ELECTKOCHUEMISTRY: de 4 brtact, BE ie chemistry clheme > from One Species Tea dnvther, Zn**eagy : oie roe ere io du ee tne a latin comtbacnui zt =f toms, a eae Librium otk ey Be ablished Ww t os or. ae a “te interface. : - ~fonbe ‘the ee fled tee ame ae ats e En (sy ——> En tng) + LE ~ “Oxidation _ = Thee vals» Ktindenc p Ba ios eta yeduced. to Zac me 14 .En** (ap 4+ 2@ ——> Fi w> Reductim: - For tn metal, oxidation tances place Moye readily than reduction. — The aleckos fet ita ae tom 1'seo Ore eo. é om Aone fete e- sy rod a is ad heb -Ve hows bose tive. JD a iC nek ositive = 5G a a £p>t Cag) ). oo a fe - Tie ee ek dia oa maa ae ae ete obo eae “Con we ™ e Lf ee pees Value se ‘We C3 nob Medawre the oxack value D deckcde otemtialh. Meaourmig Hira Lue. nERP require a Voltmelee and. tie wits, OMe Connected Ue ip fond the Dee bie elcioss hat Ung octu ok A wire di ab es Et ea eee fel po icrt thes tnolhee potential weiss a obscure the vale of olectrode Pe ent ab: ~The potential of a given calf cell ce 5 whe gt nr. i Hay), 48K—>. “Tin abe ae Latin A mold? HC 1— ee : a black — The sue consists of qo ak 298K, A ake see my ber platinum, whic!l, is ae tate gi Solution of A meldm? HCI. a a = “The. Lefatnyea ease coated uot Hf, eae f u flies divid ade tn Knvwn deln pet horge Suef ace Oe { Ue. dda tdaorbid ay si ict teas & eee andl senda i 2H¥ cag) + 26 =H, 204) = neh rae tho, catalyses the above ittactim whitch val Oe Large ee on ergy = The SHE has been Ocbitrarily assi, ned. ae oor teode Ee ae 0.0 Vabe Knoum aa i replies meerECT E POTENTIAL LUPAC CONVENTION meee ‘ding ts the WiPat contention the Sint ae de. polant fea re 2 Lx Vi ce hi il er Lake’ ele exc Lusi V3 fe “half ll of reactims ely — There La_ a ob ‘tctim tb fs Using : anes tee fn aE pcofl -reae tis oe es oes chgol jase” Bate hbETERMINATIDN oe STANA Ae E EcCTRpbE PoTENT AL} a 0) A metal in cmtact with ib tms; — — he ptentiol, off a Given half cell fs brea 2B byepbe etsy = i ele are costuctd wit, te HE lo fe halt nde mekal EPP as bt pel dag ee of He othen.Hy Haistance Vettmetie == Me Ca Lali cell dre cmnec de MeAns vf Q salt e (ch ts ret U-tube ont arias g kwod : = Emf ts medoured | iSelect trait ice alkene a nt ; ale Medoured Emf to the brit ‘Stam—of the potent tle of the tito h f cel = ‘Swace th SHE is ie ce ference, Uectende Ee: inortledet a {1 y.2erp Sd That He EP of the atte T f. bi Let wen twp (Os pf dy LE ee Lat , Oxidabi on takes 4 et Ee “tap igh stage Swe bridge Ree 4 wee! dan conked un'th PL crated ust Pt black PL _bLac« he nb dh met al. in cmtact el iS eins lms: a4 STs= Za High réotstdnce. Voltmeteett} Agta in emtact with tb ims e4 ORM is Wy Hg resist dace Volemeteaicenne Uecterde potential, EP = Thiet the. Cia wectiion paeantial “of. if. palf c cell relative t 'Hie standard — ctode at 248K, Latm : pede @ tind 4 moldm? emicadte-ation. Limplicabions—of —E° ey me Ths, oe =pesilive He 4 — mb. sheong er : : oe 0 ist A posity 7 | te ade po sehen ee ne ens PRE eo he : a uci ee the substance takes place mapre. Tad so tts Se —iImakeo the other Crea cant lelet-ms dnd hence fel anid eed — the pabie peg abies Th 2 BEEP. ie = ce in ént. A heqgativ pata Means AE | eet ot £ Aces beat fee rather oxid, i oa iQ Met | ies fie ron rea - 4 metal baste — tht et my {This mates