sans2017 Lime for Dry Scrubbing
DRY SCRUBBING
Spray Dryer Absorption (SDA) is a dry scrubbing process that is generally
used for low-sulfur coal. SDA FGD systems are typically located after the
air preheaters, and the waste products are collected either in a baghouse
or electrostatic precipitator. However, to achieve sulfur dioxide (SO)
reduction above 80% with good reagent use, the dry scrubber is generally
followed by a baghouse.
Flue gas is treated in an absorber by mixing the gas stream concurrently with atomized lime
slurry droplets. The lime slurry is atomized through rotary cup spray atomizers or through dual
fluid nozzles. Some of the water in the spray droplets evaporates, cooling the gas at the inlet
from 300°F or higher to 160°F to 180°F, depending on the relationship between approach to
saturation and removal efficiency. The droplets absorb SO, from the gas and reacts the
SQ) with the lime in the slurry. The desulfurized flue gas, along with reaction products,
unreacted lime, and the fly ash passes out of the dry scrubber to the bag-house.
PROCESS CHEMISTRY
The SO, absorbed in the atomized slurry reacts with lime in the slurry to form calcium sulfite
(CaS0x) in the following reaction
SO, + CaO + 1/2 H2O => CaSO3¢ 1/2 H20
A part of the CaSO; reacts with oxygen in the flue gas to form calcium sulfate (CaSO4):
CaSOg + 7502 + 2H,0 => CaSO,-2H,0sans2017 Lime for ry Scrubbing
Spray Dryer Absorber (SDA)
Particulate
Collector
Dry FOO fy ash
by product
Dry by product
toute or disposal
CIRCULATING DRY SCRUBBER (CDS)
There have been tremendous improvements in dry scrubbing technologies as their performance
is now equal to wet FGD in most cases. Both of the new technologies Circulating Dry
Scrubbers (CDS) and Novel Integrated Desulfurization (NID) are similar in nature and
performance. They can achieve 98% SO, removal on 2.5% sulfur coal. They are able to do this
by recycling each particle 50 to 100 times back to a fluidized bed before discharging.
The flue gas flows through a reactor from the bottom to the top and then enters a downstream
particulate control device, which can be either a fabric filter or an electrostatic precipitator. Fly
ash from incineration and fresh hydrate is dosed into the reactor, while a large part of the solid
material from the reactor is fed back to the fluidized bed as recirculate. Water is also injected to
lower the flue gas temperature and achieve higher separation performance. CDS systems use
a separate conventional hydrator to prepare the quicklime. Several companies offer this
technology in the USsans2017 Le for Dry Scrubbing
Tit rt
ul
Recirevation_|
Byproduet discharge
NOVEL INTEGRATED DESULFURIZATION (NID) BY ALSTOM
Alstom's design is the same for the reaction chamber but they add quicklime and water directly
into the particles being recycled in a patented device they call their "mixer/hydrator." Of the two
NID systems currently installed in the US Carmeuse supplies quicklime to both units.
hipsiwmcarmeusena.com/marletiiue-gas-reatmentry scrubbing 38