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Automation in Construction 146 (2023) 104693

Contents lists available at ScienceDirect

Automation in Construction
journal homepage: www.elsevier.com/locate/autcon

Review

3D printing with cementitious materials: Challenges and opportunities for


the construction sector
Rafael Robayo-Salazar, Ruby Mejía de Gutiérrez *, Mónica A. Villaquirán-Caicedo,
Silvio Delvasto Arjona
Composite Materials Group (CENM), School of Materials Engineering, Universidad del Valle, Cali, Colombia

A R T I C L E I N F O A B S T R A C T

Keywords: This review article includes a description of additive manufacturing from its advantages and opportunities for the
Additive manufacturing construction sector, highlighting the definition of a design methodology for cementitious material mixes suitable
3D concrete printing for 3D printing and the properties required of them. Included among the materials analyzed are conventional
3D printers
ones based on Ordinary Portland Cement (OPC) and non-conventional ones, with alkali-activated materials
Building materials
Cementitious materials
(geopolymers) to the fore. In United States, Europe and Asia this technology has interesting construction projects,
Alkali-activated materials however, in Latin America, 3D printing is still in the experimental phase, so it can be considered as a technology
Geopolymers that is in the process of being adopted. The results obtained in the development and research phase in different
countries such as Mexico, Brazil, Chile, Colombia, Guatemala, Peru, among others, are promising and it is
projected as an industrial reality in the near future. This paper presents the main challenges and opportunities in
implementing additive manufacturing.

1. Introduction and bibliometric analysis interest in 3D printing of cementitious material. The analysis was based
on the results of an advanced search conducted in Elsevier’s Scopus
Additive manufacturing, as defined by ASTM Committee F42 [1], is database, using the TITLE-ABS-KEY formula: 3d AND printing OR printed
the layer-by-layer fabrication of an element or piece from a 3D AND concrete. The results obtained correspond to those reported up to
computer-aided design (CAD). Application of this concept in the con­ October 2022, the date on which the query was last updated. From the
struction sector is considered an innovative and revolutionary solution bibliometric data extracted, a mapping of the co-occurrences of the
to the current challenges of the industry [2]. It enables printing parts keywords (text mining) was carried out using VOSviewer free software.
with a complex geometry - without using molds and with minimum The search returned a total of 1657 documents published between 1998
labor - while reducing both construction times and waste generation, and 2022 (October) (Fig. 1). In general, the results show a trend of
among other advantages. Additive manufacturing is assured a promising exponential growth in the number of publications related to the key­
future and will undoubtedly be employed widely by the construction words, especially from the year 2015, soaring from just 11 documents
sector for the 3D printing of housing, sustainably and at a more reported that year to 377 by 2021. China reports the most publications
affordable cost. This possibility has resulted in a growing interest in the to date, with 302 documents, followed by the United States with 227,
scientific community worldwide, becoming one of the lines of research Germany with 172 and Australia with 153 publications. The author with
with the greatest projection and potential for technology transfer at an the most publications related to this search is Jay G. Sanjayan from the
industrial level. In Latin American, implementation of additive Swinburne University of Technology (Melbourne, Australia) with 59 doc­
manufacturing in constructing housing and civil infrastructure is still in uments, followed by Viktor Mechtcherine from the Technishe Universität
the experimental phase. However, the technology is acknowledged as Dresden (Dresden, Germany) with 58 and Ming J. Tan of the Singapore
the construction method of the future. Center for 3D Printing (Singapore City, Singapore) with 39 publications.
Given the above, initially a bibliometric analysis was carried out to Meanwhile, the distribution of publications by areas of knowledge
analyze the behavior of scientific production and the international yielded Engineering as the first result with 45.5% (1358 documents),

* Corresponding author.
E-mail addresses: rafael.robayo@correounivalle.edu.co (R. Robayo-Salazar), ruby.mejia@correounivalle.edu.co (R. Mejía de Gutiérrez), monica.villaquiran@
correounivalle.edu.co (M.A. Villaquirán-Caicedo), silvio.delvasto@correounivalle.edu.co (S. Delvasto Arjona).

https://doi.org/10.1016/j.autcon.2022.104693
Received 29 September 2022; Received in revised form 14 November 2022; Accepted 26 November 2022
Available online 5 December 2022
0926-5805/© 2023 Elsevier B.V. All rights reserved.
R. Robayo-Salazar et al. Automation in Construction 146 (2023) 104693

Fig. 1. Trend of the number of publications related to the search (TITLE-ABS-


KEY): 3d AND printing OR printed AND concrete. Information collected from the
Fig. 3. Mapping of the density of co-occurrences related to the keywords (“3d”
Scopus database.
AND “printing” OR “printed” AND “concrete”). Analysis performed in the VOS­
viewer software.
followed by Materials Science with 24.9% (744 documents).
The analysis of co-occurrences of the keywords reported in the bib­
(yellow). Among the results, co-occurrences predominate related to the
liometric analysis can be seen in Fig. 2 (clusters) and Fig. 3 (mapping the
word “geopolymers”, also known as alkali-activated materials. This type
density of the co-occurrences). As can be seen, there are four clusters,
of non-conventional cementitious material is one of the options with the
related to the following keywords: 1) “3d printers” (red); 2) “cementitious
greatest potential for implementation in 3D technology, as will be
materials” (green); 3) “geopolymers” (blue) and 4) “3d concrete printing”

Fig. 2. Analysis carried out in the VOSviewer software of the main clusters identified in text mining (co-occurrences) applied to the combination TITLE-ABS-KEY (3d
AND printing OR printed AND concrete) (search carried out in Scopus). Cluster 1 (red): 3D printers; Cluster 2 (green): cementitious materials; Cluster 3 (blue): geo­
polymers; Cluster 4 (yellow) 3D concrete printing. Analysis performed in the VOSviewer software. (For interpretation of the references to colour in this figure legend,
the reader is referred to the web version of this article.)