e._oth a rence don le | the ctr ons easily tad. gek edidcedJ — dud electrode potiutial eg hp tele praictple be aged ay fet Pee be eee Chan Mm Conc entation. iCmstderi bes¢ Cag be == RB, EP-+ FLV (ae Cre’ creloed baum a ie ts te Fight tnd ited os 4 More. positive: Sl shi § ere deft Bed ae tt al a Se ee hee weg abiver P ernst 3 | E=E* = eT , 9 NE athere E = Vion standacd electrode as potential. | EP = Standard electrode | : potentralPfs tele cnckg | R= Molar jo constént | T= “Tep ui_k ; N= number of moles of elections Q= Reactim quotient ao set Tf T= 298K — ~ [ESE = 8.31y x 2498x2303 Paes | . - mn xX FLS0D : ee ee lh 0.054 bog Qe >| “Cana de: Fe? “tags hE Fe 2+ ng). : E= E*% + 01054 log CFe™ EESH. ; | (oe | Tn General s oa Ee + 0.054 bog Lostdied Twa J 4 a 5 — eae reduced forms | esis \ ci{ =] bf this Vs the MAX. Wm D | _ Standard cell potential Beet oli ntal Fferdnce Proflacea tt ee aS Wall cells Ln 2rol Curr Paden 3 Under Shandacd Corditios. tthe uv i ls Comben ation of bal poet ,colled. a eee n- Vel tare mi Cell. Oud thd cell Voltage gener in-such @ Cell lh meas A A Peart ance Voltmeter Suite. hye hi deme e eof Current mde tllows clots 24, Se ee ae pi be : iain of by _Circeutt Ems | | { } Lr (fots-—|-]——Sekt bet de ae ee i ee (Cathode) ua catma PIA 4 | S eS mol dat ZnS04+ bit eo Uae Frade here io CCU cra) ae de alice red uction inyzare | £ lec Eo des Birk ee cs)_Is a — half cel Plan ‘ap cell, make ppc a 3 a out Su — the -other eis them: i: = Tp a meal Paka iubeedentc gsi i —— He Mn 1.0 4 Zn.s) —> Ent $20, ae i Ctrede sl cca Eieedd 2 egbe onot diel Ive =| Conperstly Fetal, tone have a tendency edule dk ar Curteag)d 4. 2€ ae: tk &s. : metal at become a oo ets ne : Wn 2. COMe SI es re ase Selution ie “te ies ~ | Overs Ms Cutbay £ znco—> EnMtng + CassCELL IUPAC CoNVENTION) According. Ee re aice — Reductim pecurs at the RYE = Oxi dabion occure at the LW filoee E® cell = Biles (LHS) + Cored (R-u-5) pa Eup Ete + Sk Fright —— “ep t ree of cell reactions? ca ar ere —n FE Peel mie Whee a pele of ie Erdas Lerced = aca Cmst ant at tae = Facadl cell potential | AGE = Shin dard Gibbs free antedy oe Nim - pr pe cmd bons, e 2 Ae eePreduct petieret, (ties tte bf oh (eat . oy : =e =| Tf veachon— to “spmtantowa— i = ‘AG in negative vr. E.cell_ us positive. a A reaction isnot. Spent ane di ip oe bo positive. sy _Ecell i> iamQUANTITATIVE ELECT@oLNS IS: | Ftraday's Laws of Unebrolysis: ia, or ~The m f the Substance pte ted. s he i eek ode Heute ste : oe Tp of abe cleciotty ¢ ty Measured a be Coloumb On electric cha When a Current of 1A {luce “ Qe txt LQ xm. C2 ies be tortitieof aie Neg wert ib deposit Lipa ares tach Substunce. bear a pieaple Oe. tavlhér. i aa al Pan ae ZL — elec temace robles Avogadess Constant Charge. ~ ite ee Faraday's comstént 1's the Charge ie eee eat) enadea pe cee Ie_ betermcnation of Avogadro's comstdnt — “by electrolytic Methods : aes The ee onah Fa Le S ae . Used . Cee iS the Value of Vo ae 5 GSU. ant. =a electrolytic cef/ ee ee uedts Stlier niteale ts see upton d a Know const dnt Curcént 1 pacced for 4 Known times : = The cakhode reaction la: Agta tt ——> Agus = thcrease tn. Mos ab She Cathode. ib Tyedleuced dnd Lie eee a eectireity fe peeps Dae op Pioid af = [Buia 42 A mole ee b sippne b ws [eae is Constant