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JEE Main 2023: Chemical Bonding PYQs

The document provides 10 questions regarding chemical bonding and molecular structure that appeared in the JEE Main 2023 January exam. It also includes the answer key for the questions as per the official NTA release. Students are encouraged to practice more chapter-wise questions from the MARKS app to prepare for JEE Main exams.

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0% found this document useful (0 votes)
431 views82 pages

JEE Main 2023: Chemical Bonding PYQs

The document provides 10 questions regarding chemical bonding and molecular structure that appeared in the JEE Main 2023 January exam. It also includes the answer key for the questions as per the official NTA release. Students are encouraged to practice more chapter-wise questions from the MARKS app to prepare for JEE Main exams.

Uploaded by

hindutavadi009
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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Chemical Bonding and Molecular Structure JEE Main 2023 (January) Chapter-wise Qs Bank

Questions with Solutions MathonGo

Q1 - 24 January - Shift 2

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Q2 - 25 January - Shift 1

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Q3 - 25 January - Shift 2

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Q4 - 25 January - Shift 2

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Q5 - 29 January - Shift 2

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Q6 - 30 January - Shift 1

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Q7 - 30 January - Shift 1

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Q8 - 30 January - Shift 2

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Q9 - 31 January - Shift 1

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Q10 - 31 January - Shift 2

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Answer Key
(As per Official NTA Key released on 2 Feb)

Q1 (1) Q2 (6) Q3 (4) Q4 (5)

Q5 (1) Q6 (4) Q7 (2) Q8 (4)

Q9 (4) Q10 (5)

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Q1 (1)

Q2 (6)

Q3 (4)

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Q4 (5)

Q5 (1)

Q6 (4)

Q7 (2)

Q8 (4)

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Q9 (4)

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Q10 (5)

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1. The number of species from the following which have square pyramidal structure is _______
− −
PF5 , BrF , IF5 , BrF5 , XeOF4 , ICl
4 4

[2023 (06 Apr Shift 1)]


2. The number of species having a square planar shape from the following is
2+ 2− 2−
− −
XeF4 , SF4 , SiF4 , BF4 , BrF4 , [Cu (NH3 ) ] , [FeCl4 ] , [PtCl4 ]
4

[2023 (06 Apr Shift 2)]


3. In an ice crystal, each water molecule is hydrogen bonded to _____ neighbouring molecules.
[2023 (06 Apr Shift 2)]
4. Given below are two statements : One is labelled as Assertion A and the other is labelled as Reason R .
Assertion A : Butan–1–ol has higher boiling point than ethoxyethane.
Reason R : Extensive hydrogen bonding leads to stronger association of molecules.
In the light of the above statements, choose the correct answer from the options given below :
[2023 (08 Apr Shift 1)]
(1) A is true but R is false
(2) Both A and R are true and R is the correct explanation of A
(3) Both A and R are true but R is not the correct explanation of A
(4) A is false but R is true
5. The number of following factors which affect the percent covalent character of the ionic bond is______
A) Polarising power of cation
B) Extent of distortion of anion
C) Polarisability of the anion
D) Polarising power of anion
[2023 (08 Apr Shift 1)]
6. The number of species trom the following carrying a single lone pair on central atom Xenon is
+ −
XeF , XeO3 , XeO2 F2 , XeF , XeO3 F2 , XeOF4 , XeF4
5 5

[2023 (08 Apr Shift 2)]


7. The pair from the following pairs having both compounds with net non-zero dipole moment is
[2023 (10 Apr Shift 1)]
(1) 1, 4 -Dichlorobenzene, 1, 3-Dichlorobenzene
(2) cis-butene, trans-butene
(3) CH2 Cl2 , CHCl3

(4) Benzene, anisidine


8. The compound which does not exist is
[2023 (10 Apr Shift 1)]
(1) NaO2

(2) BeH2

(3) PbEt4

(4) (NH4 )
2
BeF4

9. The number of bent-shaped molecule/s from the following is ______ N −

3
, NO

2
, I

3
, O3 , SO2

[2023 (10 Apr Shift 1)]


10. The sum of lone pairs present on the central atom of the interhalogen IF and IF is ______ 5 7

[2023 (10 Apr Shift 1)]


11. The number of molecules from the following which contain only two lone pair of electrons is _____________
H2 O, N2 , CO, XeF4 , NH3 , NO, CO2 , F2

[2023 (10 Apr Shift 2)]

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12. Match List-I with List-II:


