Wastewater

Eng ineeri ng
Treatment and Resource Recovery

Fifth Edition
Metcalf & Eddy I AECOM
Revised by
George Tchobanoglous Contributing Authors:
Profcssor Emcritus of Civil and Mohammad Abu·Orf
Environmental Engineering North America Biosolids Praccice
University of Califomia at Davis Leader. AECOM

H. David Stensel Gregory Bowden

Profcssor of Civil and Environmental
Engincering
University of Washington, Seattle
Ryuiiro Tsuchihashi
Wastewater Tcchnical Leader, AECOM
Wastcwater Technical Leader, AECOM
William Pfrang
Wastewater Treatment Technology
Leacler, AECOM

Franklin Burton
Consulting Engincer
Los Altos, CA
WASTEWATER ENGINEERING: TREATMENT AND RESOURCE RECOVERY, FIFfH EDITION

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 About the Authors

George Tchobanoglous is Professor Emeritus in the Department of Civil and Envi-

ronmental Engineering at the Universily of California, Davis. He received a B.S. degree in
civil engineering from lhe University of the Pacific, an M.S. degree in s,rnitary eugineering
frorn the University of California at Berkeley, and a Ph.D. from Stanford University in
1969. Dr. Tchobanoglous' research interests are in the areas of wastewater treatment and
reuse, wastewater filtration, UV disinfection, aquatic wastewater managemenl systems,
wastewater managemenl for small and decentralized wastewater mauagement systems, and
solid waste managemenl. He has authored or co-authored over 500 technical publications
including 22 textbooks and 8 reference works. The text.books are usecl in more than 225
colleges and universities. by practicing engineers, and in universities worldwicle both in
English and in translation. His books are famous for successfully bridging lhe gap between
academia and the day-lo-day world of the engineer. He is a Pasl Presidenl of the Associa-
tion of Environmental Engineers and Science Professors. Among his man y honors, in 2003
Professor Tchobanoglous received the Clarke Prize frorn the National Water Research
Institute. In 2004, he received lhe Distinguished Service Award for Research and Education
in Integrated Waste Management from the Wasle-To-Energy Research and Technology
Council. In 2004, he was also inducted into the Nacional Academy of Engineering. In 2005,
he was awarded an honorary Doctor of Engineering from the Colorado School of Mines.
In 2007, he received the Frederick George Pohland M edal awarded by AAEE ancl AEESP.
In 2012 he was made a WEF Fellow. He is a registered Civil Engineer in California.

H. David Stensel is a Professor in the Civil and Environmental Engineering Deparlment

at the University of Washington, Seanle, WA. Prior to his academic positions, he spent
JO years in practice developing and applying industrial and municipal wastewater treatrnent
processes. He received a B.S. degree in cívil engineering frorn Union College, Schenecrady,
NY, and M.E. and Ph.D. degrees in environmental engineering frum Cornell Uníver:;ity. His
principal research interests are in the areas of wastewater treatment, biological nutríent
removal, sludge processing methods, resource recovery. and biodegradation of micropollut-
ants. He is a Past Chair of the Environmental Engineering Dívision of ASCE, has served on
the board oftheAssociation of Environmental Engineering Professors and on various commit-
tees for ASCE and the Water Environmenl Federation. He has authored or coauthored over
150 technical publícations and a textbook on biological outrient removal. Research recogni-
tion honors include the ASCE Ruclolf Hering Meda!, the Water Environment Federation
Harrison Prescott Eddy Meda! twice, and the Bradley Gascoigne Meda!. In 2013, he received
the Frederick George Pohland Meda! awarded by AAEE and AEESP. He is a registered profes-
sional engineer, a diplomate in the American Academy ofEnvironmental Engineers anda life
member of the American Society of Civil Engineers and the Water Environmenl Federation.

Ryu¡iro Tsuchihashi is a technical leader wilh AECOM. He received his B.S. and M.S. in
civil and environ mental engineeringfrom Kyoto University, Japan, anda Ph.D. in environmen-
tal enginee1ing from che Uníversity of California, Davis. The areas of his expe1tise include
wastewater/water reclamation process evaluation and design, evaluation and assessment of
water reuse systems, biologicaJ nutrient removal, and eval.uation of greenhouse gas emission
V
vi About the Authors

reduction frorn wastewater treatment processes. He was a co-author of the textbook "Water
Reuse: lssues, Technologies and Applications;' a companion textbook to this textbook. He is a
technical practice coordinatorfor AECOM's water reuse leadership team. Ryujiro Tsuchihashi
is a member of tl1e Water Environment Federation, Ame1ican Society of Civil Engineer, and
International Water Association, and has been an employee of AECOM for 10 years, during
which he has workecl on various prqjects in the United State, Australia, Jordan, and Canacla.

Franklin Burton served as vice presiden! and chief engineer of the western region of
Metcalf & Eddy in Palo Alto, California for 30 years. He retired from Metcalf & Edcly in
1986 and has been in prívate practice in Los Altos, California, specializing in treatment
technology evaluation, facilities design review, energy management, and value engineer-
ing. He received his B.S. in mechanical engineering from Lehigh University andan M.S.
in cívil engineering from the University of Michigan. He was co-author of tbe third and
fourth editions of the Metcalf & Eddy textbook "Wastewater Engineeru1g: Treatrnent and
Reuse." He has authored over 30 publications on water and wastewater treatment
ancl energy managernent in water and wastewater applications. He is a registered civil
engineer io California and is a liJe member of lhe American Society of Civil Engineers,
American Water Works Association, and Water Environment Federation.

Mohammad Abu-Orf is AECOM's North America biosolids practice leader ancl

wastewater director. He received bis B.S. in civil engineering from Birzeit University, West
Bank, Palestine and received bis M.S. and Ph.D. in civil and environmental engineering
from tlle University of Delaware. He worked with Siemens Water Technology and Veolia
Water as biosolids director of research ancl development. He is the main inventor on five
patents and authored and co-authored more than 120 publications foc using on condition-
ing, dewatering, stabilization and energy recovery from biosolids. He was awarded first
place for Ph.D. in the student paper competition by the Water Environment Federation for
two consecutive years in 1993 ancl 1994. He coauthored maouals of practice and reports
for the Water Environment Research Foundation. He served as an editor of the Specialty
Group for Sludge Management of the International World Association for six years and
served on the editorial board of the biosolids technical bulletin of the Water Environment
Federation. Mohammad Abu-Orf has been an employee of AECOM for 6 years.

Gregory Bowden is a technical leader with AECOM. He received his B.S. in chem.i-
cal engineering from Oklahoma State University anda Ph.D. in chemical engineering from
the University of Texas at Austin. He worked for Hoechst Celanese (Celanese AG) for
10 years as a senior process engineer, supporting wastewater treatment facility operations
at chemical production plants in North America. He also worked as a project manager in
the US Filter/Veolia North American Technology Center. His areas of expertise include
industrial wastewater treatment, biological and physical/chemical nutrient removal tech-
nologies and biological process modeling. Greg Bowden is a meinber of the Water Envi-
ronment Fecleration and has been an AECOM employee for 9 years.

W illiam pfrang is a Vice-President of AECOM and Technical Director of their Metrn-

New York Water Division. He began his professional career with Metcalf & Eddy, lnc., as a
civil engineer in 1968. During his career, he has specialized in municipal wastewater treat-
ment plant design including master planning, alternative process assessmcnts, conceptual, and
detailed design. Globally, he has been the lead engineer for wastewater treatment projects in
the United States, Southeast Asia, South Ameiica, and the Middle East. He received his B.S.
and M.S. in civil engineering from Norlheastem University. He is a registered professional
engíneer, a member of the American Academy of Environmental Engineers, and tbe Water
Envisonment Federation. William Pfrang has been an ernployee of the firm for over 40 years.
 Contents

About the Authors 1-8 Reactors Used in Wasrewater Trealment 22

Preface ,Lriii Types of Reacrors 22
A cknowledgmems xxvii Hydraulic Charac/eristin· uf Reac:lors 24
Foreword xxix Applicarion <l Reacwrs 25
1-9 Mode ling Ideal Flow in Reactors 26
Ideo/ F/ow in Complete-Mix Reactor 26
1 lntroduction to Wastewater
ideal Plug-Flow Reactor 27
Treatment and Process 1-10 lntroducrion 10 Process Kinetics 29
Analysis Types of Reac1i011s 29
1-1 Evolution of Wastewater TreatmcnL 4 Rafe of Reacrion 30
7i-entmelll Objectives 5 Specific Reaction Rafe 3 J
Curre111 Health a1Ul E11viro11111.enta/ Concems 5 Ej]ecrs of Temperature 011 Reaction Rate
S1wai11ability Considerations 5 Coe.fjicients 3 1
Reac:1io11 Order 33
1-2 Evol ution of Regulations of Signilicance to
Rafe Expressions Used in Wasiewaler
Wastewater Engineering 6
Treat111en1 34
E.vtablisl11m:11t ()j' E11vimn111enflll Protection
Analysis cf Reac1io11 Rafe Coe.fficiems 39
/lgency 6
Importan/ Federal Regulatio11s 6 1-11 lnlroductíon LO Treaunent Process Mocle ling 42
01her Federal Regulatio11s 9 Batch Reactor wilh Reae1ion 43
State <md Regional Regulalirms 9 Complete-Mix Reactor wit/1 Reactio11. 43
Comple1e-Mix Reactors in Series wi1h Reac1ion 44
1-3 Characteristics of Wastewater 9
Ideal Plug-Flow Reactor wilh ReaClion. 47
Sources o/Wa.~rewa1er 9
Co111parison of Com.plete-Mix and Plug-Flow
Twes o/' Colleuio11 Sys1e111s 9
N.eac/Ors with Reac1ion 48
Wasrewa1er Co11sti1uents lO
Plug-Flow Reactor with Axial Dispe1:~io11 and
1-4 C lassitication of Wastewater Treatment
Reactirm 50
Methods 10
Other l?eactor F/ow Regimes wul Reacfor
Physical Unif Pmcesses JO
Comhinalirms 51
Chemical /Jrúf Processes 12
Problems and Discussion Topics 53
Biological Unif Processes 12
1-5 Application of Treatment Methods 12
Wastewa1er Processing 12 2 Wastewater Characteristics 57
Residua/s Pmcessi11p, 13
2-1 Wastewater Characterization 60
Typical Treatme11/ Process Flow Diagrams 13
Wasfewater Properfies cmd Constilue11ts 60
1-6 Status of Wastewater Treatment in the Canstif1iems of Concern i11 Wastewmer Treatment 60
Un ited States 17
2-2 Sam pling and Analytical Procedures 60
Recen/ Survey Resul!s J8
Sampling 63
Tre11ds 18
Methods ofAnalysis 65
1-7 lntroduction to Process Ana lysis J9 Unit.1· of Expressionfor Physicc,/ and Chemical
Mass-Balam:e Analysis 19 Paramelers 66
Applica1io11 of rhe Ma.\·s-Ba/anc<' Analysis 2 1 Use.ful Chemical Re/(lfionships 66

