ JEE MAIN 2022 ]
orbital is .......... (Round off to the Nearest Integer).
[ JEE MAIN 2021 ] Solution: −34 8
ϕ = 6.63 × 10−19 J = hc = 6.63×10 λ ×3×10
Solution: λ
⇒ λ = 3 × 10−7 m = 300 nm
n = 4 and mℓ = −3
Hence, ℓ value must be 3. [92] The total number of orbitals associated with the principal quantum number 5
Now, number of radial nodes = n − ℓ − 1 is
[ JEE MAIN 2016 ]
=4−3−1=0
Solution:
[86] The minimum uncertainty in the speed of an electron in an one dimensional Number of orbitals in a shell = n2 = (5)2 = 25.
region of length 2ao
(Where a0 = Bohr radius 52.9pm ) is kms−1 [93] The minimum energy that must be possessed by photons in order to produce
(Given : Mass of electron = 9.1 × 10−31 kg, Planck's constant h = 6.63 × the photoelectric effect with platinum metal is .... × 10−19 J
10 −34 Js ) [Given: The threshold frequency of platinum is 1.3 ×1015 s−1 and h = 6.6 ×
[ JEE MAIN 2022 ]
10−34 J s.]
Solution: [ JEE MAIN 2022 ]
Heisenberg's uncertainty principle Solution:
∆x × ∆px ≥ 4π h
W = hv
⇒ 2a0 × m∆vr = 4π h
( minimum ) = 6.6 × 10−34 × 1.3 × 1015
⇒ ∆vx = h
× 1
× 1 = 8.58 × 10−19 J
4π 2a0 m
6.63×10−34 [94] Ejection of the photoelectron from metal in the photoelectric effect experi-
= 4×3.14×2×52.9×10−12 ×9.1×10−31
ment can be stopped by applying 0.5 V when the radiation of 250 nm is used.
= 548273 ms−1 The work function of the metal is ................ eV
= 548.273 km s−1 [ JEE MAIN 2018 ]
= 548 km s−1
Solution:
o
[87] The number of subshells associated with n = 4 and m = −2 quantum num- λ = 250 nm = 2500 A
bers is : E = hc = 12400 = 4.96 eV
[ JEE MAIN 2020 ] λ 2500
KE = stopping potential = 0.5 eV
Solution: E = W0 + K.E.
4.96 = W0 + 0.5
W0 = 4.46 ≈ 4.5 eV
[95] If the uncertainty

( in)velocity and position of a minute particle in space are,
2.4 × 10−26 m s−1 and 10−7 (m) respectively. The mass of the particle in g
For n = 4 is .... (Nearest integer)
ℓ = 0, 1, 2, 3 (Given : h = 6.626 × 10−34 Js )
∴ 4d&4f subshell associated with n = 4, m = −2 [ JEE MAIN 2022 ]
[88] An accelerated electron has a speed of 5 × 106 ms−1 with an uncertainty of Solution:
0.02 %. The uncertainty in finding its location while in motion is x × 10−9 m. ∆V = 2.4 × 10−26 ms−1
The value of x is ...... (Nearest integer) ] ∆x = 10−7 m
[Use mass of electron = 9.1 × 10−31 kg, h = 6.63 × 10−34 J s, π = 3.14 ∵ ∆p · ∆x = 4π
h
[ JEE MAIN 2021 ] ∴ m∆V ∆x = 4π h
Solution: ⇒ m × 2.4 × 10−26 × 10−7 = 6.626×10−34

