Scribd Logo
Upload

Welcome to Scribd!

  • Toso CSM Ts 530 Chlorosulphonated Polyethylene

    Uploaded by

    BalajiYachawad
    33 views11 pages

    Original Title

    Toso Csm Ts 530 Chlorosulphonated Polyethylene

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    33 views11 pages

    Toso CSM Ts 530 Chlorosulphonated Polyethylene

    Uploaded by

    BalajiYachawad

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 11
    TOSOH The Chemistry of Innovation O0SO-CSM:-::-~- ; Alkylated ) Chlorosulphonated Polyethylene TOSOH CORPORATION Production method of TOSO-CSM’and extos® Production process Chiorosulphonated Polyethylene (CSM) is a Special Synthetic Rubber manufactured through chloriaton and chlorosulphonation TOSO-CSM* of polyethylene (Polyethyione) Extos is new type of CSM with improved Dynamics and Low ‘Temperature Properties He Structural Features Chote citation | choosdpontn con | son “oiler rose.) + Higher glass-transition temperature ‘Sulphony| Chloride Groups Cree en nena + Cross-Linking Point Single Bond on the main chain (alkylated polyethylene) Chlorination | Chlorosuiphonation (on (so.c)) 10S0.c8¥andaxtos re roared uk cated [So 001 easton a Tosot’s Nany Comex Comparison of TOSO-CSM° with other syntheti Tensile strength (pure gum] O|p| D Tear strength Abrasion resistance [compression set Anti-gas permeability Weather resistance Ozone resistance Heat resistance Fiame resistance Discolour resistance Strong acid resistance alkali resistance Gasoline resistance O}] O} EO} O}O|O}O]O/O/C/C/O|O| OR O}O} O}O}| O|O| O|>|O}O|P|P} ><|><|O]O]O}Xx|O|O}O}O|>}O|O}O O}O/OJOJ|O}X| |x| >| O/O|O ><|><|O] D>] O}>| P| ><] P| >|O}O] P| Gil resistance x|xlo]Plolx|p}|>/ole|ole]s ©- Excellent, O - Good, A — Possible, X — Impossible protective barriers on public transportation systems (Urban liner/Kintetsu Corporation) Rubber panels for railroad crossings Features and specifications = faa nla | all = |ts-340| 43 4 350" | Good solubility, low solution viscosity, oil resistance ICN-1500 30 14 1400" | Good solubility, low solution viscosity alt al eee ‘5255 lolunen solution vscosly ((mPars/BTo0KT FO 10 ype wiscom TOSO-CSM* TS-530 Mostwell-balanced grade, superior in physical properties anli-degration, and processability TS-430 Low viscosity form of the TS-530, mith good processability TS- 830 Visocity is between TS.530 and TS.930 TS-930 Highest visocity ofthe TS-series. Suitable for expansion using large amounts of filer or oil in order to reduce costs TS~320 Loworchiorine content than general grades, with high hardness and good resistance to cold TS~340 Superior solubilly as an organic solvent CN-1500 Superior solubilty as an organic solvent extos F 7-801 0 Good resistance to cold, offering better dynamic fatigue resistance E7-8510. Similar to ET-2010 in allrespects, with good resistance to oil TOSOCSHFoeniveihnien exp chmpann hao TOSO-CSM® Applications Toso-csM* Applications ke Automotive parts Fuel hoses, power steering hoses, hydraulic hoses, brake hoses Electric parts, electric wire High-tension cables, ow-tension cables, communication cables, submarine cables, ship's wires, heat-resistant wire coverings, radioactive resistant cables General industrial articles High-pressure hoses, LPG hoses, chemical-esistant hoses, rolls, linings Escalator handrails, building gaskets Engineering and building articles pond lining sheets, roofing sheets Weather-resistant paints Others Rubber boats, rainwears, chemical-resistant gloves adhesives, paints, coatings extos® Applications extos® eee ks lr igen a a i SST a coverings for the weatherstrips Trin pets nero Enginooing and buing ances Bulking gosets bert orton manuacuing TOSO-CSM° Properties Grades ene Pee enemy Toso.cswe 100phr ‘MgO (High activity) 4 Pertoeryiol 3 ‘Accelerator DPTT 2 Mooney vscosty 7 eee se] o | m |] | a ] an 1B [Mooney Scorch £ | mayrsc BF] om aw | « | o | os | a | vw | 20 ror tonsiesressivnon} mea | ona] ora] re) 12) a0 | 33/43 soon tensiesressivon| wpa | 23] 24] 30| 29| «a | i25| a6 Tena strong) wpa | 206| 203] 20] ars) 306 | ter] 74 | conan