STOICHIOMETRY (CHEMISTRY ASSIGNMENT) Gl. [molecular weight of KMnO, is M, then its equivalent weight in acidic medium would be DM ae ay 62, 74.5 gota metallic chlor sof chlorine, the equivalent weight of the metal is 19s 23s 339 4)78.0 vely, then what will be the eM, and M, respec 63. Ifthe molecular weight of NayS,0, and I, equivalent weight of NajS)0, and I, in the following reaction? 28,037 +1, > $4027 + 217 1M, Mz 2)M,, M2 /2 3)2M,, Ma 4)M,, 2M 64. A compound contains 69.5% oxygen and 30.5% nitrogen and its vapour density is 46. The formula of the compound is, 1)N20 2)NOz 3)N204 4)N205 65. For the reaction: X + 2¥ — Z; 5 Moles of X and 9 moles of ¥ will produce 1)5 moles of Z 2)8 moles of Z 3)14 moles of Z 4)4 moles of Z 66. aK,Cr,0; + bKCI+ cHyS0, —> xCrO,Cl + yKHSO, + 2H, 0.The above equation balances when 1a=2,b=4,c= 6 andx= 2a=4,b and x 3)a=6,b and x 4) a=1,b=4,c=6andx=2,y=6, 67. For redox reactionMn0j + C,03- + Ht — Mn?* + CO2 + H20 coefficient of reactants (MnOj ,C,03- & H*) in balanced states respectively are 12 5 16 2) 16 5 2 2 3)5 16 2 42 16 5 68. Which of the following is a redox reaction? 1)NaCl + KNO3 — NaNO, + KCl 2)CaC,0, + 2HC] — CaCl, + H2C20, 3) Ca(OH), + 2NH,Cl — CaCl, + 2NH; + 2H,0 4)2K[Ag(CN)2] + Zn —> 2Ag + K,{Zn(CN) 4] 69. The number of electrons lost or gained during the change Fe + H,0 — Fe30, + Hz is 1)2 2)4 3)6 4)8 70. Inthe reaction, H,0, + Na,CO, > Na,02 + CO, + H20 the substance undergoing oxidation is 1)H202 2)Na2CO3 _ 3)Na202 4) None of these 71. The coefficients of I”, 103 and H* in the redox reaction, I” + 10; + H* — I, + H20 in the balanced form respectively are D516 2)1,5,6 3)6, 1,5 4)5,6.1 72. "In the following reaction, 4P + 3KOH + 3H,0 + 3KH;PO, + PH 1) P is only oxidized . 2) P is only reduced 3) P is both oxidized as well as reduced 4) None of the above7B. 71. SSEe@Q@ 82, 84, 85. 86. on. SO, + 21,8 —> 38 + 21,0 the substance that onidia In the react nus 2) SO, a8 LO The empirical formula of a compound is CH. One w lis molecular formula is: 1) CH 2) CoH 3) Cy 4) Calg Which of the following i comproportionation reaction VD) Clay) OW ogy WO fagy * TF fagy* B2y 2) AB(agy * ARs) > PAB ag 3) Nag) +HyQy, > NaOH gg, + Hayy, 4) Zig) + CUSO gay) > ZS ggg) + Cts The equivalent mass of H3PO, in the reaction given below is H,PO,~ NaOH — 1)49 2)98 3) 32.6 A compound contains 92.3% of carbon and 7.7% of hydr 39 times heavier than hydrogen molecule. The molecular formula 1) C3H3 2) CoH 3) CoHy ‘The molality ofa solution having 18 gof glucose dissolved in $00 g of wa’ im 2)0.5m 3)0.2m If 5.85 g of NaCI is dissolved in 90 g of water, the mole fraction of sol 1) 0.0196 2)0.01 3) 01 Oxidation number of Sodium in Sodium amalgam 1)#2 ael 3)2 40 The equivalent weight of glucose in the reaction C,H,,0, ~ 60, - 6CO, - M M M De aD vg 2 A compound contains 90% C and 10% H. The empirical formula of the compor 1) Cy 4 2)'C,sHyy 3) CH, D) Cf, ‘When 20 ml of methane and 20 ml of oxygen are exploded together and the cooled to laboratory temperature, The