List-I Species List-II Geometry/Shape
A. H3 O
+
I. Tetrahedral
B. Acetylide anion II. Linear
C. NH
+

4
III. Pyramidal
D. ClO

2
IV. Bent
Choose the correct answer from the options given below:
[2023 (11 Apr Shift 1)]
(1) A(III), B(IV), C(I), D(II)
(2) A(III), B(I), C(II), D(IV)
(3) A(III), B(II), C(I), D(IV)
(4) A(III), B(IV), C(II), D(I)
13. Which one of the following pairs is an example of polar molecular solids?
[2023 (11 Apr Shift 2)]
(1) SO2 ( s), CO2 ( s)

(2) SO2 ( s), NH3 ( s)

(3) MgO(s), SO2 (s)

(4) HCl(s), AlN(s)

14. The maximum number of lone pairs of electron on the central atom from the following species is ......
ClO
3
− , XeF4 , SF4 and l 3

[2023 (11 Apr Shift 2)]


15. The bond order and magnetic property of acetylide ion are same as that of
[2023 (12 Apr Shift 1)]
(1) O2
+

(2) N2
+

(3) NO
+

(4) O2

16. Given below are two statements:


Statement I: SbCl is more covalent than SbCl
5 3

Statement II: The higher oxides of halogens also tend to be more stable than the lower ones.
In the light of the above statements, choose the most appropriate answer from the options given below.
[2023 (12 Apr Shift 1)]
(1) Statement I is incorrect but statement II is correct
(2) Both Statement I and Statement II are incorrect
(3) Both Statement I and Statement II are correct
(4) Statement I is correct but statement II is incorrect
17. In which of the following processes, the bond order increases and paramagnetic character changes to diamagnetic one?
[2023 (13 Apr Shift 1)]
(1) O2 → O
+

(2) O2 → O
2−

(3) NO → NO
+

(4) N2 → N
+

18. ClF5 at room temperature is a


[2023 (13 Apr Shift 1)]
(1) Colourless liquid with trigonal bipyramidal geometry
(2) Colourless gas with square pyramidal geometry
(3) Colourless gas with trigonal bipyramidal geometry
(4) Colourless liquid with square pyramidal geometry

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19. Among the following compounds, the one which shows highest dipole moment is
[2023 (13 Apr Shift 1)]
(1)

(2)

(3)

(4)

20. Match Lis-I with List-II.


List-1 List-II
Hexamethylenediamine
A. Weak intermolecular forces of attraction I.
+ adipic acid
B. Hydrogen bonding II. AlEt3 + TiCl4

C. Heavily branched polymer III. 2 − chloro − 1, 3 − butadiene

D. High density polymer IV. Phenol + formaldehyde

Choose the correct answer from the options given below


[2023 (13 Apr Shift 2)]
(1) A-IV, B-II, C-III, D-I
(2) A-IV, B-I, C-III, D-II
(3) A-II, B-IV, C-I, D-III
(4) A-III, B-I, C-IV, D-II
21. Given below are two statements :
Statement I : SO and H
2 2
O both possess V-shaped structure
Statement II : The bond angle of SO is less than that of H
2 2O .
In the light of the above statements, choose the most appropriate answer from the options given below:
[2023 (13 Apr Shift 2)]
(1) Both Statement I and Statement II are incorrect
(2) Both Statement I and Statement II are correct
(3) Statement I is incorrect but Statement II is correct
(4) Statement I is correct but Statement II is incorrect
22. Consider the following statement
(A) NF molecules has a trigonal planar structure.
3

(B) Bond Length of N is shorter than O .


2 2

(C) Isoelectronic molecules or ions have identical bond order.


(D) Dipole moment of H 2S is higher than that of water molecule.
Choose the correct answer from the options given below:
[2023 (15 Apr Shift 1)]
(1) (A) and (B) are correct
(2) (A) and (D) are correct
(3) (C) and (D) are correct
(4) (B) and (C) are correct

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ANSWER KEYS
1. (3) 2. (4) 3. (4) 4. (2) 5. (3) 6. (4) 7. (3) 8. (1)
9. (3) 10. (1) 11. (3) 12. (3) 13. (2) 14. (3) 15. (3) 16. (3)
17. (3) 18. (4) 19. (4) 20. (4) 21. (4) 22. (4)

1. (3)

Among the given, IF 5; BrF5 and XeOF have squre pyramidal structure. VSEPR theory helps us to predict the shape of molecules from the
4

number of electron pairs and lone pairs of electrons that surrounds the central atoms.

