Model Answer AQA2 ease wie learn Block casts cat uber [ ‘Sumame Forename(s) Candidate signature AS CHEMISTRY Paper 4: Inorganic and Physical Chemistry Friday 26 May 2017 Morning ‘Time allowed: 1 hour 30 minutes Matorials For this paper you must have: «the Periodic ToblelData Shes, provided as an insort (enclosed) ‘Queston [i + aruer wih mismetra measurements ¢ a caleuisor, wich you are expected to use where appropiate Instructions + Us black ink or black balpintpen. 1 Filinthe boros athe top of thi page. + Answer all questions. + You must answer the questions in tho spaces provided. Do not wile ‘outside tho box around each pape or on blank pages + Alworking must be shou. 1 Dosall rough work inthis book, Cross through any work you do not want tobe marke, Information 1 marks for questions are show n brackets. {The mavimum mark fortes papa is 80 1 You ee acvisod to spend about 6S mints on Section A and 25 minutes an Section B. rs 7404/1: H Section A Answer al questions inthis section, br.) (ol4].2] ret _Ist 26t Op set 56k This quner but sc sr, eerefilemncntantentert eterna o_o eth \Wite an equation including slate symbols, to represent he process that occurs ‘when the tid ionisation energy of manganese is measured. a A ttmar post FO ul Met, —» May +e” seen ‘State which ef the elements magnesium and aluinium has the loner {rst ionization ener. ‘pan your answer. marks} luminioe has a lowe Pest ionisation energy as iks tan is in Ue Bp ofbital whichis in_the 2s. -_<———=___—3 ‘Table mie ‘Abundance/% a oto oo 234 ot 29 Give to sy nlcng mas nb, olen at woul rach he derecor tine samp mee Calculate th reat omic maas of tho ick n the sample. (Gio your arsuer to ono decimal place. pees eoritve fo 168 mark 6s, ante tng Symbalofion| i esr (os x6r0) Gort) (Orv4) . 59.4 100 = Relative atomic mass ‘Tum over4 = ‘This question's about energetics. Wee an equation, incudng state symbol, forthe reaction wih an enthalpy change equalto the anay of formation for ret) sa, senor cts 888 mack JE Op — 10 os ants eS “Table 2 contshs some standard enthalpy of formation dota Table 2 01a) Fe,0ule) aarrasme'| 8 ~na Fe,0ys) + SCO(G) -» 2Fels) + 3CO,9) —-AH=—19 I mol Use these dea and the equation fr th reaction of rol) oxide with carbon ‘monoxide to aiouate a vals fr th standard enthapyof formation for carbon dove, Show our vo. [mars] fey + 300 Ar Dfe + 30, = 8124-288) 24155 2415s4(E14)= -1 “ee = - 391.25 or 34 Boat 5 a aH kd mote £ + : 5 = [B1Z].[3] some enthalpy data are given in Table 3 Tables Process BH Ks mor" Nida) + Hela) 2NFa) 2 No) -»2N¢0) es Hla) -» 24) 4436 Use be data ey Table 3 o cael the to ei or N+ n ammonia NaN Baie etn [Baris] 0 Na + 3H, —> UNH3, Reactarty- prubouts > DH Gut) Goteises) 6) = 2 sia | 1252 — 1) Gx?) + 90-1052 00 Ged) = 2808 «© Gud)s 1h 234 123906" Gate Meat 18 3a eer eee Font |-[] Give ane reasen why the bond enthalpy that you caluated in Gueston 2.318 2463-5 +127 dated Ue Wy = Loh S oto st2 1 fehl JPR 002 B43 % GaSe) - ‘Suggest the Monty ofthe nogative lon presant in solution ¥. \Wrte anionic equation, including state symbols, or the reaction that akes place ‘hen magnesum nates added to soldfonY. Tamarks} Negatieion OH” onic equation Dipay 4 OHag —> Malou) 6 ve‘6 < ‘When an acid soliton of sou tite (NaNO:) sade to aqueous asst, nina me nrngen mes (NO) fred [OTE]. ive te oxitason stat of nzogen nthe fling species. mH marke} an Noy +3 NO +2 [21 Wate a hattecuatin forthe eanversion of NO; an aciic solution rio NO ge eee oH : ey et bes ma 2H", NOx” 4 ¢” —» NO + Hr0 [31] Write @ hatt-equation fr the conversion of Tinto ly [1 arg 4" =» Ta + Ze" [1 Write an overationic eqution forthe reaction of NO, In an acide solution wn abby tt marey ad Ht + 2NOy" » 20-—» 2NO + 220+ Ty [5] state the rote o NO,” Inthe reaction with 1 ma ap nag is mead ok, 11 mara * ty odie’. Onidising agente ~ kd ‘urstion& continues on the nox page wud ‘Tum over16 [6] tr aqueous solution, nite ions react with acidified chlrat(¥) fons according to the aquston 20104" + BNO; + BH» Cl, + BNO, + 0 ~~ KR ‘25.0 cm® sample of an aqueous solution of sodium nitrite required 27.40 cm® ‘of-2 0.0200 nol dm’* solution of potassium chlorate(V) for complete reaction. Calculate the concentration, in g dm”*, of sodium nitite inthe sample. — [4 marks] saeaiee xe 0:02 2 94 8«(0"% mk of CLOy" vol SABO 5 2 1.86 P noes oF NOY 18H? © 9.0548 aadn'3 Fant s 0848 x NANO, 2 3:78qde"?