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emphasized later in Section 4.2. technology would allow the restoration, in a short time, of the infra­
The bibliometric analysis identified the topics of interest to the sci­ structure and housing that have been affected. Likewise, the application
entific community and thus defined the topics addressed in this study. of this technology can reduce the volume of construction waste to almost
Based on this analysis, this article presents the challenges and op­ zero values (zero waste manufacturing). Another extremely important
portunities for academia and the industry of the construction sector, advantage for ensuring the sustainability of the construction sector is the
especially in those countries where the technology is still in the initial possibility of reducing the demand for materials compared to conven­
phase of development. Additionally, a methodology to be followed for tional (subtractive) construction methods, thus reducing the environ­
the design and characterization of cement mixes suitable for 3D printing mental impact. This is achieved through the integration of the concept of
is proposed. Based on this methodology, the additive manufacturing of typological optimization in 3D printing, which in turn allows structural
both conventional OPC-based and non-conventional cementitious ma­ lightening while maintaining the mechanical functionalities of the
terials is analyzed, placing emphasis on geopolymers or alkali-activated target component and reducing the weight loads of buildings.
materials. Finally, the main challenges for the construction sector to Additionally, 3D printing can reduce the cost of structures compared
implement large format 3D printing are highlighted specifically in those to conventional methods, since in the latter, labor can represent >50%
countries where it is still in the experimental phase. of the total cost, and materials and equipment could represent as much
as an additional 20%. In the case of 3D printed structures, although the
2. Additive manufacturing: Advantages and opportunities in the cost of the material may be higher, the cost of labor and occupational
construction sector accidents are significantly reduced [8]. In this regard, Ma & Wang [9]
present a comparative analysis of the construction of a low wall from
3D printing is an automated process of fabrication of products layer two methods; the traditional based on conventional concrete and 3D
by layer. As a result, the technology acquires the name of “additive printing. The authors consider the costs associated with the material,
manufacturing” and is considered one of the pillars of the fourth in­ pumping, labor and the use of forms, reporting that with 3D printing
dustrial revolution or “Industries 4.0”. In recent years, the construction technology, and applying the methods currently developed, the cost
industry has come to consider the use of 3D technology due to the ad­ reduction is 78%. The authors point out that, in the future, with new
vantages it offers compared to conventional construction methods [3]. developments in materials and equipment for 3D printing, the per­
Although the term additive manufacturing has become very popular in centage of cost reduction may increase. Thus, at the beginning of the
the last decade, application of this concept in the construction sector is construction of housing by 3D printing, it was estimated that the costs of
not new, since, for example, the use of slip forming techniques or a habitable house were reduced by 20%. Currently with new techno­
shotcrete technology has been widely used and numerous structures logical developments it is estimated that savings of up to 50% can be
have been built in sectors where traditional construction is not feasible, achieved. Additionally, some authors [10] highlight that the use of 3D
or would have been too complex, making the execution time of the work printing can promote greater thermal insulation of the building and
unfeasible [4]. reduce energy consumption achieving structures with greater thermal
Among the most outstanding advantages of 3D printing compared comfort. This is possible printing of geometries designed for a higher
with traditional construction methods are those listed in Fig. 4. level of thermal insulation (cellular or lattice structures) or modifying
In general, the higher productivity of 3D printing technology is due the mix to print, by incorporating air bubbles or aerogels [10].
to faster construction processes and reduced labor demand [5]. It is As shown in Fig. 5, 3D printing allows greater design freedom and
estimated that the 3D construction process takes a quarter of the time to the manufacture of elements with complex geometries that adapt to the
build a structure compared to conventional methods [6,7]. This futuristic vision of modern architecture [11]. This technology likewise
advantage can take on greater importance in the case of natural disasters facilitates the design of functional buildings and favors modular con­
(hurricanes, earthquakes, or others) or armed conflicts, where 3D struction from large-format prefabricated elements. These innovative
systems not only contribute to the efficiency of the construction pro­
cesses, but also of the deconstruction processes. In other words, a
modular construction based on 3D printed elements would facilitate the
selective demolition of buildings and therefore reduce the waste
generated. Together, these techniques point to the construction sector
adapting to the concept of the Circular Economy and at the same time
projecting itself towards a “zero waste” industry, according to the Sus­
tainable Development Goals (SDG) established by Agenda 2030 [12].
Indeed, the need to comply with the principles of sustainability in
construction processes requires the use of innovative methods that allow
the negative environmental impacts generated by the construction
sector to be mitigated, at least partially [7]. Taking into account that the
construction sector has been considered responsible for a high impact
due to high energy consumption (40%), generation of solid waste (40%),
CO2 emissions (38%) and water consumption (68%) [8], 3D printing
technology is promoted as an alternative option to conventional con­
struction processes. However, among the recommendations for the use
of 3D printing technology, it is stated that the raw materials used must
be local to ensure their technical, economic, and environmental sus­
tainability. With this purpose in mind, local printing reduces costs, de­
lays and the ecological footprint associated with the transportation of
the various materials and tools necessary to carry out the construction
project. It means then that 3D printing should preferably use local or
recycled (waste) materials, applying the concepts of the Circular
Economy.
Fig. 4. Advantages of 3D printing (additive manufacturing) in the construc­ To evaluate that a construction process is sustainable, a Life Cycle
tion sector. Analysis (LCA) must be conducted. Alhumayani et al. [14] researched

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Fig. 5. Some applications of additive manufacturing of cementitious materials. Source: the authors from [13].

the environmental impacts of large-scale 3D printing compared to Elsewhere, Weng et al. [15] compared the economic costs, envi­
conventional construction methods, using two different types of build­ ronmental impacts and productivity associated with an element pre­
ing materials: concrete and adobe. The results obtained showed that fabricated with the conventional system versus the implementation of
adobe-based methods generate lower environmental impacts, that is, a 3D printing. In this case, they analyzed the consumption of material,
lower global warming potential (GWP) than concrete-based methods, electrical expenditure, labor, and productivity. The results showed a
which is attributable to the OPC content. However, they highlight that, 25.4% reduction in total cost, 85% less CO2 emissions and 87.1% less
even so, the use of OPC concrete in 3D printing is less polluting (50%) energy consumption. Overall, productivity was improved by 48% with
than the use of the same material by conventional methods. the use of additive manufacturing technology.