2. (4)

XeF4 is sp 3
d
2
hybridised with two lone pairs of electrons, hence, it is square planar.
SF4 is sp 3
d hybridised with one lone pairs of electrons, hence, it is See saw.
SiF4 is sp hybridised with zero lone pairs of electrons, hence, it is Tetrahedral
3

BF4

is sp hybridised with zero lone pairs of electrons, hence, it is Tetrahedral
3

[Cu(NH3 ) ]
4
2+
is dsp hybridised and is Square planar
2

[FeCl4 ]
2–
is sp hybridised and is Tetrahedral
3

[PtCl4 ]
2–
is dsp hybridised and is Square planar
2

BrF4

is sp 3
d
2
with Square planar geometry.
So, 4 square planer shape compounds are present.

3. (4)

Hydrogen bonding occurs between hydrogen and strongly electronegative atoms like F, N, O . In water or ice hydrogen bonding occurs as there is
hydrogen as well as oxygen both are present. Water has 2 hydrogen atoms and 1 oxygen atom. The oxygen of one water molecule has two lone
pairs of electrons, each of which can form hydrogen bonds with hydrogen on other two water molecules.
Each water molecule is H-bonded to 4 neighbouring molecules.

4. (2)

Butan-1-ol can undergo hydrogen bonding due to the presence of an − OH group, ethoxyethane (also known as diethyl ether) can also participate
in hydrogen bonding.
Even though there are no hydrogen atoms directly bonded to a highly electronegative atom (like F, O, or N ) in ethoxyethane, the molecule still
has polar C − O bonds that can lead to dipole-dipole interactions with other polar molecules.
Owing to intermolecular hydrogen bonding in butanol, it has higher boiling point than ethoxyethane.

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5. (3)

The percentage of covalent character in an ionic bond is determined by the polarization power of the cation, the polarizing ability of the anion, and
the degree of distortion of the anion's electron cloud that occurs due to the electric field of the cation. The polarization power of a cation refers to
its ability to distort the electron cloud of the anion in the ionic bond. So the options A, B, C are correct.

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6. (4)

The central Xe atom in XeO has three bonding domains and one lone pair of electrons. Hence, the electron geometry is tetrahedral and molecular
3

geometry is pyramidal.
XeO2 F2 is trigonal bipyramidal and the shape is a see-saw.
XeOF4 is in square pyramidal shape.

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So, XeF +

5
, XeO3 , XeO2 F2 and XeOF have single lone pair on central atom.
4

7. (3)

The dipole moment is the vector sum of all the bond moments. The CH 2 Cl2 and CHCl both have net non-zero dipole moment because the bond
3

moments are not cancelled each other due to their tetrahedral structure. The 1, 4-dichlorobenzene, trans-butene, benzene have zero dipole moment
due to cancellation of bond moments. The 1, 3-dichlorobenzene, cis-butene, anisidine has non-zero dipole moment.

8. (1)

Oxide and peroxides of sodium are stable (Na 2 O and Na 2 O2 ) K, Rb, Cs form superoxides. Beryllium forms a hydride with molecular formula
BeH2 Organic lead (tetraethyl lead; TEL) is used as an antiknock agent in gasoline and jet fuels. The compound (NH 4)
2
BeF4 on thermal
decomposition produces BeF and NH 2 4 F .

9. (3)

+ +

N (Azide): ¯
¯
N¯ = N = ¯
¯
N¯ ↔ ¯
¯
N¯− N ≡ N
3

It has sp hybridised central atom. Hence it is linear in shape.


I

3
(triiodide):

It has linear geometry, sp 3


d hybridisation with three lone pairs at central atom.

NO

2
(nitrite) :
It is (nonlinear) bent shaped as it has sp hybridisation with one lone pair at central atom.
2

O3 (ozone) :
It Is bent in shape with sp hybridisation and one lone pair at central atom.
2

SO2 (sulphur dioxide) :

It is bent in shape with sp hybridisation and one lone pair at central atom.
2

So 3 among the given molecules is bent in shape.

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10. (1)

In IF , the central atom is iodine, which has 7 valence electrons. Iodine in this molecule has 5 bonding pairs and 1 lone pair. Therefore, the number
5

of lone pairs on the central atom of IF is 1.


5

In IF , the central atom is also iodine, which has 7 valence electrons. Iodine in this molecule has 7 bond pairs and 0 lone pairs. Therefore, the
7

number of lone pairs on the central atom of IF is 0.


