| il Haloalkane and Haloarenes S518 D © CHEMISTRY eSaral.comBe Saral Haloalkane and Haloarenes Contents 1 Module Description Page - i 2 Homework Index Page - il 3. Exercise 1 Page - 1 4, Exercise 1A Page - 3 5 Exercise 2 Page - 7 6 Exercise 2A Page - 12 7 Answer Key Page - 16 Note Detailed solutions are available on the eSaral App. wWSaral & at wae area Slws Saral Haloalkane and Haloarenes Module Description For mastering the concepts only learning is not sufficient. We have to practice and apply those concepts in problem solving. This sheet does just that. It contains a collection of problems segregated in the following exercises to help you master the concepts in a systematic and organized way. “Practice makes a man perfect” 1. Concept builder—1& 1A As soon as you have finished learning the concept do the problems from these exercises first These exercises contains easy level questions to help you build your concepts. 1 —+» Contains Single Correct Type questions 1A —» Contains pattern based questions incorporating the latest JEE Advanced based patterns like more than one correct, matching list, match the column, ete. 2. Brain Booster— 2 & 2A Now that you have built your concepts it’s time to master them by solving Brain Boosting problems, Don’t hurry through these problems. Take time to solve & learn from them. These exercises contains Medium & Tough level problems. Do questions from 2 & 2A after attempting I & 1A 2 —+ Single Correct Type questions. 2A ——» Pattern Based questions. 3. Simulator — JM & JA Contains questions from previous year JEE Mains & JEE Advanced questions in exercise JM & exercise JA respectively. Get the real taste & feel of the type of questions being asked in JEE. It’s a great tool for simulating your mind with JEE problems. These exercises are not included in the module but are provided separately. JM —» JEE Mains previous years topic wise questions. JA —+ IEE Advance previous years topic wise questions. Eee scat (rodBe Saral Haloalkane and Haloarenes Home Work Index Problem solving is an integral part of learning, Find questions to solve after each video in the homework Index, Make sure that you attempt all the problems (in Ex 1 to 2A) after learning a topic from the videos. For example if you have finished topic 8, first attempt all the problems listed in the index corresponding to topic 8 before proceeding to the video of topic 9. Sr. No. Topics Ex-l Ex-1A | Ex-2 | Ex-2A 1 Introduction to Haloalkenes and Haloarenes 2 [Basics of Reaction Mechanism 3. |Blectrophile, Nuckophile and Role of Solvent! 1-2 [Nucleophilcity, Basic Strength and Leaving 4 \ciroups 3-4 1 12 1 5 |Preparation Methods Recap 5-6 35 2,12 6 |Nucleophilic Substitution Reaction Via SN1 | 6-9 2 6 13 7 |Nucleophilic Substitution Reaction Via SN2_} 10-12 pone 3) 7.16 3 Preparation of Alkyl Halides by Nucleophilic 8 petition 13-14 TR 17-18 10 9 |Blimination Reactions 15-17 19-25 | 9,11 19 _[SNESSSN2, EI ws F2, Sustiuton vs 9 Elimination 1 _ [Chemical and Physical properties of [Haloarenes: 12 Jacc 18-21 | 14-15,19 | 26-30 |4-8, 14-15 wWSaral & at wae area SlwSaral Exercise - I Haloalkane and Haloarenes Concept Builder SINGLE CORRECT TYPE Each question has FOUR options for correct answer. ONLY ONE of these four options is correct option. For each question, choose the correct option to answer the question. Electrophile, Nucleophile and Role of Solvent QU. CH, GH, and GH, respectively are = (A) Electrophile, nucleophile, nucleophile (B) Electrophile, nucleophile, electrophile (C) Nucleophile, nucleophile, nucleophile (D) Electrophile, electrophile, electrophile Q2. Which one of the