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Although successful cases have been reported using cementitious proposed in Fig. 6. Among the most important parameters to take into
materials, such as those presented in Fig. 5, there are still issues that account for the design of the 3D printing cementitious materials are the
have not been fully resolved in order to take advantage of the full po­ following:
tential of 3D structural printing. These limitations include the following:
i) the modification of the properties in the fresh and hardened state of • Extrudability: cementitious materials used in 3D printing must have
the cementitious materials through the use of additions and special an acceptable degree of extrusion. This parameter is related to the
additives, ii) the 3D printing of fiber reinforced concretes, iii) the ability of the material to be supplied continuously through the
addition of reinforcement during the 3D printing process iv) the dura­ extrusion system and the pipes that transport it to the printing
bility of the structures printed in concrete, and v) the inclusion of 3D nozzle. Evaluation of this capacity must be carried out by adjusting
technology in construction codes and standards. These are some of the extrusion pressure and nozzle design, since these process parameters
current challenges that should be the object of research both at an ac­ directly influence it.
ademic and industrial level [16]. • Flowability: this is considered a key parameter for assessing the
printing performance of a cement mix. The printing process requires
3. Cementitious material mix design methodology and the printable mix to flow through the pipes, pass through the nozzle
properties required for 3D printing and be deposited layer by layer on the printing surface. One of the
design parameters that control the fluidity of mixes is the water/
Selection of the material to be printed must take account of the cement ratio. Likewise, the use of superplasticizer admixtures has a
material’s own parameters (properties in the fresh and hardened state) significant effect on this property, with the type and dose of
as well as the printing parameters (nozzle size, extrusion pressure, admixture being the most influential parameters. For their part, the
printing speed, size, and shape of element, etc.). In general, cementitious size distribution, morphology, and absorption capacity of the parti­
material suitable for 3D printing must have adequate extrusion capacity cles are factors that govern the rheological properties and therefore
(moldable and extrudable material), be fluid, be buildable, have an the fluidity in the fresh state of cementitious materials. Through an
adequate setting time, dimensional stability (low shrinkage) and possess adequate dosage of the mix. Fillers densify the microstructure by
a certain level of mechanical strength (structural applications). filling the voids between particles (greater packing) and exert a
A methodology for the optimization of cementitious material based lubricating effect to prevent the cement particles from flocculating
on the properties and variables of the additive manufacturing process is together, thus improving the fluidity of the mix in the fresh state.

Fig. 6. Methodology for the design and optimization of cementitious material for 3D printing.

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• Buildability: this refers to the ability of the material to retain its use of superplasticizer admixtures and the incorporation of setting
extruded shape under the action of its own weight and the pressure of accelerator or retarder admixtures.
the upper layers. The rheological properties of the cementitious In relation to the methodology proposed in Fig. 6, some authors
material must ensure accurate deposition and maintain shape just report the use of alternative techniques that are easy to implement for
after deposition, being strong enough to support the weight of sub­ assessing the extrudability, flowability and buildability of cementitious
sequent layers without collapsing and still be able to bond with materials for 3D printing [17].
adjacent layers. Buildability of cementitious materials can be Indeed, using the flow table test (Fig. 7) (ASTM C1437) it is possible
controlled by viscosity modifying agents and optimization of the mix to determine the flowability index of the mixes. The change in height
setting time. Design aspects (geometry and/or number of layers recorded immediately after lifting the truncated cone (mold) is known as
(height)) of the element can affect the buildability of a cementitious the mini slump or settlement. The diameter of the mix, recorded after
material and as a result must be taken into account in assessing a mix. applying 25 drops on the flow table is used to calculate the flowability
• Setting time: this must be long enough to ensure a continuous supply index, applying Eq. 1:
of material through the pipes while ensuring rapid modeling of the
d1 + d2 /2
piece. However, once deposited in its place, the material requires a Iflowability = (1)
d0
short setting time to achieve sufficient strength to support the upper
layers. Adjustment of mix setting time is based on the size of the where, d0 is the lower diameter of the truncated cone mold (100 mm), d1
element to be printed and the inter-layer time. A short setting time is the maximum diameter of the mix in direction 1 and d2 is the diameter
could affect the adhesion between layers and therefore the me­ perpendicular to d1 (Fig. 7).
chanical strength of the element. A very long setting time meanwhile As regards the flowability index, it is possible to determine it
would affect the buildability of the material, causing the piece to slip immediately after finishing the mixing process (t = 0) and after 10, 20,
and collapse during printing. In order to accelerate or prolong the 30, 45 and 60 min to evaluate the loss of workability over time. Indeed,
setting time of cement mixes, accelerating or retarding admixtures the working interval (open time) of a cementitious material could be
are used, respectively. Some authors call “open time” the work in­ directly related to the setting time of the mix. However, as mentioned,
terval that each cementitious material has before its properties in the the open time is usually less than the initial setting time, the important
fresh state are altered over time. This open time is less than the initial consideration being its correlation with the loss of flowability.
setting time of the mixes, for which it is important to find its corre­ For the case of the evaluation of buildability (layer-by-layer shape
lation through experimental tests. retention capacity), the truncated cone mold has been used, modifying
• Shrinkage: cementitious materials are susceptible to phenomena of the mini slump test (ASTM C1437) (Fig. 8) [18]. The mix is poured onto
contraction or shrinkage due to drying, which generates the the mold, which is subsequently removed, and a plate of glass (or
appearance of fissures and cracks that affect the appearance and another non-absorbent material) is placed on top of the mix to ensure a
mechanical performance of the element. Shrinkage can also affect homogeneous distribution of the load. Next, a controlled weight (for
the bond (interface) between the printed layers, causing them to example 800 g including the plate) is placed on the plate and the
detach. The content of mineral additions in the mix is one of the most deformation (collapse) of the mix is determined by means of the height
feasible ways to control shrinkage. A low water/cement ratio can difference (slump). Thus, mixes with a low slump level are characterized
reduce the deformation caused during the drying of the part. Also, by a high buildability factor.
the higher the amount of fine aggregate, the lower the shrinkage of The buildability of the mix, determined by this procedure, can be
the composite material. Additionally, the incorporation of short calculated as a percentage value according to Eq. 2:
reinforcing fibers has been shown to control levels of drying ( )
shrinkage, being effective for its implementation in 3D technology. Buildability of the mix (%) = 1 −
hi − hf
× 100 (2)
• Strength: the mechanical properties of 3D printed cementitious hi
materials have shown anisotropic behavior - their strength is
dependent on the direction of deposition of each layer. Indeed, the where, hi corresponds to the height of the truncated cone mold (50 mm)
best mechanical properties are obtained in the direction parallel to and hf is the final height of the mix in relation to the base.
the printing direction (longitudinal). In contrast, the properties Indeed, buildability is important in the parameterization of the
measured in the direction perpendicular (90◦ ) to the printing di­ element to be printed because the layers will undergo a level of settle­
rection are lower. In this regard, the addition of randomly dispersed ment that can affect the final height of the element compared to the
short fibers is considered the most effective method to reduce the initial model design. As such, the equation can be applied to determine
anisotropic behavior of the printed elements. the level of deformation (collapse) of the printed element with a certain
number of layers, in order to make the necessary height adjustments
As highlighted by Ma et al. [6], the optimization of a cementitious both in the computerized design (CAD) and in the parameterization of
material based on these parameters is a complex task, since there are two the part in the printer (G-code).
dilemmas in the mix design process with respect to meeting simulta­ Extrudability (continuity of deposition) can be evaluated by means
neously the specifications of flowability, buildability and mechanical of random extrusion processes, directly - using the 3D printer - or via
strength, thereby representing a challenge for the science and engi­ alternative assemblies such as that shown in Fig. 9 on a press or uni­
neering of the materials. The first conflict stems from the need to obtain versal testing machine. Some authors [18] have applied criteria for the
a fluid mix, which requires a high content of mixing water (high water/ indirect determination of yield stress in correlation with this method,
cement ratio). However, at the same time, a mix with good buildability taking into account that it is possible to determine the load necessary for
and adequate mechanical strength is required, properties that are pro­ the mix to start flowing through the nozzle. In fact, it is possible to
moted by low water/cement ratios. The second conflict stems from the correlate extrusion speed and pressure, depending on the diameter of the
setting time. In other words, adequate fluidity requires a sufficient open nozzle, and find the optimal variable configuration that ensures conti­
time to maintain the consistency of the mix during the process and avoid nuity of printing, before scaling the process to a real printer. Likewise,
possible blockages in the pipes and nozzle of the printer. On the other this alternative method can be used to assess, through visual inspection,
hand, obtaining a mix with sufficient buildability is related to fast setting the effect of the height between the nozzle and the printing surface,
times that ensure the buildability and the necessary support to advance avoiding the appearance of discontinuities (ruptures) generated by
with the upper layers. Consequently, these contradictions must be stresses during the deposition of the mix.
balanced, together, with the adjustment of the water/cement ratio, the Complementary to the fresh state properties (extrudability,

