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CHAPTER 3
ENERGY, CATALYSIS, AND BIOSYNTHESIS
2009 Garland Science Publishing
3-1 Chemical reactions carried out by living systems depend on the ability of some organisms
to capture and use atoms from nonliving sources in the environment. The specific subset
of these reactions that breakdown nutrients in food can be described as _____________.
(a) metabolic
(b) catabolic
(c) anabolic
(d) biosynthetic
3-2 The second law of thermodynamics states that the disorder in any system is always
increasing. In simple terms, you can think about dropping NaCl crystals into a glass of
water. The solvation and diffusion of ions is favored because there is an increase in
_____________.
(a) pH
(b) entropy
(c) ionic structure
(d) stored energy
3-3 The energy used by the cell to generate specific biological molecules and highly ordered
structures is stored in the form of _____________.
(a) Brownian motion
(b) heat
(c) light waves
(d) chemical bonds
3-4 At first glance, it may seem that living systems are able to defy the second law of
thermodynamics. However, on closer examination it becomes clear that although cells
create organization from raw materials in the environment, they also contribute to
disorder in the environment by releasing _____________.
(a) water
(b) radiation
(c) heat
(d) proteins
3-5 If you weigh yourself on a scale one morning then eat four pounds of food during the
day, will you weigh four pounds more the next morning? Why or why not? Hint: What
happens to the atoms contained in the food as useful energy is derived from metabolizing
the food molecules?
3-7 Two college roommates do not agree on the best way to handle the clutter piled up in
your dorm room. Roommate 1 explains that chaos is inevitable, so why fight it?
Roommate 2 counters that maintaining an organized environment makes life easier in
many ways, and that chaos is not inevitable. What law of thermodynamics drives the
thinking of roommate 1? What thermodynamic argument can be used to support
roommate 2?
3-8 Assume that the average human adult requires 2000 kilocalories per day to sustain all
normal processes and maintain a constant weight. If manufactured solar panels could
somehow provide power directly to the human body, what size solar panel would be
required (in cm2)? Assume there are 10 hours of sunlight per day, and that the usable
energy output for a typical solar panel is 850 kJ/ft2 per hour.
3-10 During respiration, energy is retrieved from the high-energy bonds found in certain
organic molecules. Which of the following, in addition to energy, are the ultimate
products of respiration?
(a) CO2, H2O
(b) CH3, H2O
(c) CH2OH, O2
(d) CO2, O2
3-13 For each of the pairs A–D in Figure Q3-13, pick the more reduced member of the pair.
Figure Q3-13
3-14 Oxidation is the process by which oxygen atoms are added to a target molecule.
Generally, the atom that is oxidized will experience which of the following with respect
to the electrons in its outer shell?
(a) a net gain
(b) a net loss
(c) no change
(d) an equal sharing
3-15 When elemental sodium is added to water, the sodium atoms ionize spontaneously.
Uncharged Na becomes Na+. This means that the Na atoms have been _____________.
(a) protonated
(b) oxidized
(c) hydrogenated
(d) reduced
3-16 Arrange the following molecules in order with respect to their relative levels of oxidation
(assign 5 to the most oxidized and 1 to the most reduced).
She was now daily expected, the vessel in which she had sailed
having landed at New York, and numerous preparations in honor
of her arrival were in progress at Cedar Grove, where she was
evidently regarded as a person of consequence. The best chamber
in the house was appropriated for her use; Mr. Delafield himself
taking much interest in the arrangement of its furniture, and
bringing over each morning fresh bouquets of flowers, which, in
costly vases, adorned the apartment. Every one seemed anxious
and expectant, save Jessie and Halbert, the former of whom did
not wish her to come, as she took up so much of “Uncle Dick’s”
time, while the latter openly avowed his dislike, saying, he wished
she’d stay in Europe always.
As for myself, though there was no particular reason why I
should do so, I dreaded her arrival, and when at last, word came to
the schoolroom that she was in the parlor, and the children must
come down to see her, I stole out into the garden, in order that I
might put off the interview with her as long as possible. I knew I
must meet her at the supper table, and so after a time I went up to
my room to dress, donning a plain white muslin, which I had often
been told became me better than aught else I could wear. Before
my toilet was finished, little Jessie came in and insisted upon
twining among my curls a few simple buds, which, she said,
looked “mighty nice,” adding, as she stepped back a pace or two to
witness the effect, “I think you are a heap prettier than Ada; but
Uncle Dick don’t, ’cause I asked him, and he said ‘Of course Ad
was the handsomest.’ Hal says how he’s her beau, and I reckon he
is, for he kissed her like fury!”
“He kisses everybody, don’t he?” I asked; and she replied,—
“Mighty nigh everybody but you. I never seen him kiss you, and
when I asked him why, he said you wouldn’t let him—won’t you?”
“It wouldn’t be proper,” I said, smiling down upon the little
fairy, who, poised on one foot, was whirling in circles, and then
looking up into my face, with her soft dreamy eyes.
At that moment the supper bell rang, and bounding away, she
left me alone. For full five minutes I waited trying to summon
sufficient courage to go down, and at last chiding myself for my
weakness, I started for the dining-room. My footsteps were light,
as they evidently were not aware of my approach, for they were
talking of me, and as I reached the door, I heard Jessie, who was
giving Ada a description of her teacher, say, “Why she’s the
properest person in the world, for she won’t even let Uncle Dick
kiss her.”
“Somewhat different from Miss Rawson,” said Ada, joining in
the general laugh; at the same time lifting her large, languid eyes,
she saw me, and started slightly, I fancied, as she recognized me.
