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δ- δ+
C R
where R are groups that show +I effect
• The relative magnitude of inductive effects of
alkyl groups follows the order:
Me Me
Me C > C > Me C
Me Me
Electromeric Effect
• This is the effect which involves the complete
transfer of a shared pair of electrons to one of the
atoms joined by a multiple bond at the approach
of an attacking reagent.
Reagent
Characteristics of Electromeric Effect
I II