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Fig. 7. Graphic representation of the flow table test adapted for the determination of the flowability index in cementitious mixtures for 3D printing.

Fig. 8. Graphic representation of the test applied to determine the buildability of cementitious mixtures for 3D printing.

flowability, buildability and setting time), the study of rheological hysteresis curve), two parameters are identified - the “elastic limit”
characteristics such as viscosity, yield stress and thixotropy are (yield stress (Ƭ0)) and the “plastic viscosity” (ɳ) known as the slope of
extremely important in the cementitious material for 3D printing. In a the line. The plastic viscosity of the mix is a property that defines the
cement mix, the particles have some physical-chemical interaction with suitability of the material to be used in 3D printing and measures the
each other, for which a certain amount of shear stress is required to resistance to flow when a force is applied to it. For yield stress, two types
break this structure. As the structure “breaks”, the particles flow in a are recognized in 3D printing: static yield stress (SYS) and dynamic yield
suspension under viscous forces. When the shear stress is removed, the stress (DYS). SYS represents the force required for the material to flow
particles re-associate. One of the rheological models that best describes initially and DYS represents the force required to maintain the flow of
the behavior of cementitious mixes is recognized as the “Bingham fluid” the mix after the rupture of the thixotropic structure during the extru­
(Eq. 3). sion and 3D printing process. As such, the support capacity between
This describes materials that behave like a solid when subjected to layers depends on the SYS, for which a relatively high SYS value is
low shear stresses, but flow like a viscous fluid at higher shear stresses, a desirable. The extrusion capacity and workability of the mix during
behavior typical of a thixotropic material. Indeed, Fig. 10 represents the printing meanwhile depend mainly on the DYS, and it is desirable for the
behavior of a Bingham fluid as a function of shear stress (Ƭ) (vertical material to have a low DYS for 3D printing [20–25].
axis) and shear velocity (ɣ) (horizontal axis). In the graph (a typical
τ = τ0 + η • γ (3)

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4. Cementitious materials used in 3D printing

4.1. Additive manufacturing of conventional OPC-based cementitious


materials

The 3D printing process can consider the use of conventional OPC-


based cementitious materials, which, in turn, can be modified with the
use of different raw materials, including supplementary cementitious
materials (SCM) (of natural or artificial origin), admixtures (super­
plasticizers, viscosity modifiers, accelerators or retarders), natural or
recycled fine aggregates, fillers and fibers.
The following are prominent among SCM commonly used in 3D
printing [27]:

• Fly ash (FA): this is one of the most common by-products in the
national industry, since many companies still use coal to generate
energy for their processes. FA in cementitious mixes has a close
relationship with the rheological properties of the material. In most
mixes, yield stress (Ƭ0) and plastic viscosity (ɳ) increase with the
addition of FA [28]. However, some authors report opposite effects
[29], which depend on the class of FA, its particle size distribution
and morphology.
• Ground granulated blast-furnace slag (GBFS): A by-product in steel
manufacture, it can be used as a partial substitute for OPC for the
preparation of high-performance mixes. When added finely ground,
it has a high reactivity. In general, the use of GBFS in cement mixes
reduces the plastic viscosity (ɳ) in the fresh state [22,29].
• Silica fume or microsilica (MS): its main characteristic is the high
Fig. 9. Graphic representation of the extrudability test applied to cementitious content of amorphous SiO2 and its fineness [9]. MS is one of the most
mixtures for 3D printing. Source: [19]. commonly used SCMs in this technology, because in addition to
improving cohesion of the concrete in the fresh state, it improves the
mechanical properties and impermeability in the hardened state
[30]. Moreover, MS contributes to the lubrication effect, which is
important for the pumping of the cementitious material through the
pipes [28]. Regarding its effect on yield stress (Ƭ0) and plastic vis­
cosity (ɳ), various authors report an increase in Ƭ0 and a reduction in
ɳ with the addition of MS [22,23,29].
• Metakaolin (MK): this is obtained by calcination of a kaolinitic clay,
making it a thermally activated aluminosilicate. It is characterized by
its amorphous nature and high content of reactive alumina, pro­
moting the development of mechanical strength and reduction of
permeability. In general, the use of MK increases the yield stress (Ƭ0)
and the plastic viscosity (ɳ) of cementitious materials, aspects that
are necessary to achieve adequate buildability of 3D cementitious
mixes.

Other materials commonly used as property modifiers in cement


mixes, particularly in the fresh state, are as follows:

• Limestone (CaCO3): a mineral normally used as a filler in OPC-based


cement mixes. Finely ground limestone can modify the packing
Fig. 10. Typical hysteresis curve of a thixotropic material. Source: adapted by density of cement particles and improve the workability of the mixes
the authors from [21]. [9].
• Superplasticizer (SP) admixtures: these are admixtures used in the
A review of the various test methods used to characterize the prop­ preparation of OPC-based materials to increase the flowability of the
erties of 3D printed concrete in the fresh state (flowability, extrudability, mixes without increasing the water content. Another option is using
buildability, open time), and hardened (density, compressive, flexure SP to reduce the water requirement while maintaining constant
and tensile strength, and durability), is presented by [26]. The authors workability, thus promoting increased mechanical strength since it
highlight the importance of investigating the long-term durability admits lower water/cement ratios. SPs disperse cement particles by
properties, including the performance of the printed concrete exposed to means of repulsive (electrostatic) forces, releasing trapped water by
chlorides, carbonation, freeze-thaw cycle, and fire [26]. flocculation, thus improving the flow characteristics of the mix [9].
In the following sections, the general aspects for the use of conven­ Superplasticizers thus manage to reduce the yield stress (Ƭ0) and the
tional and non-conventional cements in additive manufacturing (3D plastic viscosity (ɳ) of the mixes [22].
printing) are listed. • Accelerator admixtures: OPC-based materials for 3D printing require
a short setting time to give the material sufficient early strength right
after it is deposited by the nozzle. Setting accelerators are a class of

