01.11.20-Pta 10

Sec: Sr.
IIT_CO-SC Date: 01-11-20

Time: 3HRS Max. Marks:186
Name of the Student: ___________________ H.T. NO:
01-11-20_ SR.CO-SUPER CHAINA_Jee-Adv_PTA-10_SYLLABUS

PHYSICS: Complete Waves : Wave motion (plane waves only), longitudinal and
transverse waves, superposition of waves; Progressive and stationary
waves; Vibration of strings and air columns; Resonance; Beats; Speed of
sound in gases; Doppler effect (in sound).
CHEMISTRY: CHEMCIAL KINETICS AND NUCLEAR CHEMISTRY

REDOX REACTIONS AND TITRATIONS
Chemical kinetics: Rates of chemical reactions; Order of reactions;
Rate constant;First order reactions; Temperature dependence of rate
constant (Arrhenius equation).
Nuclear chemistry: Radioactivity: isotopes and isobars; Properties of α
,β andγ rays; Kinetics of radioactive decay (decay series excluded),
carbon dating;
REDOX REACTIONS AND TITRATIONS: Blancing reactions acid base
titrations redox Titration
MATHEMATICS: Vectors -3D : Direction Cosines And Direction Ratios, Equation Of A

Straight Line In Space, Equation Of A Plane, Distance Of A Point From A
Plane.
EXCLUDING: Angle between lines ,line and plane, two planes.
Narayana IIT Academy 01-11-20_Sr.IIT_CO-SC _JEE-Adv_PTA-10_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 5 – 12) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Total 18 62
CHEMISTRY
Sec – II (Q.N : 23 – 30) +4 -1 8 32
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62
MATHEMATICS
Sec – II (Q.N : 41 – 48) +4 -1 8 32
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62
SR.IIT_CO-SC Page. No. 2
Education consists mainly of what we have unlearned.

PHYSICS Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. A long taut string is connected to a harmonic oscillator of frequency ‘f’ at one end.
The oscillator oscillates with an amplitude ' a0 ' and delivers power ' p0 ' to the string.
Due to dissipation of energy the amplitude of wave goes on decreasing with distance 'x'
from the oscillator given as a  a0e  kx where k is constant. Upto what distance from the
oscillator, the power dissipated is equal to 3/4 th of power supplied by the source?
ln2 ln2 l n3 l n3
A) B) C) D)
2k k 2k k
2. A sufficiently long closed organ pipe has a small hole at its bottom. Initially the pipe
is empty. Water is poured into the pipe at a constant rate. The fundamental
frequency of the air column in the pipe
A) continuously increasing
B) first increases and then becomes constant
C) continuously decreases
D) first decreases and then become constant
3. A plane progressive transverse wave is passing through medium along the positive
x-axis at the given instant of time. The nature of the displacement – position (y vs x)
graph of particles of medium at that instant is as shown in figure. Which of the
following statements are correct . (A,B,C are three particles of the vibrating string)

(1) Elastic potential energy per unit length of the string at the point B is more than that
at points A and C
(2) Elastic potential energy per unit length of the string at the point C is more than that
at points A and B
(3) velocity of the particle at A is along negative y-axis.
(4) Velocity of the particle at C is along positive y-axis.
A) Only 2,3,4 are correct B) Only 1,3,4 are correct
C) Only 1,3 are correct D) Only 1,4 are correct
4. A source of sound with natural frequency f 0 moves uniformly along a straight line
separated from a stationary observer by a distance ' l ' (  ar distance). The velocity of
source is equal to    1 times of velocity of sound. Find the frequency of sound
received by the observer at the moment when the source gets closest to him?
f0 f0 f0
A) f 0 B) C) D)
1  2 1 2 1 
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
out of which ONE OR MORE is/ are correct.
5. A clamped string is oscillating in nth harmonic, then which of the following
statements is/are correct:
A) total energy of oscillation will be proportional to n2 times the fundamental
frequency
B) total energy of oscillation will be proportional to  n  1 times that of

2
fundamental frequency
C) average kinetic energy of the string over a complete oscillation is half of that of
the total energy of the string
D) average kinetic energy of the string over a complete oscillation is equal to one
fourth of the total energy of the string

6. A box of mass 14m with smooth base is sliding on an inclined plane of inclination 
under the influence of a force F. A string of mass m length l is attached at A. The box
is released from rest and a transverse pulse is produced at other end ‘B’. Mark the
correct statement(s) for the pulse.
A) If F  0 the pulse will remains stationary

B) If F  0 the pulse will not reach to end A
5l
C) F  9 mg the time taken by the pulse in moving from B to A will be 2
3g
5l
D) If F  18 mg the time taken by the pulse in moving from B to A will be 2
3g
7. A transverse harmonic wave is propagating along a taut string. Tension in the
string is 50 N and its linear mass density is 0.02 kg/m. The string is driven by a 80
Hz oscillator tied to one end, oscillating with amplitude of 1 mm. The other end of
string is terminated so that all the wave energy is absorbed and there is no
reflection. From this given data, choose the correct option(s)
A) Power of the oscillator is 0.126 w
B) If tension in the string is quadrupled and power of oscillator remains same. Then
1
new amplitude of oscillation of string is mm
2
C) Average energy of the wave on a l m long segment of the string is 2.5 mJ
D) Power of the oscillator is 0.252 w
8. There are two horns H1 and H 2 in a car. When they are sounded together, the driver
records 35 beats in 10 sec with horn H 2 blowing alone and car moving towards a
wall, at a speed of 5 m/sec, the driver noticed a beat frequency of 5 Hz with the
echo. When frequency of H1 is decreased, the beat frequency when two horns
sounded together increases (speed of sound is 332 m/sec). Choose the correct option
(s) from below.