vii
viii Contents
2-3 Physical Properties 73
Sources of Physical Properties 73
Solids 73
Panicle Size and Particle Size Measuremem 76
Particle Size Distribution 80
Nanoparticles and Nanocomposites 83
Turbidity 83
Relationship Between Turbidily and TSS 85
Color 85
AbsoqJtion/Transmittance 85
Temperature 87
Themial Energy Collfent of Wastewater 89
Conductivily 89
Density, Specific Gravity, and Specific Weight 89
2-4 lnorganic Nonmetallic Consticuents 90
Sources of lnorganic Nonmetallic Constituents
pH 90
Chlorides 91
Alkalinity 92
Nitrogen 92
Phosphorus 96
Suifur 97
Gases 98
Odors 103
2-5 Merallic Constituent~ 111
Sources of Metallic Coristituents 112
Importance of Metals 113
Sampling and Methods ~f Analysis 11 4
Typical Effluent Discharge Limitsfor Metals
2-6 Aggregace Organic Constituencs 114
Sources ofAggregare Organic Consrituenrs 114
Measurement of Organic Content l 14
Biochemica/ Oxygen Demand (BOD) 115
Total an.d Soluble Chemical Oxygen Demand
(COD and SCOD) 123
Toza/ a,ul Dissolved Organic Carbon. (TOC and
DOTC) 123
UV-Absorbing Organic Consrituents J24
Theoretical Oxygen Demand (ThOD) 125
Interrelationships berween BOD. COD, and
TOC 125
Oil and Grease 127
Surfactants 128
Chemical Energy in Wastewazer ami Biosolids 129
2- 7 Individual Organic Compouods 131
Sources of Individual Organic Compounds l32
Priority Pollutants 132
Volatile Organic Compounds (VOCs) 132
Disinfection Byproducts 132
Pesticides and Agricultura/ Chemicals J33
Unregulated Trace Organic Compounds 133
Analysis of Individual Organic Compound.1· 133
2- 8 Radionuclides in Wastewater 136
Sou rces of Radionuclide 137
Units of Expression 137
Description of lsotopes Foun.d in Wastewater and
Sludge 137
Treatment Technologies for the Removal ~f
Radionuclides 13 7
2- 9 Biological Constituents 139
Sources of Microorganisms in Wastewater 140
Enumeration and ldentification of
Microorganisms 144
Pathogenic Organisms and Prions 151
EvoLving Pathogenic Microorganisms 161
90
2- 10 Tox..icity 161
Sources ofToxicity 161
Evolution ancl Application f1{Toxicity Testing 162
Toxicity Testing 163
Analysis of Toxicity Test Results 165
Application of Toxicity Test Results 167
ldentification ~f-Yoxicity Components 169
Problems and Discussion Topics 171
3 Wastewater Flowrates and
Constituent Loadings 183
114 3- 1 Wastewater Sources and Flowrates l85
Municipal Uses (~{Water 185
Domestic Wastewater Sources and Flowrates 186
Strategiesfor Reducing Interior Water Use
and Wasrewater Flowrates 189
Water Use in Other Parrs of the World 194
Sources cmd Rafes of Industrial (Nondomestic)
Wastewater Flows 194
Varia.tion.s in Wastewater Flowrates 195
Long-Term Mulliyear Varfotions Dueto
Conservation 198
lmpact of Water Conservation on Future
Planning 200
3- 2 Impact of Collection Systcm on Wastewater
Flowrates 200
InfiLtration//riflow 200
lnjlow into Collection Systems 202
Exfiltration from Collection Systems 204
Combined Collection. System Flowrates 205
Direct Measurement of Combined Sewer Flowrates
and Wastewater Characteristics 207
Calcula/ion <!f Combined Sewer Flowrates 207
 Contents ix

3-3 Analysis o f Was tewate r Flowrate Data 208 Owner Needs 270
S1atistical Ancilysis of Flowrate Data 208 E11vironmer11at Considerations 270
Developing Design Parameters .fimn Flowrate Compatibiliry with Exis1ing Facilities 27 1
Data 2 11 Energy and Resource Requirements 271
Observed Variability Íl1 lnfluent F/owrates 2 12 Cost Considerations 272
3-4 Analysis of Wastewater Constituents 214 Other Design Considerations 273
Was1ewater Consti1Ue11ts Discharged By 4-2 Considerations in Process Selection 274
lndividuals 21 4 lmpor1ant Fac1ors in Process Selection 274
Constiluent Co11ce11tra1ions Based on Individual Process Selection Based on Reaction Kinetics 276
Mass Discharges 218 Process Selection Based On Mass Tran.¡fer 277
Mineral lncrease Resulting from Water Use 2 18 Process Desig11 Based on Loading Criteria 277
Composifio11 of Wastewater in Collection Bench-Scaie Tests cmd Tesr-Bed Pilot-Scale
Sysrems 2 19 Srudies 277
Varia1io11s in Constifuellf Conce111ralions 2 19 Wastewater Discharge Permit Requiremen1s 278
Statistical Analysis o.f Constituenf 4-3 Treaunent P rocess Relia bility and Selection of
Concentmtions 225 Design Values 279
Observed Variability Í11 l11jhumt Constituent Vu.riability in Was1ewater Trearrnem 280
Concenr ratio11s 225 Se/ec1io11 of Process Desif?n Parame1ers to Mee,
3-5 Analysis of Conslituent Mass Loading Data 226 Dischcirge Permit Limils 286
Simple Average 226 Pe1formance (~{ Combined Processes 289
Flow-Weighted Average 226 4-4 Elements of Process Design 29 1
Mass Loadings 229 Design Period 29 1
E.ffect of Mass Loading Variability 011 Treaunent Treatment Process Flow IJiagrams 29 1
Plan/ Pe1forma11ce 23 1 Process Design Criferia 291
3-6 Selection of Design Flowrntes and Mass Prelimir1ary Sizing 292
Load ings 232 Solids Balance 293
Design Flowra/es 234 Pla11t Layout 294
Design Mass Loadi11gs 240 P/ant Hydrauiics 295
3-7 Flow ancl Consti tuent Load Equalization 241 Energy Management 296
Description!Applica1io11 of Flow Equalizatio11 242 4-5 Tmplementation of Wastewater Management
Tite Bene.fi1s of Fiow Equa/ization 243 Programs 297
Design Considercuions 243 Facilities P/c11111ing 297
Equalization of Constit11ent Mass Loading Design 297
Rates 253 Value E11gi11eeri11.g 298
Equalization of Sludge ami Bioso/ids Processing Co11struction 298
Rewrn Flows 253 Facilities Srcmup and Opera/ion 299
Problems and Discussion Topics 254 4-6 Financing 299
Long-Term Municipal Debt Fincmcing 299
Non-Debt Financing 300
4 Wastewater Treatment Leasing 300
Process Selection, Design, Privatization 300
and lmplementation 263 Problems and Discussion Topics 300

4-1 Planning for New and U pgrading Existi ng

Wastewater T reatrnent Planls 265
Need 10 Upgrade Exisling Wastewater Treaunent
5 Physical Unit Processes 305

Plants 265 5-1 Screen ing 3 10

Plan11i11g for New Wastewater Treat111en1 Ciass(fication. of Screens 3 1O
Plants 266 Screenings Characterisfics and Quantilies 311
Treatment Process Desig11 Considerations 266 Coarse Screens (Bar Racks) 3 12
X Contenls
Fine Screens 318
Microscreens 323
Screenings Handling, Processing, and
Disposal 324
5-2 Coarse Solids Reduction 325
Comminutors 325
Macerators 326
Grinders 327
Design Considerations 327
5-3 Mixing and Flocculation 327
Conti1wous R(lpid Mi.xing in WastewC1ter
Treatmellf 328
Contim,ou~· Mixing in Wastewa.ter Treatmen1 329
Energy Dissipa1ion in Mi.xing a.na
Floccu/a,/011 330
Time Sea/e in Mixing 332
Types of Mi.xers Used for Rapid Mi.xing
in Wastewarer Treatment 332
Types of Mixers Usedfor Maintaining Solids in
Suspension in Wastewater Trewment and
C/remica/ Mixing 335
Types of Mixers Usedfor Flocculation
in Wastewater Trearment 338
Types of Mixers Usedfor Continuo11s Mixing
in Wasrewarer Trearmem 341
New Developmenrs in Mixing Tec/1110/ogy 344
5-4 Gravity Separation Theory 344
Description 345
Panicle Serrling T/reory 346
Discrere Portie/e Settli11g 350
F/occulent Partic/e Se11/i11g 354
lnclined Plate and Tube Se11/ing 356
Hindered (Zone) Seuling 360
Compression Set1/i11g 364
Gravity Separarían in an Accelerated Flow
Field 364
5-5 Grit Removal 365
Wastewarer Grir Clwracteristics 366
Gril Separatorsfor Wastewater 370
Grit Se/larators for Combined Wastewarer
and Stormwater 379
Grir Was/ring 380
Grit Dryi11g 382
Disposal o.f Grit 382
Solids (Sludge) Degritting 382
5-6 Primary Sedimeotation 382
Descriptio11 383
Sedimentation Ta11k Pe,:/ormance 391
Design Considerations 393
Characterisrics and Qua11tities o.f So/ids (Sludge)
and Scum 397
5-7 High-Rate Clarification 398
Enhanced Parric/e F/occula1io11 398
Analysis of Ballasted Particle Flocculation and
Settling 399
Process Application 401
S-8 A otation 403
Descriprion 404
Design Co11sideratio11sfor Dissolved-Air Flotation
Systems 406
5-9 New Approaches for Primary Treatmeni 408
Microscreening of Raw \Vastewater 409
Charged B11bble Flotation 409
Primary Ejf111ent Filtra1io11 410
5-1 O Gas Liquid Mass Transfcr 411
Historical Developme11t of Gas Tra11sfer
Theories 411
Tite Two-Film Theory o.f Gas Tra11sfer 412
Absorption of Gases Under Turb11/e11t
Conditions 415
Absorprion of Gases U11der Quiescent
Conditions 417
Desorptio11 (Removal) of Gases 4 18
5-11 Aeration Systems 419
Oxygen Transfer 4 19
Evaluation ofAlp/,a (a) Correctirm Factor 421
Types of Aeration Systems 424
Dijfused-Air Aeration 424
Mecha11ica/ Aerators 436
Energy Requiremem for Mixing in Aeratirm
Systems 439
Generation and Dissol11tion of High-Puriry
Oxygen 440
Postaeration 443
Problems and Discussion Topics 448
6 Chemical Unit Processes 455
6-1 Role of Chemical Unit Processes
in Wastewater Treatment 458
Applicmions of Chemical Uni.t Processes 458
Considerations in the Use of Chemical Unit
Processes 459
6-2 Fundamenta Is of Chemical Coagulation 460
Basic Defi11irions 461
Na.ture of Particles in Wa.vrewarer 46 l
Developmenr and Measurement of Surface
Clwrge 462