× 5 × 106 = 103 m/s
4×π
∆v = 0.02
100 6.626
m = 9.6×π × 10−1
According to Heisenberg uncertainty principle
∆X · ∆v = 4πh m m = 0.02198 kg
m = 21.98 gm
6.63×10−34
x × 10−9 × 103 = 4×3.14×9.1×10−31 nearest integer = 22
X × 10−9 × 103 = 0.058 × 10−3 o
−6
x = 0.058×10 = 58 [96] What is the work function of the metal if the light of wavelength 4000 A gen-
10−9
erates photoelectrons of velocity 6 × 105 ms−1 from it? ............. eV (Mass of
[89] A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The electron = 9 × 10−31 kg Velocity of light = 3 × 108 ms−1 Planck's constant
number of photons emitted per second by the bulb is x × 1020 . The value of x = 6.626 × 10−34 Js Charge of electron = 1.6 × 10−19 J eV −1 )
is ...... . ] [ JEE MAIN 2019 ]
[ Given : h = 6.63 × 10−34 Js and c = 3.0 × 108 ms−1
[ JEE MAIN 2021 ] Solution:
hv = ϕ + hv(o )
1
2
mv 2 = hc λ 1
− λ1
0
hv = ϕ + 12 mv 2
6.626×10−34 ×3×108
ϕ= 4000×10−10
− 12 × 9 × 10−31 × (6 × 105 )2
ϕ= 3.35 × 10−19 J
⇒ ϕ ≃ 2.1 eV
Page No : 20
[97] The wavelength of electrons accelerated from rest through a potential differ- [104] The electron in the nth orbit of Li2+ is excited to (n + 1) orbit using the ra-
ence of 40 kV is X × 10−12 m. The value of x is ....... (Nearest integer) diation of energy 1.47 × 10−17 J (as shown in the diagram). The value of n is
Given : Mass of electrons = 9.1 × 10−31 kg .....Given RH = 2.18 × 10−18 J
Charge on an electron = 1.6 × 10−19 C [ JEE MAIN 2023 ]
Planck's constant = 6.63 × 10−34 Js
[ JEE MAIN 2021 ]
Solution:
De-broglie-wave length of electron:
λc = √ h
2m(KE)
∵ e− is accelerated from rest ⇒ KE = q × V
h
λ = √2mqv
6.63×10−34 Solution:
= √ ( )
2×1.6×10−19 ×9.1×10−31 ×40×103
= 0.614 × 10−11 m ∆E = RH Z 2 1
n2
− 1
n2
= 6.16 × 10−12 m
1 2
( )
Nearest integer = 6 1.47 × 10−17 = 2.18 × 10−15 × 9 1
n2
− 1
(n+1)2
OR 1.47
1.96
= 34 = 1
n2
− 1
(n+1)2
= 12.3
√ Å So, n = 1
V
= 12.3
= 6.15 × 10−12 m
200 [105] The number of s-electrons present in an ion with 55 protons in its unipositive
[98] The energy of one mole of photons of radiation of frequency 2 × 1012 Hz state is
[ JEE MAIN 2023 ]
in Jmol−1 is .....(Nearest) integer) (Given: h = 6.626 × 10−34 JS
NA = 6.022 × 1023 mol−1 Solution:
[ JEE MAIN 2023 ] Z
[ =+55[Cs]
] ⇒ [Xe]6s1
Cs ⇒ [Xe] i.e. upto 5s count e− of s-subshell i.e. 1s, 2s, 3s, 4s, 5s ⇒ 10
Solution: electrons
For one photon E = hv
For one mole photon, [106] Electromagnetic radiation of wavelength 663 nm is just sufficient to ionise
E = 6 · 023 × 1023 × 6.626 × 10−34 × 2 × 1012 the atom of metal A. The ionization energy of metal A in kJ mol−1 is ...... .
(Rounded-off
[ to the nearest integer) ]
[99] The number of significant figures in 0.00340 is ...... h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1 , NA = 6.02 × 1023 mol−1
Solution: Solution:
Number of significant figures = 3 E = hc × NA
λ 1000
6.63×10−34 ×3×108 ×6.02×1023
[100] Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6Å. The = 663×10−9 ×1000
radius of the third Bohr orbit of He+ is .................. picometer. (Nearest Inte- = 3 × 6.02 × 10 kJ
ger) = 180.6 kJ
[ JEE MAIN 2023 ]
Solution: [107] The wavelength of an electron and a neutron will become equal when the ve-
2 locity of the electron is x times the velocity of neutron. The value of x is (Nearest
r ∝ nZ
Integer)(Mass of electron is 9.1×10−31 kg and mass of neutron is 1.6×10−27 kg
rHe+ = rH × n2
Z
)
(3)2 [ JEE MAIN 2022 ]
rHe+ = 0.6 × 2
Solution:
= 2.7Å
ve = xvN
rHe+ = 270 pm
λe = λN
[101] If the de Brogile wavelength of the electron in nth Bohr orbit in a hydrogenic ⇒ mhv = m hv
e c N N
atom is equal to 1.5 πa0 ( a0 is Bohr radius), then the value of n/z is ve = m m
N
· vN
[ JEE MAIN 2019 ]
e
−27
1.6×10
= 9.1×10 −31 vN
Solution: ve = 1758.24 × vN
2πr = nλ 2
= 2πn [108] The number of correct statements from the following
a0
λ = 2πr
n n×Z
n
= 2π Z a0
λ = 1.5πa0 A. For 1 s orbital, the probability density is maximum at the nucleus.
∴ 2π Zn
a0 = 1.5πa0 B. For 2s orbital, the probability density first increases to maximum and then
decreases sharply to zero.
∴ Z = 1.5
n
2