following is an clectrophile:- (A) RO- (NH, (B) BF, (D) ROH ucl hilicity, Ba: Leaving Groups trength an Q3. Order of nucleophilicity in polar aprotic solvent:~ (A) > Br > Cr>F (B) F > Cl > Br >I (b> cr>Br>F (D) F >I > Br > Cr Q4. The order of ease of leaving group would be = OAc OMe 1 u —OSO.Me -OSO.CF, m Vv (A) [> > 1> IV (B) IV> 1 >1>11 (©) > >1>1V (D) > m1 >1V>1 Choose that alkane which cannot give only one monochloro derivative upon reaction with chlorine in sun light ry O ok (c) xx (D) >< HBr + H,0, > Product. , Product is : (A) 3° alkyl bromide (B) 1° alkyl bromide (C) 2° alkyl bromide (D) 1° alcohol jucleophilic Substituti Reaction Via SN1 Qi. Consider the following bromides : () Mer a ZY~we Br «up Mee Br The correct order of S.1 reactivity is : (A) [> I> (B)II>MI>1 (C)U>1> UL (D) I> U>1 Reactivity order towards SN! is or" oy" —Br wWSaral & at wa area SI 0 @wSaral CH, CH, cl Br ay (AIS 1>IV>I (B)IV>I> TFT (C) VI>Hl>1>H (D)M>IV>>1 Ww Q9. The decreasing order of rate of S,1 reaction for the following compounds is ~ Pr P Ph f Ph Ph-CH-Ph CH; o a Ph-CH-CH) PhCH,Br Br a avy (A) (1) > (ID) > (IIT) > (IV) (B) (ID > (1) > (IID) > (IV). (C)(AV)> I) > aD>() (Dy att) > av) >a)> a) Reaction. a Q10. eo + Nacn PMSQ, A» Identify mechanism of above reaction (A) SN (B) SN’ SS) (D)E* qu. 1°gem, 2°gem and vie-dihalide of propane on treatment with aqueous KOH respectively gives:- (A) Propanol, propanone, propanoic acid (B) Propanone, propanol, glycol (C) Propanal, propanone, propylene glycol (D) Propanal, propanone, trimethylene glycol Qi. Haloalkane and Haloarenes CH=CH 5A 9 5 Bis Preparation of Alkyl Halides by Nucleophilic Substitution Qua. c fon 80% (4) —}—Br Hy me a (A) ft & cH Hl cl D) ¢ Mi Cl cH © n—}—on 00h, () n—|— ar Prine CH cH ination Reactions Qis. Alcoholic caustic potash is a specific reagent for :- (A) Dehydration (B) Dehydrogenation (C) Decarboxylation (D) DehydrohalogenationwSaral Q16, Major product of the following reaction is:- Br CH, ¢~ CH,-CH,- + aleo. KOH > h (A) 1-Butene (B) 2-Butene (C) Butane (D) 1-Butyne Haloalkane and Haloarenes Q19.N-bromosuccinimide is the usefull reagent and when reacts with CH,-CH = CH, := (A) The allylic hydrogen is replaced by Br atom (B) Br atom adds on double bond (©) The hydrogen atom present on unsaturated C-atom is repaleed by Br- atom (D) None of the above QI7. Possible products of the reaction are :- Q20, Iodoethane reacts with sodium in the cy HHL 9 presence of dry ether :- (A) Pentane (B) Propane (C) Butene (D) Butane (B) Qu. SSS x (major product) ; X is: (D) All of these 1 (A) (B) as. ran Br Major product will be: Br CH, CH, oO wCh« “GI © “OD ‘Br H Br CH, © cy ) LS Bi Exercise - 1A Concept Builder ONE OR MORE THAN Qi. The nucleophilicities of CH, , NH,, OH ONE CORRECT TYPE and F- decrease in the order ~ Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are) correct option(s). For each question, choose the correct option(s) to answer the question. (A) CH, > NH, > OH >F (B) OH > NH, > CH, >F (C) NH, > OH > CH, >F (D) CH > OH-> F-> NH wSaral & at wa area SlwSaral @. | H-C-OTs Which of the following compound can't give S\1 reaction readily ? (A) Opens (B) Or Br ¢ (D) A Which of the following statements is/are truc? (A) CH,-CH,-CH,1 will react more readily than (CH,), CHI for S,2 reactions. (B) CH,-CH,-CH,-Cl will react more readily than CH,-CH,-CH,-Br for S,2 reaction. (C) CH,-CH,-CH,-CH,-Br will react more readily than (CH,),C-CH,-Br for $,2 reactions (D) CH,-O-C,H,-CH, Br will react more readily than NO,-C,H,-CH,Br for ,2 reaction (©) Consider the given reaction cH, | Sy CH,CH,CH-CN C,H, (S) I as CH, which of following