Parricle-Particle lnteractions 463
Particle Deswbilization and Aggregarion
with Polyelectrolytes 466
Particle Destabilization and Removal with
Hydrolyzed Metal Ions 468
6-3 Chemical Precipitation for Lmproved
Plant Performance 473
Chemica./ Reactions in Wastewater Precipitation
J\pplications 474
Chemically Enhanced Primary Treatment
(CEPT) 477
!ndependenr Physical-Chemica/ Treatnumt 478
Estimation of Sludge Qua11tilies ji-om Chemical
Precipitation 479
6-4 Chemical Phosphorus Removal 481
Chemicals Usedfor Phosphorus Removal 481
Plwsphorus Removalf,vm rhe Liquid Stream
wíth Metal Salts 487
Phosphorus Renwvc1/ from the liquid Stream.
with Calcium 489
Strategies for Chemical Phosphorus Remo val 491
6-5 Chernical Formation of Struvite for Ammonium and
Phosphorus Removal 492
Chemistry of Struvite Formation 493
Conflvl cmd/or Mitigation Measures for
the Formation of Struvite 496
Enhanced Struvite Formation .for Nutriem
Removal 496
Chemical Precipltation for Removal of Hcavy
Metals and Dissolved Substances 498
Precípitation Reactions 498
Co-precipitalion wilh Plwsphorus 500
6-7 Conventional Chemical Oxidation 501
Applications for Conventional Chemical
Oxidation 501
Oxidants Used in Chemical Oxidation
Processes 501
Fundamentals of Chemica/ Oxidation 503
Chemical Oxidation of Organic Constituents 508
Chemical Oxidation ofAmmonium 508
Chemical Oxidation Process Limitations 5JO
6-8 Advanced Oxidation 51 O
Applications for Advanced Oxidation 51 O
Processes for Advanced Oxidation 513
Basic Considerations.for Advanced Oxidation
Processes 517
Advanced Oxidation Process Limitations 520
6-9 Photolysis 521
Applicalion:; for Photolysis 52 1
Confenfs xi
Photolysis Processes 522
Basic Co11sidera1io11sfor Photolysis Processes 522
Photolysis P,vce:;:; l.,imitu1ions 528
6-10 Chemical Neu tral ization, Scale
Control, and Stabilization 529
pH Adjustmenl 529
Analysis of Scaling Potential 530
Scale Control 535
Stabilizalion 536
6-11 Chemical Storage, Feeding, Piping,
and Control System5 536
Chemical Storage and Handling 536
Dry Chemical Feed Systems 538
Liquid Chemical Feed Systems 542
Gas Chemical Feed Systems 542
/nitial Chemical Mixi11g 543
Problems and Discussion Topics 544
7 Fundamentals of Biological
Treatment 551
7-1 Overview of Biological Wastewater Treatrnenl 555
Objectives of Bioiogical Treatme,11 555
Role of Microorganisms in Wastewater
Trealmelll 555
Types of Biological Processes for Was1ewater
Treatmenf 556
7-2 Composition and C lass ification of
Microorganisms 561
Cell Components 562
CeLI Compositüm 564
Environmentul Factors 564
Microorganism ldem(fication and
Classification 565
Use of Molecular Tools 568
7-3 lnlroduction to Microbial Metabolism 571
Carbo1·1 and Energy Sources for Micmbial
Gmwth 571
Nutrient (//Uf Growth Factor Requireme/lJs 573
7-4 Bacteria! Growth, Energetics, and Dccay 573
Bacierial Reproduction 574
Bacteria/ Growth Pattem s in a Batch Reactor 574
Bacteria/ Growth and Biomass Yie/d 575
Measurin.g Biomass Growth 575
Estimating Biomass Yie/d mul Oxygen Requirem.ents
from Stoichiometry 576
Esti111ating Biomass Yield.frmn Bioe11ergetics 579
Stoichiomefly (!( Biofogical Reactio11s 586
xii Contents

Biomass Synrhesis Yie/ds.for Different 7-9 Biological Oxidation of Inorganic Nitrogen 618
Growth Condirio11s 587 Process Descriptio11 6 19
Biomass Decay 587 Microbiology 6 19
Observed versus Synthesis Yield 588 Stoichiometry of Bíological Nitriftcation 622
7-5 Microbial Growth Kinetics 588 Nitijica1ion Kinetics 624
Microbial Growth Kinetics Terminology 589 AOB Kinetics 626
Rate of Uti/ization of Soluble Substrates 589 NOB Kinetics 627
Other Rate Expressions for Soluble Substrate Environmenta/ Factors 628
Utilization 591 7- 10 Denitrification 63 1
Rote of Soluble Substrcue Production from Pn1cess Descriptio11 632
Biodegradable Paniculate Organic Microbiology 633
M atrer 591 Stoichiometry oj Biologica/ Denilrijicatio11 ,md
Net Biomass Crowth Rate 592 Denirritation 634
Kinetic Coefficientsfor Su.bstrate Uti/ization and Organic Substrate Requirementsfor Denitrification
Biomass Growth 593 and Denitritaticm 635
Rare of Oxygen Uptake 593 Denitrification Kin.etics 637
Effects of Temperature 594 Em,ironmental Factors 640
Total \lolatile Suspended Solids cmd Active 7- 11 Anaerob ic Anunoitium Oxidation 640
Biomass 594 Proces.1· Description 640
Net Biomass Yield cmd Observed Yield 595 Micmbiology 641
7-6 Modeljng Suspended Growth Treatmem Anammox Stoichiometry 64 1
Processes 597 Growth Kinetics 644
Description of Suspended Growrh Trea/ment Environmemal f'actors 645
Processes 597 7- 12 Greenhouse Gas from Biological Nitrogen
Solids Reten/ion Time 597 Transform ations 645
Biomass Mass Balance 598 Source of Nitrous Oxide Emissions 645
Sub.mate Mass Balance 600 Nitrous Oxide Production Pathways 646
Mi.xed Liquor Solids Concemration and Solids
7-13 Enhanced Biological Phosphorus Removal 648
Production 600
Prvcess Descrip1io11 648
The Observed Yie[(l 603
Prvcesses Occurring in the Anaerobic Z.me 650
Oxygen Requirements 603
Proce1>\fes Occurring in a D0wns1ream Aerobic
Design and Operating Pararnerers 606
or Anoxic Zone 650
P1vcess Perfornumce and Stability 607
Microbiology 651
Modeling Plug-Flow Reaccors 609
Other Process Considerationsjor EBPR 652
7-7 Substrate Removal in Attached Growth Treatment
Swichiometry of Enhanced Biological Phosphorus
Process 610
Removed 653
Biofilm. Chara.cteristics 61 l Growtlt Kinetics 655
Biomass Characterizalion 611 Environmenral Facrors 655
Mechanistic Models 612
7- 14 Anaerobic Fermentation and Oxidation 655
Substrate Flux in Biojilms 612
Pivcess Description. 656
Substrate Mass Balancefor Biofilm 613
Microbiology 657
Substrate Flux Limitations 613
Stoichiometry of Anae,vbic Fermentation and
7-8 Aerobic Oxidation 615 Oxidation 659
Process Description 615 Process Kinetics 660
Microbio/ogy 615 Enviromn.ental 1'11ctors 663
Process Operation lssues 6 16
7- 15 Biological Removal of Toxic and Recalcitrant
Stoichiometry of Aerobic 8 iological Oxída1ion 617
Organic Compounds 663
Growth Kinetics 6 17
Development of Biological Trea/ment
Environmental Factors 6 18
Methods 664

Aerobíc /Jíoclegradation 665
Abio1ic Losses 666
Mode/i11g Biolíc and Abio1íc Losses 669
7-16 Biological Removal of Trace Organic
Compounds 671
Removal oj"li'ace Organic Co111po1111ds 672
S1eady-S1ate Fr¡/() Mnde/ 672
7-17 Biological Removal of Heavy Metals 674
Problcms ancl Discussion Topics 674
8 Suspended Growth Biological
Treatment Processes 697
8-1 Introduction to the Acrivmccl-Sludge Proccss
Hístoríca/ Deve/opment af Aclirnted Sludge
Procesr 701
Basic Pmcess Descríptio11 701
Evo/u1io11 <l the Cu11ve111io11a/ Activwed-Sludge
Process 702
Nutríent Re1110\'{// Processes 706
8-2 Wastewater C haracteri7ation 707
Key Hi1stewmer Co11sti111e111s for Process
Desígn 707
Measurement Methods far Waste1rnter
Characterí::,ation 7 12
Recycle Flmvs 011d Loadi11gs 7 J6
8-3 Fundamcnrals of Proccss Sclection, Dcsign. and
Control 717
Overa// Co11.1íderations in Treatme111 Pmcess
lmple111e111a1ion 7 17
lmportant Fl,i·tors in P,vcess Se/ection cmd
Des(i:n 717
Process Cmuml 726
Opermimwl Problems i11 Activated Sludge Systems
1vith Sec(Jlu/wy C/arifie,:r 732
Operaticmal Prvble1m with MBR Systems 738
8-4 Selector Types and Design Consideration 738
Selector Types anti Desig11 Considem1io11.1· 739
Poor Settling Even wi1h Use of Selector 741
8-5 Activatcd Sludge Proccss Design
Considera1ions 742
Steady-Swte Design Approach 742
Use o.f Si11111/atio11 Mod<!I 744
Model Matrix Formal, Co111po11e111s, a11d
Reacti011s 747
Other Simuftttion Model Applications 751
8-6 Processcs ror Bod Removal al)(! Ni trifica1ion
01·ervieiv of BOD Re111ova/ and Nitri.ficatio11
Processes 752
Contents x iii
General Process Desig11 Corrsiderations 754
Comple1e-Mix Activa1ed-Sl11dge Process
Design 754
Seq11e11ci11g Batch Reactor Process Desig11 771
Staged Activated-Sludge Process Design 782
Alternative Processesfor l:JOD Removal c111d
Nitrificatio11 786
8-7 Processes for Biological Nitrogeo Removal 795
Process Development 796
Overview of Types o.f Biologica/ Nitrogen-Removal
Processe.1 797
General Pmcess Desig11 Co11sideratio11s 802
Prea11oxic De11i1rijica1i011 Processes 804
Postanoxic De11irrijicc11io11 Processes 831
700 Low DO 011d Cyclic Ni1r(tirarion!De11irr(fication
Processes 833
Alternmfre P1vcess Conjigurwions Jor Biological
Nirrogen Removal 838
Denitrification wirh Externa/ Carbo11
Addition 848
Process Co1111vl and Perfnmrance 860
8-8 Processcs for Enhanced Biological Phosphorus
Remova l 861
P,vcess Development 86 1
01·el"l'iell' of E11ha11ced Biological Phosphnnis
Remova/ Processes 862
General Proc:ess Design Consideratio11s 864
Operatio11al Factors That A.fJect Enlwnced
Biological Phosplrorus Removal 878
E11ha11ced Biological Plrosplrorus Removal Process
Desig11 880
Provision .for Chemical Addition 883
Process Control and Pe,formance
Op1i111i:.01io11 884
8-9 Aeration Tm1k Design for Activated-S ludge
Processe~ 885
Aeration System 885
Aera1io11 Tw,k:. aI1d App11rte11a11ces 886
8-10 Analysis of Liquid-Solicls Separation for
Activatccl-Sludge Processes with C larificrs 889
Solids Separatio11 by Secondary Clarifiers 889
A.rsessíng S/udge Tlricke11i11g Characteristics 891
Clarífier Design Based on Solids Flux
Analysis 893
C/arífier Desig11 Based 011 State Point
Analysis 900
8-11 Design Considemtions for Secondary
752 Clari fíers 906
Types e!{ Sedí111e11tatio11 Tank 906
Sidewater Depth 91 O
xiv Contents
Flow Distribution 910
Tank lnlet Design 9 JO
Weir Placement a11d Loading 912
Scum. Removal and Managemen.t 912
8- 12 Soli ds Separation for Membrane Bioreactors
Design Parameter 913
Membrane Properties 9J4
Membrane Design and Operating
Characteristics 917
Membrane Usage 917
Membrane Fouling lssues 917
Problems and Discussion Topics 9 19
9 Process Developm.en.t 1026
Attached Growth a nd
Combined Biological
Trea tment Processes 941
9-1 lntroductioo to Attached Growth Processes 943
Types ofAuached Growth Processes 943
Mass Transfer Limítations inAttached Growth
Processes 947
9-2 Nonsubmerged Attached Growth Proce~ses 947
General Pro<.:ess Description 947
Trickling Filter Classijication an,/
Applications 950
Advaniages ami Disadvantages of Trickling
Filters 953
Physical Facilítíesfor Trickling Filters 954
Design Consi.derationsfor Physícal
Facilities 957
Process Desí.gn Considerarionsfor BOD
Removal 968
Process Analysisfor BOD Removal. 972
Process Analysis for Nitrijication 978
9- 3 Sequential Combined Trickli ng Filter and
Suspended Solids Processes 987
Process Development 987
Process Applications 987
Trickling Filter/Solids Contact Process 988
Trick/ing Filter!Activated Sludge Process 990
Series Trickling-Filler Activated-Sludge
Process 997
9-4 lntegrated Fixed-Filrn Aclivated
Sludge Process 997
Process Development 998
Process Applications 1000
!FAS Process Adl'antc1ges and
Disadvantages 1002
Design of Physical Facilities l003
I FAS Process Design Analysis 1005
BOD and Nitrijication Design Approach l 008
9-5 Movi ng Bed Biofilm Reactor (MBBR) lOJ 5
913 Background 1015
MBBR Process Applications JO 16
MBBR Process Advantages ami
Dísad11antages 1016
Design o.f Physica/ Facilities 1019
MBBR Process Design Analysis 1020
BOD Removal a11d Nitrification Design. 102 1
9-6 Submerged Aerobic Attached Growth
Processes l 026
Process Applicalions 1027
Process Advantages and Disadva,11ages 1027
Desig11 of Physical Facilities 1029
BAF Process Desigrz Analysis 1031
FBBR Process Design Anal.ysis 1034
9-7 Attached Growth Denitrification Processes l034
Process Development 1034
Description and Application <~f'Altached Growth
Denürification Processes 1035
Process Design Analysis of Postanoxic Attached
Growth Denitr(fication. 1037
Operational Considerations fór Postan.oxic Attached
Gl1)wth Denitrijication. 1041
9-8 Emergíng Biofilm Processes 1045
Membrane Biofibn Reactors 1045
Biofilm Airlifi Reactors 1046
Aerobic Granules Reactor 1046
Problems and Discussiou Topics l 046
10 Anaerobic Suspended and
Atta ched Growth Biological
Treatment Processes 1059
10-1 The Rationa le for Anaerobic TreaU11ent 106 1
Advamages ofAnaerobic Treatmen.t
Processes 106 1
Disadvaruages ofAn.aerobic Treatment
Processes 1062
Summaiy Assessmen.t J063
10-2 Development of A naerobíc Technologíes 1063
Historical Developments in Liquefaction. 1063
Treatment ofWastewater Sludges 1065
Treatment of High Strength. Wastes 1066
Future Developments J067