= 0.75 C. Boundary surface diagrams of the orbitals encloses a region of 100% proba-
bility of finding the electron.
[102] Maximum number of electrons that can be accommodated in shell with n = 4 D. p and d-orbitals have 1 and 2 angular nodes respectively.
are:
[ JEE MAIN 2023 ] E. Probability density of p-orbital is zero at the nucleus.
[ JEE MAIN 2023 ]
Solution:
Solution:
The number of electrons in the orbitals of sub-shell of n = 4 are
[103] If the wavelength for an electron emitted from H atom is 3.3 × 10−10 m, then A, D and E statements are correct.
energy absorbed by the electron in its ground state compared to minimum en- For 2s orbital, the probability density first decreases and then increases.
ergy required for its escape from the atom, is .......times. (Nearest integer). At any distance from nucleus the probability density of finding electron is never
[Given : h = 6.626 × 10−34 Js,Mass of electron = 9.1 × 10−31 ] zero and it always have some finite value.
[ JEE MAIN 2022 ]
Solution: [109] The number of incorrect statement /s about the black body from the follow-
ing is .........
λ= √ h
2mK (A) Emit or absorb energy in the form of electromagnetic radiation
K= h2 (B) Frequency distribution of the emitted radiation depends on temperature
2mλ2
h2 43.9×10−68
(C) At a given temperature, intensity vs frequency curve passes through a max-
K= 2mλ2
= 2×9.1×10−31 ×10.89×10−20 imum value
K = 2.215 × 10−18 (D) The maximum of the intensity vs frequency curve is at a higher frequency
Eabs = Ereq + K at higher temperature compared to that at lower temperature
[ JEE MAIN 2023 ]
Eabs K 2.215×10−18
Ereq
=1+ Ereq
=1+ 13.6×1.602×10−19
= 2.0166
Page No : 21
Solution: Solution:
Total energy provided by
Source per second = 1000
10
= 100 J
Energy required to eject electron = hc
λ
6.626×10−34
= 400×10−9
×3× 108
Number of electrons ejected
100
6.626×10−34 ×3×108
= 400×10−9
−7 26
400×10 ×10
= 6.626×3
−20
40×10
= 6.626×3
= 2.01 × 1020
A blackbody can emit and absorb all the wavelengths in electromagnetic [115] The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom
h2
spectrum ⇒ (A) is correct is equal to xma2
. The value of 10x is ........ . (a0 is radius of Bohr's orbit) (Nearest
⇒ (B), (C), (D) correct
0
integer) [Given : π = 3.14]
[ JEE MAIN 2021 ]
[110] The longest wavelength of light that can be used for the ionisation of lithium
atom (Li) in its ground state is x × 10−8 m. The value of x is ..... (Nearest In- Solution:
nh
teger) mvr = 2π
(Given : Energy of the electron in the first shell of the hydrogen atom is n h 2 2
4 h2
K.E. = 8π =
−2.2 × 10−18 J; h = 6.63 × 10−34 Js and c = 3 × 108 ms−1 ) (
2 mr2
) 2 8π 2 m(4a0 )2
[ JEE MAIN 2022 ] = 8π24×16 ma h
2
Solution:
0
⇒ x = 315.507
We can not calculate I.E. of lithium atom. ⇒ 10x = 3155 (nearest integer)
[111] Following figure shows spectrum of an ideal black body at four different tem- [116] The value of magnetic quantum number of the outermost electron of Zn+ ion
peratures. The number of correct statement/s from the following is ............... is ..... .
A. T4 > T3 > T2 > T1 [ JEE MAIN 2021 ]
B. The black body consists of particles performing simple harmonic motion.
C. The peak of the spectrum shifts to shorter wavelength as temperature in- Solution:
creases. Zn+ → 1 s2 2 s2 2p6 3 s2 3p6 3 d10 4 s1
D. T 1
v1
= T 2
v2
= T 3
v3
̸= constant Outermost electron is in 4 s subshell m = 0
E. The given spectrum could be explained using quantisation of energy.
[ JEE MAIN 2023 ] [117] The number of photons emitted by a monochromatic (single frequency) in-
frared range finder of power 1 mW and wavelength of 1000 nm, in 0.1 second
is x × 1013 . The value of x is ..... .
(Nearest
( integer) )
h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1
[ JEE MAIN 2021 ]
Solution:
Energy emitted in 0.1 sec.
= 0.1 sec · ×10−3 sJ
= 10−4 J
If ′ n′ photons of λ = 1000 nm are emitted,
then ; 10−4 = n × hc λ
n×6.63×10−34 ×3×108
⇒ 10−4 = 1000×10−9
⇒n= 5.02 × 1014 = 50.2 × 1013
⇒ 50 (nearest integer)
[118] The number of orbitals associated with quantum numbers n = 5, ms = + 21