7

Therefore, the sum of the number of lone pairs in the central atom of IF and IF is 1 + 0 = 1..
5 7

11. (3)
The lone pair of electrons can be identified by drawing structure of the given moleules as follows,

The number of molecules having only 2 lone pair of electrons = 3

Which are H 2
O, N2 and CO. XeF have 2 lone pairs on central atom, but we are asked about lone pair in molecule
4

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12. (3)
The molecular geometry of H 3
O
+
is pyramidal. It consists of three hydrogen atoms bonded to the central oxygen atom, with one lone pair of electrons on the
oxygen atom.
The acetylide ion consists of two carbon atoms bonded together by a triple bond (C ≡ C) with a lone pair of electrons on the terminal carbon atom. So it is
linear.
The NH 4
+
ion consists of a central nitrogen atom bonded to four hydrogen atoms. It is tetrahedral.
The ClO ion is bent in shape due to its molecular geometry. It consists of one central chlorine atom bonded to two oxygen atoms, with an additional lone pair

of electrons on the central chlorine atom.


(A) H 3O
+
→ (III) Pyramidal

(B) Acetylide ion → (II) Linear

(C) NH ion →
+

4
(I) Tetrahedral

(D) ClO ion →


2
(IV) Bent

13. (2)
SO2 is a bent molecule with a central sulfur atom bonded to two oxygen atoms. The oxygen atoms are more electronegative than sulfur, causing a separation of
charge. This results in a bent molecular geometry and a net dipole moment, making SO a polar molecule.2

NH3 is a trigonal pyramidal molecule with a central nitrogen atom bonded to three hydrogen atoms. Again, the electronegativity difference between nitrogen and
hydrogen leads to a separation of charge. The arrangement of the atoms in NH gives it a net dipole moment, making it a polar molecule.
3

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14. (3)
ClO3

: The central atom is Cl, there is one lone pair of electrons on the central atom.
XeF4 : The central atom is Xe. It has two lone pair on central atom.
SF4 : The central atom is S. It contains one lone pair on central atom.
I3

: It contains three lone pair on central atom.

15. (3)
The bond order of the acetylide ion HC ≡ C is 3, indicating a triple bond between the carbon atoms.

The acetylide ion consists of two carbon atoms with a triple bond between them and a negative charge. In the triple bond, there are six bonding electrons (two pi
bonds and one sigma bond) and zero antibonding electrons.
Among the given options NO will have the same bond order and magnetic property like acetylide ion.
+

Species Bond Order Magnetic moment



HC ≡ C 3 0

+
O2 2. 5 √3 B. M

+
N2 2. 5 √3 B. M

+
NO 3 0


O2 1. 5 √3 B. M

16. (3)
The oxidation state of +5 in pentahalides is more covalent as compared to the +3 oxidation state in trihalides. Due to the higher positive oxidation state of the
central atom in pentahalide state, these atoms will have larger polarising power than the halogen atom attached to them since the polarising power is directly
proportional to the charge. More is the polarisation, larger will be the covalent character of the bond. Hence, due to larger polarisation of bond in pentahalide
state as compared to trihalide state, the SbCl is more covalent than SbCl .
5 3

Higher oxides of halogens are more stable than lower ones due to the formation of more number of bonds, which results in higher release of energy. So, both the
statements I and II are correct.
17. (3)
Change in Bonad order
Process
magnetic nature change
N2 → N
+

2
Dia → Para 3 → 2. 5

NO → NO
+
Para →Dia 2. 5 → 3

O2 → O
−2

2
Para→ Dia 2 → 1

O2 → O
+

2
Para → Para 2 → 2. 5

18. (4)
Chlorine pentafluoride is an inter halogen compound. ClF is colourless liquid. The central chlorine atom is having five bond pairs and one lone pair on it.
5

Hence, according to VSEPR theory it has square pyramidal geometry. It is toxic by inhalation and an irritant to skin, eyes and mucus membranes.

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19. (4)
The compound which possess aromatic character will show highest dipole moment. From the given compounds the following compound will have the highest
dipole moment. Because the Positive and negative ends acquire aromaticity.

