DPP - Daily Practice Problems

Chapter-wise Sheets

Date : L..�-----l Start Time : End Time :

C H E M I STRY (Ceo�
SYLLABUS : Classification of Elements and Periodicity in Properties

Max. Marks : 180 Marking Scheme : + 4 for correct & (-1 ) for incorrect Time : 60 min.

INSTRUCTIONS : This Daily Practice Problem Sheet contains 45 MCQ's. For each question only one option is correct.

Darken the correct drcle/ bubble in the Response Grid provided on each page.

1. Which of the following is not an actinoid ? D. SiF4 IV 2, +2

(a) Curium (Z= 96) (b) Californium (Z= 98) E TF V 4,+1
7
(c) Uranium (Z= 92) (d) Terbium (Z= 65) (a) A- IV; B-II;C- V; D-Ill; E - 1
2. Which of the following species has lowest ionization (b) A-V; B- ID; C-IY; D-U; E - I

(a) 0 (b) 02 (c) o2+ (d) o2-

potential? (c) A-Tl ; B - TTI;C-V; D- IY; E - I
(d) A- TIJ; B-Il; C - IV; D- I ; E - V
3. 0n going down a main sub-group in the periodic table 5. The decreasing order of the ionization potential o f the
(example Li toCs in IA or Be to Ra in ITA), the expected trend following elements is
ofchanges in atomic radius is a (a) Ne> Cl > P> S >AI > Mg
(a) continuous increase (b) Ne> Cl > P > S > Mg>Al
(b) continuous decrease (c) Ne> Cl > S > P >
(c) periodic one, an increase followed by a decrease
ofF F-, 0 and 02-are in the order
Mg>Al Ne> Cl > S >P>Al > Mg
(d) decrease followed by increase
4. Match the columns 6. The
(d) radii ,

Column-! Column-IT (a) 0 2- > F- > F > 0 (b) F- > 02- > F > 0
(Compounds) (Co-ordination number,
oxidation number)
(c) 0 2- > 0 > F - > F (d) 02- > F- > 0 > F
A. [BF4]­ 1 7,+7 7. Which group ofthe periodic table contains coinage metal ?
B. [AlF6]3- n. 4 +4
,
(a) IIA (b) IB
c OF2 ill. 6,+3 (c) IA (d) None of these
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 DPP/ CC03
8. Which of the following statements are correct? (c) Oxygen is more electronegative
(i) The second period (n = 2) starts with lithium and third (d) Addition ofelectron in oxygen results in larger size of
electron enters the 2s orbital. The next element, the ion.
beryllium has four electrons and has the electronic 13. In any period the valency of an element with respect to
configuration 1 s22s2. From the next element boron, the oxygen
2p orbitals are filled with 6electrons when the L shell is (a) Increases one by one from IA to VUA
completed at neon (2s22p ). Thus there are 8 elements (b) Decreases one by one form TA to VIlA
in the second period. (c) Increases one by one from IA to IVA and then decreases
(ii) Successive filling of 3s and 3p orbitals gives rise to from VA to VITA one by one
the third period of8 elements from sodium to argon. (d) Decreases one byonefromiA to IVA and then increases
(iii) The fourth period (n = 4) starts at potassium and the from VA to VIlA one by one
added electron fill up the first 4s and 4p orbitals than 14. An element having electronic configuration ls
3d orbital is filled. 2 2 6 2 6 1
2s 2p 3s 3p 4s forms
(iv) Fifth period begins with mbidium with the filling of5s
orbital and ends at xenon with the filling up ofthe 5p (a) Acidic oxide (b) Basic oxide
orbital. (c) Amphoteric oxide (d) Neutral oxide
(a) (i) and (ii) (b) (i), (ii) and (iii) 15. Which ofthe following order is wrong?
(c) (iii) and (iv) (d) (i), (ii) and (iv) (a) NH3 < PH3 < AsH3 -Acidic
9. Which ionisation potential (IP) in the following equations
involves the greatest ammmt of energy ? (b) Li < Be < B < C - IE 1
(a) Na -t Na+ + e- (b) K+ -t K 2+ + e- (c) Al203 < MgO < Na20 < K20- Basic
(c) c2+ -+ c3+ + e- (d) ca+ -t Ca 2+ + e- (d) Li+ < Na + < K + < Cs+ - Ionic radius
10. Which of the following arrangements represents the 16. The first ionisation potential of aluminium is smaller than
increasing order (smallest to largest) of ionic radii of d1at of magnesium because
the given species 02-, S2-, N3-, p3-? (a) Atomic size ofAl >Atomic size ofMg.
00 � <� < � < � M � <�<� <� (b) Atomic size ofAl <Atomic size ofMg.
(c) W < o2- < P3- < S2- (d) W- < s2- < 02- < P3- (c) Al has one electron in p - orbital
11. Which ofthe following series correctly represents relations (d) None of these
17. The first (�iH ) and second (�iHz) ionization enthalpies
between the elements from X to Y? (in kJ tnol-1) 1 and the electron gain enthalpy (�egH)
X -tY (in kJ mol- 1) of the elements I, TI, I ll , IV and V are given
(a) 3Li -+ 1 9K Ionization enthalpy increases below
Element aiHt ai� a H
-6b
(b) 9F -+ 35Br Electron gain enthalpy (negative sign)
I 520 7300
increases II 419 3051 -48
(c) 6 C -+ 32Ge Atomic radii increases m 1681 3374 - 328
N 1008 1846 -295
(d) 1 sAr -+ 54Xe Noble character increases
12. The formation of the oxide ion 02-(g), from oxygen atom v 2372 5251 +48
requires first an exothermic and then an endothermic step The most reactive metal and the least reactive non-metal of
as shown below : these are respectively
O(g) + e- -+ O-(g); �r H6 =-141 (a) I and V (b) ill and n (c) U and V (d) IV and V
kJmol-1 18. Consider the following statements:
(i) The discovery of inert gases later on did not
�r H = +780 kJ mot-•
o- (g) + e- -+ 02-(g); 6
Thus process of formation of 0 2-in gas phase is disturb Mendeleev's arrangement.
unfavourable even though 02-is isoelectronic with (ii) In the present periodic table, periodicity in the
neon. It is due to the fact that properties of elements is related to the periodicity in
(a) Electron repulsion outweighs the stability gained by their electronic configurations.
achieving noble gas configuration Which of these statement(s) is/are correct ?
(a) (i) only (b) (ii) only
(b) o- ion has comparatively smaller size than oxygen atom
(c) Both (i) and (ii) (d) Neither (i) nor (ii)

