CHEMISTRY

Butterworth 29/9/22

Run A Run B Run C Run D

1. Why was water added to some of the reaction mixtures?

to make sure the volume of the solution remained the same
CHEMISTRY
Lamb 23/9/22
Energetics

13A: lattice energy

•Calculate the standard enthalpy of formation of propan-1-ol from the following enthalpy of
combustion data.
⁃CH3CH2CH2OH (l) H, 0= -2010 kJmol-1
- C (s) H, O= -393.5 kJmol-1
- H2 (g) Н. 0= -285.8 kJmol-1

3C(s) + 4H2(g) + O2(g)  C3H7OH(l)

3CO2 + 4H20
= -393.5 X 3
-285.8X4
= -2323.7
Hess cycle +A – B
=-2323.7 –(-2010)
= -313.7 KJmol−1

• Calculate the standard enthalpy change for the following reaction using the standard
enthalpies of formation given.
2 NaHCO, (s) -> Na,CO, (s) + CO, (g) + H,0 (1)
ㅽ하
-948
-1131
-394
-286 complete later
Bond Energies
•Bond dissociation energy - what is it?

•Mean bond enthalpy - what it is?

•Use the bond energies provided to calculate the enthalpy of combustion of ethanol
C-C C-Н O-Н C-O 0=0 С=O Н-Н С=С
348 412 463 360 496 743 436 612

•Write an equation for the enthalpy of combustion of ethanol.

C3H7OH + 3O2  3CO2 + 4H2O

C3H7OH= 3CO2 + 4H2O=

5 X 412 8 X 463
1 X 612
6 X 463
1 X 463
1 X 360
•Use the enthalpy of formation data to calculate the enthalpy of combustion of ethanol
(DRAW OUT THE HESS CYCLE!!!)
•DHf values, kJmol-1: ethanol (-277.7), carbon dioxide (-393.5), water (-241.8)
 CHEMISTRY
Lamb 27/9/22
Born Harber Cycles

+ e-
+
atomisation Electron
affinity

+ e-
+

ionisation

Lattice
energy
vaporisation

Enthalpy of
formation

Mg+2 (g) 2Cl(g)

Extra
step for
extra Mg+2 (g) +2e- + 2Cl(g)
charge
Mg+(g)+ e- + Cl2 (g)

Mg+2. 2cl-(g)

Mg(g) + Cl2(g)

Mg(s) + Cl2 (g)

MgCl2
 titre
18
16
14
12
10
8
6
4
2
0
2 4 6 8 10 12 14 16 18 20 22
CHEMISTRY
5th period /9/22