10-3 Avai la ble Anaerobic Technologies 1067
Type.1 of Anaerobic Tecluwlogies 1067
App/ication of Anaerobic Teclmologies !071
lo-4 Fundamental Considerations in the Appl ication of
Auaerobic Treatment Processcs 1075
Characteris1ics ofthe l.füstewater !075
Pretrealment of Wastewa1er 1080
E.xpecled Gas Producli<m 1083
Energy Produc1io11 Pote111ial 1085
Suljide Produclion 1088
Ammrmia Toxicily 1090
10-5 Design Considerations for lmplementation
of Anaerobic Treatment Processes 1090
Treatmellt Efficie11cy Needed 1091
General Process Design Paromeiers 1091
Process lmplememation Jssues 1093
1()-6 Process Design Examples 1095
Upflow Anaerobic Sludge Blanker Pmcess 1095
Anaerobic Conracl Process 1103
Use of Simularion Models 1107
10-7 Codigestion of Organic Wastes with Munici pal
SJudge 1108
Problems and DiscllS.5ion Topics 1109
11 Separation Processes for
Removal of Residual
Constituents 11 11
11-1 Need for Additional Wastewater Treatment 1120
11-2 Overview ofTcchnologies Used for Removal of
Residual Paiticulate and Dissolved
Constituents 11 20
Separa/ion Processes Based 011 Mass
Transfer 1120
Tra11sformation Based on Chemical and
Biologica/ Processes 1122
Applicalion of U11i1 Processes for Removed
of l<esidual Constiwents J123
11-3 Unit Processes for the Removal of Residual
Particulate and Dissolved Constituents 1123
Typical Process Flow Diagrams 1124
Process Performance Expectations 1125
11-4 lntroduction to Depth Filtration 1129
Description of the Filtratio11 Process 1 129
Filter Hydraulics 1134
Mode/i11g 1/ze Fi/tration Process 1142
11-5 Oepth Filtration: Selection and
Design Considerations 1144
Contents XV
Avoi/t1ble Filtration Technologies 1144
Perfon11a11ce of Different Types of Deptl,
Fillers 1146
Considerations Re/ated to Design and Operation
of Treatment Facilities 11 56
Selecrion of Fi/tration Technolngy 1158
Design Considera1ions for Granular Medium
Filters 11 61
11-6 Surface Filtration 1171
Available Filtra1io11 Teclmologies 1172
Description of the Swface Fi/1ratio11 Process 1175
Performance of S111face Filters J178
De~ig11 Considerations 1180
Pilot Plafll S!udies 1180
11-7 Membrane Filtration Processes 1181
Membra11e Process Ten11i110/ogy 1181
Membr<me Process Classijica1ion 1182
Memhrane Comaimnent Vessels 1185
Operationa.l Modes for Pres.mrized
Conjigurations 1189
Pmcl'ss Analysisfor MF and UF
Memhranes 1190
Opera1i11g Strategiesfor MF and UF
M embranes 1192
Process Analysis.for Reverse Osmosis 1193
Membrane Fouling 1198
Cnnr rol ofMembra11e Fo11Li11g 1201
Application and Pe,fnmwnce of Membranes 1204
Fnrwtml Osmosis: An Emergi11g Membrane
Technology 1212
Pilor-P/ant S111dies for Membrane
Applications 12 14
Management o.f Retentate 1215
11- 8 Elcctrodialysis 1217
Descriplion of the E/ectrodialysis Process 1217
Electrodialysis Reversa/ 1218
Power Co11sumprio11 1220
Opera1ing Cnnsidera1ions 1222
Electrodialysis Versus Reverse Osmosis 1223
11-9 Adsorplion 1224
Applications for Adsorptio11 1224
Types of Adsorbe11ts 1224
Fundam.entals of Ad.rnrp1io11 Processes 1227
Deve/opmenr o/Adso,ption lsothenns 1227
Adsorption of Mix111res 1232
Adsorption Capacity 1232
Sma/1 Sea/e Co/1111111 Tests 1240
Analysis o/ Powdered Actil'{//ed Carbon
Co111ac1or 1243
xvi Contenfs
Acrivated Sludge-Powdered Activated Carbon
'freatment 1244
Carbon Regenera/ion 1245
Adso11-1tíon Process Limitatíons 1245
11-10 Gas Stripping 1245
Ana/.ysis of Gas Stripping 1245
Design o.f Stripping Towers 1256
Air Stripping Applications 126 1
11-11 loo Exchange 1261
Ion Exchange Materials 1262
Typica/. Ion Exchange Reactions 1263
Exchange Capaciry of Ion Exchange Resins 1264
fon Exchange Chemistry 1266
App/.icatüm of Ion Exchange 1270
Operationa.l Considerations 1275
11-12 Distillation 1275
Distillation Processes 1276
Performance Expectations in Reclamatio11
Applications 1277
Operating Problems 1278
Disposa/ of Con.cen.trated Was te 1278
Ptoblems and Discussion Topics 1278
12 Disinfection Processes 1291
12-1 Tntroduction to Disinfectants Used in
Wastewater 1294
Characteristics for a11 ideal Disi11fec1a111 1294
Disinfection Agen1s and Methods 1294
Mechanisms Used to Explain Ac1ion of
Disinfecranrs 1296
Comparison of Disü!fe c1ams l297
12-2 Disinfection Process Considerations 1297
Physical Fa.ciliries Usedfor Disinfection 1297
Factors Ajfecting Pe1:formance 1300
Developmenr of rhe CT Concep1 for Predicring
Disin.fe ction Pe,jorman.ce l 306
Application of the CT Concept 10 Wastewarer
Disinfec1ion 1307
Performance Comparison of Disinfection
Techno/ogies 1308
12- 3 Disinfection with Chlorine 1312
Characterisrics of Ch/orine Compounds 1312
Chemistry of Chlorine Compou11ds 1314
Breakpoint Reaction with Ch/orine 13 16
EjJ'ectiveness of Free and Combined Chlorine
as Disinfectants 1320
Measurement and Reporting of Disinfe ction Process
Pe,jormance 1322
Faciors that Ajfecl Disinfectio11 of 1*1stewa1er
with Ch/orine Compounds l 323
Modeling the Ch/orine Disinfection Pmcess 1328
Required Chori11e Dosages jor Disinfeclion 1329
Forma/ion and Control of Disinfection Byproducts
(DBPs) 1333
Envimnmental Impacrs of Disirif'ection with
Ch/orine l 336
12-4 DisiJ1fection with Chlorine Dioxide 1337
Characteristics of Ch/orine Dioxide 1337
Chforine Dioxide Chemistry 1337
Ejfectiveness of Chlorine Di oxide as a
Disin.fectant 1338
Modeling the Ch/orine Dioxide Disin.fection
Process 1338
Required Chlorine Dioxide Dosages for
Disinfeclion 1338
Byproduct Formation and Control 1338
Environmental lmpac1s 1339
12-5 Dechlorínation 1339
Dechlorination of Treated Wastewater
with Sul,fur Dioxide 1339
Dechiorirwtion of Treated Wastewafer with Sodium
Based Compounds 1341
Dechlorinatíon with Hyd1vgen Peroxide l 342
Dech/orination with Activated Carbo11 1342
Dechlorination. of Ch/orine Dioxide with Sulfur
Dioxide 1342
12-6 Design of Chlorination and Dechloriuation
Facilities 1343
Sizing Chlorinalion Faciliries 1343
Disinj'ec1ion Process Flow Diagrams 1344
Dosage Conrrol 1347
Injection a,ut lnitia/ Mixing 1349
Chlorine Contact Basin Design 1349
Assessir1g the Hydrau/ic Performance of Existing
Chlorine Contact Basins 1359
Outlet Control and Ch/orine Residual
Meas1.1rement 1365
Ch/orine Srorage Facilities 1365
Chemical Contaimne/'11 Facilities l366
Dechlorination Facilities l 366
12-7 Disinfection with Ozone 1367
Ozone Properties 1367
Ozone Chemistry 1368
Effectiveness of Ozone as a Disiefectant 1369
Modeling the Ozone Disinf'ection Process 1369
Required Ozone Dosages for Disinfection 1372
Es1imation of th.e CT Value 1372
 Contents xvii