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admixtures commonly used to obtain rapid setting, since they modify concretes [22]. However, some authors have reported satisfactory
the kinetics of the hydration reactions of the Clinker phases in the results at the micro-concrete level, using coarse aggregates with
OPC. Among the most common accelerators are those based on cal­ particle sizes of up to 10 mm [33]. The use of recycled aggregates
cium chloride (CaCl2). meanwhile from the crushing of construction and demolition waste
• Retarded admixtures: these are the opposite of accelerating admix­ [34], brick waste [35] and/or glass waste [36,37] has shown promise
tures and are used to extend the setting time of the mixes. In general, in 3D printing of mortars and/or micro-concrete, thus allowing the
the admixture is absorbed on the surface of the cement particles to production of more sustainable cementitious materials from an
form an insoluble layer, which delays the hydration process of the environmental point of view (Circular Economy). According to Zou
Clinker phases. The use of retarding admixtures prolongs the open et al. [38] and Wu et al. [39], the use of recycled aggregates can
time of the mixes for 3D printing. increase yield strength (Ƭ0) and plastic viscosity (ɳ) of the mixes -
• Viscosity modifying admixtures: these are water-soluble polymers favoring buildability and thixotropy, but at the same time affecting
that control the flow characteristics and rheological performance of extrusion capacity (extrudability), for which a balance of all prop­
the cementitious materials. A small dose of these admixtures can erties must be found with the use of admixtures (SP).
improve the dimensional stability of the materials and provide an
increase in the plastic viscosity (ɳ) of the mix. However, it should be Table 1 below summarizes the main parameters that have been taken
noted that when using pumped 3D printer mixes, mixes with higher into account for the design of conventional OPC-based cement mixes and
viscosity may require higher placement pressure. An example of a their 3D printing.
commonly used viscosity modifying admixture is hydroxypropyl SCM: supplementary cementitious materials, HPMC:
methylcellulose (HPMC). hydroxypropylmethylcellulose.
• Fibers: cementitious materials for 3D printing can be reinforced by
incorporating short fibers such as fiberglass, carbon, polypropylene
(PP), polyvinyl alcohol (PVA), steel, basalt, natural fiber, etc. to 4.2. Additive manufacturing of non-conventional cementitious materials:
improve the flexural-tensile properties and post-fracture toughness geopolymers
of the printed structures. The fibers also contribute to the control of
the appearance and propagation of fissures and cracks caused by Most designs of cementitious mixes for 3D printing employ OPC as
phenomena of contraction or shrinkage due to drying, a pathology the main material, although as mentioned above, the use of SCMs such
that can affect 3D printed structures. Likewise, short fibers have as FA, GBFS, MS and MK as a partial replacement for OPC has been
turned out to be an effective solution for mitigating the phenomenon evaluated (Table 1). Given that the production of OPC is associated with
of anisotropy present in 3D printed elements [16,31,32]. a high consumption of natural resources and high CO2 emissions (≈0.8
• Aggregates: The use of aggregates provides dimensional stability ton of CO2/ton of OPC), other alternative materials that incorporate
both in the fresh and hardened states and therefore can contribute to high proportions (≥70%) of SCM have been proposed for some appli­
the control of the phenomena of contraction or shrinkage due to cations. Among these are geopolymers (inorganic polymers) and alkali
drying of the mixes. The type of aggregate is mainly limited by the activated materials (AAM), considered mostly as low carbon footprint
size of the nozzle, feeding pipes and the extrusion or pumping sys­ materials as they are commonly based on locally available minerals and/
tem. A particle size of <2 mm is generally used. Therefore, 3D or industrial by-products (wastes) and produced at relatively low tem­
printing cementitious materials are usually mortars, rather than peratures (25–90 ◦ C) compared to those reached during the clinkeriza­
tion process (≈1450 ◦ C) of OPC. In this regard, geopolymerization is a

Table 1
Summary of the main design parameters of conventional OPC-based cement mixtures for 3D printing. Source: the authors.
MCS Admixtures Fibers a/c ratio Aggregates Printing parameters Ref.

0–40% MK Nozzle = 15 mm, 40 ×


SP (2%)
20–60% – 0.30 Sand (ratio 1:1.5) 13.5 mm Chen et al. [40]
HPMC (0.24%)
CaCO3 Velocity = 35–100 mm/s
Nozzle = 40 × 100 mm
16.6% FA SP (0.1%) Sand (≤4.75 mm)
– 0.36 Layer height = 40 mm Ji et al. [33]
7.1% MS HPMC (0.2%) Gravel (≤10 mm)
Velocity = 13 mm/s
60% FA
Nozzle = 50 mm
3% MS SP (1%) PP (6 mm) (1.4–5.4%) 0.22–0.30 Sand (≤2 mm) (ratio 1:1/1:1.6) Tran et al. [31]
Velocidad = 60 mm/s
8% CaCO3
SP (0.95%)
15% FA Nozzle = 10–20 mm
CaSO4 (3%) PP (12 mm) (0.09%) 0.30 Sand (≤0.85 mm) (ratio 1:1) Huang et al. [41]
6% MS Velocity = 13–40 mm/s
HPMC (0.02%)
10% MS SP Nozzle = 25.4 × 38.1
Kazemian et al.
0.3% Nano- (0.05–0.16%) PP (6 mm) (0.12%) 0.43 Sand (≤2.36 mm) (ratio 1:2.3) mm
[30]
clay CaCl2 (1–3%) Velocity = 60 mm/s
16.5% FA
SP (1%) Steel (6 mm, 10 mm) Nozzle = 15 mm
16.5% MS 0.15 Sand (ratio 1:1) Yang et al. [32]
HPMC (0.1%) (1% vol.) Velocity = 15 mm/s
2.4% CaCO3
25–30% FA Nozzle = 15 mm
SP – 0.33–0.35 Sand (21–26%) Lui et al. [28]
2–4% MS Velocity = 100 mm/s
Nozzle = 6 mm
1.8% SP de Matos et al.
10% MS – 0.30 Ground quartz (ratio 1:1) Layer height = 3.5 mm
1.5% TiO2 [42]
Velocity = 15 mm/s
21.1% FA SP (1%) 64% Recycled sand (brick residue) (≤4.75 mm) Christen et al.
PP (6 mm) (1% vol.) 0.45–0.58 Velocity = 60 mm/s
10.6% MS HPMC (0.3%) (ratio 1:1.6) [35]
20% FA 25, 50, 75 y 100% Recycled sand (glass residue)
– – 0.35 Nozzle = 10 mm Ting et al. [36]
10% MS (≤2 mm) (ratio 1:0.8)
SP (0.7%) Nozzle = 50 × 20 mm
50% GBFS – 0.35 30% recycled gravel (≤8 mm) (ratio 1:1.7) Rahul et al. [34]
HPMC (0.1%) Velocity = 100 mm/s