She had changed since I saw her last, and her face now wore a
weary, jaded look, while the dark circle beneath her eyelids told of
late hours and heated rooms.
“Miss Lee—Miss Montrose,” said Mrs. Lansing, and the proud
Ada bowed haughtily to the humble governess, who with
heightened color took her accustomed seat at the table.
“You have seen each other before, I believe,” said Mr. Delafield,
looking curiously at both of us, while Mrs. Lansing, in much
surprise, exclaimed, “Seen each other! Where, pray?”
I waited for Ada to answer, and after staring at me a moment,
she replied, quite indifferently, “Miss Lee’s face does seem
familiar, and if I mistake not, I met her once or twice in Boston”—
and this was all she said, if I except a glance, half entreating, half
threatening, which she threw at me from beneath her long,
drooping eyelashes. This glance I did not then understand, but I
now know it to have been prompted by a dread lest I should tell of
her engagement with Herbert Langley, and thus betray her to Mr.
Delafield, to whom, it seems, she had positively denied the whole,
solemnly assuring him that there had never been between them
anything more serious than a mere friendly acquaintance. When,
therefore, she saw me, her fears were awakened, and knowing that
I had her secret in my possession, she looked upon me with
suspicion and dislike, while I, wholly unconscious of her feelings,
had not the least intention of ever speaking of the past, unless
circumstances should render it necessary. But of this she was not
aware, and that night, in the privacy of her room, she communed
with herself as to the best means of counteracting anything which
I might say concerning her conduct in Boston, deciding at last that
the surest way of accomplishing her object was to brand me as a
person whose word could not be trusted! And this she deemed an
easy task, inasmuch as no one there had ever seen or heard of me
before. Strange, too, as it may seem, there was mingled with her
distrust of me a slight shade of jealously lest Mr. Delafield should
in any way notice me. True, I was a poor obscure girl, earning my
daily bread, and on no point could I compete with her save one,
and that was age, I being, as she well knew, eight or nine years her
junior. To be old and unmarried was with her almost a crime, and
as year after year passed on, leaving her still Ada Montrose, her
horror of single blessedness increased, while at the same time she
seemed to look upon those much younger than herself as almost
her enemies, especially if they came between her and Mr.
Delafield, who, as the world goes, was at the age of thirty-one
more likely to choose a girl of eighteen than one of twenty-seven.
This, then, was my fault. I was young and had also in my
possession a secret which she did not wish to have divulged, for
well she knew that one as upright and honorable as Mr. Delafield
would despise a woman who could stoop to a falsehood as she had
done.
“No, it shall not be!” said she, as she sat alone in her room with
her face resting upon her hands; “it shall not be! I will thwart her
and she shall never triumph over me, as did her pale-faced sister,
but for whom I might now have borne the title of Mrs. instead of
trembling lest some one should ask how old I am!” And the proud
belle felt a pang of envy towards my poor widowed sister whose
heart was buried in the grave of her unfortunate husband.
Not that she (Ada) had ever cared particularly for Herbert
Langley, but women of the world sometimes bestow their hand
where the heart cannot be given, and thus might she have done
had not circumstances prevented, for she had then no hope of ever
winning her guardian.
Here, ere we proceed farther, it may be well to relate briefly her
past history, going back to the time when on his death-bed her
father had not only given her to the charge of Mr. Delafield, but
had also made a request that, if it were consistent with his
feelings, Richard would one day make her his wife. As we have
said elsewhere, Mr. Delafield was a great admirer of beauty, and
when he looked upon the exceedingly lovely face of the youthful
Ada, and thought of her as a lonely orphan, his heart was touched,
and he found no difficulty in promising to protect her, and also to
make her his wife, if, upon a more intimate acquaintance, he
found her all he could wish her to be. That he did not find her thus
was proved by the fact that nearly ten years had elapsed since her
father’s death, and she was Ada Montrose still, while he, as he
grew older, seemed less likely to find any one who fully came up to
his standard of excellence, beauty, in reality, now being of minor
importance, notwithstanding his sister’s assertion that he would
never marry one who had not a pretty face.
Upon this point, however, Ada had some doubts; for if beauty
were what he desired, she still possessed it to an uncommon
degree, and it did not seem to move him in the least. Rumor,
indeed, said they were on the eve of marriage, but she knew better,
for never yet had he really told her in earnest that he loved her. It
is true that years before, when she first came a weeping orphan to
Cedar Grove, he had devoted himself to her entirely, feeling,
perhaps, a little proud of his ward, to whom he sometimes talked
of love, or hinted vaguely of the time when she would be his bride,
as they wandered together beneath the whispering pines, which
grew around his home, and once, when she was in Boston, he had
actually made up his mind to offer himself immediately and take
her to Sunny Bank as its mistress. To this resolution he was urged
by her cousin, a strong-minded woman, who, in visiting at Cedar
Grove, had labored to impress upon him the sense of the duty he
owed not only to her father but to Ada herself, who was
represented as loving him devotedly, and who was said to have
made a vow never to marry unless it were her guardian. Very
artfully, too, did Mrs. Johnson insinuate that her illness, of which
they had heard, had its origin in “hope deferred which maketh the
heart sick.”
The knowledge that a beautiful girl loves you—nay, is dying for
you, is sufficient, I suppose, to touch the feelings of men less
susceptible to female charms than Richard Delafield, and acting
upon the impulse of the moment, he started off without, however,
leaving any word as to his destination. Arrived in Boston, he went
to the Revere House, where, as we know, he casually heard of
Ada’s engagement with Herbert Langley. To say he was not
disappointed would hardly be just, for his self-pride was touched
in knowing that Ada had given her affections to another, and that