Byproduct Formation and Control 1374 13-2 Regulations for the Reuse aod Disposition of SJudge
Environmental lmpacts <~f Using Ozone 1374 in the U11ited States 1461
01her Bene.fits of Using Ozon.e 1375 Land Application 1461
Ozo11e DisinfeClion Systems Components 1375 Su,face Disposition 1462
12-8 O ther Chemical Disinfection Methods 1378 Paihoge11 and Vector Attraction Reduction 1462
Peracetic Acid l379 lncineration 1463
Use of Peroxone as a Disinfectant 1380 13-3 Sludge Processing Flow Diagrams 1466
Sequential Chlorination 1381 13-4 Sludge and Scum Pumping 1467
Combined Chemical Disinfection Processes 1381 Pumps 1467
12-9 Ultraviolet (UV) Radiation Disinfectioo 1.382 Headloss Determination 1475
Source of UV Radiation 1383 S/udge Piping 1480
Types o.f UV Lamps 1384 13-S Prelimioary Sludge Processing Operations 1481
UV Disiufecrion System Co11/iguratio11s 1387 Grindi11g 1481
Quartz Sleeve Cleanin.g Systems J 390 Screenillg l 482
Mechnnism of /11activatio11 by UV Degriuing 1482
lrradiation 139 l 8/ending 1483
Gennicida/ Effectiveness of UV Jrradiation J 393 Storage 1484
Estirnating UV Dose 1399 13-6 Thickening 1486
Ultraviolet Disi11fection Guidelines 1404 Application 1486
Relc1tionship of UV Guidelines to UV System Description and Design <~f Thickeners 1487
Design 1405
13-7 lntroduction to Slu dge Stabilization 1497
Validation of UV Reactor or System
Pe,formance 1405
13-8 Alkaline Stabilization 1498
Chemicai Rea.ctions in Lime Stabi/iza1io11 1498
Factors Effecti11g UV System Design 14 13
Heat Generation 1499
Se/ection and Sizi11g of a UV Disinfec1io11
Applicatiori oj Alkali11e Stabi/ization
System 1420
Processes 1500
Use of Spot-Check Bioassay to Validare UV System
Pe1.formance 1422 13-9 Anaerobic Digestion 1.502
Troub/eshooting UV Disinfection Systems 1426 Pmcess Fundamentals 1503
Enviror1111entaL lmpacts o.f UV Racliation Description of Mesophilic Anaerobic Digestion
Disinfection 1428 Processes 1504
Process Design for Mesophi/ic Anaerobic
12-10 Dis.infection By Pasteurization 1428
Dige.1·1io11 1506
Description of the Pasreurization Process 1428
Selectio11 ofTank Design and Mixing System 1512
Thermal Disi1if'ec1ion Kinetics 1429
Methods for Enhancing Sludge Loading and
Germicida/ E.fj'ectivene.u of Pasteurizc,tion 1433
Digester Pe,forman.ce 1520
Regularory Requirements 1433
Gas Production, CoLlection, a11d Use 1520
Application of Pasteurization.for
Digester Heming 1525
Disi11fection 1433
Advancerl Anaerohic Digestion 1530
Problems and Discussion Topics 1434 Sludge Pre-treatment.for A11aerobic
Digestion l 533
13 Processing and Treatment Co-digesrion with Other Organic Waste
Material 1538
of Sludges 1449
13-10 Aerobic Digestion 154 1
13-1 Sludge Sources. Characteristics, and Process Description 1542
Quantities 1453 Conventional Air Aerobic Digestion l.544
Sources 1453 Dual Digestion 1549
Characteristics 1454 Autothermal Thennophilic Aerobic Digestion
Qua11tities 1456 (ATAD) 1549
xviii Contents
lmproved ATAD Systems 1553
High-Purity Oxygen Digestion 1553
Problems and Discussion Topics 1554
14 Biosolids Processing, Resource
Recovery and Beneficial
Use 1561
14-1 Chemical Conditioning 1564
Polymers 1564
Factors A.ffecling Polymer Conditioning
Polymer Dosage Determination 1565
Mixing 1566
Condirioning Makeup and Feed L567
14-2 Dewatering J567
Overview of Dewa.tering Technologies
Centrifugation 157 1
Belt-Filter Press 1574
Rotary Press 1577
Screw Press 1580
Filter Presses 1583
Elec1ro-Dewatering 1585
Sludge Drying Beds 1588
Reed Beds 1.592
Lagoons 1593
14-3 Heat Drying 1593
Heat-Trans.fer Methods 1593
Process Description 1595
Produce Characteristics and Use 1599
Product Transport and Storage 1600
Fire and Explosion Hazards 1601
Air Pollution and Odor Con.hvl 1601
14-4 Advanced Thermal Oxjdation 1602
Fundamental Aspect.~ of Complete
Combus1ion 1603
Multiple-Hearth lncineration 1606
F/uidized-Bed Incineration 1608
Energy Recovery from Thermal Oxidation 1610
Coincineration with Municipal Solid Waste 1611
Air-Pollution Control ] 612
14-5 Composting 1613
P1vcess Microbiology 1614
Composting Process Sta.ges 1614
Composting Process Steps 1614
Composling Methods 16 16
Design Considerations 1618
Co-composting with Municipal Solid Wastes [620
P11blic Health and Environmental lssues 1620
14-6 Sludge and Biosolids Conveyance and Storage 1621
Conveyance Methods 1621
Storage 1622
14-7 Solids Mass Balances 1623
Preparation of Solids Mass Balances 1623
Performance Data.far Solids Processing
Facilities 1623
lmpact of Return Flows and Loads 1623
14-8 Resource Recovery from Sludges ancl
Biosolids 1636
1565 Recovery oj Nutrients 1637
Agricultura/ Land Application 1637
Non-Agricultura/ Lana Applications 1637
14-9 Energy Recovery from Sludge and Biosolids 1638
Energy Recovery through Anaerobic
1568 Digestion 1638
Energy Recovery by Thermal Oxidation 1639
Energy Recoveryfrom Dried Material through
Gasifica/ion and Pyrolysís 1639
Production <1f Oíl and Liquid Fue[ 1640
14-1 O Application of Biosolids to Land 1640
Benefits oj úmd Application 1640
U.S. EPA Regulations for Beneficia.( Use and
Disposal of Biosolids 1640
Management Practices 1641
Site Evaluation and Selection 1643
Design Loading Rafes 1644
Application Methods 1648
Application to Dedica.red Lands 1650
Landjilling 1651
Problems and Discussion Topics 1651
15 Plant Recycle Flow Treatment
and Nutrient Recovery 1659
15-1 Sidestream Identifü:ation and
Characterization 1661
Sidestreams Derived fivm Primary
and Secondary Sludges 1662
Sidestreams Derived from Fermen.ted Primary
and Digested Prima,y and Secon.{Ú¡ry
Sludges 1662
15-2 Mitigating Recycle Flows and Loads 1667
Sidestream Pretreatmenl 1667
Equalization of Sidestream Ffows and Loads 1667
1S-3 Reduction of Suspended Solids and Colloidal
Material 1673
Sidesrreams Derived from Sludge Thickening 1673
 Contents xix

Sidestreams Derived from Biosolids Design Loadi11.g and Load Equalizatio11 1717
Dewatering 1673 Sidestream Pretrea1111ent 1717
Remo val of Colloida/ Matter 1674 Sidestream Reactor Volwne 1718
Aeration System 17'18
15-4 Physiochemical P rocesses for P hosphorus
Recovery L674
Sl11dge Rete11tio11 Time and Mixed Liq11or Suspended
Description of 1/ie Crystailiza1ion Solids Concen1ratio11 1721
Process 1675 Chemica/ Requirements 1721
Recove1y of Phosphorus as Magnesium Ani111011iw11. Operaling Tempera111re and pH 1723
Plwsp/wte (Struvite) 1678 Opera1ing pH 1723
Recovery of Phosphorns as Q1lcium Energy Balance to De1ermine /?eactor Cooling
Requirements 1723
Phosphate J 683
Plwsphorus Recovery from Mainstream Problems and Oiscussion Topics l728
Pmcesses 1684
15-5 Physiochemical Processcs for Amrnonia Recovery 16 Air Emissions from
a11d Destruction 1686
Wastewater Treatment
Recove1y of Ammonia by Air Stripping
and Acid Absorption 1686 Facilities and Their
Recovery of Ammo11.ic1 by Steam S1rippi11g 1690 Control 1737
Air Stripping with Thermocatalytic: Destruction
16-1 Types of Em issions 1739
of Ar111nonia 1692
16- 2 Regu latory Req uirernents 1739
15-6 Beneficia! Use of Recovered Phosphate a nd
Ambienl Air Quaiity and Attainmenl
Ammonium Products 1693
Status 1739
Magnesium Am111011i11m Phosphate Hexahydrate Preconstruc1io11 and Operaling Permitting
(Struvite) 1693 Programs 1741
Calcium Phosphate (Hydroxapatite) 1694 S1a1ionary Source Control Technology
A111moniu111 Sulfme 1694 Requirements 1741
Ammonium Nitra/e 1695
16-3 Odor Management 1742
15-7 Biological Removal of Nitrogen from
Types of Odors 1742
Sidestrea ms 1696
S011rces of Odors 1742
Nitrogen Removal Processes 1696 Measurement of Odors 1745
Separate Trearme111 Processes .f<)r Nitrogen Odor Dispersion Modeling 1746
Removed 1697 Movement of Odors from W.:1stewcaer
lntegrated Sidestream-Mainstream Treannent
Treatment Facilities 1746
a11d Bioaugmentation 1699 Strategiesfor Odor Manageme,u 1747
15-8 Nitrification and Deuitrification Processes J700 Odor Treatment Methods 1751
F1.111da111e111al Process Co11.sideratio11s 1700 Selection and Design of Odor Control
Trea1me11t Processes 1703 Facilities 1760
15-9 Nitiitalion and Denitritation Prucesses 1706 Design Comideralions for Chemical
Fundamental Process Considera1io11s 1706 Scrubbers 1760
Trearment Processes 1709 Design Consideracions for Odor Control
15-10 Partial Nitritation and Anaerobic Am monium Bio.filters 1762
Oxidation (Deammonification) Processes 1709 16-4 Control of Volati le Organic Carbon
Fundamental Process Considera1ions 1710 Emissions 1767
Treatment Processes 17 15 Physical Properties of Selected VOCs 1768
15- 11 Process Design Considcrations for B iologicaJ Emission <i VOCs L768
Treau11ent Processes 1715 Mass Transfer Ra1es for VOCs 177 l
Sides1ream Characteristics and Treamrelll Mass Transfer of VOCs from Swjace
Objectives 1716 and Dijfused-Air Aerc,tion Processes 1771
XX Contents