20. (4)
(A) Weak Intermolecular Forces are present in polymer of 2−chloro, 1, 3− butadiene.It is a monomer of neoprene which is a rubber(elastomer.).
(B). Hydrogen Bonding is present in NYLON−6, 6 which is a polymer of Hexamethylenediamine and adipic acid. This hydrogen bonding is due to the presence
of amide group.
(C) Heavily branched polymer is Bakelite which is polymer of phenol and formaldehyde. It is a crosslinked polymer.
(D) High density polymer(polyethylene) preparation requires Al(Et) and TiCl as a catalyst (Ziegler Natta Catalyst)
3 4

21. (4)
The molecule SO is having two sigma bond pairs and lone pair, hence, it exhibits angular or V-shape structure. The molecule H
2 2O is having two sigma bond
pairs and a lone pair hence, it exhibits angular or V-shape structure. So, both molecules are having same shape. But double bond-double bond repulsions are
greater than single bond repulsions, hence, the bond angle in sulphur dioxide is greater than water.

SO2 and H 2O both have V-Shape


Bond angle: SO 2 > H2 O

22. (4)
In NF , nitrogen is having three bond pairs and a lone pair, hence, it has pyramidal shape.
3

The bond order of N 2


= 3, and The bond order of O 2
= 2 . Bond length is inversely related to bond order. Hence, bond length of N is shorter than O
2 2

Isoelectronic species have identical bond order

Dipole moment of H 2O is more than that of H 2S due to higher electronegativity of O.

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Q1 - 24 June - Shift 2

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Q2 - 25 June - Shift 1

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Q3 - 25 June - Shift 2

Space for your notes:

Q4 - 26 June - Shift 1

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Q5 - 26 June - Shift 2

Space for your notes:

Q6 - 26 June - Shift 2

Space for your notes:

Q7 - 27 June - Shift 1

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Q8 - 27 June - Shift 2

Space for your notes:

Q9 - 27 June - Shift 2

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Q10 - 28 June - Shift 1

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Q11 - 28 June - Shift 2

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Q12 - 29 June - Shift 1

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Q13 - 29 June - Shift 2

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Q14 - 29 June - Shift 2

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Answer Key

Q1 (B) Q2 (C) Q3 (3) Q4 (A)

Q5 (B) Q6 (3) Q7 (B) Q8 (C)

Q9 (C) Q10 (1) Q11 (A) Q12 (C)

Q13 (B) Q14 (C)

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Q1 (B)

Q2 (C)

Q3 (3)

Q4 (A)

Q5 (B)

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Q6 (3)

Q7 (B)

Q8 (C)

Q9 (C)

Q10 (1)

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Chemical Bonding and Molecular Structure JEE Main 2022 (June) Chapter-wise Qs Bank
Hints and Solutions MathonGo

Q11 (A)

Q12 (C)

Q13 (B)

Q14 (C)

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Chemical Bonding and Molecular Structure JEE Main 2022 (June) Chapter-wise Qs Bank
Hints and Solutions MathonGo

#MathBoleTohMathonGo
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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Q1 - 25 July - Shift 1

Space for your notes:

Q2 - 25 July - Shift 2

Space for your notes:

Q3 - 25 July - Shift 2

Space for your notes:

Q4 - 25 July - Shift 2

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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Space for your notes:

Q5 - 26 July - Shift 1

Space for your notes:

Q6 - 26 July - Shift 2

Space for your notes:

Q7 - 27 July - Shift 1

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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Space for your notes:

Q8 - 27 July - Shift 1

Space for your notes:

Q9 - 27 July - Shift 1

Space for your notes:

Q10 - 27 July - Shift 2

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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Space for your notes:

Q11 - 27 July - Shift 2

Space for your notes:

Q12 - 28 July - Shift 1

Space for your notes:

Q13 - 28 July - Shift 2

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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Space for your notes:

Q14 - 29 July - Shift 1

Space for your notes:

Q15 - 29 July - Shift 2

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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Space for your notes:

#MathBoleTohMathonGo
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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Answer Key

Q1 (2) Q2 (A) Q3 (B) Q4 (3)

Q5 (C) Q6 (B) Q7 (A) Q8 (4)

Q9 (3) Q10 (C) Q11 (6) Q12 (4)

Q13 (A) Q14 (B) Q15 (4)

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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Hints and Solutions MathonGo

Q1 (2)

Q2 (A)

Q3 (B)

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Hints and Solutions MathonGo

Q4 (3)

Q5 (C)

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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Hints and Solutions MathonGo

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Chemical Bonding and Molecular Structure JEE Main 2022 (July) Chapter-wise Qs Bank
Hints and Solutions MathonGo

Q6 (B)

Q7 (A)

Q8 (4)

Q9 (3)

Q10 (C)

Q11 (6)

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Hints and Solutions MathonGo

Q12 (4)

Q13 (A)

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Hints and Solutions MathonGo

Q14 (B)

Q15 (4)

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Hints and Solutions MathonGo

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Chemical Bonding and Molecular Structure JEE Main 2021 (August) Chapter-wise Questions
Questions with Answer Keys MathonGo

Q1 2021 (01 Sep Shift 2)

The spin-only magnetic moment value of B +

species is ____ ×10 −2


BM . (Nearest integer)

[Given : √3 = 1.73 ]

Q2 2021 (01 Sep Shift 2)

Number of paramagnetic oxides among the following given oxides is ____.