A) frequency of one of horns is 160 Hz
B) frequency of one of horns is 156. 5 Hz
C) frequency of one of horns is 163.5 Hz
D) frequency of one of horns is 153 Hz
9. A person riding on a source ‘S’ of sound (frequency 48Hz) moves in a medium (in
which velocity of sound is 310 m/s) with speed 10 m/s as shown towards a liquid
reservoir (in which velocity of sound is 1240 m/s). A detector ‘D’ in the reservoir moves
towards the free surface of the reservoir (along line SD) at a speed 20m/s. The sound
produced by ‘S’ gets reflected and transmitted at the free surface. Mark the
INCORRECT statement(s) among the following, assuming the liquid in the reservoir
stays still and calm.
A) Wavelength of sound received by detector D is 25m

B) Beat frequency registered by the person is 1.6Hz
C) Frequency of sound detected by detector D is 56Hz
D) A compression pulse incident on the free surface due to ‘S’ is reflected as a
rarefaction pulse
10. Mark the correct statement(s)
A) When a sound wave strikes a wall, the compression pulse is reflected as compression
pulse
B) When a sound wave strikes a wall, the compression pulse is reflected as rarefraction
pulse
C) When a sound wave is coming out after passing through a narrow pipe, then
reflection would be there at open end.
D) When a sound wave is coming out after passing through a narrow pipe, then
compression pulse reflected as rare fraction pulse.

11. Two strings of same material are joined to form a large string and is stretched between
rigid supports. The diameter of the second string is twice that of the first. It is observed
that the whole string was oscillating in 4 loops with a node at the joint. The possible
lengths of the second string if the length of first string is 90cm are
A) 15cm B) 45cm C) 84cm D) 135cm
12. A hypothetical pulse is travelling along positive x direction on a taut string. The speed
of the pulse is 10cm / sec . The shape of the pulse at t  0 is given as
x
y  1 for  6  x  0
6
  x  1 for 0  x  1
 0 for all other values of x
 x, y are in cm
Choose correct options from following
5
A) The vertical displacement of the particle at x  1cm at t  0.2sec is cm
6
3
B) The vertical displacement of the particle at x  1cm at t  0.2sec is cm
5
C) The magnitude of transverse velocity of the particle at x  1cm at t  0.2sec is
4
cm / sec
3
D) The magnitude of transverse velocity of the particle at x  1cm at t  0.2sec is
5
cm / sec
3
SECTION – III
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
13. A glass tube of 1.0 m length is filled with water. The water is drained out very slowly
from the tube through a hole in the bottom while a vibrating 500 Hz tuning fork is held
near the open upper end of the tube. If the speed of sound is 320 ms 1 find the number of
resonances that can be obtained.

14. A parachutist jumps from the top of a very high tower with a siren of frequency 800 Hz
on his back. Assume his initial velocity to be zero. After falling freely for 12s, he
observes that the frequency of sound heard by him reflected from level ground below
him is differing by 700 Hz w.r.t the original frequency. The height of tower is given by
1000  10 x  7.5  m then find the value of x ?. Velocity of sound in air is 330 m/s, and
g  10m / s 2 .
15. An aluminium wire of length 0.6 m and cross - sectional area 106 m2 is connected to a
steel wire of same cross - sectional area and having length 0.8 m. The compound wire
is loaded with 10kg weight. number of nodes (excluding the two at the ends of wire) in
oscillation of wire with lowest frequency for which the joint of the wires as node is 5x
(density of aluminium 1300 kg / m3 and that of steel 5200 kg / m3 )
16. Two sound waves y1  A sin  200 t  m and y2  A sin  204 t  m are interfering at a
point where stationary detector is placed which can detect waves of amplitude greater
than or equal to A. In a time interval of 12 seconds, Find the total duration (in sec) in
which detector is active?
17. Sound level /loudness at any point in a room is increased from 50 dB to 60 dB by

increasing the pressure amplitude, if final pressure amplitude is K times that of initial.
K2
Find the value of .
5
18. A siren is placed at a railway platform is emitting a sound of frequency 5KHz. A

passenger sitting in a moving train A records a frequency of 5.5KHz, while the train
approaches the siren. During his journey in a different train B he records a frequency of
6KHz while approaches the same siren. The ratio of velocity of train B to that of train A
is ( take velocity of sound in air is 330m/sec).