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19. Consider the following ionization enthalpies oftwo elements (b) Np3 > C02 > 8203 > BeO> Lip
'A' and 'B'. (c) C02>Np3 > Bp3> BeO>Lip
Element Ionization enthalpy (kJ/mol) (d) Bp3 > C02 > Np3 > Lip> BeO
22 22 6 2 6
lst 2nd 3rd 25. � atom 2 has electronic configuration 1 s s p 3s 3p
A 899 1757 14847 3d·' 4s , you will place it in which group?
B 737 1450 7731 (a) Fifth (b) Fifteenth
(c) Second (d) Third
Which ofthe following statements is correct ? 26. In which ofthe following arrangements, the sequence is not
(a) Both 'A' and 'B' belong to group-1 where 'B' comes strictly according to the property written against it?
below 'A'. (a) C02 < Si02 < Sn02 < Pb02: increasing oxidising power
(b) Both 'A' and 'B' belong to group-1 where 'A' comes (b) Nil:, < PH3 <AsH;,< SbR:,: increasing basic strength
below 'S'. (c) HFas<inHgCacid
l < HBr < HI : incr e
strength
(c) Both 'A' and 'B' belong to group-2 where 'B' comes (d) B < C < 0 < N: increasing first ionisation enthalpy.
below 'A'. 27. Which one ofthe following statements is incorrect ?
(d) Both 'A' and 'B' belong to group-2 where 'A' comes (a) Greater the nuclear charge, greater is the electron
below 'S'. affinity
20. Sodium sulphate is soluble in water whereas barium sulphate (b) Nitrogen has zero electron affinity
is sparingly soluble because : (c) Electron affinity decreases from fluorine to iodine in
(a) the hydration energy of sodium sulphate is less than 1 7th group
its lattice energy (d) Chlorine has highest electron affinity
the lattice energy of barium sulphate is more than its An element X occurs in short period having configuration
ns2 np1. The formula and nature ofits oxide is
(b) 28.
hydration energy
(c) the lattice energy has no role to play in solubility (a) X03, basic (b) X03 acidic
(d) the hydration energy of sodium sulphate is less than (c) xp3, amphoteric (d) �03 basic
its lattice energy. 29. Ionic radii of
21. Which of the following is the reason for the different (a) Ti 4+ < Mn 2+ (b) 3sc1- < 37CI-
chemical behaviour of the first member of a group of
elements in the s- and p-blocks compared to that of the (c) K+ > Cl -1 (d) p3+ > p5+
30. The ionic radii (in A) ofW-, 02- and F-are respectively :
subsequent members in the same group? (a) 1.71, 1 .40and 1 .36 (b) 1.71, 1.36and 1.40
(i) Small size (c) 1 .36, 1.40 and 1 .71 (d) 1.36, 1.71 and 1.40
(ii) Large charge I radius ratio 31. Amongst �O, �S, �Se and �Te, tbeonewith the highest
(iii)
(a) Low
(i) andelectronegativity
(iii) of(b)the(i),
element
(ii) and(iii) boiling point is
(c) (i) and (ii) (d) (ii) and (iii) (a) �0 because of hydrogen bonding
22. The element with outer electronic configuration 3d 6 4s 2 is a (b) �Te because ofhigher molecular weight
(c) H2S because of hydrogen bonding
(a) metalloid (b) non-metal (d) �Se because of lower molecular weight
(c) transition metal (d) noble gas 32. Match the Column-! and Column-II and select the correct
23. Which of the following statements is wrong ? answer by given codes.
(a) van der Waal's radius ofiodine is more than its covalent Column-I Column-I I
radius (Elements) (Properties)
(b) All isoelectronic ions belong to same period of the A. Li+<AI3+< Mg2+< K+ L DEA (Electron affinity)
periodic table B. Li+> AJ3+> Mg2+> K+ ll. Ionic radii
(c) I.E., ofN is higher than that ofO while I . E.2 ofO is
C Cl> F> Br> I ID. EN (Eiectronegativity)
higher than that ofN
(d) The electron gain enthalpy ofN is almost zero while D. F > Cl > Br > I IY. Effective nuclear charge
that ofP is 74.3 kJ mol-' (a) A - II; B - IV; C - UI; D - I
24. Which of the following sequence correctly represents the (b) A - II; B- IV; C - I; D -III
decreasing acidic nature ofoxides ? (c) A- IV; B - 11; C- lll; D - I
(a) Lip> BeO > 8203 > C02 > N203 (d) A- IV; B - 11; C - 1; D - III