resulting volume of the mixture és 1) 40ml 2) 20 ml 3)30 ml 410 2H PO,- HO 1)36 2)25 3)40 44s Gram molecular weight of a compound is 602.3 gm. The mass of one mole 1) 3.1x10 kg 2) 6.023x10kg 3) 10 kg 10 Nitric acid acting as an oxidant in a certain reaction accepts 4 moles of electrons pe: reduction product can be » Lote of A moe of NO, 2) Smoke of Ny 3) Fmote of xoA compound contains atoms of three clements: A, B and C, Ifthe oxidation number of A is +2, B is +5 & that of C is —2, the possible formula of the compound 1) 4,(BC,), 2) ABC, 3) 4(B,C), 4) 4,(BC,), 88. In two oxides of a metal,Zombines with 27.6 % & 30 % of oxygen respectively. If the formula of 1* oxide is M,O,, the formula of the 2” oxide is 1) MO, 2) M,0, 3) MO 4) M,0 89. 1.5 moles of hydrazine ( 'N,H4)loses 15 moles of electrons in being converted to a new compound (X), Assuming tha all ofthese nitrogen atoms appear in the new compound, what is the oxidation state of Nitrogen in the compound (X). 1-1 2-2 3)+3 ats 90. A hydrated salt (M.W = 250) looses 36% of water on heating, The number of moles of water present in 1 mole of that hydrated salt is 12 25 3)6 4)7 61)3 62)3 63)2 64)3 65)4 66)4 67)1 68) 4 69) 4 70)4 9-71) 72)3 73)1 74)3 75)2 76)2 774 78)3.—=—«79)2.—=« BO) BAYA 82)3 , §3)2 84) 1 85)4 86)4 87) 4, 88)2 89)3 90)2 a @ MnO + 8H* + Se~ + Mn?* + 4H20 Gain electrons-5 ‘ Molecular weight=M Equivalent weight="2seeaewet = 62) Equivalent weight of metal wt. of metal x 35.5 = \gtof chlorine (745 ='35.5) x 355 355 63 (2) Change in oxidation nufnber 0.5 2 ° 42.5 + yp SOF + 28,0) (Change in osidation number = 1X2 = 264 65 66 67 68 o 70 a Me Equivalent mass of Naz5203 = | = My Equivalent mass of lp = “2 @) fo [Element [% | % At wt Ratio | N 305 | 305/14=2.18 | ° 695 |o9s/6-434 |? Empirical formula=NO, ical formula weight=46 : 24° a Molecular formula=(NOz)2 = N2Ox (4) In a chemical reaction, coefficient represents mole of that substance. X+2¥ 92 This indicates 1 mole of X reacts with 2 moles of ¥ to form 1 mole of Z So, 5 moles of X will require 10 moles of¥. But we have taken only 9 moles of Y. Hence, ¥ is in limiting quantity. Hence, we determine product fromY. Thus, 5 moles of X react with 9 moles of ¥ to form 4 moles of Z @) aK C1407 + DKCI+ cHl2S04—> xCrOpCl + YKHSOg + 220 7 x 6 3 (0) Following is balanced redox reaction. 2Mn0; + 5C,03- + 16H* — 2Mn®* + 100, + 8H,0 So, coefficients of Mn0;z,C,03" and H*are 2,5, and 16 respectively. @) 2K[Ag(CN) 2] + Zn > 2Ag + Ko[Zn(CN)«] + Zn —> 2Ag + KalZ(CN)a) aK[Ag Reduction Oxidation (4) 3Fe > Fe;0, + 8e~ oxidation 4H,0 + 8e~ > 4H, ‘Thus, there are lose of 8 electrons in the reaction @ 10242 Ha M2 2 ), + Na, C Oy —>NayO +CO, + 11,0 HA None of the elements changes its oxidation number @ 45 ° T+(0y'+H —> h+H,0 a —> hte @xs 45 0 "100" +2003)! —> bh Gi) 7 On adding Eq. (i) and (ii), we get 101” + 2105 > 61, To balance O atom, add 6H,0 molecules on RHS and 12H* on LHS, then 101” + 2105 + 12H* > 61, + 6H,0 or SI” +103 + 6H* > 3l, + 3H2082. 