Control Strategies for VOCs J774 Energy Recovery from Gaseous Fuels with
Trearmen1 ofOff-Gases 1774 Boilers 1824
16-5 Emissions frorn the Combustion Energy Recovery fmm Solid Fuels 1826
Of Gases And Sofids 1777 Energy Recovery from Syngas 1833
Sources of Fuels 1777 Energy Recovery with Fuel Cell J833
Combustion Systems Used al Wastewater 17- 7 Recovery and Utilization of Thermal
Treatmen.t Plants 1778 Energy 1834
Emissions of Concem .from Combustion Sources of Heat 1835
Sources 1779 Dem.andsfor Hea1. 1836
Flaring of Digester Gas 1780 Devices for Waste Heat Recovery and
16-6 Emission of Greenhouse Gases 1784 Utilization 1838
Frameworkfor Greenhouse Gases Reduction 1784 Design Considerations for Thermal Energy
Assessment Protocols 1784 Recovery Systems 1843
Opportunitiesfor GHG Reduction at Wastewater 17-8 Recovery and Utiljzation of Hydraulic Potential
Trealment Facilities 179 1 Energy 1846
Problems and Discussion Topics 1793 Type of Hydraulic Potential Energy Recovery
Devices 1846
Application of Hydraulic Energy Recovery
17 Energy Considerations in Devices 1847
Wastewater Management 1797 Use of Residual Pressure Head in Treatment
17-1 Factors Driving Energy Managemen1 1799 Processes 1849
Potentialfor Energy Cost Savings 1799 17-9 Energy Management 1850
En.ergy Supply Reliability 1800 Process Optimization and Modijication
Considera.tüms far Sustainability 1800 far Energy Saving 1850
17-2 Energy in Wastewater 1800 Process Modificationfor lncreased Energy
Chemical Energy 1800 Produclion 1856
Thermal Energy 1804 Peak Flmvrate Ma.nagement (Peak Energy
Hydraulic Energy 1805 Usage) 1857
Selection of Energy Sources 1858
17-3 Fundamentals of a Heat Balance 1807
Concept of a Heat Balance J807 17-1 O Future Opportunities for Ahernative Wastewater
Preparatio11 of a Heat Balance 1808 Treatment Processes 1858
17-4 Energy Usage in Wastewater Treatrnent Enhanced Energy Recove,y of Particulate Organic
Plants 1809 Matter 1858
Reduced Energy Usage in Biological
Types of Energy Sources Used at Wastewater
Treatment 1859
Treatment Facilities 1810
Reduced Energy Usage through the Use of
Energy Usefor Wastewater Treatment 1810
Altern.ative Treatment Processes 1859
Energy Use by In,lividual Treatment
Prospects for the Future 1860
Processes 18 lO
Advanced and New Wastewater Treatment Problems and Discussion Topics l860
Tecfmologies 1811
17-5 Energy Audits and Benchmarking 1813 18 Wastewater Management:
Benchmarking Energy Usage 1814
Future Challenges and
Benchmarking Protocol 1815
17-6 Recovery and Utilization of Chemical
Opportunities 1865
Energy 1819 18-1 Futurc Challenges and Opportunities 1867
Fuels Derivedfrom Waslewater 1819 Asset Management 1867
Energy Recovery fmm Gaseous Fuels with Engines Design for Energy and Resource Recovery 1869
and Turbines 1821
 Contents xxi

Desig11 of Wastewater Treatment Plant.v SSO Guidarice 1895

for Potable Reuse 1869 Wet-Wea1her Management Options 1895
Decet11ralized (Satellite) Wastewater Discussion Topics 1899
Treatment 1872
Low lmpact Development 1873
Triple Bottom Li11e 1875 Appendix es
18- 2 Impact of Population Demographics, Climate A Conversion Factors 1901
Change and Sea Leve! Rise, Uocontrollable Events, 8 Physical Properties of Selcclcd Gases and the
and Uninteoded Coosequences 1875 Composilion oí Air 1909
lmpact of Popu/(ltion Demogruphics 1876 e Physical Properties ofWater 1913
lmpact of Clima te Change and Sea Leve/
D Statislical Analysis of Data 1917
Rise 1877
lmpact of Unco111rollable Evems 1879 E Dissolved Oxygen Concenlration in Water as a
lmpact of the Lc1w of Unintended Function ofTempernture, Salinity, and Barornetric
Consequences 1879 Pressu re 1923

18-3 Upgrading Trcatment Plant Performance Through F Carbonate Equilibrium 1925

Process Optimization and/or Operational G Moody Diagrarns for the Analysis of Flow in
Changes 1882 Pipes 1929
Process Optimization 1882 H Analysis of Nonidcal Plow in Rcactors using
Operational Ch(l11ges to lmprove Plan/ Tracers 1931
Performance 1886 Modeling Nonideal Flow in Reactors 1941
18-4 Upgrnding Treaunent Planl Performance Through
Process Modilication 1889
Upgrading Physical Facilities 1889
Indexes
VpRrading to Meet New Co11sti111ent Re111oval Namc lndex 1953
Require111e111s 1890 Subject Tndex 1966
18-5 Management of Wet-Weather Flows 1890
SSO Policy Issues 1892
 Suspended Growth Biological
Treatment Processes

8- 1 INTRODUCTION TO THE ACTIVATED SLUDGE PROCESS 700

Historical Development of Activated Sludge Process 70 7
Basic Process Description 101
Evolution of the Conventional Activated Sludge Process 702
Nutrient Removaf Processes 706
8- 2 WASTEWATER CHARACTERIZATION 707
Key Wastewater Constituents far Process Design 707
Measurement Methods far Wastewater Characterization 77 2
Recycle Flows and Loadings 716
8- 3 FUNDAMENTALS OF PROCESS SELECTION, DESIGN, AND CONTROL 717
Overa// Considerations in Treatment Process lmplementation 717
lmportant Factors in Process Sefection and Design 717
Process Control 726
Operationaf Problems in Activated Sfudge Systems with Secondary Cforifiers 7 32
Operotionol Problems with MBR Systems 138
8-4 SELECTOR TYPES AND DESIGN CONSIDERATION 738
Selector Types and Design Considerations 739
Poor Settling Even With Use of Selector 7 41
8-5 ACTIVATED SLUDGE PROCESS DESIGN CONSIDERATIONS 7 42
Steady-State Design Approach 7 42
Use of Simulation Model 7 44
Modef Matrix Formal, Components, and Reactions 7 47
Other Simufation Model Applicotions 751
8-6 PROCESSES FOR BOD REMOVAL AND NITRIFICATION 752
Overview of BOD Removal and Nitrification Processes 752
General Process Design Considerations 754
Complete-Mix Activated Sfudge Process Design 754
Sequencing Batch Reactor Process Design 771
Staged Activated Sludge Process Design 782
Afternative Processes far 800 Removaf and Nitrification 786
8- 7 PROCESSES FOR BIOLOGICAL NITROGEN REMOVAL 795
Process Development 796
Overview of Types of Biological Nitrogen-Removal Processes 797
General Process Design Considerotions 802
Preanoxic Denitrification Processes 804
Postanoxic Denitrification Processes 831
Low DO and Cycfic Nitrification/Denifrificotion Processes 833
Afternative Process Configurations for Biofogicol Nitrogen Removaf 838

697
698 Chopter 8 Suspended Growth Biologicol Treolment Processes

Denitrification with Externa/ Carbon Addition 848

Process Control and Performance 860
8-8 PROCESSES FOR ENHANCED BIOLOGICAL PHOSPHORUS REMOVAL 861
Process Development 86 1
Overview of Enhanced Biological Phosphorus Removal
Processes 862
General Process Design Considerations 864
Operational Factors That Affect Enhanced Biological Phosphorus Removal 878
Enhanced Biological Phosphorus Removal Process Design 880
Provision for Chemicaf Addition 883
Process Control and Performance Optimiza/ion 884
8-9 AERATION TANK DESIGN FOR ACTIVATED SLUDGE PROCESSES 885
Aeration System 885
Aeration Tonks and Appurtenances 886
8-1 O ANALYSIS OF LIOUID-SOLIDS SEPARATION FOR ACTIVATED SLUDGE
PROCESSES WITH CLARIFIERS 889
Solids Separation by Secondary Clarifiers 889
Assessing Sludge Thickening Characteristics 891
Clarifier Design Based on Solids Flux Analysis 893
Clarifier Design Based on $tate Point Analysis 900
8-11 DESIGN CONSIDERATIONS FOR SECONDARY CLARIFIERS 906
Types of Sedimenta/ion Tank 906
Sidewater Depth 91 O
Flow Distribution 91 O
Tonk In/et Design 91 O
Weir Placement and Loading 912
Scum Removal and Management 912
8-12 SOLIDS SEPARATION FOR MEMBRANE BIOREACTORS 913
Design Parameter 913
Membrane Properties 914
Membrane Design and Operating Characteristics 917
Membrane Usage 917
Membrane Fouling lssues 917
PROBLEMS AND DISCUSSION TOPICS 919
REFERENCES 934

WORKING TERMINOLOGY
Term Definition

Activoted sludge process
Biologicol treotment process thot involves the convers ion of orgonic motter ond/or other constit-
uents in the wostewoter to gases ond cell tissue by o lorge moss o f oerobic microorgonisms
mointo ined in suspension by mixing ond oerotion. The microorgonisms form flocculent particles
that are separoted from the process efAuent in a sedimentation tank (clorifier) and are returned
subsequently to the aeration process or wasted.

Term
Aerobic (oxic} processes
A naerob ic processes
A noxic process
Biomoss
Biological nutrient removal
{BNR)
Denilrification
Enhanced biologica l phos-
phorus removal (EBPR)
Hindered settling
Focultotive processes
Fermenlalion
Membrane bioreoctor (MBR)
Membrane flux
Mixed liquor suspended
solids (MLSS}
N itrificotion
Nocardioform foom
Nonbiodegradable volatile
suspended solids (nbVSS)
Phosphorus occumuloting
orgonisms (PAOs)
Readily biodegradable
COD (rbCOD)
Sequencing ba tch reactor
(SBR)
Simulo tion models
Simultaneous nitrificalion
and denitrificotion {SNdN)
Chopter 8 Suspended Growth Biological Treatment Processes 699
Definition
Biologicol treatment processes that occur in the presence of free d issolved oxygen; oxygen is
consumed by oerobic microorgan isms in oxidation/reduction reaclions to produce energy for
cell growth o nd cell maintenonce.
Biologicol treatment processes that occur in the absence of oxygen.
Biologica l treatment process that occurs in the absence of free d issolved oxyg en where nitrate
and nitrite ore used as the main electron acceptors in biologi cal oxidotion/reduction reocti ons;
denitrification is an exomple of an a noxic process.
The total mass of solids in a reactor consisti ng mainly of organic matter ond microorgonisms.
The term opplied to the removol of nitrogen ond phosphorus in biologica l trea tment processes.
The biological process by w hich nilrate ar nitrite is reduced to nitrogen ond other gaseous end
products.
Removal of phosphorus by exlraord inary storoge in bacteria selected in anoerobic/oerobic
process configuration ond subsequent solids separation.
Settling which occurs when the octivoted sludge flocs interfere wi th each other as they settle.
Biologico l treotm ent processes in w hich the organisms con function in the presence or obsence
of molecular oxygen.
The conversion o f orgonic matter to volotile fatty ocids in the obsence of oxygen, nitrate, ond
nitrite.
A process thot combines a suspended growth process with o membrone seporation systern
w ithin !he process oeration tan k; membrane seporotion is accomplished by either microfiltrotion
ar ultrofiltration.
The rote of flow ocross a membrane per unit of surloce orea, L/m 2 ·h.
The biomoss contoined in a treo tment reactor used to bring obout treotment of the organic
material in wastewater.
The two-step biological process by wh ich nitrogen (mostly in the form of ammonio) is converted
to nitrite and then to nitrate.
A thick layer of brown, biologica l foom caused by o filamentous bacteria that forms o n the top
of aeration tanks and secon dary clo rifiers.
These ore suspended solids contained in influent wastewoter to octivated sludge processes that
ore organic but not biodegradoble. They impacl sludge production.
Heterotrophic bacteria selected in EBPR processes that hove the obility for high inlracellulor
phosphorus storoge.
Dissolved biodegradoble orgonic substroles w hich ore removed by bacteria much faster ~, on
colloidal or porticulate degradoble COD. Th e rbCOD impacts spotia l oxygen demand, EBPR
removal efficiency, and denitrification roles.
An SBR is a batch fill and draw octivated sludge lreatrnent process. lt involves o treatment
sequence of fi ll, reoct, settling, supernaton t deconting, a nd idle. Activated sludge aerotion and
liquid solids separotion occurs in the sorne tank.
Mathernoticol models, bosed on a set of equotions, used to ossess the effects of ki netics ond
changes in the wostewater characterizes on process performance.
Nitrogen removol occurs in sorne activated sludge floc or in a biofilm due to nitrificotion in
oerobic outer layer and denitrification in interior due to the lack of dissolved oxygen and
presence of nitrate or nitrite.
700 Chopter 8 Suspended Growth Biologicol Treotment Processes

Term
Sludge production
Sludge yield
Solids flux onolysis
Solids retention time (SRT)
Stoged process
Surface overflow rote
Suspended growth processes
Volumetric orgonic loading
role
Definition
The omount of solids produced during the biologicol processing of wostewoter including
influent nonbiodegradoble solids ond the biomoss resulting from the conversion of orgonic.
The omounl of solids produced relotive to the omount of BOD or COD removed during the
biologicol processing of wostewoter.
A method used to determine the oreo requ ired for hindered settling bosed on on onolysis of the
solids (moss) flux.
The average period of time in which solids remoin in o suspended growth process (olso called
sludge oge).
Processes which occur with more thon one independent reactor or comportment in series.
The hydraulic flowrote applied relative to the clorifier surface oreo (m 3/m 2 ·d ).
Biologicol treotment processes in w hich microorgonisms responsible for the conversion of
organic matter or other constituents in the wostewaler lo gases ond cell tissue ore maintoined in
suspension within the liquid.
The omount of BOD or COD opplied to the aeration tank volume per doy (e.g ., kg BOD or
C0D/m 3 ·d).