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R. Robayo-Salazar et al. Automation in Construction 146 (2023) 104693

process from which aluminosilicate-type materials in the presence of an [48]. As such, the addition of secondary sources of calcium replaces the
alkaline medium (activator) give rise to a three-dimensional structure thermal curing processes (60–90 ◦ C), which are necessary in precursors
that allows obtaining a strength and durable material, with similar or with low calcium content, allowing the development of adequate
even superior properties to those of traditional binder materials such as strength at room temperature (≈25 ◦ C). Naphthalene and
OPC. polycarboxylate-type superplasticizer admixtures have been used to
In addition to the possibility of obtaining more environmentally promote the workability of geopolymeric mixes. As in OPC-based sys­
friendly cements, geopolymers have some additional advantages such as tems, the use of CaCO3-type modifier materials has shown rheological
greater resistance to fire, chemical agents, aggressive environments and mechanical benefits in 3D printing of geopolymers. Regarding the
(durability) and a higher level of thermal insulation (low conductivity). incorporation of aggregates, the use of fine aggregates with cement:
Additive manufacturing of geopolymers is thus considered a promising aggregate ratios of <1:2 and particle sizes of up to 2 mm is reported. In
technology to address current challenges of industry and offer new this regard, larger particle sizes can lead to blockages in the extrusion
design opportunities, understanding that conventional methods should nozzle or pipes. Among fibers used to reinforce geopolymeric mixes;
not necessarily be eliminated. There is thus a marked tendency towards carbon, PP, PVA and glass fibers stand out [20,27,49–52].
research on these types of non-conventional cements and their imple­ Table 2 lists the main design conditions for geopolymeric and the
mentation in additive manufacturing processes, as can be seen in the most important parameters for 3D printing.
bibliometric analysis reported above. As previously noted, geopolymers Among the most interesting geopolymeric precursors today, CDW is
represent the third cluster in text mining (co-occurrences) applied to 3D capturing the attention, largely due to its worldwide availability and the
printing of concrete (Fig. 2). According to Raza et al. [20], applying environmental liability associated with its poor handling and manage­
geopolymers in 3D printing was introduced in 2016 by Xia and Sanjayan ment, as is the case in some countries of Latin America such as Colombia
[43], this topic being very recent, innovative and interesting for research [58]. Şahin et al. [19] report promising results in this regard related to
groups from various universities and centers worldwide. the alkaline activation of ceramic and glass-type residues, using mixes of
In general, geopolymeric precursors commonly used for 3D printing NaOH, Ca(OH)2 and/or Na2SiO3. The RCD geopolymer activated with
include SCMs such as FA, GBFS, MS and MK. Other industrial residues or NaOH (6.25 M) and 10%-Ca(OH)2 exhibited the best performance in
by-products rich in silica (SiO2) and alumina (Al2O3) also have an op­ terms of rheology and compressive strength for use in 3D printing pro­
portunity to be used through alkaline activation technology and its cesses [19]. The authors conclude that Ca(OH)2 increases the plastic
implementation in 3D printing [29,44]. Such is the case of construction viscosity (ɳ) and the buildability of the mixes. They report meanwhile
and demolition waste (CDW), especially concrete, ceramic and masonry that Na2SiO3 drastically decreases the plastic viscosity (ɳ) of the mixes,
waste [45,46]. Among the alkaline activators used, hydroxides (ROH, R increasing workability and therefore affecting buildability (adverse
(OH)2), weak acid salts (R2CO3), strong acid salts (Na2SO4, consequence). Additionally, they affirm that Na2SiO3 accelerates the
CaSO4⋅2H2O), and siliceous salts R2O(n)SiO2 stand out, where R it is an setting of the mixes, reducing the open time necessary for 3D printing.
alkaline ion of the Na, K or Li type. Among these, mixes of sodium hy­ Regarding the environmental sustainability of these non-
droxide (NaOH) and sodium silicate (Na2SiO3) are recognized as the conventional cements, Amran et al. [52] report that the use of geo­
most common alkaline activator. The use of anhydrous (solid) sodium polymers in 3D printing allows the reduction of the carbon footprint by
silicates stands out as an alternative for the synthesis of what are known ≈61% compared to conventional cementitious materials based on OPC
as “one-part” or “just add water” geopolymers [47]. Solid activators (3D geopolymer (0.114 kg•CO2/L) vs. 3D OPC (0.296 kg•CO2/L)).
meanwhile such as sodium sulfate (Na2SO4) and sodium carbonate Consistent with these results, Zhong and Zhang et al. [49] report 59%
(Na2CO3) have been successfully used in the synthesis of hybrid ce­ reductions in CO2 emissions from a geopolymer for 3D printing based on
ments, in which the geopolymeric precursor is mixed with additions the combination of 50%FA + 50%GBFS in relation to conventional
(≤30%) of materials rich in calcium, such as lime (Ca(OH)2) [19] or OPC cementitious materials based on OPC and SCM. The content and type of

Table 2
Summary of the main design conditions of geopolymeric and parameters for 3D printing. Source: the authors.
Precursor Alkaline activator Admixtures Aggregates Curing Printing parameters Ref.