statements are correct for above reaction, (A) Product formation takes place due to the breaking of O-Ts (B) The reaction is S,. (©) The reaction is S.. (D) Configuration of product is (R) Rate of S,2 will be negligible in a Br qv. Qs. Qio. Haloalkane and Haloarenes Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to - (A) The format ion (B) Resonance stabilization (C) The inductive effect (D) sp? hybridised carbon attached to the halogen n of less stable carbonium Which reactions giving alkyl chloride from alcohol (A) EtOH + SOC —> (B) E1OH + SOCI, + Pyridine —> (C) OH + PC, —> (D) Me,COH + HCI + ZnCl, —> A gem dichloride is formed in the reaction : (A) CH,CHO and PCI, (B) CH,COCH, and PCI, (©) CH, 1, and Cl, (D) CH, = CHCl and HCI Correct statement (A) Order of reactivity in E, mechanism tea (B) Order of nucleophilicity F- Br (D) Order of reactivity in S,1 mechanism So \ a > fe Bromination can take place at NBS! bv cel, yl (B)2 3 (D4 on a (rodwSaral QUI. Toluene, when treated with Bry Fe, gives p-bromotoluene as the major product, because the CH, group - (A) is para directing (B) is meta directing (C) activates the ring by hyperconjugation (D) deactivates the ring PARAGRAPH TYPE This section contains PARAGRAPHS. Based on each paragraph, there are questions. Each question has FOUR options. ONE OR MORE THAN ONE of these four options corresponds to the correct answer. For each question, choose the option corresponding to the correct answer: Paragraph for Q. 12 to 13 Consider the following reaction - CH3-Cl + of ——> CH3-OH + cj? Experimentally it has been found that rate of this reaction depends on the concentration of CH3-Cl and replaces Cl i.e. one nucleophile replaces another so this reaction is known as nucleophilic substitution bimolecular reaction, Haloalkane and Haloarenes Choose the correct statement for the reaction given in passage (A) solvent like DMF and DMSO favour this reaction (B) It is a Bimolecular reaction (C) On doubling the concentration of CH3~- Cl rate becomes four times (D) None of these Qu QI. Rate of S,2 depends on (A) Cone of Nucleophile (B) Cone of substrate (C) Nature of leaving group (D) Nature of solvent Paragraph for Q. 14 to 15 ren ora Which of following is/are correct : (A) All products are optically active (B) All products are optically inactive (C) It gives two pair of enantiomer (D) It give 2 pair of geometrical isomerism Qs. QI5. Number of products which is separate by fractional distillation is (A)6 (B)4 © (D)3 MATCHING LIST TYPE Each question has TWO (02) matching list LIST I and LIST I. FOUR options are given representing matching of elements from LIST I and LIST Il. ONLY ONE of these four options corresponds to a correct ‘matching. For each question, choose the option corresponding to the correct matching. Qs. List- ¢ “OD List- (1) S,1 reaction may takes place wSaral & at wa area SIwSaral MATCH THE COLU. e @Q Haloalkane and Haloarenes (2) S,2 reaction may takes place (R) (3) S.1 is not possible 8) or Code : P Q R Ss (A) 34 12 34 34 ®) 34 22 12 44 © 44 22 Ll 33 ) 44 11 22 3,3 TYPE (4) 8,2 is not possible Following questions contain statements given in two columns, which have to be matched. The statements in Column-t are labelled as A, B, Cand D while the statements in Colunn-II are labelled as (P), (O), (R) and (S). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-II. Qt. Match the four reactions with type of mechnism given in List IT with the corresponding reaction provided in List - I and select the correct answer given below in lists. Column - 1 (A) CH,- O° @) CHy-¢ O° +CH,-cl—> CH, Gh (©) H,0 + CH, CL—> CH, HL, (D) CH, OH + CH, C—Cl > CH, Column - I (P) SN? (R) SN (S) E! CSG soci (rodwSaral QI8. Match Column I with Column II for given S,2 reaction & select the correct answer from the codes given below : Z-CH,Br + CH,O® —+ Z-CH,-OCH, + Br° Column I Column IL @® (Rate of SN,) (A) H- (P) 0.1 (B) CH, (Q)3 (©) CH ® cHy © dar (S) 100 cHy Haloalkane and Haloarenes NUMERICAL TYPE The answer to each question is a NUMERICAL VALUE, For each question, find the correct numerical value (in decimal notation, truncated’ rounded-off to the second decimal place; ¢.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) Q19. How many total products possible when 2-chloro butane reacts with alcoholic potash. Exercise - 2 Brain Booster SINGLE CORRECT TYPE Each question has FOUR options for correct answer. ONLY ONE of these four options is correct option. For each question, choose the correct option 10 answer the question. QU. The leaving group ability of the following groups in a nucleophilic acyl substitution by a given nucleophile decreases in the order:~ (A) -NH, > -Cl > -OCOR > -OR (B) Cl > -OCOR > -OR > -NH, (C) -OCOR > -OR > ~Cl > -NH, (D) -OR > -Cl > — NH, > -OCOR Q. Consider the following nuecleophiles : @ ay g oS CH-C-O” aul) (lv) When attached to sp’ hybridised carbon, their leaving group ability in nucleophilic substitution reactions decreases in the order. (A) 1 >> > TV (By > > TV >I (QWerl>U>M ()Iv>m>1>1 CH, | The reaction of HBr with CHC the presence of peroxide will give :- Q. H, in (A) CH,CBrCH, cH, (B) CH,CH,CH,CH,Br cH, © CH,CHCH,Br cn, (vy cHCH,CHCH, Select incorrect statements about the product (P) of the reaction : Me BRICK yp Me~ MH wSaral & at wa area SlwSaral Qi. (A) P is optically inactive due to internal compensation (B) P isoptically inactive due to the presence of plane of symmetry in the molecule (C) The structure of P can have three optical isomers possible. (D) P can have four possible optical isomers. In the given reaction as major product ) can not be cy wee cH oly cH, CH, oO” oY Consider the given reaction: CH,-CH=CH-CH,-OH —"!8"_, [P] Sur In the given reaction the product [P] is : (A) CH,-CH-CH-CH,-Br Br (B) cu, -Cu-cu=cH, (C) CH,-CH-CH-CH, Br (D) cH,-CH—cH, cH, —OH The major product of the following reaction is - Me. ,Br NO, Qs. Qi0. Haloalkane and Haloarenes fe pSPh 20" wh Bee Which of the following is most reactive toward SN’ reaction ? cl cl (A) 6 (B) O cH cl cl (3) O (D) © a NO, Which of the following represent correct reactivity order for SN! as well as SN? mechanism - a “yO 7 ~y (B) CH, = CHCl > CH,CE cl © ore . ow (D) CH, = CHC! > CH, = CHH cl Arrange the following compounds in order of decreasing rate of hydrolysis for SN! reaction: ) -cu. ay neXO-CH,-BsHaloalkane and Haloarenes Me Me (CQ) I--H mfow D (IV) CH, -CH.-€O>-CHBr Me Me (Ay T> IV >> 1 (>) 1-8 Ho (B) M>IV>1>1 D D (©lv>m>1>1 (D) >> 1V>1 cH, QI4, CH, ~CH,~Cl+ CH, -C-ONa—>? Compound A CH, Qu. [CHCl] —Y&->[R]-2-methyl Butane cH Ope re (A) CH,-CH,-0-C-CH, Nitrile; Identify compound 'A' ? cu, cl gl (B) CH,-¢ “ cH, CH, cl (C) CH,-C-Cl © SH én, (D) CH, - CH, - OH Q12. Which of the following compounds will give racemic mixture by 8,1 reaction ? QUIS. The major product of the following reaction is - CH; oO é (A) Me—}—Br —(B) Ph-CH,-Br co yaa” i) BY -cny u No cD, 9 € (©) Me—t+—Br_—(D) Chis FH-CH “ OLY cH H CH,-Br No Pp iG M (B) CL en Qu. pa x KOH y No J (Major) (jon) - X &Y should be : q wt M © Ly © © ‘0-cH {Br a Hon 2 ¢ Me Me (B) utr tion 0 p-cucr wWSaral & at wa area SIwSaral Que. Me won LH ier eon Bt Ki z B A Mechanism involved : (A) Teantt be S.1 (B) Hean't be S,2 (COIS &US2 (D)IS.2& USI Me cl, 50% Phe (- OH “pyridine > h ut. Which statement is true for the above reaction - (A) Retention of configuration (B) Inversion of configuration (C) Retention and inversion both (D) None of these Q18. Which of the following option is correct regarding X & Y. He de=0+PCL—> X + Y HC (organic (inorganic product) product) (A) X is vicinal dihatide (B) X is gemdihalide (©) Y having central atom which is sp’d hybridised (D) In, phosphorus has +3 oxidation state Q19. Which ester on pyrolysis gives isobutylene:~ (A) CH,-CH,-CH,-O-¢-CH, (B) CH,COOC (©) CH,CoocH.