Solution: is
The spectrum of Black body radiation is explained using quantization of energy. [ JEE MAIN 2020 ]
With increase in temperature, peak of spectrum shifts to shorter wavelength or Solution:
higher frequency. For above graph No. of orbitals = n2 = 52 = 25
→ T1 > T2 > T3 > T4 . For n = 5, no. of orbitals = n2 = 25
Total number of orbitals is equal to no. of electrons having ms = 1
[112] The orbital angular momentum of an electron in 3s orbital is xh
2π
. The value of.x 2
is ........... [119] The wavelength of an electron of kinetic energy 4.50 × 10−29 J is . . . .. ×

[ JEE MAIN 2023 ]
10−5 m. (Nearest integer)Given : mass of electron is 9 × 10−31 kg, h = 6.6×
Solution: √ 10−34 Js
[ JEE MAIN 2023 ]
Orbital angular momentum = 1(1 + 1) 2π
h
Value of 1 for s = 0
Solution:
[113] The energy of one mole of photons of radiation of wavelength 300nm is ...... λd = mvh
= √ h
= √ 6.6×10−34
kJ mol−1 . 2mKE 2×9×10−31 ×4.5×10−29
(Given : h = 6.63 × 10−34 Js, NA = 6.02 × 1023 mol−1 , c = 3 × 108 ms−1 ) = √
6.6×10 −34
[ JEE MAIN 2022 ] 29 ×10−60

6.6×10−34
Solution: = 9×10−30
= 6.6
9
× 10−4
Energy of one mole of photons = hc
λ
× NA = 7.3 × 10−5 m
6.63×10−34 ×3×108
× 6.02 × 1023 Therefore Ans = 7
300×10−9
= 399.13 × 103 Joule/mole [120] The number of following statement/s which is/are incorrect is
= 399 kJ/mole (A) Line emission spectra are used to study the electronic structure
(B) The emission spectra of atoms in the gas phase show a continuous spread
[114] A source of monochromatic radiation of wavelength 400 nm provides 1000 J of wavelength from red to violet
of energy in 10 seconds. When this radiation falls on the surface of sodium, (C) An absorption spectrum is like the photographic negative of an emission
x × 1020 electrons are ejected per second. Assume that wavelength 400 nm is spectrum
sufficient for ejection of electron
( from the surface of) sodium metal. The value (D) The element helium was discovered in the sun by spectroscopic method
of x is ....... (Nearest integer) h = 6.626 × 10−34 Js [ JEE MAIN 2023 ]
[ JEE MAIN 2021 ]
Solution:
[121] Which of the following is the energy of a possible excited state of hydrogen ?
............ eV
[ JEE MAIN 2015 ]
Solution:
Page No :For
22 1st excited state, the value of n = 2

JEE Main PYQs Atomic Structure 28399275

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JEE Main PYQs Atomic Structure 28399275

