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is
(A) NaBH4
(B) LiAlH4
(C) H3B·THF
(D) Zn(Hg)/HCl
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is
(A)
(B)
(C)
(D)
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is
(A)
(B)
(C)
(D)
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K + O2
is
(A) K2O
(B) K2O2
(C) KO2
(D) K2O3
CY 5/40
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Q.5 Which one of the following options is best suited for effecting the
transformation?
(A) MnO2
(C) Al(Oi-Pr)3
(D) Ag2O/NH4OH
CY 6/40
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Q.6 2
The structure of [XeF8] is
(A) cubic
(D) octagonal
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Q.7 Among the following, the compound that forms the strongest hydrogen bond is
(A) HF
(B) HCl
(C) HBr
(D) HI
Q.8 Among the following, the biomolecule with a direct metal-carbon bond is
(B) nitrogenase
(C) chlorophyll
(D) hemoglobin
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(A) tripled
(B) halved
(C) doubled
(D) unchanged
(A) ionic
(D) covalent
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is
(A)
(B)
(C)
(D)
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1
H NMR: 9.72 (t, 1H), 7.1 (d, 2H), 6.7 (d, 2H), 3.8 (s, 3H), 3.6 (d, 2H)
(A)
(B)
(C)
(D)
CY 11/40
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(A) (E)-2-phenyl-but-2-ene
(B) (Z)-2-phenyl-but-2-ene
(C) 3-phenyl-but-1-ene
(D) (2R,3R)-2-ethoxy-3-phenylbutane
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is
(A)
(B)
(C)
(D)
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CY 14/40
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Q.17 2
The structure types of B10H10 and B10H14 , respectively, are
Q.18 The ground state and the maximum number of spin-allowed electronic
2+
transitions possible in a Co tetrahedral complex, respectively, are
4
(A) A2 and 3
4
(B) T1 and 2
4
(C) A2 and 2
4
(D) T1 and 3
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+ +
Q.19 The correct statement about the geometries of BH2 and NH2 based on valence
shell electron pair repulsion (VSEPR) theory is
+
Q.20 The order of increasing CO stretching frequencies in [Co(CO)4]–, [Cu(CO)4] ,
2–
[Fe(CO)4] and [Ni(CO)4] is
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(A)
(B)
(C)
(D)
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Q.22 The stability of adducts H3B·PF3, H3B·NMe3, H3B·CO, H3B·OMe2 follows the
order
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(A)
EJ 1 EJ
XY
X 'Y '
0
0
J
(B)
XY
EJ 1 EJ
X 'Y '
0
0
J
(C)
EJ 1 EJ
XY
X 'Y '
0
0 J
(D)
EJ 1 EJ
XY
X 'Y '
0
0 J
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+
Q.24 The ratio of the 2p 1s transition energy in He to that in the H atom
is closest to
(A) 1
(B) 2
(C) 4
(D) 8
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(A)
g
T s
l
P
(B)
g
P s
l
T
(C)
l
T s
g
P
(D)
l
P s
g
T
CY 21/40
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Q.26 Capillary W contains water and capillary M contains mercury. The contact
angles between the capillary wall and the edge of the meniscus at the air-liquid
interface in W and M are W and M , respectively.
The contact angles satisfy the conditions
(A) W 90 and M 90
(B) W 90 and M 90
(C) W 90 and M 90
(D) W 90 and M 90
CY 22/40
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[Given: A is a normalization constant such that f (vx ) dvx 1 , and kB is the
Boltzmann constant]
(A) A exp(mvx2 / 2k BT )
(B) A exp(mvx2 / k BT )
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(A) m 12
x L
n
(B) m
x L
n
(C) m
x L
n 1
(D) m 1
x L
n 1
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(A) 1
(B) 2
(C) 3
(D) 4
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Q.30 The standard Gibbs free energy change for the reaction
H2O (g) → H2 (g) + 1O
2 2
(g)
(A) 0.994
(B) 1.006
(D) 292.12
CY 26/40
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Q.31 Among the following, the reaction(s) that favor(s) the formation of the products
at 25 C is/are
(A)
(B)
(C)
(D)
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(A) The first pKa of malonic acid is lower than the pKa of acetic acid while its
(B) The first pKa of malonic acid is higher than the pKa of acetic acid while its
(C) Both the first and the second pKas of malonic acid are lower than the pKa of
acetic acid.
(D) Both the first and the second pKas of malonic acid are higher than the pKa of
acetic acid.
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(A)
(B)
(C)
(D)
CY 29/40
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Q.34 Among the following, the suitable route(s) for the conversion of benzaldehyde
to acetophenone is/are
(B) (i) HS(CH2)3SH, F3B·OEt2; (ii) n-BuLi; (iii) MeI; (iv) HgCl2, CdCO3, H2O
(D) (i) MeMgBr; (ii) aq. acid; (iii) pyridinium chlorochromate (PCC)
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involve(s)
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Q.36 The reason(s) for the lower stability of Si2H6 compared to C2H6 is/are
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Q.37 For an N-atom nonlinear polyatomic gas, the constant volume molar heat
capacity Cv,m has the expected value of 3(N 1)R, based on the principle of
(C) The measured Cv,m is typically lower than the expected value.
(D) The measured Cv,m is typically higher than the expected value.
(A) carboxypeptidase
(B) hydrogenase
(D) urease
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+
Q.39 The conversion of ICl to ICl involve(s)
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Q.42 The number of stereoisomers possible for the major product formed
in the reaction
is ________.
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1
Q.43 The number of signals observed in the H NMR spectrum of the compound
is _______.
The yield of the product is _______ %. (round off to the nearest integer)
2+
Q.46 The number of unpaired electrons in [Co(H2O)6] is _______.
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Q.48 The d spacing for the first-order X-ray ( = 1.54 Å) diffraction event of metallic
iron (fcc) at 2 = 20.2 is ________ Å. (round off to three decimal places)
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is ______.
Fe2O3 + 3 CO → 2 Fe + 3 CO2
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3+
Q.54 Total degeneracy (number of microstates) for a Ti ion in
spherical symmetry is ______.
2+ 2+
Q.55 A galvanic electrochemical cell made of Zn /Zn and Cu /Cu half-cells
produces 1.10 V at 25 C. The ratio of [Zn ] to [Cu ] is maintained at 1.0.
2+ 2+
The G for the reaction when 1.0 mol of Zn gets dissolved is ______ kJ.
(round off to the nearest integer)
Q.57 Two close lying bands in a UV spectrum occur at 274 nm and 269 nm. The
magnitude of the energy gap between the two bands is _____ cm1.
(round off to the nearest integer)
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Q.60 For a van der Waals gas, the critical temperature is 150 K and the
critical pressure is 5 106 Pa. The volume occupied by each gas
3
molecule is _______ Å .
(round off to two decimal places)
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