The theory of biological wastewater treatment is presented and discussed in detail in

Cbap. 7. Biological treatment processes, as noted in Chap. 7, may be classitied as aerobic
and anaerobic suspended growth, attached growth, and various combinations thereof. The
focus of this chapter is on s uspended growth treatment processes as exemplified by the
actívated sludge process for BOD and nitrification and for nitrogen and phosphorus removal.
Attached growth and combined processes are cliscussed in Chap. 9, a.ne! suspended and
attached grnwth anaerobic processes are considered in Cbap. 1O. lncluded in this chapter
are ( 1) íntroduction to the activated sludge process. (2) wastewater characterizatioo, (3) fun -
damentals of process selection, design, and control, (4) selector types and design consider-
ations, (5) use of simulation models for activated sludge process design considerarioos,
(6) proce~ses for BOD removal and nit1ification, (7) processes for biological nitrogen
removal, (8) processes for enhanced bio\ogical phosphorus removal, (9) aeration tank design
for activatecl sludge processes, () 0) analysis of liquid separation for activated sludge pro-
cesses with clarifiers, ( 11) design considerations for secondarily clarifiers, ancl (12) solids
separation for membrane bioreactors. Aerated lagoons, non-aerated lagoons, ancl stabiliza-
lion ponds are not covered in this text, as they are used mainly for small rural communities
where sufficient land is avai\able and discharge requirements may not be as st1ingent as in
urban areas. Detailed design information on aerated lagoons and stabilization ponds may be
found i.n the 4th edition of this textbook (Tchobanoglous et al., 2<X)3). Additional sources
of information may be found in Crites and Tchobanoglous (J 998) and Reed et al. (1995).

8-1 INTRODUCTION TO THE ACTIVATED SLUDGE PROCESS

To provide a basis for the process designs presentecl in the subsequent sect.ions of this
chapter, it will be useful to consider (1) a brief summary of the historical development of
the activat.ed sludge process, (2) a description of the basic process, (3) a brief review of the
evolution of the activated sludge process, and (4) an overview of recent process
developments.
 8-1 lntroduction to the Activated Sludge Process 701

Historical Development ol Activated Sludge Process

Tbe activated sludge process is now used routinely for the biological treatment of
municipal and industrial wastewaters. The antecedents of the activated sludge process
date back to the early l 880s in England, to the work of Dr. Angus Smith, who inves-
tigated the aeration of wastew,1Ler in tanks, which hastened the oxidation of the
organic matter. The aeration of wastewater was stuclied subsequently by a number of
iuvestigators, and in 19 l O Black and Phelps reported lhat a considerable reduction in
putrcscibility could be secured by forcing air into wastewater in basins. In experiments
with aerated wastewater, conducted at the Lawrence Experiment Station during 1912
and 1913, Clark and Gage found that growths of organisms could be cultivated in
bottles and in tanks pa1tially filled with roofing slate spaced about 25 mm (l in.) apart
and that these growths greatly increased Lhe degree of purificalion obtained (Clark and
Adams, 1914). /
The resulLs of the work at the Lawrence Experiment Station, with respect to Lhe treat-
ment of wastewater, were so striking that knowll?dge of rhem led Dr. G. J. Fowler of the
University of Maochester, England to suggest that experiments along sinúlar lines be
conducted at the Manchester Sewage Works where Ardero and Lockett carried out valu-
able research on the subject. During the course of theü· experiments, Ardern and Lockelt
found that the sludge played an important pai1 in the results obtained by aeration, as
,mnounced in their paper of May 3, 1914 (Ardem and Lockett, 1914). The process was
named activatecl sludge by Ardern and Lockell because it involved the production of an
activated mass of microorganjsms capable of aerobic stabilization of organic material in
wastewaler (Metcalf & Eddy, 1935).

Basic Process D~scription

By definition, the basic activated sludge treatment process, as illustrated on Figs. 8- 1(a)
and (b), consists of,the following three basic components: ( 1) a reactor in which thc
microorganisms respousible for treatment are kept in suspension and aerated; (2) liquid-
solids separation unit, usually in a sedimentation tank; and (3) a recycle system for
returning solids removed from the liquid-solids separation unit back to the reactor.
Numerous process configurations have evolved employing these compone11ts. An i_mpor-
taot fealure of the activated sludge process is the forma ti oo of flocculent settleable sol ids
lhat can be removed by gravity settling in sedimentation tanks. In most cases, the acti-
vated sludge process is employed in conjunction with physical and chemical processes
that aJe used for the prelim.ínary and primary treatment of wastewater (discussed in
Chap. 5), and post treatment, incl uding disinfection (Cha p. 12), and possibly filtration
(Chap. l J).
Historically, most activated sludge plants have been used to trcat wastewaters that
have been pretreated by primary sedimeotation, as shown on Figs. 8-l(a) and (b). Primary
sedirnentation is most efficient at removing settleable solids, whereas thc biological pro-
cesses are essential for removiog soluble, colloidal, and particuJate (suspended) orgaiúc
substances; for nitrification and dcnitrification; and for biological phosphorus removal. For
apptications such as treating wastewater from smaller-sized cornmunüíes, primary LTeat-
ment is often not used as more cmphasis is placed on simpler and less operator-iutensive
treatmcnt methods. Primary treatment is ornitted frequently in areas of the world tbat have
hot climates, wbere odor problems from primary tanks and primary sludge can be signifi-
cant. For these applications, various modifications of conventional activated sludge pro-
cesses are used, including sequencing batch reactors, oxidation d.itch systems, and mem-
brane bioreactors.
702 Chapter 8 Suspended Growth Biological Treatment Processes

Primary
clarifier

lnílu~ o _ _ , _ (: -)

T Plan view of aeration tank

Sludge
Return activated sludge

(a) Sludge

Aeraüon tank

lnfluent

Return activated sludge

- Fill - React/ - Settl e - Decant -

aeration
(e) Time sequence

Figure 8-1
Typica l octivated sludge processes w ith di fieren! types of reactors: (a) schematic llow d iagram of p lug-
llow process ond view of plug-ffow reactor, (b) schematic flow diogrom o f complete-m ix process a nd
v iew of complete-m ix activoted sludge reactor, a nd (c) sc hemolic d iagram o f sequencing bolch
reactor process a nd view of sequenci ng batch reactor.

Evolution of the Conventional Activated 5/udge Process

Prior to the 1980s, the pri ncipal objective of actívated sludge process designs was aimed
mainly at achieving a "secondary treatment" standard of 85 percent BOD and TSS
removal. Since then, more emphasis has been placed on meeting more stringent discharge
limits as well as the removal of nutrients (nitrogen and phosphorus). Thus, a number of
activated sludge processes and design configurations have evolved in response to (J) the
need for higher-quality eftluents from wastewater treatment plants; (2) the need to remove
nutrients; (3) increased discoveries and understanding of microbial processes and funda-
mentals; (4) technological advauces in equipment, materials, electronics, and process
control; and (5) the continua) need to reduce capital and operati ng and energy costs for
municipalities and industries. Many activated sludge processes used today and expected to
be used in the foture may incorporate nitrification, biological nitrogen rcmoval, and/or
biological phosphorus removal. Typically, reactors in series, operated under aerobic,
anoxic, and anaerobic conditions are used. T he general types of activated sludge processes
used (i.e., plug flow, complete mix, and sequencing batch reactor), illustrated on Fig. 8- 1,
are considered in the followi ng discussion.
 8-1 lntroduction to the Activated Sludge Process 703

Plug-Flow Process Configurations. Since the process carne into common use in
the early 1920s and up until the late l 970s, the type of activated sludge process used most
commonly was the one in which a plug-tlow reactor with large length to width ratios
(typically > 1O: l) was used Lsee Fig. 8-1 (a)). In considering the evolution of the activated
sludge process, it is important to note lbat the discharge of industrial wastes to domestic
wastewater collection systems increased ÍJl the late 1960s. The use of a plug-flow process
became problematic when industrial wast.es were introduced because of the toxic effects
of sorne of the discharges.

Complete-Mix Process Configurations. The complete-mix reactor was devel-

oped, in part, beca.use the larger volume allowed for greater diJution and thus mitigated the
effects of toxic discharges. The more common type of activated sludge process in the
1970s and early 1980s tended to be single-stage, complete-mix activated sludge (CMAS)
processes [see Fig. 8- l(b)J, as advanced by McKinney ( 1962). For sorne niuification
applications, two-stage systems (ea.ch stage consisting of an aeration tank and clarifier)
were used with the first stage designed for BOD removal, followed by a second stage for
nitrification.

Comparing Plug Flow and Complete Mix Process Configurations. In

cornparing the plug-flow [see Fig. 8- 1(a)] and complete-mix activated sludge (CMAS)
ísee Fig. 8-l(b)] processes, the mixing regimes and tank geometry are quite different. In
the CMAS process, the mixing of the tank contents is sufficient so that ideally the concen-
trations of the mixed-liquor constituents, soluble substances (i.e., COD, BOD, NH4 -N),
and co!Joidal and suspended solids do not vary with location in tbe aeration basin. Tbe
plug-flow process involves relatively long, narrow aeration ba~ins, so that the concenu·ation
of soluble substances and co!Joidal and suspended solids varies along tbe reactor length.
Altbough process configurations employing long, nan-ow tanks are commonly referred to
as plug-flow processes, in reality, b·ue plug tlow does not exist. Depending on tbe type of
aeration system, back mixing of the mixed liquor can occur and, dependi ng on the layout
of the reactor and the system reaction kinetics, nominal plug flow may be described more
appropriately by the series of complete-mix reactors as discussed in Chap. 4.

Sequencing Batch Process Configuration. With the development of simple

inexpensive program logic controllers (PLCs) and the availability of leve! sensors and auto-
rnatically operated valves, the sequencing batch reactor (SBR) process [see Fig. 8- l(c))
became used more widely by the late 1970s, especially for smaller communities and i11dus-
trial installatfons wit.h intermittent 11ows. In recen! years, however, SBRs are being used for
larger cities. TJ1e SBR is a fill -and-draw type of reactor system involving a single complete-
mix reactor in which all steps of lhe activated sludge process occur. Mjxed liquor remains in
the reactor during ali cycles, thereby eLiminating tbe need for separate sedimentation tanks.