attratceny | % | sso | sao | sao | szo | s20 | ao | azo g al E | varanasi) usa | se | ss | 57 | 97 | 0 | a2 | 55 & & | rontence « | «0 | a2 | x | a | os «| 4 4 foompecanear = Gmoennseote | % | 79 | 73 | a | oo | v2 | 03 | as oxame Olestsonce Fauna] % | a | so | 73 | 1 | ao | a5 | 200 Grange ao vane Tet eitnce Gorwisrwme wera | % | ase | tze | ast | ze | as | tae | 10 esta fr Ts resiuaractres | % | oo | oo | 5 | 1 | o | nm | oe Change in Hs pon | 42 8 a] oa] ia vo | a3 B | shox 160% mn | 2 | 2 | 2 | 2 | 2 | a5 | as : B | compressions eor | mn | 25 | 25 | 25 | 2 | a0 | «0 | 40 '& Figs ae proved nye lace and don tvs ay eae Spe extos® Properties erat Mooney vscosiy t ML (14) 100% ‘Mooney Scorch E | merase Z| vm 6 25 ac wm | ual ate 100% Tensile stess(Mi) | MPa 1 13 300% Tensile stress(Mioo) | MPa 2 27 Tensile swength(Ts) MPa 22. 18 Elongation at break(Es) % s70 | 540 : Hardness(Hs) JIS-A 56 56 § | poston «| | o & 5, 3 jon 361 (25% Compression, egg for % 70 70 Yow 21700 Oil resistance (Gstniank agra ex ors at1280] 260 | 184 Change rate in volume Heat resistance “Gag er fons 91070 % 56 67 Residual rate for Ts Residual rate for Ee % 65 68 Change in Hs point 2 +3 z ‘ Shost 160°C in 20 25 E | Compression set 160°C ‘min 25 30 "Figaro are provided ony az reference ane do it wave ae exae specials O80. oecranoudhiye era CenvevuadFoe TOSO-CSM" Chiorosulphonated Polyethylene @XtOS* Alkylated Chiorosulphonated Polyethylene ee eed Rg cod Acid acceptors | Magnesium Oxide -Starmag | Acid acceptors have to be added to CSM compound to ‘Synthetic Hydrotalcite catch & absorb acid when CSMis vulcanized Hisor 44 Reinforcing agents Carbon Black The effects of Carbon Black on vulcanized product are similar to other vulcanized rubber. They increase modulus and hardness and improve abrasion resistance. SRF, FEF, FT and MT are used frequently. With a decrease in the Particle Size, the Viscosity of the compounds, modulus and hardness of the vulcanized product are increased, working Reinforcing stability, elongation and rebound elasticity are decreased agents and Tensile Strength is increased slightly Silica Elongation and Tear Strength are increased but tensile strength and Abrasion Resistance are decreased when ‘compared with carbon black. Fillers rear Used as diluents for cutting down on expenses lay Talc Oils Phthalic acid derivatives The use of oils results in characteristics of low temperature Plasticizers: Fatty acid derivatives and flexibility of the vulcanized product. Alarger amount of Softeners Mineral oils oil is required for obtaining the vulcanized products having ‘Aromatic oils the same hardness as other vulcanized rubber products. Vegetable oils Naphthenic oil may be bled by adding an amount higher Rapeseed oil than 20 phr. When a large amount is to be used, aromatic oilorchlorinated paraffinis effective. Processing ald | Vaseline, microcrystalline ‘Added to improve the processability of compounds ‘wax, Low molecular p , ae weight polyethylene, (AC-617) Stearic acid Antone ‘Added to improve Ozone Resistance. NBC is used on gonerally. When NBC is used in an amount higher than 3 phr, the working stability isreduced caer ‘Added to give tackiness to compound. Aromatic oil or low molecular weight Cournarone Indene resin Blowing agents Used to make foaming products Flame retardants | Antimony Trioxide Chlorinated Paraffin ‘Aluminium Hydroxide TOSO-CSM*’ chiorosulphonated Polyethylene €XtOS* Aikylated Chlorosulphonated Polyethylene ied Be ue cay Thiuram vulcanization system + Dipentamethylenethiuram tetrasulfide, DPTT (TRA) ‘+ Tetramethytthiuramdisulfide, TMTD (TT) + Tetraethylthiuramdisulfide, TETD (TET) + + Pentaerythritol Merit '* Stability of compound during mixing process ‘Tensile strength + Elongation at break Demertt + Stability of compound under storage Compression set ‘+ Heat resistance * Discolour resistance Bismaleimide vulcanization system *'N, N'-m-phenylendimaleimide (Vulnoc PM) + ‘= Nickel dibutyldithiocarbonate (NBC) + 6-Ethoxy-2, 2, 4-trimethyl-1, 2-dihydroquinoline Merit ‘Heat resistance + Compression set Demerit * Stability of compound under storage * Stability of compound during rubber mixing process + Tensile strength * Elongation at break Peroxide vulcanization System + 1,3-bis (tert-butylperoxy isopropy!) benzene + ‘Trial isocyanurate (TAIL) Merit * Stability of compound under mixing process * Heat resistance * Compression set * Discolour resistance Demerit * Tensile strength ‘= Elongation at break ‘+ Handelling of peroxide + Smell of peroxide TOSO-CSM" Chiorosuiphonated Polyethylene extS* Akylated Chiorosulphonated Polyethylene Mixing CSM compounds are mixed in internal mixers and on roll mills. Internal mixers are preferred for speed and batch sizes. For small batches mill mixing is satisfactory. Internal Mixing ‘A: Upside-down Mixing (recommended) Ist stage (internal mixer) 1) Charging of all ingredients except accelerators, 2) Charging of CSM 3) Cleaning 4) Mixing 5) Dumping 6) Sheeting off 7) Cooling and storage 2nd stage (mixing roll) 8) Banding of compound 9) Charging of accelerator 10) Mixing to adequate distribution 11) Release at mil 12) Cooling and storage Mill Mixing 1) Mastication of COM 2) Charging of reinforcements (1/2) and acid acceptors 3) Charing of processing aids (1/2) 4) Charging of reinforcements (1/2) and processing aids (1/2) 5) Charging of filers and plasticizers 6) Charging of accelerators 7) Mixing to adequate distribution 8) Release at mill 9) Cooling and storage Notes on Mixing and storage Mixing (1) Internal mixing (1)The milling can be carried through normal procedure, however the up-side-down procedure is most effective, (2) Charging : 70 ~75% as a proportion standard (G) Scorching can be prevented by ) Controlling the temperature of dumped compound to a value of less than 100'%o 110°C ) Adding the vulcanizing agent and accelerator using the rolls ©) Cooling the compound. However when the compound is cooled by dipping it in cold water, the water that adheres should be completely removed and the sheets dried, (Q) Milling through rolls (1) Suppression of heat generation by passing cooling water through the rolls (2) The milling is facilitated by passing the thin sheet 3 to 5 passes through the rolls (3) Cool sheets quickly by reducing the thickness of sheet Storage of compounds + Mixed compounds should not be stored in conditions of high humidity. + Mixed compounds containing accelerators should be used immediately. * If the mixed compounds need to be stored, accelerators should be added just before use, Comparison of TOSO-CSM° with other synthetic rubbers = Blectrcal wire and cable i “Starmag 150 ‘TOSO-CSM™ TS-530 [100 phe ‘Special Wax tarmag 150, g ‘ACPE 6ITA special Wax z 3 ‘Sirukiol WE222 White Vaseine_ z 2 | -—~ reseemee : - TAF Carbon Tack i & ‘Hydrous Silica 3 Dixie clay 30 TOT i Mio vapour = ae Kites perce? T TAIC M-60_ x - ‘Chlorinated paraffin (C1:45%) TS Mooney Search ML-(1) 138 Antioxidant NBC, T = os einen z 3 wh Ez Resear DPTT Z TF TenTe HSS TWIT Wap oe ‘Accelerator DM 5 | Tease waght) Msp 30 Sp anes Seon EV TRC 4 ~__ Elongation at break (Eq) % 200 FE a a Hardness Ts) ISA | 78 = 5 Min | 18.6 z = a BT é $i campeon aging or 7h 1 LC) A Tensile strength (Tey MPa] 136 ¢ | Heat resistance (aging for TOhrsat 150) | —% | 92 = ‘Elongation at break (Fs) Residual rate for Ts & Hardness (Hs) Tesidual ate for ee & Compression Set al pest TTT min | a | eatresistnce (aging for 70hrs at ISOC) ])—caronsereoc sins i Residual eat for, “S| a ‘Residual rate for Fy 38 = Set TTC mL i Cera STC So Se EFIOTT Tp ‘Starmag 150 4 Fiydrotalcite KW2T00 2 ACHESITR z cl Wik + é Patjetiyiene glycol AWD 7 . rato) ANS z ia Culcined clay wo 2 FEF Curbon Black 30 5 “Light Caleium carbonate 30 Hydrowssilica————SSSC~wdC? © |e aT 3 5 Dos is OF 7 aC a aaa 5 TeaeTT =] 3 "Mooney Scorch ML (1) 1250. ‘Accelerator DPT. os = —- 5 Tileaniing agen FT > : —|— Money Sch ML () 1ST Te Tense sees M00) | ha | ae ise eae ae Tester —| we |5 = alae Test seg) ‘Mx | Te C “Elongation at break (Ea 30 Seg Pees Heng how + Png IWC XT “fae Tey WSAT[a Crain Pesta OF CX minX OP P Cooling 23°C X I min X 5 MPa Sy

    You might also like