CHEMISTRY Max.Marks:62
SECTION – I
0
19. For a gaseous reaction, 2A+B2   2AB, the following rate data was obtained at 300 C.
Rate of disappearance of B2. (Mole litre-1min-1) Conc. [A] (mole/litre) [B2]
1.810-3 0.015 0.15
1.0810-2 0.09 0.15
5.410-3 0.015 0.45
Calculate the rate of formation of AB when A is [0.02] and [B2] is [0.04] mole litre-1 at
3000K?
A) 1.2810-3 M min-1 B) 2.5610-3 M min-1

C) 6.410-4 M min-1 D) 1.2810-2 M min-1
20. The radioactive decay 83 Bi 211  81TI 207 , takes place in 100 L closed vessel at
270 C starting with 2 moles of 83 Bi 211 (t1/2  130sec) , the additional pressure developed in
the vessel after 520 sec will be
A) 1.875 atm B) 0.2155 atm C) 0.4618 atm D) 4.618 atm
21. The amount of 6 C 14 isotope in a piece of wood is found to one fourth (1/4) of that present
in a fresh piece of wood. Calculate the age of the piece of wood
(t12 of 6 C14  5770 years )
A) 7999 year B) 11540 year C) 16320 year D) 23080 year
22. 0.5 g mixture of K 2Cr2O7 and KMnO4 was treated with excess if KI in acidic medium.
Iodine liberated required 150cm3 of 0.10 N solution of Sodium thiosulphate solution for
titration. Find the percentage of K 2Cr2O7 in the mixture.
A) 14.64 B) 34.2 C) 65.69 D) 50

SECTION – II
23. A reaction takes place in three steps. The rate constant of the three steps are K1 , K 2 , K 3
K1 K 3
respectively. The overall constant K  .
K2
The energy of activation for the three steps are 40,30 & 20 KJ respectively. Therefore
A) Overall energy of activation is 10 KJ
B) Overall energy of activation is 30 KJ

K1
C) The reaction mechanism is 2 A    

 A  A; A 
K3

 Pr oducts & overall order is
K 2 RDS
one.
D) The reaction mechanism is A 

K1
 B; B 
K2
 C; C 
K2
 Pr oduct & overall order
is one.
24. The half-life of 99Tc is 6.0 hrs. The total residual activity in a patient after receiving an
injection containing 99Tc must not be more than 0.01Ci , after 36.0 hours. What is the
maximum activity (in  Ci ) that the sample injected can have?
A) 0.06 B) 0.16 C) 0.32 D) 0.64
25. Identify the correct statements

A) 1 mole of MnO4 ions can oxidize 5 moles of Fe2 ions in acidic medium
B) 1 mole of Cr2O72 ions can oxidize 6 moles of Fe2 ions in acidic medium
C) 1 mole of Cu2 S can be oxidized (to CuSO4 ) by 2 moles of MnO4 ions in acidic
medium
D) 1 mole of Cu2 S can be oxidized (to CuSO4 ) 1.66 moles of Cr2O72 ions in acidic
medium

26. Consider the first order decomposition reaction, A4(g) → 4A (g). Which of the following
statements regarding the reaction are correct?
A) At 30 min., only 20% reaction is complete

B) t1/2 of reaction is approximately 90 min.
C) Rate of reaction decreases linearly with time
D) The time for intersection of two curves is independent of initial concentration
of A4.
27. For the two reactions I : A  B; II : C  D following graph is obtained:
Which of the following statement is/are false?
A) If [ B]  [ A] then at time [ D]  0.75M

B) If [C ]  [ A] then at that time [ B]  [ D]
C) (t100% ) Re action1  (t100% ) Re action 2
3
D) [ A]  [C ] at t  min
2
28. Select the correct statement(s):
A) On bombarding 7 N 14 nuclei with  -particle, the nuclei of the product formed after
release of proton would be 8 O17
B) Decay constant does not depend upon temperature

C) Nuclide and it’s decay product after  -emission are called isodiaphers
D) Half-life of radium is 1580 years. It’s average life will be 1097.22 years.
29. Dichromate ion in acidic medium oxidizes stannous ion as:
xSn 2  yCr2O72  zH   aSn 4  bCr 3  cH 2O
A) The value of x : y is 1: 3
B) The value of x  y  z is 18
C) a : b is 3: 2
D) The value of z  c is 7
30. The decomposition of N2O5 according to the equation 2N2O5(g)   4NO2(g)+O2(g), is
a first order reaction. After 30 minutes from the start of the decomposition in a closed
vessel, the total pressure developed is found to be 425mm of Hg and on complete
decomposition the total pressure is 500mm Hg.
A) The rate constant of the reaction is 4.62x10-2min-1
B) The partial pressure of N2O5 at 45th minute is 25mm
C) The half life of the reaction is 30minutes
D) The total pressure of gases at 15th minute is 350mm
SECTION – III
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
31. A mixture of compounds A and B undergo first order decomposition. Then half-lives
are 54.0 min and 18.0 min respectively. If both the concentrations of A and B are equal
initially, the time taken for the concentration of A to be four times that of B is
32. In the reaction of formation of Sulphur trioxide by contact process 2SO2  O2  2SO3 , the
rate of disappearance of oxygen was measured as 8 g / sec . The rate of disappearance of
SO2 in g/sec will be