Nozzle = 20 × 4
NaOH Powdered quartz (≤250 μm) (ratio
FA – – mm Ranjbar et al. [53]
Na2SiO3 1:1.5)
Velocity = 5 mm/s
90–100% FA
NaOH Nozzle = 10 mm
0–10% GBFS – Sand (ratio 1:1.5) 25 ◦ C Panda et al. [54]
Na2SiO3 Velocity = 80 mm/s
0–10% MS
Magnesium aluminum silicate
50% FA Anhydrous Fine steel (ratio 1:0.5) Nozzle = 30 mm Muthukrishnan et al.
(0.75%) 23 ◦ C
50% GBFS Na2SiO3 Gravel Coarse sand (ratio 1:1) Velocity = 10 mm/s [55]
Sucrose (retardant) (0.5–1.5%)
60–70% FA
15–35% NaOH 60 ◦ C (24 Nozzle = 20 mm
Graphite nanoparticles (0.1–1%) Sand (≤1 mm) (ratio 1:0.55) Chougan et al. [56]
GBFS Na2SiO3 h) Velocity = 20 mm/s
5–15% MS
50–85% FA
0–30% GBFS NaOH Nozzle = 4 mm, 6
0–30% OPC Na2SiO3 Powdered alumina (Al2O3) (1%) – – mm Alghamdi et al. [57]
15–30% Na2SO4 Velocity = 20 mm/s
CaCO3
Fine sand Nozzle = 30 mm
50% FA Anhydrous 60 ◦ C (24
– (≤840 μm) Layer height = 10 Bong et al. [47]
50% GBFS Na2SiO3 h)
(ratio 1:1.5) mm
NaOH Nozzle = 15 mm
CDW Ca(OH)2 – 23 ◦ C Şahin et al. [19]
Na2SiO3 Velocity = 16 mm/s
NaOH Nozzle = 20 mm
CDW Ca(OH)2 – 23 ◦ C Ilcan et al. [18]
Na2SiO3 Velocity = 60 mm/s

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R. Robayo-Salazar et al. Automation in Construction 146 (2023) 104693

alkaline activator plays a fundamental role in the level of reduction of via the implementation of 3D printing technology. Regarding the con­
the carbon footprint of geopolymers, with Na2SO4 and Na2CO3 being the struction of new housing, the DANE reports a total of 32 million square
most attractive from the environmental point of view [48]. meters for housing in the first quarter of 2022, of which 88.5% were
Regarding the application of 3D printed geopolymers, like conven­ apartments and the remaining 11.5% were houses. Likewise, of the total
tional cementitious materials (OPC) these are related to the construction census area for housing, 62% corresponded to housing other than social
sector. However, the intrinsic characteristics and/or properties of geo­ interest housing and 38% to VIS [63]. This distribution reflects that
polymers also make them attractive for other industries, such as aero­ industrialized construction (apartments) predominates in the housing
space. As mentioned by Lazorenko et al. [51], the use of geopolymers for sector, which is considered an advantage considering the introduction of
the 3D printing of infrastructure that needs to withstand high temper­ large-format additive manufacturing as a precursor for new housing
atures and/or chemically aggressive environments (durability) is construction in the country.
considered advantageous in relation to materials based on conventional In general, the 3D printing of cementitious materials in Latin
cements (OPC). Nodehi et al. [59] presented a critical review on the American is still in the experimental phase. However, progress has been
durability properties of 3D printed concrete, including the different made in printing full-scale prototypes. In Tabasco, Mexico, a community
variables related to the materials and the printing process, and states of houses has been built for the population living in extreme poverty, the
that exposure to environmental conditions is a key variable in the ma­ objective is that these can withstand a magnitude 7.4 earthquake and
terial performance because printed materials are generally used in the tolerate extreme weather conditions. In Guatemala, a cement company
same place where they are printed. For example, variables such as print in association with a European company is investigating the application
speed and pump pressure can have a significant influence on the of 3D printing to help reduce the housing deficit in the country. Uni­
porosity of deposited layers. The author points out that, although the versities in Chile at a laboratory scale have managed to develop micro-
durability of cementitious materials has been investigated for approxi­ concrete elements up to 1.50 m high by integrating the principles of
mately a century and its results are well documented, 3D technology circular economy and reusing industrial wastes. In Peru, it is intended to
applied to construction materials is relatively new and there are no build houses using soil mixtures stabilized with organic additives and
codes or standards that allow its evaluation, so which research on the Portland cement-based mortars. In Colombia, in 2017, the construction
durability of structures once exposed to different aggressive environ­ company Conconcreto [64] developed a large-format 3D printer capable
ments should be studied [59]. of printing prefabricated parts and reinforced concrete elements. In as­
Geopolymers have thus been proposed as a sustainable alternative sociation with the Corona group, they developed different mixes that
for 3D printing of extraterrestrial habitats that allow human presence in have made it possible to materialize the first prototype of a habitable
future space missions. This is how the various space agencies, including module printed with 3D technology, called “Origami House” (Fig. 11).
NASA, are studying the use of 3D geopolymer printing technology for This housing prototype has a functional area of 23.4 m2 and consists of a
the construction of future human colonies on the Moon and/or Mars, set of 32 elements printed in 27 h and assembled in-situ [64]. Addi­
without the need to bring prefabricated materials or constructions from tionally, different elements of urban furniture have been produced
Earth. In this regard, the feasibility of using the regolith of the Moon and applying this technology. The projects are located in the facilities of the
similar extraterrestrial surfaces as raw material for the synthesis of 3D School of Engineering of Antioquia in Medellín.
geopolymers is being studied in various research centers [60–62]. Regarding the study of conventional cementitious materials based on
OPC of Colombian origin, Vergara and Colorado [66] report promising
5. Challenges and opportunities in 3D printing in Latin America results in OPC mortars modified with kaolin (0–50%), calcium carbon­
ate (CaCO3) (0–20%) and superplasticizer (2%). To date, no studies
In general, Latin America has been slower in adopting 3D technol­ related to non-conventional cementitious materials have been reported,
ogies compared to European countries, probably because for companies which means a challenge or an opportunity for academia and industry.
it involves a strong investment and at the same time there is a lack of Regarding the availability of alternative raw materials for 3D printing in
knowledge of the advantages and possibilities of additive manufacturing Colombia, several supplementary cementitious materials (SCMs, natural
compared to conventional construction technologies, all this coupled and artificial) have been identified that could be used, not only as
with the lack of recognition of technology in construction codes and modifiers of OPC-based cement mixes but as geopolymeric precursors.
standards. However, today, 3D technology is recognized as one of the Among these materials, the following stand out: natural pozzolan, MK,
possible solutions to the global housing crisis. It should be added that, by FA, GBFS, glass waste and CDW (concrete waste, ceramics waste and/or
2030, the UN Habitat predicts that 3 billion people will live without a brick waste) [19,45,46,67,68], among others.
safe haven, for which they will need access to housing, basic infra­ It should be added that the possibility of using locally available
structure, and water and sanitation systems [59]. And considering that materials for the in situ printing of housing is considered an alternative
Latin America represents about 10% of the world’s population, 3D even more sustainable, from the environmental and economic point of
technology is considered an option to help reduce the deficit of social view, than the additive manufacturing of conventional OPC-based
interest housing at an affordable cost for a greater number of people. cementitious materials. However, according to Schuldt et al., [69],
For example, in Colombia, the National Quality of Life Survey carried one of the most relevant aspects to consider for on-site 3D printing from
out in 2020 by National Administrative Department of Statistics (DANE) locally available materials is the minimization of transport logistics, a
[63], with the support and observation of UN-Habitat, reported that the critical aspect in rural or remote areas with difficult access for 3D
housing deficit in the country was 31.4%. It should be clarified that the printers and mixers. This means that, in some cases, transporting pre-
housing deficit refers to families that live in homes with structural and fabricated elements (3D printed modular components) and their sub­
non-structural deficiencies and for which it is possible to make im­ sequent assembly in place (off-site 3D printing) may be more advanta­
provements or adjustments in order to achieve adequate habitability geous versus on-site 3D printing of locally available materials.
conditions. On reviewing the survey results, it was observed that, in the In this regard, 3D printed construction aims to use locally sourced or
capitals, 21.6% of households were in housing deficit, while in popu­ in situ materials when available and accessible [69], highlighting 3D
lated and dispersed rural centers the proportion was 64.5% of house­ printing of soils and clays. According to that reported by Gomaa et al.
holds, rural areas being the most affected. As such, only Bogotá and 10 of [70], earth-based construction materials (soils) are divided into sands,
the 32 departments of the country reported a percentage of households clays, adobe (cob) and rammed earth. Among these, 3D printing of clays
in housing deficit lower than the national total (31.4%). The compo­ has received the most attention from the construction sector, due to their
nents of this indicator (housing deficit) were related to the structure of rheological properties and the high extrudability that characterizes
the house and the material of the walls, aspects that might be mitigated them. Moreover, the constructions designed from these materials are