83 TFS ion numer of § increases fim ~2t00 in elemental suiphur and hence, HS net s oxidized MF ans kL Molir EEN Conceptual No of 1 ions given by 11,70, to NaOH is one Conceptual w 1000 Wiof solvent(g) “Gur 5 “4 C,Hi0, +60, + 6CO, + 6H,0 &wtol CHO, % of elements H 10% Atomicratio 22-75 !.10 : 12 1 simple a 1o_4 imple ratio 5 um 75 3 CH, a4 . ‘ CH, + 20, > CO,+2H,0 Imole 2mole Initial 20 ml 20 ml Om! Omi Reacted 10m! 20 ml 10 ml 20 mi Final volume 10 ml Oml 10 ml Oml Vapour converts into liquid at room temperature 10+ 10= 20 ml89, (15 moles V,17, loses 15 moles of & 5 I mole N,/, loses = 10 moles of e's )a 8 133. 134, 135, 13¢ 137, 3. KMn0, (molawt.= 158) ox STOICHIOMETRY (CHEMISTRY ASSIGNMENT) ent weight of a bivalent metal is 37.2. The molecular weight of its: chloride is 2) 216 3) Ms4 4) 108.2 goof chlorine, the equivalent weight of the metal is, 3)39 4) 78.0 oxalic acid in acid mediuni to CO, and water as follows 5C,03- + 2Mn0j + 16H* > LOCO, + 2Mn** + 81,0 What is the equivalent weight of KMn0,? 1) 158 2)31.6 3)39.5 479 irical formula (CHO) its vapour density is 45, The gofa metallic chlotide contains 195 2) 35.5 . An organic compound has an ent molecular formula of the compound is 1) CHO 2) CaHsO 3)C,H,0 4)C lO 5. In which of the following numbers all zeros are significant? 1)0.500 2)30.000 3)0.00030 4)0.0050 . Two oxides of a metal contain 50% and 40% metal (AM) respectively. If the formula of fist oxide is MO», the formula of second oxide will be 1)M0, 2)M03 3)M,0 4)Mz0; . In the reaction, 1, + 2$,037 — 21~ + $,02°. Equivalent weight of iodine will be equal to 1) Molecular weight 2)1/2 of molecular weight 3)1/4 of molecular weight 4) Twice of molecular weight ‘A. compound contains 54.55% carbon, 9.09 % hydrogen, 36.36% oxygen. The empirical formula of this compound is 1)C3H50 2)CqHg02 3)C,H40z 4)C,H,0 . One mole of CO, contains 1)3 g atoms of CO, 2)18.1 x 10? molecules of CO, 3) 6.02 x 108 atoms of 0 4) 6.02 x 103 atoms of C . In the conversion of Br, to BrO;, the oxidation number of Br changes from 1) Zero to #5 2) +1 to +5 3) Zero to -3 4) 42 to +5 . The molality of solution having 18 g of glucose dissolved in 500 g of water is Dim 2)0.5m 3) 0.2m 4)2m . The equivalent weight of glucose in the reaction C,H,,O, + 60, > 6CO, + 6H,0 is M M M DM 2 12 4) 18 4 24 In which of the following oxygen shows —1 oxidation state? 1)H202 2)CO, 3)H20 4) OF, When 20 ml of methane and 20 mil of oxygen are exploded together and the reaction mixture is cooled to laboratory temperature. The resulting volume of the mixture is 1) 40ml 2)20 ml 3) 30 ml 4) 10 ml How many atoms are present in a mole of HzS0,4? 1) 7x 6.02 x10? 2) 1.5x 6.02 x 107° 3) 6.02 x 1023 4) 2 x 6.02 x 1073 . Oxidation number of Sodium in Sodium amalgam 142 2)4+1 3) -2 4)0 Equivalent weight of CaCl is Formula weight 9) Formula weight | ani 2 1 3) Formula weight 3) eae weight 32 145. 146. 8. The conve 143. 