33. The time required for 13.5% completion of first order reaction at 300K is equal that
required for its 25% completion at 310K. If pre exponential factor for the reaction is
5  107 sec1 . The energy of activation for the reaction is (in KJ/mole)
25
[Given: log 1.156=0.06, log 2=0.3, log 3=0.48, ln10=2.3, R  J / mol  K ]
3
34. 100ml of a saturated solution of M 2 SO4 is giving 24 disintegrations per hour due to
radioactive Metal ‘M’.    2  1017 hour 1; N 0  6  1023  . If the Solubility product of
the salt is  x  103 y  . The value of  x  y  is _____
35. An impure sample of sodium oxalate ( Na2C2O4 ) weighing 0.20 g is dissolved in aqueous
solution of H 2 SO4 and sodium is titrated at 700 C , requiring 45 mL of 0.02 M

KMnO4 solution. The end point is over run, and back titration in carried out with 10 mL
of 0.1 M oxalic acid solution. Find the % purity of Na2C2O4 in sample.
36. 2 litres of an acidified solution of KMnO4 , containing 1.58 g of KMnO4 per litre, is
decolourised by passing sufficient amount of SO2 gas. If whole of the of the sulphur
from ‘x’ g of FeS2 is converted into SO2 to be used in above reaction, calculate the value
of x: [Atomic weight Mn  55, K  39, Fe  56, S  32 ]

MATHEMATICS Max.Marks:62
SECTION – I
x  2 y  6 z  34
37. The point on the line   which is nearest to the line
2 3 10
x6 y7 z 7
  is  a, b, c  then the value of a  b  c 
4 3 2
A) 9 B) 10 C) 11 D) 12
38. The locus of a point which is equidistant from the lines y  x, z  1 and y   x, z  1 is
A) xy  z B) xy  2 z C) xy   z D) xy  2 z
y z
39. If lines x  y  z and x   and third line passing through (1,1,1) form a triangle of
2 3
area 6 units, then point of intersection of third line with second line will be
A) 1,2,3 B)  2, 4,6 C)  , ,  D)  2,1,3

4 8 12
3 3 3 
40. Minimum distance of (1,1,1) from the plane x  y  z  1 measured perpendicular to line
x  x1 y  y1 z  z1
  is
1 2 3
28 18 7 3
A) B) C) D)
3 3 3 28
SECTION – II
41. In R3 space consider the planes P1 : y  0 and P2 : x  z  1 . Let P3 be a plane different from
P1 and P2 which passes through the intersection of P1 and P2 . If the distance of the point
0,1,0 from P3 is 1 and the distance of a point  ,  ,   from P3 is 2 , then which of the
following relation (s) is / are true ?
A) 2    2  2  0 B) 2    2  4  0
C) 2    2  10  0 D) 2    2  8  0

x 1 y 1 z  3
42. Projection of the line   on the plane x  2 y  z  6 has the possible
2 1 4
equation is
A) x  2 y  z  6  0  9 x  2 y  5 z  8 B) x  2 y  z  6  0  9 x  2 y  5 z  8
x 1 y  3 z  1 x3 y2 z 7
C)   D)  
4 7 10 4 4 10
x  2 y z 1
43. A ray of light eminating from P 1, 3, 2 and traveling parallel to the line  
1 3 2
is incident on the plane x  y  3z  0 at the point Q . After reflection from the plane the ray
travels along the line QR. It is also given that incident ray, reflected ray, normal to the
plane of incidence are in the same plane then
A) Q   3, 15, 6
x  12 y  22 z  4
B) Equation of line QR is  
15 37 10
C) Equation of plane PQR is 11x  5 y  2 z  30
x  3 y  15 z  6
D) Equation of the normal to the plane x  y  3z  0 is  
1 1 3
44. If the 3-planes P1  2 x  y  z  1  0 , P2  x  y  z  2  0 , P3   x  y  3 z  5  0 intersect each
other at point P on XOY plane and at point Q on YOZ-plane. Where O is origin then
A)   4
x 1 y 1 z
B) Equation of line perpendicular to P3 and passing through P is  
4 1 3
C) Projection of PQ on X-axis is 1
1 1 1
D) Centroid of triangle OPQ is  , , 
3 2 2
45. A 1,1,1 , B 1,0,0 ,C 3,0,0 are 3-vertices of a tetrahedron whose 4th vertex is D. The
perpendicular drawn from D on to opposite face ABC meets the median line through A
2 2
of triangle ABC at E. If AD=4 and volume of tetrahedron is then
3

A) The length of attitude from D to opposite face ABC is 2
B) Only one E exist i.e., E  1,3,3
C) There exist two positions for E   1,3,3 and  3, 1, 1

 
D) j  k is normal to the plane of A, B, C
y z
46. A plane  contains the line L1 :   1, x  0 and is parallel to the line
b c
x z
L2 :   1, y  0 then
a c
x y z
A) Equation of plane  is   1  0
a b c
x y z
B) Equation of plane  is   1  0
a b c
1 1 1 1
C) If the shortest distance between line L1 and line L2 is , then 2  2  2 is 64
4 a b c
1 1 1 1
D) If the shortest distance between line L1 and line L2 is , then 2  2  2 is 192
4 a b c
47. Plane  meets the co-ordinate axes (X,Y & Z axes respectively) at A,B & C. If areas of
OAB , OBC & OCA are 3,6 & 4 units respectively. Now which of the following are
correct?
A) Area of ABC  61 square units
B) Equation of plane  may be 6 x  4 y  3 z  12
C) Equation of plane  may be 6 x  4 y  3 z  12
D) Volume of tetrahedron OABC is 2 unit

x  3 y 1 z  a x2 y4 z 5
48. If lines   and   are perpendicular coplanar lines, then
2 3 p 2 4 2
2 4 30
A) p =4 B) p =  C) a= D) a = 
7 7 7