_ OO nL a Rn DS ‘Concenitation of sodium nite ganca ‘e ‘Section 8 Answer all qvatins nls scton Cniy one anwar por qustn ls alowed. For ent ani: conplesy lhe rie longs th apport enswer cunscrienco [2] vnaourons [oo [ss] twat charg or enseryu meses of our oan ston, DI you wish osetia ase revue rosea ou, ig tha answer you now wish oealoe = ‘Yu may do your wera inthe Bk spsc8 aru each quoston but his wl not be marke. Do mat uso ana hecs forts wera. Wiichis the cee crystal suture forthe substance named? Ut mark ‘Substanes ‘Structure a] tei ‘Simple molecular = B |. Diamena Ionic So cc | sodium chide | Gientcoveent e | Grpiite Metalic e Which s the best technique to rerowe the siver chord that forms when ‘aquoaus soltns of siver vate and secu chiorida react? : markt sere A Reosing south ite HE est eS) 8 Evaporation fines” ae © Fatalon = D Dataton ei Nu ‘Tum over > _ sauna1” rower Lange heat, ight be urate |! Smee Ts Tae fovseves [oven [ee Which staterent about astatine Is corect? tt mort ‘A. Astatine has a grsaie electranogatiity than brosniine = sl Se Aastra gt tay apt remiss [ES] Astatina has a greater boiling point than bromine (=) D Asn ht a galt nation nay roine [=>] Which statement about tine of fight mass spectramety is correct? 1 marl A Recent dencerispepatenaio teen (&] snare 1 Sanpla paris go eaconnta orm pst ne ioe, [=] C Particles are detected in the order of their kinetic energies x [>] tons are ccceloratedby a magnéic fall» ese ee Chlorine exists as wo schopes *Cl and "Clin he rato 3:4 ‘Which statement about peaks inthe mass spectrum of Cl is carect? 1 mark) [A Pools at m'2= 70 and 74 nthe rato 3:1 a Peaks at ni2~ 70, 72-and 74 nthe rao 9:4 [=] © Peaks at m/z = 70, 72 and 74 in the ratio 8:3:1 eS. Peaks at mz=70 and 72 n thera 3 &) we fk oy 2133 fparwoes |oiens 1S 3314 pasaens loons 1% uuu ere 16 > _comsmis 2a (Geostad x26 rey) 0-56 nig = T el. ee © B10madndoide Cx Gon ara) gol] 9 sees actamm yy = i asrnat Gurguceret) ats stew 3 =< 25,0 cm’ sariplas of NaOH solution were taken by pipette from a beaker. These ‘wor then ivted with an aqueous slution of ethanok acid. The concentration of ‘tranole acid ealculated rom the experimental esis was found tobe lower ‘hon the actual lus. Wich of these could explain the ference? 1° Nag = _——__________*_, Neste nee _ Gr) 'A.4.85 g sample of anhyrous socium Sua is dissolved in water and the ‘ohion made (p10 250 cn? in vokmet ak ‘Whats the corcenraton n ma én sodium state inthe solution? [1 maelg ane = mh A onan wi Ss B ovr SSE, ono ttneles f © 016s Wat D oars G08 = e152 eS Gsm) = ors \Wiich ofthese contains the greatest number ofoms?)) Tt mara sermg otiotne 21 (Worry ecoruetad 215500 x [S] 1.54% 104 wephonus Py (048i ré-nwitd)er , [S] neste anger [1 mari Rinsing the pipette with tiled water bofor fing with NaOH orntd gia per ve Rirsing teburete with csi water bofore fing wih [=] ebanaleadd Rinsing the walls ofthe conical flak wth cette water [©] ding te twat, See ‘Rinsing the beakor wih dstiled water before fing wth [=] NaOH woh gi er Tumover >: Hf 0 phys ite. mr chee ‘420.0 cn? sample of 20.400 mol dn ® aqueous sotuton of ‘otal bromide (MB) reacts exacty with 160 em? of 0.100 mal an? aqusous sive irate. ‘Whats te emu of the metal bromide? cones mtg ofa) tos wa oo) MB orf We) = ties tr ey © Me, 1 mark > Boag D MB, 1 mary aga “The forward action in tis equim is endothermic Coot, (a) # COVa) + Cl, (@) Which statement cortct? (1 mark AA. tho tata pressure is ineeased at constant temperature, tho [=] % proparion of COC, th equim mistarol| daceesse 1B Use of catalyst wlincrease the proporton of COC inthe ‘quiron mu at constant temperature end pressure Reducing equixum concentration of CO wl increase tho vat the equliium constant 3. only ey char D Rang te onperte om 979KipA7aKwlinease [5] eval he eran ost “ [it seperate rgu wh msn sna)a ~~ Which of these s net a redox reaction? ne A cu + 180,180, + cu + H,0 oe B igo + Zhe tgoy + 8 =] © sacl, + Hic +Ha + Sct a D t0y + AHL Nac +2140 + Cy =] eo ‘Which ofthese 1as the highest fst ionisation eneray? (vant ai AY iin peaath 3. in gent inition fl 2B AL) ca ams rss He pete Si ees w Fopa es PE) Whats the empl oma of an ade of egen ht contains 25% trogen ast eos tt many A 0, Baan Hotes a BNO, Ma Hag i) v8 ee tel e C Nos 2. D N05 a e@ [ETS] veh epee bot reson bya redox reeion beveen a sou ae screams aa” Mal + Sy — Noltioys HE puny A NOSOX pier ¢ Heo ot, Boe] Led) BS gure, Tet eino SI es * 2 S SN ilo ak Hab it gees 135m is] D801 tit 5 cotd be fre tener TE) ‘ho abode O — = enone2 “Tere are no quostions printed on this page bo norwre/6N THis PAGE ‘ANSWER IN THE/SPACES PROVIDED