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 DPP/ CC03
33. Which ofthe following statement(s) is/are correct ? 40. As we move across the second period from C to F ionisation
(i) Aluminium react with HCl to form AP+ and � is enthalpy increases but the trend from C to F for ionisation
liberated enthalpyis C < 0 < N < F why it is not e < N < 0 < F. This
(ii) Aluminium dissolve in NaOH to form NaAl(OH\ and is because
H? (a) atomic radii ofO > atomic radii ofN
(a) (i)and(ii) (b) Only(ii) (b) electronic configuration of N is more stable than
(c) Only(i) (d) Neither(i) nor(ii) electronic configuration ofO
34. Which has most stable+2 oxidation state :
(c) atomic radii ofN > atomic radii ofO
(a) Sn (b) Pb (c) Fe (d) Ag (d) None of these
35. Match Column-! (IUPAC nomenclature of element) with
Column-IT (IUPAC official name). 41. The electron affinity ofchlorine is 3.7 eV. l gram of chlor-
Column-1 Column-11 ine is completely converted to CJ-ion in a gaseous
A. Unnilheximn 1 Lawrencium state. (leV= 23.06 kcalmol-1).
B. Unniltrimn ll. Dubnium Energy released in the process is
C Unnilunium J1l Seaborgium (a) 4.8 kcal (b) 7.2 kcal (c) 8.2kcal (d) 2.4kcal
D. Unnilpentium IV Mendelevium 42. Gradual addition of electronic shells in the noble gases
(a) A- IV; B- I; C - III; D -JI causes a decrease in their
(b) A- III; B -I; C-IV; D - IT (a) ionization energy (b) atomic radius
(c) A - III; B- IV; C - I; D - ll (c) boiling point (d) density
(d) A - ll; B - III; C-l; D - IV 43. The formation of the oxide ion Ofg) requires first an
36. In the Mendeleev periodic table, which of the following
element instead ofhaving lower atomic weight was placed exothermic and then an endothermic step as shown
after the element ofhigher atomic weight thereby ignoring
the order of increasing atomic weights. below O(g) +e-= O(g) �W= -142 kJmol -1
t
=Ofg) �W=844 kJmol
(a) Iodine (b) Antimony
(c) Bromine (d) Molybdenum o-(g)+e-
This is because
37. The van der Waal and covalent radii of fluorine atom (a) o-ion will tend to resist the addition ofanother electron
respectively from the following figure are. (b) Oxygen has high electron affinity
(c) Oxygen is more elecronegative
(d) o- ion has comparatively larger size than oxygen atom
44. Which ofthe following is correct about Eka-Aluminium
and Eka-Silicon ?
(a) Oxides ofEka-Aluminium is Alp3 and Eka-Silicon is
Sip3
(b) Oxides ofEka-Aluminium is Gap3 and Eka-Silicon is
144 pm 144 pill Ge02
(a) 219pm, 72pm (c) Melting point of Eka-Altuninium is lower than the
(b) 75pm, 72pm melting point ofEka-Silicon
(c) l47pm, 72pm (d) l47pm, l44pm (d) Both (a) and (c)
38. Cl, Br, I, ifthis is Dobereiner 's triad and the atomic masses of 45. Covalent radii ofatoms varies in range of72 pm to 133 pm
Cl and l are 35.5 and 127 respectively the atomic mass ofBr from F to I while that ofnoble gases He to Xe varies from
is 120pm to 220pm. This is because in case ofnoble gases
(a) 162.5 (b) 91.5 (c) 81.25 (d) 45.625
39. The first ionisation potential ofNa is 5.1 eV. The value of (a) covalent radius is very large
electron gain enthalpy ofNa+ will be: (b) van der Waal radius is considered
(a) -2.55eV (b) -5. 1 eV (c) metallic radii is considered
(c) - 10.2eV (d) +2.55eV (d) None of these

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