SECTION – III
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
49. Let the equation of the plane containing the line x  y  z  4  0  x  y  2 z  4 and is
parallel to the line of intersection of the planes 2 x  3 y  z  1 and x  3 y  2 z  2 be
x  Ay  Bz  C  0 . Compute the value of A  B  C .
50. A plane P intersects 4 lines L1 , L2 , L3 and L4 (given below) at A,B,C,D
x 3 y 3 z 3 x3 y 3 z x y 3 z x y 3 z 3
L1 :   , L2 :   , L3 :   , L4 :   ,
2 1 2 2 1 2 2 1 2 2 1 2
then the minimum area of quadrilateral ABCD is
x y z
51. The plane    1intersect x-axis, y-axis, z-axis at A,B,C respectively. If the
1 2 3
distance between origin and orthocenter of ABC is equal to k the the value of 7k is
equal to ___
52. The plane x  2 y  3 z  7 is rotated about the line where it cut yz-plane by an angle .
p
In the new position the plane contains the point (  1, 0, 2) . If cos  (where p and q
q
are coprime) then the absolute value of (p-q) is
53. Given a tetrahedron ABCD with AB = 12, CD =6. If the shortest distance between the

skew lines AB and CD is 8 and the angle between them is , then find the volume of
6
tetrahedron.
54. The angle between the lines whose direction cosines are given by
3l  4m  5n  0, l 2  m2  n 2  0 is

Sec: INC.SR.IIT_CO-SC PTA-10 Date: 01-11-20
Time: 3HRS 2019_P1 Max. Marks: 186
KEY SHEET
PHYSICS
1 B 2 B 3 A 4 B 5 AC
6 BC 7 ABC 8 AC 9 BCD 10 ACD
11 ABD 12 AD 13 3 14 5 15 2
16 8 17 2 18 2
CHEMISTRY
19 A 20 C 21 B 22 A 23 BC
24 D 25 ABCD 26 ABD 27 BCD 28 ABC
53.40
29 BCD 30 ABD 31 54.00 32 32.00 33 to
53.48
34 9.00 35 83.75 36 1.50
MATHEMATICS
37 C 38 D 39 B 40 A 41 BD
42 AC 43 ABCD 44 ABCD 45 ACD 46 AC
47 ABC 48 AD 49 11 50 3 51 6
52 1 53 48 54 0
Narayana IIT Academy 01-11-20_ Sr.IIT_CO-SC _JEE-Adv_PTA-10_KEY&SOL
SOLUTIONS
PHYSICS
p0 1 ln2
1. P p  a 2 , a 2 kx  ,2kx  l n 4, x 
4 4 k
2. Water level in the pipe initially increases and then become constant. So frequency first increases and
then become constant.
dk dU
3.  ( at all points)
dx dx
 dy 
V p   V   
 dx 
 v0 
4. f 1  f0  
 v0   v0 cos 
 v0 
f  f0 
1

 v0 1   2  
 
f0 x x2  l 2
f 
1
, 
1   2  v0 v0
x

x2  l 2
T
7. Wave speed  v   2500  50m / sec

Power   a v  2 f a v  2  3.14   80  1 10   50  0.02   0.126w

1 2 2 2 2 2 2 2 3 2
2
P  a  v, a12v1  a22v2  a12v1  a22  2v 
2
a
a2  1
2
1 1
Eavg  Pavg  t  Pavg    0.126   2.5mJ
  50
8. f1  f 2  3.5
f 2  f1  3.5
 332  5   337 
f  f2    f2  
 332  5   327 
 337   10  327
f2    f2  5  f2    5  f2   163.5 Hz
 327   327  2
f1  160 Hz
11. 1) String-1  one loop; string-2  3 slops
2) String-1  2 loops; string-2  2 sloops
SR.IIT_CO-SC Page 2

3) String-1  3 loops; strinf-2  one sloops  y  atx  0.5m   2.57  10 sin t   
6
Where   2 f  62400 s
1
 y  2.57  10 6 sin  62400t   
12. y  f  x  vt 
C
13. Lmin   16cm
4f
So, resonance for length 16 cm, 48 cm, 80 cm i.e., 3 cases.
14. Let the sound observed by the parachutist at t0  12 s be produced at t1 sec . Velocity of source at
the instant of emitting sound  gt1 . Hence the relation between apparent frequency f and f will
'
 v  gt0 
be f '  f  
 v  gt1 
Here f  800 Hz , g  10m / s , v  330m / s
2
T0  12 s and f  800  700  1500 Hz