144, 147, ion of Glucose to carbon dioxide with respect to carbon IS 1) Oxidation 2) Reduction | 3) both oxidation & recution 4) Neither oxidation nor reduction . Which of the following is not disproportionatios 1) ROH ay PU, Ps) 2) Sy HOW ay PI a Py PMY 3) chy FOU uy A CIO oy * Oy 4 OT BOM uy PF yyy FOB, +O |. If 5.85 g of NaCT is dissolved in. 90 g of water, the mole fraction of solute is 1) 0.0196 2) 0.01 3)0.1 4) 0.2 . Sulphur forms the chlorides $C/y and SCi. TI ivalent weight of sulphur in SCI2 is Ys 2) 16 3) 64.8 4) 32 ‘he empirical formula of an organic compound is CHO. The weight of 1.2 Lit at NTP of this compound is 45, The molecular formula of the compound is 1) CH,O 2) Cyl1,O, 3) CHO, 4) CoH,05 A compound contains atoms of three clements: X, Y and Z. If the oxidation number of X is + 2, Y is +5 & that of Z is—2, the possible formula of the compound > 1) X3(¥Z,), 2) XYZ, 3) X,(¥Z,), 4) X,(¥,Z), “The molality ofa solution having 18 g of glucose dissolved in 500 g of water is Dim 2) 0.5m 3) 0.2m 4)2m Oxidation number of carbon in carbon suboxide (C302) 2 ne ns 3) +4 the wrong statement for the above 1) Curis oxidized 2) HINO} is reduced 3) Cwis reduced 4) Cu acts as redueting agent The relative number of atoms of different clements in a compound are as follows: A=1.33, B=1 and C=1.5, The emperical formula of the compound is 1) ABC, 2) ABC 3) A,B,C, 4) ABC, In the balanced chemical reaction 10; +al_+ 6H” > cH,O+dI, a,b,c and d respectively correspond to ol” 1) 5,633 2) 5,3,6,3 = 2)3,53,6 4) 5,6,5,5 . Inthe reaction $,07° +21" > 2807 +1, . 1) Oxidaton of iodide into iodine takes place 2) Reduction of iodine into iodide takes place 3) Both oxidation ane reduction of iodine takes place 4) None of the above . 10 grams of each Op, Nz and Clz are kept in three bottles. The correct order of arrangment of bottles containing decreasing number of Molecules. 1) 02, No, Cla 2) Cl, Nz, O7 3) Clz, O2, Nz 4) Nz, 02, Cla . A molar solution is one that contains one mole of the solute in 1) 100 gr of solvent . 2) One litre of the solvent 3) 1000 gr of solvent 4) One litre of the solution |. Oxidation state of nitrogen is not an integer in 1) Hydroxyl amine (NH 20H) 2) Ammonia (NH3) 3) Hydrazine (N24) 4) Hydrazoic acid (N34) Pagel2j Pre erie he ioe pe clement als ays exhibits only -1 oxidation state in all of its compounds 1) Hydrogen s f,, Which of the following statements is wrong, 1) Oxidation number of oxygen is +1 in peroxides » ae number of oxygen is +2 in oxygen difluoride > xidation number of oxygen is -1/2 is super oxides iss *) a number of oxygen is -2 in most of its compounds . Law of multiple proportions is illustrated by one of the following pairs 3) Fluorine 4) Oxygen 1) HS and SO 2) NH3 and NO2 3) Nap8 and NayO 4) N20 and NO 156. ‘The no. of electrons present in one mole of Azide ion are(5) 1)21N 2)20N 3)22N 4) 43.N 157. Oxidation number of carbon in carbon suboxide (C302) 2 4 y= a +4 at 3 a5 3y dS 158. The normality of 0.25M H,SO, solution is 1) 0.25 2)2.5N 3) 0.50 N 4) 5.0N 159, When 4g of sodium hydroxide is present in 200m of its solution, the molarity of the solution is 1) 0.25M 2)0.5M 