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InfinIITy Academy

Subject : Chemistry Paper Set : 1

Standard : 11 JEE Main_ PYQs _Mole concept Date : 19-07-2023

Total Mark : 800 Time : 0H:0M

(A) Br − and Be2+ (B) Cl− and Li+ (C) 9λ1

(C) S 2− and K + (D) O2− and M g 2+

(A) 1.214 × 10−7 m (B) 2.816 × 10−7 m

(C) 6.500 × 10−7 m (D) 8.500 × 10−7 m

(A) 8.041 × 10−40 J (B) 2.680 × 10−19 J

(C) 1.640 × 10−18 J (D) 6.111 × 10−17 J

(C) (I), (III), (IV ) (D) (I), (II), (IV )

(A) Lyman and Paschen (B) Brackett and Pfund

(C) A is true but R is false.

(A) Lyman series (B) Balmer series (B) 3 and 2

(C) (A) is true but (R) is false (C) 3 p (D) 2 p

(D) (A) is false but (R) is true

(C) 6.626 × 10−31 m (D) 6.626 × 10−30 m

[46] Given below are two statements:

(A) Statement I is false but statement II is true.

(A) Ci+ , N a+ , M g 2+ , Ca2+ (B) Ba2+ , Sr 2+ , K+, Ca2+

(C) N 3− , O 2− , F, S 2− (D) K + , Cl− , Ca2+ , Sc3+

[48] Identify the incorrect statement from the following.

(D) Atomic orbital is characterised by the quantum numbers n and l only

[66] Which of the following sets of quantum numbers is not allowed?

[67] A metal surface is exposed to 500 nm radiation. The threshold frequency of

(C) 1 (D) 500

(C) 3.15 × 1015 s−1 (D) 1.24 × 1015 s−1

[70] At temperature T , the average kinetic energy of any particle is 3

(C) Eu2+ and T b4+ (D) T b2+ and T m4+ (C) r4 = 3

(C) Three times of this value (D) 1

.....Given RH = 2.18 × 10 −18 J is ..... .

Total Mark : 800 Time : 0H:0M

Standard : 11 JEE Main_ PYQs _Mole concept (Solutions) Date : 19-07-2023

Total Mark : 800 Time : 0H:0M

[3] Consider the following pairs of electrons

(C) Only C (D) (B) and (C)

Solution:[ Correct Answer : B ]

Based on ′ n + 1′ rule only (B) has pair of electron in degenerate or-

For longest wavelength ∆E = minimum for Balmer series n = 3 to n = 2 will

(C) 1.640 × 10−18 J (D) 6.111 × 10−17 J

Solution:[ Correct Answer : C ]

Energy of orbitals decreases on increasing the atomic number.

(A) 10−33 m (B) 10−35 m

(C) 10−31 m (D) 10−25 m

De Broglie wavelength (λ) = h

[19] The de Broglie wavelength of an electron in the 4th Bohr orbit is

(A) 8πa0 (B) 2πa0

(C) 4πa0 (D) 6πa0

(C) 6s, 5d, 5f, 6p (D) 6s, 4f, 5d, 6p

Solution:[ Correct Answer : D ] For balmer : n1[ = 2, n2 =] 3, 4, 5, . . . ∞

T.E = −K.E = P2E Solution:[ Correct Answer : A ]

(C) meV (D) 2meV Solution:[ Correct Answer : A ]

As for shortest wavelength both n1 and n12 are ∞

[31] The wave function (Ψ) of 2s is given by

Solution:[ Correct Answer : B ]

5f orbital not buried as 4f orbitals so e− present in 5f orbital experi-

[36] Consider the following statements:

∴ v × nαz (A) 2 s (B) 3 s

Chemical Species Bond Order (A) 5 (B) 3

Solution:[ Correct Answer : B ] Solution:[ Correct Answer : B ]

There is a characteristic minimum frequency, or 'threshold frequency,' for (A) n = 3; 1 = 0; m = 0; 3s orbital

Solution:[ Correct Answer : B ]

(A) Ci+ , N a+ , M g 2+ , Ca2+ (B) Ba2+ , Sr 2+ , K+, Ca2+

(C) N 3− , O 2− , F, S 2− (D) K + , Cl− , Ca2+ , Sc3+