Putting these, we get
T1  9 s
 1 2  1 
Now the distance travelled by sound in  t0  t1  sec is v  t0  t1    h  gt0    h  gt 2 
 2   2 
Putting the values, we get H  1057.5m
n1 T n T
15. f   2
2l1 1 2l2 2
n1 l1 1 n1 0.6 1300
  
n2 l2 2 n2 0.8 5200
n1 0.6 1 3
  
n2 0.8 2 8
In fundamental mode there will be 10 nodes excluding ends.
16. y1  A sin  2 f1t 
y2  A sin  2 f 2t 
 2  f1  f 2    f f 
y  y1  y2  2 A sin  t  cos  1 2 t 
 2   2 
A  t   2 A cos   f1  f 2  t  , A  t   2 A cos  2 t 
1
2 A cos  2 t   A  cos  2 t  
2
 2 4 5
2 t  , , , ,.......
3 3 3 3
2
On one sec, total sec duration detector detests.
3
SR.IIT_CO-SC Page 3

 I 
17. dB  10log10   and I  Pm2
 I0 
 5.5 
 1
 v   f '  v A  5 1
18. f '  f 1  0   v0  v   1  
 v  f  vB 6  2
  1
5 
CHEMISTRY
d[B2 ] 1.8
19. Rate law for the reaction,  =K[A][B2] K 
dt 1.5 1.5
1 d[A] d[B2 ] 1 d[AB]
    K[A][B2 ]
2 dt dt 2 dt
20. 83 Bi 211  81Ti 207  2 He 4 ; total time  n  half  life
initial moles 2
Moles of substance left after ‘n’ halves   4  0.125
2n 2
Moles of He produced  2  0.125  1.875
1.875  0.0821  300
Pressure developed due to He   0.4618 atm
100
2.303 4
21. Age of wood   5770  log   years
0.693 1
22. Reactions of K 2Cr2O7 and KMnO4 with KI may be given as:
K 2Cr2O7  7 H 2 SO4  6 KI  4 K 2 SO4  Cr2 ( SO4 )3  7 H 2O  3I 2
2 KMnO4  8 H 2 SO4  10 KI  6 K 2 SO4  2 MnSO4  5 I 2
294
Thus, equivalent weight of K 2Cr2O7   49
6
158
equivalent weight of KMnO4   31.6
5
 m-eq. of K 2Cr2O7 +m-eq. of KMnO4 =m-eq. of I 2 =m-eq. of hypo.
Let the mass of K 2Cr2O7  x g ;
mass of KMnO4  (0.5  x) g
x (0.5  x)
  150  0.1  103 or x  0.0732
49 31.6
0.0732
 % of K 2Cr2O7   100  14.64%
0.5
SR.IIT_CO-SC Page 4

K1K 3
23. K
K2
Ea  E1  E3  E2
 40  20  30  30 KJ / mol

K1
2 A  
 A  A( fast )
*
K 2
K1 [ A* ][ A] K
 2
 [ A* ]  1 [ A]
K2 [ A] K2
 A  
K3
RDS
 products ( slow)
Rate  K 3[ A* ]
 K 
Rate   K 3 . 1 [ A]
 K2 
First order reaction
A0 A
24. Activity after ‘n’ half lives  n
so, 0.01  60 ; Hence A0  0.64  Ci .
2 2
25. Conceptual
A4  4A
26. t 0 aM 0
t  30min (a  x) M 4 xM
x
Percentage reaction at (t  30min)   100  20%
a
2.303 a
30   t1/2 log  t1/2  90min
0.693 (4 / 5)a
a 0.5 3
27. A) If [ B ]  [ A], thent  t1/2   
2k 2  1 4
3
3
At t  to find [ D ]
4
3 3
x  [ D]  3    0.75M
4 4
B) If [C ]  [ A], then at that time [ B ]  [ D]
a 0.5 3
C) I : t100%   
k 1/ 3 2
1
II : t100% 
3
SR.IIT_CO-SC Page 5

D) [ A]t  [ A]0  kt
1
[ A]t  0.5  t
3
[C ]t  1  3t
3
If [C ]t  [ A]t then t  min
4
28. Conceptual
29. 3Sn 2  Cr2O72  14 H   3Sn 4  2Cr 3  7 H 2O
2.303 3P
30. K log
t 5(P  Pt )
1 1
31. nA  nA
; nB  nB
2 2
n A  4  nB
nA 2nB
 4  nA  2[ nB nA ] => 22  2[ nB nA ] => nB  nA  2
nB 2
t t
 2
18 54
3t  t
 2  t  54min
54
32. 2SO2  O2  2SO3
1 d  SO2  d O2  1 d  SO3 
Rate    
2 dt dt 2 dt
33. t298 K  t308 K
2.303 100 2.303 100 K 308
log  log => 2
K 298 86.5 K 308 75 K 298
K 308 Ea  1 1 
log   => Ea  53.475kJ / mole
K 298 2.3  25  300 310 
3
34. Activity    N
24
N 17
 12  1017
2  10
12  1017
No. of moles of ‘M’   2  106 moles.
6  10 23
2  106
 Molarity of M 2 SO4  solubility  1  1  105 M.
10  2
SR.IIT_CO-SC Page 6