Other Activated Sludge Processes. Other activated sludge processes that have
fou nd application, with their dates of major intcrest in parentheses, include the oxidation
ditch ( 1950s), contact stabilization ( 1950s), Krause process ( 1960s), pure oxygen activated
sludge (1970s), Orbal process (J970s), deep shaft aeration (1970s), and sequencing batch
reactor process ( 1980).

Development of Selectors. Activated sludge process designs before and until the
late J970s generally involved the configurations shown on Figs. 8-l(a) and (b). These
designs very often suffered from solicls settli ng problems in the secoudary clarifiers dueto
704 Chopter 8 Suspended Growth Biologicol Treotment Processes

the proliferation of filamentous-type bacteria. Jn the early 1980s researchers and practiciJ1g
engineers advanced the concept of a "biological selector" in activated sludge design, wbich
was first introduced in a patent by Davidson (1957) to select for good settling "floc-
forming" activated sludge over fiJamentous bacteria. Selectors are smaller single or multi-
staged aerated reactors in front of the main activated sludge treatment aeration basin. The
selector concept is also inherent in designs with single or multi-staged anoxic or anaerobic
reactors before the main aeration tank to select for conditions for denitrification of nitrate/
nitrite or for phosphorus-storing bacteria. The anoxic or anaerobic reactors also serve as
selectors resulting in the development of good settling activated sludge. Selectors are con-
sidered in detail in Sec. 8-4.

M embrane Bioreactor Process Configuration. A membrane bioreactor

(MBR) is an activatecl sludge system witb membranes located at the end of the activated
sludge basin(s) for liquid-solids separation in lieu of using secondary clarifiers (see
Fig. 8- 2). In the integrated MBR system shown on Fig. 8-2 the key componen! is the
microfiltration or ultrafiltration membrane that is immersed directly into the activated
sludge reactor. The membraoes are mounted in modules (sometimes called cassettes)
that can be lowered into the bioreactor. The modules are com.prised of the membranes,
support structure for the membranes, feed inlet and outlet connections, and an overall
support struclltre. The membranes are subjected to a vacuum (less than 50 kPa) that

Mixed liquor solids Solids

,--- -'-'='ª::::.ºirc::,u::::l
"-' a:,::lis:,on.,___ _ _~_t_o~waste

Screened
influ ~ Screened
Aerobic influenl
zone Aeration
basin

Solids
towaste
Interna! r~ycle
Membrane Submerged
compartment membrane
(a) (oplional) (b) modules

(e) (d)

Figure 8-2
Membrane bioreoctor (MBR). A multi-stoged octivoted sludge system with membrones far liquid-solids
seporotion: (o) section through MBR wi th seporate comporfment far the membranes, (b) p io n view of
MBR, (e) view of membrana cassettes being placed in seporote compartment, and (d) view o f
seporate membrane comportment.
 8-1 lntroduction to the Activoted Sludge Process 705

draws water (permeate) through the membrane while retaining solids in the reactor. To
minirnize the accumulation of solids and fouling on the exterior of the membranes, com-
pressed air is inrroduced through a disufüution manifold ar the base of the mernbrane
module. As lhe air bubbles rise to the surface, scouring of the membrane surface occurs;
the air also provides oxygen to maintain aerobic cooditions and solids suspension
within the reactor.

lmplementatioo of MBR Proccss. In 1969, U.S. Patent 3,472,765 was issued to

William E. Budd and Robert W. Okey of Dorr-Oliver for a process that integrated com-
plete-mix activated sludge process with rnembrane technology. Membrane separation for
activated sludge treatment was first demonstrated al Pikes Peak, CO, in 1974 by Dorr
Oliver, but it was not economically feasible for widespread use unlil membrane materials
and rnanufacturing methods improved. 1n addition, the initial designs employed cross-
flow mernbrane separation units located outside the activated sludge tanks, whicb had
high energy requirements for pumping mixed liquor across the membrane to control foul-
ing. Placement of the membrane separation unit in the activated sludge reactor and using
co~u·se bubble aeration, in the late 1980s, was less eoergy intensive and led to future MBR
applications (Yamamoto et al., 1989). The lower energy MBR systcm was first commer-
cialized with flat plate membranes by Kubota for wastewater treatment in Japan in l 990.
About three years later an MBR system using Zenon's hollow fibcr ZceWccd® system
was installed at Stoney Creek, Ontario Canada. The first MBR installation for biological
wastewater treatment in the U.S. was in 1998 at lhe Arapohoe County Lonc Tree Creek
WWTP in Colorado. The use of ultrafiltration (UF) and microfiltration (MF) membranes
in MBR systems for activated sludge treatment was well accepted in the late 1990s and
carly 2000s.

MBR Proccss Advantages and Disadvantages. The use of membrane liquid-solids

separation provides many advantages compared to activated sludge processes with gravity
clarifiers. Tbese are (l) a much smaller area requirement (less than 50%) dueto operation
with a higher mixed liquor concentration (typically 8000 to 12,000) and the reduced space
for membrane separation compared to clarifiers, (2) simpler process operation with no
concerns about the effect of filamentous activated sludge, (3) a redaimed water quality
eft1uent due to complete suspended solids capture across the membrane separation, and
(4) a lower disinfection dose requirement dueto the low turbidity effluent. Disadvantages
are an increased energy cost, the need for future mernbrane replacement, and the cleaning
and operational demands for membrane fouling control.

MBR Process Applications. The mosl frequent applications for MBRs have been for
domeslic wastewater treatme11t and water reuse, ranging in flows from smaU housing
developments and apartments to large centralized wastewater treatment facilities. The Iarg-
est facility, as of 2008, is the King County, Washington Brightwater wastewater treatment
plant, at an average design flowrate of 117,000 rn 3/d (Judd, 2008a). MBR designs have
also been used for industrial wastewater treatment applications, including food and
beverage processing, chenúcal plants, automotive plants, dairy wastewater, oíl refinery
wastewater, landfill leacbate and pharmaceuticals, and also in anaerobic treatment
processes (Yang el al., 2006).
Process applications of MBRs are described along with similar applications using
activated sludge and clarifiers for nitrification, nitrogen removal and enhanced biological
phosphorus removal in Secs. 8-7 and 8-8. Design considerations assocíated with the use
of gravity clarifiers or membranes for activated sludge liquid-solids separation are
706 Chapter 8 Suspended Growth Bialogical Treatmenf Processes

discussed in Secs. 8- 10, 8-11, and 8-1 2. Membrane systems used in advanced wastewater
applications including membrane materials, membrane designs, and operating conditions
are discussed in Sec. 11-6 in Chap. 11.

Nutrient Removal Processes

Over the past JO years, achieving higher nutrient (nitrogen and phosphorus) removals has
gained importance in lhe implementation of the activated sludge treatment process. As a
result, a number of biologica\ nutrient-removal configurations have been developed
including those using aclivated sludge with secondary claritiers or membranes for Jiquid-
solids separation. Nem-Ly all of the various activated sludge process modifications, wbether
witb secondary clarifiers or membranes, are based on the same fundamental principies of
biological treatment as described previously in Chap. 7. Processes used in fu ll-scale
operalion are clescribed in Secs. 8-6, 8-7, and 8- 8; design examples for the processes most
commonJy used are also included.
A key element in the new nutrient removal designs is the use of interna! recycle
from the aeration or anoxic tanks to upstream reactors (see Fig. 8-3), in contrast to
recycle in the past being only from che secondary clarifier underflow to the head of the
aclivated sludge aeraLion tank as shown on Figs. 8- l(a) and (b) . The process efliciency
benefits of using reactors in series as well as staged reactors has also been recognizecl
and implemented in ful l-scale designs. However, because the design and operation of
activated sludge nut1ient removal processes has become more complex, computer mod-
eling is an increasingly in1portanr too! to incorporate Lhe large number of components
ancl reactions necessary to evaluate aclivated sludge performance in nuu"ient removal
application. The use of sirnu lation modeJs for suspended growth systems is discussed in
Sec. 8-S .

Interna! recycle
Anaerobic

lnfluent
Aerobic

Return activated sludge

Sludge

(a) (b)

Figure 8-3
Modified Borden pha process with slage reoclo rs for biologico l nitrogen removal a nd enhonced
biologicol p hosphorus removol: (o) schemalic diagram o f slaged process and (b) view o f a Modified
Bardenp ho lreatmenl plan! in Pa lmetto, FL; the firsl o f ifs type in the United Stafes built in 1979.
[From H. D. Stensel.) (Coordinates 27.5256 N 82.5959 W, view a l oltitude 360 m, since then,
an oxidotion d itch has been built alo ng side.)
 8-6 Processes fer 8od Removal and Nitrification 793

1 Table 8-19
Typical design parameters for commonly used activated sludge processes
Volumetric looding
F/M,
Type of kg BOD/ lb BOD/ kg BOD/ MLSS,
Process name reactor SRT, d kg MLVSS·d 1000 ft3·d m 3 ·d mg/L Total T, h

High-rate aeration CMAS or 0.5-2 1.5-2.0 75-150 1.2-2.4 500-1 500 1-2
(first step in AB Process) plug Aow
Contad stabilization CMAS or 5-10 0.2-0.6 60-75 1.0-1.3 1000-3000° 0.5... 1°
plug flow 6000-1 O,OOOb 2,_4b

High-purity oxygen Staged 1-4 0.5-1.0 80-200 1.3-3.2 2000-4000 1-3

Conventionol plug Aow Plug Row 3-15 0.2-0.4 20-40 0.3-0.7 1000-3000 4.8
Step feed Plug Row 3- 15 0.2-0.4 40-60 0.7-1 .0 1500-4000 3- 5
or staged
Complete mix CMAS 3-15 0.2-0.6 20-100 0.3-1.6 1500- 4000 3-6
Extended aeration CMAS or 20-40 0.04-0.l 5-15 0.1-0.3 2000-4000 20-30
plug Aow
Oxidation ditch CMAS+ 15- 30 0.04-0.l 5-15 0.1-0.3 3000-5000 15-30
plug flow
Batch decont Plug flow 12-30 0.04-0.1 5-15 0.1-0.3 2000-5000 20- 40
(ICEAS, CMS)
Sequencing batch Batch 15-30 0.04-0.1 5-1 5 0.1-0.3 2000-5000 15~40
reactor
Counter current aerotion Plvg Row 15-30 0.04-0.1 5- 10 0.1-0.3 2000-4000 15-40
system (CCAS™)

ª MLSS and detention time in contact bosin.

b MLSS ond detention time in stobilizotion basin.

may be completely mixed, staged, or plug flow. The oxidation ditch is a combj.nation
of complete mix and plug flow. The recirculation flowrate in the ditch provides a
flowrate that is typically 20-30 times the intluent flowrate so the dilution factor
approaches a complete mix substrate condition. In additíon, plug flow kinetics condi -
tions are approached as thc flow moves down the ditch channels away from the mixed
acration zone.

Process Selection Considerations. Selection of an activated sludge process for

BOD removal and 1útrífication is a function of many considerations including spec\fi.C site
constraints, compatibility with the ex.isting process, compatibility witb existing equipment,
present and futurc treatmenl needs, level of capability of the operating staff, capital costs,
and operating costs. Significant features and limitations of the various activated ,sludge
process alternativcs that affect process selection in certain applications are summartized in
Table 8-20.