www.sigmaaldrich.

com

Certificate of Analysis – Certified Reference Material

Certipur® Lead ICP Standard 10 000 mg/l Pb

Product no.: 1.70372.0100
Lot no.: HC17403372
Description of CRM: Lead ICP Standard 10 000 mg/l Pb
Expiry date: 2025/11/30
Storage: +15°C to +25°C tightly closed in the original container
Composition: Pb(NO3)2 in HNO3 2-3% Suprapur®

Analyte Certified value as mass fraction Associated uncertainty, U=k·u

(k=2) as mass fraction
Pb 9767 mg/kg ± 60 mg/kg

Metrological traceability: Directly traceable to NIST SRM 3128, lot 101026

Measurement method: Inductively coupled plasma optical emission spectrometry ICP-OES
Intended use: This reference material is intended for use as a calibration standard in element
analysis.
Instructions for handling Shake well before use and never pipet directly from the original container. See
and correct use: Details for correct use on page 2.
Health and safety Please refer to the Safety Data Sheet for detailed information about the nature of
information: any hazard and appropriate precautions to be taken.
Accreditation: Merck KGaA, Darmstadt, Germany is accredited by the German accreditation
authority DAkkS as registered reference material producer D-RM-15185-01-00 in
accordance with ISO 17034.
Certificate issue date: 2021/11/19

CRM released by Approving Officer

or delegate LS-OII-QS3

ͲZDͲϭϱϭϴϱͲϬϭͲϬϬ Dipl.-Ing. Ayfer Yildirim

ISO 17034 Responsible Manager of LS-OII-QS3
(Accredited Calibration Laboratory)

Merck KGaA, 64271 Darmstadt, Germany, Tel. +49(0)6151 72-2440

EMD Millipore Corporation, 400 Summit Drive, Burlington MA 01803, USA, Tel. +1-978-715-4321
Sigma-Aldrich Canada Co. or Millipore (Canada) Ltd. 2149 Winston Park, Dr. Oakville,
Ontario, L6H 6J8, Phone: +1 800-565-1400

Certificate Page 1 of 2 Certificate version 01

 Details on correct use:
The user should be aware of the additional effect of transpiration losses of solvent through the container walls of
the unopened bottle. The effect leads to an increase of the mass fraction in the range of 0.23 mg/kg per month.
It is the responsibility of the user to account for this effect by correction of the certified value by
w(t) = 0.23 · t + w(t0)
w(t) = element mass fraction after storage time in months
t = storage in months of the unopened bottle
w(t0) = element mass fraction at the time of certification

Certification process details:

Certipur® ICP single element standards are prepared gravimetrically from high purity raw materials in either high
purity acids or high purity bases Suprapur® and diluted with filtered (0.22 µm) high purity water (18 MΩ). All
balances are regularly calibrated with analytical weight sets traceable to primary weights by PTB (Physikalisch
Technische Bundesanstalt). The density of each batch is measured in g/cm3 at 20°C and is used to calculate the
concentration in mg/l. Characterisation of Certipur® ICP single element standards is carried out by the accredited
quality control (QC) laboratory at Merck KGaA, Darmstadt, Germany according to DIN EN ISO / IEC 17025 by
inductively coupled plasma optical emission spectroscopy (ICP – OES).
Homogeneity and stability studies are performed with the material according to the requirements of ISO 17034
and ISO Guide 35.

Associated uncertainty:
The associated uncertainty UCRM reported with the certified values is calculated as combined expanded uncertainty
UCRM=k·uCRM in accordance with GUM and EA-4/02, with k=2 as the coverage factor for a 95% coverage probability.

The combined uncertainty uCRM is derived from combination of the squared uncertainty contributions:
uCRM = √ u2Characterisation + u2Homogeneity + u2Stability

ucharacterisation: is the uncertainty in accordance with DIN EN ISO/IEC 17025 which includes the
contributions of the primary reference material and the measuring system. The
characterisation measurements have been conducted by our DAkkS accredited
calibration laboratory (D-K-15185-01).
uhomogeneity: is the between-bottle variation in accordance with ISO 17034. The assessment of
homogeneity is performed by analysis of a representative number of systematical-
ly chosen sample units.
ustability: is the uncertainty obtained from short-term and long-term stability in accordance
with ISO 17034. The stability studies are the basis for the quantification of the
expiry date of this elemental standard for the unopened bottle.

Informative values:
The density of the elemental standard solution is 1.0250 g/cm3 at 20°C and is used to calculate the
concentration 10011 mg/l.
Trace impurities in µg/ml:
Ag <0.10 Cr <0.02 In <0.02 Ni <0.02 Sb <0.02 Tl <0.02
Al <0.05 Cu <0.02 Ir <0.02 Os <0.20 Sc <0.02 Tm <0.02
As <0.20 Dy <0.02 K <0.20 P <0.20 Se <0.20 U <0.02
Au <0.02 Er <0.02 La <0.02 Pb * Si <0.20 V <0.02
B <0.10 Eu <0.02 Li <0.02 Pd <0.05 Sm <0.02 W <0.20
Ba <0.02 Fe <0.05 Lu <0.02 Pr <0.02 Sn <0.02 Y <0.02
Be <0.02 Ga <0.02 Mg <0.02 Pt <0.02 Sr <0.02 Yb <0.02
Bi <0.20 Gd <0.02 Mn <0.02 Rb <0.02 Ta <0.05 Zn <0.02
Ca <0.05 Ge <0.02 Mo <0.02 Re <0.02 Tb <0.02 Zr <0.02
Cd <0.20 Hf <0.02 Na <0.10 Rh <0.02 Te <0.20
Ce <0.02 Hg <0.05 Nb <0.60 Ru <0.02 Th <0.02
Co <0.02 Ho <0.02 Nd <0.02 S <0.20 Ti <0.05

For more detailed information please read the certification report on our website.
Certificate of analysis revision history:
Certificate version Date Reason for version
01 2021/11/19 Initial version

The vibrant M, Supelco, Certipur, Suprapur and Sigma-Aldrich are trademarks of Merck KGaA, Darmstadt,
Germany or its affiliates.
Detailed information on trademarks is available via publicly accessible resources.
© 2021 Merck KGaA, Darmstadt, Germany and/or its affiliates. All Rights Reserved.

The life science business of Merck KGaA, Darmstadt, Germany operates

as MilliporeSigma in the U.S. and Canada.

Certificate Page 2 of 2 Certificate version 01