-C (D) All the above 20, sercH.ciEs(cr1JOHF on pyrolysis gives = cucu, Haloalkane and Haloarenes. (A) Propene (major) + ethene (B) Ethene (major) + propene (C) Ethene : propene :: 1 : 1 (product) (D) None QUI. Identify (C) product of following reaction ? Aw HA) br 1B) Gis OO) amr oN OAZ Orr 22. For the reaction [—> CH CH-CH-CH, ale, KOH CH,CHOOC t— ci (A) CH-CH=CH-CH, predominates. (B) CH.=CH-CH,-CH, predominates. (©) Both are formed in equal amounts. (D) The product ratio do not dependent on the halogen X. 3. CH-CH-CH-CH, —Nst 5 X + & X and Y in the above set are expected as :~ (A) 2-Butanol and 1-butene (B) 2-Butene and 1-butanol (C) 2-Butene and I-butene (D) 1-Butanol and 1-butene Qu. CH, -CH, ~CH-CH, —"4°#_, (x) (Major) | Br CH, -CH, ~CH-CH. SS OY) (Major) 2-butene (A) L-butene, trans (B) L-butene, cis-2-butene (C) cis-2-butene, 1-butene (D) trans-2-butene, I-butenems cut 2s. Gf, MS a Ais- by (D) None is correct 26. The final product (B) formed in the reaction sequence cH O- wea, WO, product (B) is - w)-com (o)1 LO) th oO) one, se an. O aes BS ew +) enantiomeric pair tr (A) 2 + enantiomer br be OL +entne “Oy Be Br © Cr + enantiomer (D) None of these Haloalkane and Haloarenes Q28. What is the order of reaction with HBr ? = (b) > Hy © >= CHO: (A)a>b>e (B)b>a>e (Qe>b>a (D)b>e>a ws. OO mae (x) ; Xis- (B) = (© (D) None of these Q30. Inthe given reaction |. [XT is: t ; : wSaral & at wa area SIwSaral Exercise - 2A Haloalkane and Haloarenes Brain Booster ONE OR MORE THAN ONE CORRECT TYPE Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are) correct option(s). For each question, choose the correct option(s) to answer the question QI. Which of the following option is/are not correct regarding CH,S° and CH,O° (A) CH,O%is stronger base than CH,-S° (B) CH,0° is stronger nucleophile than CH,S° (in H,O) (C) CH,O® is weaker base than CH,S® (D) CH,0° & CH,S® both give elimination product when react with CHy GHC CH; Q2. Products formed when HCI adds to 24-hexadiene is (A) 4-chloro-2-hexene (B) 2-chloro-3-hexene (C) 2-chloro-4-hexene (D) 1-chloro-2-hexene Q3. In the given pair in which pair the first compound is more reactive than second towards 8,2 reaction, (a) (Oya {O)-cuscr (B) Q4. In which of the following reaction configuration about chiral C is retained in the final product : Me (A) H+—on ett D Me (8) Hon 0, 18.0% On PCy _£10Ne Me (py Hon ort Et PARAGRAPH TYPE This section contains PARAGRAPHS. Based on each paragraph, there are questions. Each question has FOUR options. ONE OR MORE THAN ONE of these four options corresponds to the correct answer. For each question, choose the option corresponding to the correct answer Paragraph for Q. 5 to 6 Radicals are obtained by homolysis of bond. Since energy is required to break a bond in homolytic pattern, hence light is a possible energy source and ultravoilet light with an associated energy of 586 KJ/mole (hy) is used for homolysis. It can decompose many organic compounds including DNA in skin cells, During halogenation in presence of ultravoilet light a free radical substitution reaction takes pl A