 Ksp  4s3  4  10 

5 3  35
 4  1015  4  10 .
x  y  4  5  9.
35. m-eq. of Na2C2O4  m-eq. of KMnO4 reacted
[Total m-eq. of KMnO4 ]  [excess m-eq.of KMnO4 reacted with H 2C2O4 ]
 45  0.02  5  10  0.1  2  2.5
w
1000   2  2.5  WNa2C2O4  0.1675 g
134
0.1675
% purity of Na2C2O4 in sample   100  83.75
0.2
36. FeS 2  O 2  Fe 2 O 3  SO 2
x F  11
MnO 4  SO 2  SO 42  Mn 2
xF  5 xF  2
eqts.MnO  eqts.SO2  n MnO  5  n SO2  2
4 4
5 1
n SO2   0.01  n FeS 2  n SO2
2 2
4 5
  0.1
56  64 4
5
x   .01  120
4
x  1.5gm
MATHS
37. Let P and Q be point on the lines, then P  2  2s, 6  3s,34  10s  , Q  6  4t , 7  3t , 7  2t 
The d .r ' s of PQ are  4  4t  2s,13  3t  3s, 27  2t  10s 
PQ is perpendicular to the two lines with d .r ' s 2,3, -10 and 4, -3, -2.
 2  4  4t  2s   3 13  3t  3s   10  27  2t  10s   0
4  4  4t  2s   3 13  3t  3s   2  27  2t  10s   0
 113s  19t  301, 29  19 s  1
Solving s  3, t  2, P   4,3, 4    a, b, c   a  b  c  11
x y z 1 x y z 1
38. The lines are   ,  
1 1 0 1 1 0
Let C   ,  ,  
 
    c  a   b
The distance of C from r  a  sb is 
b
   
2
   1 
2
Distance of C from the first line is .....(i )
2
SR.IIT_CO-SC Page 7

   
2
   1 
2
The distance of C from the second line is .....(ii )
2
       
2 2
(i ), (ii )     1      1 
2 2
4  2 . Locus of C is xy = -2z.
2 2
39. x  y  z ...(1)
y z
x  .....(2)
2 3
Clearly point of intersection of (1) and (2) is (0, 0, 0)
D.r’s of (1) are (1,1,1)
D.r’s of (2) are (1,2,3)
Let  be the angle between (1) and (2)
6 6
cos   ,sin  
42 42
Let any point on second line be   , 2 ,3 
Third line passing through (1,1,1)
(1,1,1) lies on (1) A=(1,1,1)
1
Area of OAB   OA  OB sin 
2
1 6
 3 14   6
2 42
   2 so B is (2,4,6).
1111 2
40. MR  
3 3
 RM 
sin(90   ) 
RQ  RM sec  RQ 
 
  RQ  RM sin  
 
2 14
 
3 2
28

3
(SINCE ' ' angle between line & plane
1 2  3
cos(90   ) 
3 1 4  9
6
sin   )
3 14
41. Here P3 is  x  z  1   y  0 Distance from  0,1, 0  is 1
1
  1   2  2   
2
SR.IIT_CO-SC Page 8

 Equation of P3 is 2 x  y  2 z  2  0
 2    2  2  6  2    2  2  6
42. It is the line of intersection of the given plane and a plane perpendicular to given plane and
containing the given line
43. Equation given plane is   x  y  3 z  0
x 1 y  3 z  2
Line PQ is   r
1 3 2
 Q   r  1,3r  3, 2r  r   lies on   r  4
 Q  3, 15, 6 
x  3 y  15 z  6
 Equation of normal to the line is    1
1 5 3
Let R   ,  ,    mid  PR  lies on (1)
  2r  7,   2r  27,   6r  14
16
PR //   r   D.R’s of QR 15, 37, 10
22
 Equation of plane PQR  A  x  1  B  y  3  C  z  2   0
A B C
It is containing P and Q   
11 5 2
 plane is 11x  5 y  2 z  30
1 1 1
44.  1 3  0    4
2 1 1
 1 3 
P  1, 1, 0  , Q   0, ,  , O   0, 0, 0 
 2 2
  
i j k
i 2 2
45. 0 1 1 h
6 3
2 1 1
  2 2
h. j  k 
3
h2
If E  divides median through A in  :1
 2  1 1 1 
E  , , 
  1  1  1 
2 
 AE 2   DE 2   AD 2  4  2
   1 2
 1
 E   1,3,3 or  3, 1, 1
SR.IIT_CO-SC Page 9

x y zc
46. Equation of L1   
0 b c
x y zc
Equation of L2   
a 0 c
iˆ ˆj kˆ
Direction of  is 0 b c  bciˆ  acjˆ  abkˆ
a 0 c
Equation of is bc( x  0)  ac( y  0)  ab( z  c)  0
x y z
   1  0
a b c
Distance between L1 & L2 is
(0,0,2c),(bc, ac, ab)

b 2 c 2  c 2 a 2  a 2b 2
1 1 1
2
 2  2  64
a b c
 ar (ABC )   ar (OAB)   ar (OBC )   ar (OCA)
2 2 2 2
47.
x y z
If A & C are on positive axes & B is on negative axis then the equation of plane is   1
2 3 4
If A & B are on positive axes & C is on negative axis then the equation of plane is
x y z
  1
2 3 4
5 5 5  a
48. 2 3 p 0
2 4 2
 60  30 p  14a  0.....(1)
Lines are perpendicular
 4  12  2 p  0 ....(2) from (1) & (2)
30
P  4, a 
7
SR.IIT_CO-SC Page 10