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R. Robayo-Salazar et al. Automation in Construction 146 (2023) 104693

Fig. 11. a) “The Origami House”, a housing prototype by the Conconcreto construction company and b) urban furniture elements produced with 3D printing.
Source: [65].

characterized by their bioclimatic properties, maintaining a relatively housing construction in rural areas.
stable temperature inside, regardless of the heat or cold in the external
environment [70]. In Colombia, 3D printing of soils and clays could be 6. Conclusions and limitations
applied in remote (rural) areas where the transportation and acquisition
of raw materials is complex. • As has been shown in this study, technological advances related to
In light of the above, researchers from the University of Antioquia 3D printing of cementitious materials are increasing. The numerous
reported promising results in the 3D printing of local materials such as advantages in economic and environmental terms (sustainability)
kaolinitic clays [71]. In their research, they adapted a syringe to a ro­ that the implementation of additive manufacturing has shown in the
botic arm to extrude the material (direct printing technique), managing construction sector has promoted the interest of the industry in this
to assess the effect of the water/solids ratio on the physical, mechanical technology and neither has the scientific community been indif­
and microstructural properties of clays, which subsequently were sin­ ferent; on the contrary, 3D printing is positioned as one of the
tered at 1100 ◦ C. It should be noted that the dependence on high- strongest lines of research in the world, with an exponential trend
temperature sintering processes is considered a technological limita­ since 1998.
tion for in situ applications. Regarding the results, the authors showed • The use of recycled and locally generated raw materials (waste and/
that the water content should be between 36 and 40% (by weight) to or industrial by-products) allows technological solutions with a
achieve a good surface finish and adequate rheological behavior. sustainable and environmentally friendly approach. 3D printing can
Additionally, they reported that the failure of the printed materials was even use locally available materials, such as native clay or soil. This
in the interface between the layers (beads), due to the presence of approach also significantly reduces construction costs and moves
cracking phenomena. In a subsequent study, members of the same group towards zero marginal cost. In addition, 3D printing should respect
evaluated the incorporation of additives such as sodium silicate and the forms of nature and avoid forms imposed by traditional con­
sodium polyacrylate with the aim of improving the properties of the struction materials, giving rise to architectural designs that enhance
material [72]. Likewise, the effect of incorporating industrial waste, in the built environment.
this case electric arc slag (10–30%), on the 3D printing capacity of • The development of new cementitious materials and dosages that
kaolinitic clays was evaluated [73]. allow increasing the possibilities of applying additive manufacturing
In general, advances in this line of research are very recent and few in the construction of housing and civil infrastructure is one of the
publications have been reported to date in Latin American countries. greatest challenges for research groups and industry. Among the new
However, additive manufacturing technology applied to the construc­ (non-conventional) cementitious materials used in 3D printing,
tion sector is a potential sustainable solution for the current housing geopolymers stand out, these being one of the main clusters identi­
deficit, a situation enhanced by the possibility of using locally available fied in the text mining (bibliometric analysis) carried out in this
raw materials (the use of waste and/or industrial by-products – and to study. The use of alkali-activated materials (geopolymers) as
some degree a circular economy approach). This aspect is an opportu­ cementitious material in 3D printing processes would indeed allow
nity to promote the sustainability of the construction sector through the the construction sector a higher level of incorporation of supple­
implementation of alternative house-building methods to conventional mentary cementitious materials (SCMs, natural and artificial), even
ones, which can also be implemented in many Latin American countries. until achieving total substitution of OPC in some applications, which
Indeed, since some countries with a high seismic hazard risk, it is is noteworthy from an environmental point of view. Among the
necessary to ensure that the constructions comply with the country’s geopolymeric precursors, natural pozzolans, MK, FA, cane bagasse
seismic design standards, an aspect that must be demonstrated through ash, rice husk ash, GBFS and glass residues stand out due to their
trials and experimental tests. availability, along with CDW (concrete waste, ceramics waste and/or
The study of cementitious materials compatible with 3D technology, brick waste), among other aluminosilicate materials. It is highlighted
as well as the development of technical standards and specifications for that the SCMs available are mostly waste or industrial by-products
the correct assessment of the mechanical behavior of the elements and that lack any added or commercial value, currently presenting low
structures manufactured with these materials, requires the linking up of levels of use and their final disposal being a real problem for those
various disciplines or fields of knowledge, such as Materials Science and generating large quantities. As such, the joint implementation of
Engineering, Civil Engineering, Mechatronics Engineering, Robotics, alkaline activation (geopolymerization) and additive manufacturing
Design, and Architecture, among other disciplines. Currently, research (3D) technologies is proposed as a sustainable solution to the housing
groups from the School of Materials Engineering in alliance with the deficit, making use of locally available raw materials that are mostly
School of Civil Engineering of the Universidad del Valle, in Cali waste or industrial by-products.
(Colombia), supported by professionals from Mechanical Engineering • 3D printing being a relatively recent technology in the construction
and Architecture, are researching 3D printing of conventional and non- industry, it requires innovation and progressive developments in
conventional cementitious materials for their application in sustainable order to reap the technical, environmental and social benefits.

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R. Robayo-Salazar et al. Automation in Construction 146 (2023) 104693

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