reaction is given as~ QS. Total number of possible monochloride obtained. (A) 5 (B)9 (C)10 (D)6 on P: (rodwSaral Q6. Total number of fractions obtained on fractional distillation of product mixture “M7 Bs O8 We Paragraph for Q. 7 to 8 In given reaction sequence il ee (i) CH,—CH QT. Product 'R'is wr oY OH OH OAK © Av Haloalkane and Haloarenes Product R can't obtained as a major product in reaction : 0 (ay \~4 (i Liat wo AK (HO c () BATHE ONS (in ,07 0H Oona, o wolfe (NaBH, + CHMgBr aa JfH MATCHING LIST TYPE Each question has TWO (02) matching lists: LIST I and LIST Il. FOUR options are given representing matching of elements from LIST I and LIST H. ONLY ONE of these four options corresponds to a correct ‘matching. For each question, choose the option corresponding to the correct matching. Q. List-I (Reaction) Ne ero re) CL te re I (8) H-C-CH-CH-CH, at OH © oa ictnco (Gi), OTF List-II (Major product / mechanism preferred) (1) E, gy Mech. (2) E, Mech. (3) E, Mech. (4) Saytzeff product wSaral & at wa area SIwSaral Haloalkane and Haloarenes Code : P QR Ss M 3 2 4 1 ®) 2 2 1 3 © 2 3 41 4 1 4 3 2 MATCH THE COLUMN TYPE Following questions contain statements given in two columns, which have to be matched. The statements in Column-1 are labelled as A, B, Cand D while the statements in Column-II are labelled as (P), (Q), (R) and (S). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-Il. Quo. Column -1 Column - II (A) CH,Br+ Nal => (P) Markownikov product is formed (B) R—Br + AgF —> (Q) Finkelstein Reaction (©) CH,CH = CH, + HCI (R) Swarts Reaction (D) CH,-CH = CH, + HOCL—> (S) Substitution Reaction QI. Match the Column I with Column II and select the correct answer using the codes given below the Lists. Column I ‘Column I (A) CF-CHCI, 8°48, cp (P) Elimination Reaction CH, (B) CH,-C-oH —""5 CH,-C=CH, (Q) Carbocation CH, CH, (©) CH-CH,-Br “5 5 ¢| a 5 (R) Carbanion r () CH ~G—CH, Agi > CHC oH, CH, CH, (S) Free radical eSaral APP ppGetiton (rodwSaral NUMERICAL TYPE The answer to each question is a NUMERICAL VALUE. For each question, find the correct numerical value (in decimal notation, truncated! rounded-off to the second decimal place; &.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) Qn. Q13. Number of compound which form single monochloroderivativeson monochlorination. w O- i) or | (iti O w A wX (vii) _/ (viii) IK (x) Oo Co) >_< How many of following in compare with 2- chloro propane give fast SN1 reaction: a CHCl (A) ) © CH,-Cl oD cl (D) CH,=CH-Cl » ‘O7 C1 Qs. Haloalkane and Haloarenes SUBJECTIVE TYPE QI4. A primary alkyl bromide (A), C,H,Br, reacted with alcoholic KOH to give compound (B). Compound (B) reacted with HBr to givean isomer of (A). When (A) was reacted with sodium metal it gave compound (D), C,H,,. which was different from the compound produced when n-butyl bromide ‘was reacted with sodium. Draw the structure of (A) and write equations for all the reactions. Which of following reaction products are diastereomer of each other (A)|__ ens > = ccty CHO (B) > NaC «iy? CH HC CH uy © Soh BS n7 - Nu ch (D) cua! -CH CHP ae Et (Optically pure) wSaral & at wa area SlwSa ral Haloalkane and Haloarenes Answer Key Ex-1 p_[| eb | pe { gp | ¢ | pf] ep | pf] a | a Ex-1A LA 2. BC 3. AC 4.B,D 5. A,B,C 6. B,D 7. A.B,C,D 8. A.B,D 9. A,B,D 10. A,C.D 1. AC 12. A,B 13.AB,CD 14. C,D 15, 16. A 17.(A) > Q(B) > P3()>R3(D) 98 18. (A) ; (B)>Q ; (CR ; (D)>P 19.3 Ex-2 poi op | ¢ | p {| pf ep ft a | p fT cy] a B | a | c | 5 | p | cl 8B Ex-2A 1. B,C.D 2. AB 3. BD 4.A,C 5.C 6A 2C &C 9.8 10. (A) > Q,8;(B) > R83) >P:(D) oP 11. (A) > PR (B) > P.Q5(C) > P53 (D) P,Q CH; 12.5 13.3 14, A= Br 15. A,B,