49. A plane containing the line of intersection of the given planes is
x  y  z  4   ( x  y  2 z  4)  0
i.e.,(  1) x  (  1) y  (2  1) z  4(  1)  0
Vector normal to it
V  (  1)iˆ  (  1) ˆj  (2  1)kˆ
Now the vector along the line of intersection of the planes
2 x  3 y  z  1  0 and x  3 y  2 z  2  0
iˆ ˆj kˆ

n  2 3 1  (6  3)iˆ  (4  1) ˆj  (6  3) kˆ
1 3 2
 3(iˆ  ˆj  kˆ)

As n is parallel to the plane (1)
 
Hence nV . 0
(  1)  (  1)  (2  1)  0
2  2  1  0
1
 
2
Hence, the required plane is
x 3y
  2z  2  0
2 2
x  3y  4z  4  0
Hence, A  B  C  11
50. A(3,3,3) B(3,3,0) C ( 0,3,0) D (0,3,3,)
 
Minimum area  .n ,where   AB  AC
 9 j
1
 
n  2i  j  2k
3
Required area = 3 square units.
51. Orthocentre is the foot of perpendicular drawn from origin on the plane
52. Let equation of plane be x  2 y  3 z  7   x  0
Since ( 1,0,2) lies on it   2
Equation of plane is  x  2 y  3 z  7  0
6 p
cos  
7 q

  
53. Given b  a  12; c  6
 
Equation of CD is r   c and
   
Equation of AB is r  a   (b  a )
  
a.c  (b  a )
S .D      8
c  (b  a )

[ a c b]
   8
c  (b  a )
   
[a c b]  8 c  (b  a )
  
8c ba
6V 
2
6V  (4)(6)(12)
V  48
 3l  4m 
2
54. Eliminating n between the relations, l  m

2 2

25
 16l  24lm  9m  0
2 2
3m
 4l  3m   0, l 
2
4
 The d .r ' s are  3, 4, 5  ,  3, 4, 5  .
The lines are parallel and the angle between them is zero.

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Sec: Sr.

IIT_CO-SC Date: 01-11-20

Name of the Student: ___________________ H.T. NO:

01-11-20_ SR.CO-SUPER CHAINA_Jee-Adv_PTA-10_SYLLABUS

CHEMISTRY: CHEMCIAL KINETICS AND NUCLEAR CHEMISTRY

MATHEMATICS: Vectors -3D : Direction Cosines And Direction Ratios, Equation Of A

SR.IIT_CO-SC Page. No. 2

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC Page. No. 3

Education consists mainly of what we have unlearned.

B) total energy of oscillation will be proportional to  n  1 times that of

SR.IIT_CO-SC Page. No. 4

Education consists mainly of what we have unlearned.

A) If F  0 the pulse will remains stationary

SR.IIT_CO-SC Page. No. 5

Education consists mainly of what we have unlearned.

A) Wavelength of sound received by detector D is 25m

SR.IIT_CO-SC Page. No. 6

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC Page. No. 7

Education consists mainly of what we have unlearned.

17. Sound level /loudness at any point in a room is increased from 50 dB to 60 dB by

18. A siren is placed at a railway platform is emitting a sound of frequency 5KHz. A

SR.IIT_CO-SC Page. No. 8

Education consists mainly of what we have unlearned.

Rate of disappearance of B2. (Mole litre-1min-1) Conc. [A] (mole/litre) [B2]

1.810-3 0.015 0.15

1.0810-2 0.09 0.15

5.410-3 0.015 0.45

A) 1.2810-3 M min-1 B) 2.5610-3 M min-1

SR.IIT_CO-SC Page. No. 9

Education consists mainly of what we have unlearned.

A) Overall energy of activation is 10 KJ

B) Overall energy of activation is 30 KJ

D) The reaction mechanism is A 

A) 0.06 B) 0.16 C) 0.32 D) 0.64

25. Identify the correct statements

SR.IIT_CO-SC Page. No. 10

Education consists mainly of what we have unlearned.

A) At 30 min., only 20% reaction is complete

A) If [ B]  [ A] then at time [ D]  0.75M

SR.IIT_CO-SC Page. No. 11

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC Page. No. 12

Education consists mainly of what we have unlearned.

the salt is  x  103 y  . The value of  x  y  is _____

solution of H 2 SO4 and sodium is titrated at 700 C , requiring 45 mL of 0.02 M

SR.IIT_CO-SC Page. No. 13

Education consists mainly of what we have unlearned.

A) 1,2,3 B)  2, 4,6 C)  , ,  D)  2,1,3

SR.IIT_CO-SC Page. No. 14

Education consists mainly of what we have unlearned.

SR.IIT_CO-SC Page. No. 15

Education consists mainly of what we have unlearned.

C) There exist two positions for E   1,3,3 and  3, 1, 1

A) Area of ABC  61 square units

B) Equation of plane  may be 6 x  4 y  3 z  12

C) Equation of plane  may be 6 x  4 y  3 z  12

D) Volume of tetrahedron OABC is 2 unit

SR.IIT_CO-SC Page. No. 16

Education consists mainly of what we have unlearned.

x  Ay  Bz  C  0 . Compute the value of A  B  C .

50. A plane P intersects 4 lines L1 , L2 , L3 and L4 (given below) at A,B,C,D