3) 10M 4) 15M 160, 2KCIO, > 2KCI-+30;. The volume of O, liberated at STP on the decomposition of 12.25g of KCIO, is 1) 2.24 lit 2) 3.36 lit 3) 1.12 lit 4) 4.48 lit Key 121)3 122)3 123)2 124)4 125)2 126)2 127)2 128) 4 129) 4 130) 1 131)3 132)4 133)1 134)2 135)1 136) 4 137)1 138)1 139) 4 140)1 141)2 142)3 143)3 144) 3 145) 2 146) 3 147)3 148)1 149)1 150)4 151)4 152)4 153)3 154) 1 155) 4 156) 3 157)2 158) 3 159) 2 160) 2 oe Ee “ 121 @) _2 Ee ya? \ Equivalent weight of bivalent metal Patomic weight of metal=37.2 x 2 = 744 gt yews «. Formula of chloride=MCls Hence, molecular weight of chlotide MCl, = 744+ 2355 WW = 1454 eee te + 122 © valent weight of metal ian \o 2 pagel3wt.of metal = x 355 wh of chlorine (745 = 35.5) x 35.5 =39 355 123 Q) 5C,03- + yy) + 16H* > 10€0, + 2Mn2* + 81,0 208" + oMn0; 2 n molecular wi Equivalent weight=< oe in oxidation number 158 _ > 316 124 (4) Mol. wt.=2 x vapour density 2x45 =90 Empirical formula weight=12+2+16=30 oe mol.wt *™ © Gmpirical formula wt 90 30, + Molecular formula of the compound (CH,0)3 CaH03 126 (2) Oxide I Oxide II Metal, M 50% 40% Oxygen, 0 50% 60% As first oxide is MO, Let atomic mass of M xo = 22 + 960 = shag 100 OF t00 = 38 Or 0.5= aa Or 05xx+16 = 32 Or 0.5x = 16 x=32 «At. Mass of metal M = 32 Let formula of second oxide is MzOn . . 2*_ x 100 = —*— x 100 %M = 2x+i6n ~ 64tien 40 64 100 64+ 16n 100 64#i6n Or fo et 25=1+025n 15 n=i= ‘Therefore, formula of second oxide = M,0g Or = M0; ‘ 128 (4) . Given, % of C=54.55% % of H=9.09% %ot O=36.36% Loe Pagelarn Ratio ofatoms — { Simplest ration 34.55 2 | 5455/2454 | 4.54/2.27°-2 9,09 L 9,09/1=9.09 9,09/2.27-4 36.06 16 36.16/16=2.27 | 2.27/2.27=1 | + Empirical formula is CpH,0. 129 (4) One mole of CO, contains 6.02 x 108 atoms of carbon and 6.023 x 102? molecules of oxygen. 130 () Bromine has zoro oxidation state because itis in free state, a Brz — BrOz Let the oxidation number of Br in BrO3 is x. xt(-2x3)s-1 x+(-6) xat6- x=45 So, oxidation number changes from 0 to +5. BI w 1000 "= GMIV * Wiof solvent(g) 132 0 44 C,Hj.0; +60, > 6CO, + 6H,O L224 J i M | &wtof C,H,,0, x4 | “ 24 | 133 (1) Oxygen shows — 1 oxidation state in Hz02- | 2(+1) + 2x =0 2x 2 x=-1 134 CH, + 20, > CO,+2H,0 . Imole 2mole | Initial 20 ml 20 ml om om | Reacted 10 ml 20 ml 10 ml 20 ml | — — Final volume 10 ml Omi 10 ml Om! . Vapour converts into liquid at room temperature 10+ 10=20ml 135 (I) (0 oLof H,S0, = 6.02 x 10% molecules = 7x 6.02 x 10? atoms eS Pagel136. Conceptual 137. Conceptual 138. Conceptual 139. Conceptual 1, nny 140. x, = 141. Conceptual 142. Conceptual 143. Conceptual w 1000 44, og 1000 ___ GMIV " Wiof solvent(g) 145. Conceptual 146. 0.8 of Cu increase From oto+2 cu oxidised 147. Conceptual 148. Balancing according to oxidation number method 149. Conceptual ww 150. No. of molecules =-——_x N MW 151. Conceptual 152. Conceptual 153. Conceptual 154. Conceptual 155. Conceptual 156, Azide ion = Ny No. of electrons in one N; ion=21+1 157. Conceptual 158. Conceptual . 159. Conceptual 160. Conceptual Pagels