Li2 O, CaO, Na2 O2 , KO2 , MgO and K 2O

(1) 1
(2) 2

(3) 3
(4) 0

Q3 2021 (31 Aug Shift 2)

According to molecular orbital theory, the number of unpaired electron(s) in O 2−

2
is :

Q4 2021 (27 Aug Shift 2)

The number of species having non-pyramidal shape among the following is ____.
(A) SO 3

(B) NO

(C) PCl 3

(D) CO 2−

Q5 2021 (27 Aug Shift 2)

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Chemical Bonding and Molecular Structure JEE Main 2021 (August) Chapter-wise Questions
Questions with Answer Keys MathonGo

The compound/s which will show significant intermolecular H-bonding is/are :

(1) (b) only


(2) (c) only
(3) (a) and (b) only
(4) (a), (b) and (c)

Q6 2021 (26 Aug Shift 2)

The bond order and magnetic behaviour of O ion are, respectively :


(1) 1.5 and paramagnetic


(2) 1.5 and diamagnetic
(3) 2 and diamagnetic
(4) 1 and paramagnetic

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Chemical Bonding and Molecular Structure JEE Main 2021 (August) Chapter-wise Questions
Questions with Answer Keys MathonGo

Q7 2021 (26 Aug Shift 2)

The interaction energy of London forces between two particles is proportional to r , where r is the distance
x

between the particles. The value of x is :

(1) 3
(2) −3

(3) −6
(4) 6

Q8 2021 (26 Aug Shift 1)

AB3 is an interhalogen T-shaped molecule. The number of lone pairs of electrons on A is ____. (Integer
answer)

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Chemical Bonding and Molecular Structure JEE Main 2021 (August) Chapter-wise Questions
Questions with Answer Keys MathonGo

Answer Key

Q1 (173) Q2 (1) Q3 (0) Q4 (3)

Q5 (1) Q6 (1) Q7 (3) Q8 (2)

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Chemical Bonding and Molecular Structure JEE Main 2021 (August) Chapter-wise Questions
Hints and Solutions MathonGo

Q1 (173)

+ 2 ∗2 2 ∗2 1 0
B ⇒ σ σ σ σ π ≃ π
2 1 s 1s 2s 2 s 2py 2pz


⇒ 9e

μ = √1(1 + 2) = √3 BM

= 1.73 BM

−2
= 1.73 × 10 BM

Q2 (1)
+ 2−
Li2 O ⇒ 2Li O

2+ 2−
CaO ⇒ Ca O

+ 2−
Na2 O2 ⇒ 2Na O
2

+ −
KO2 ⇒ K O
2

2+ 2−
MgO ⇒ Mg O

+ 2
K2 O ⇒ 2 K O

O

2
⇒ Complete octet, diamagnetic
2 2 ∗2 2 ∗2 2 2 2 ∗2 ∗2
O ⇒ σ σ σ σ σ π ≃ π π ≃ π (dia)
1s 1s 2 s 2 s 2px 2py 2pz 2py 2pz

O

2
⇒ σ
2
1 s
σ
∗2
1s
σ
2
2 s
σ
∗2
2 s
σ
2px
2
π
2
2py
≃ π
2
2pz
π
∗2
2py
≃ π
∗1

2pz
( para )

Q3 (0)

Molecular orbital configuration of O is


2−

2 ∗2 2 ∗2 2 2 ∗2 ∗2
σ σ σ σ (π2px = π2py ) (π = π )
1 s 1 s 2 s 2 s 2px 2py

Zero unpaired electron

Q4 (3)

Trigonal planar

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Chemical Bonding and Molecular Structure JEE Main 2021 (August) Chapter-wise Questions
Hints and Solutions MathonGo

Trigonal planar

Trigonal planar

Pyramidal
Hence non-pyramidal species are SO 3, NO

3
and
CO
2−

3
.

Q5 (1)

(a) Shows intra molecular H−bonding


(b) Shows significant intermolecular H−bonding
(c) It do not show intermolecular H−bonding due to steric hindrance.

Q6 (1)

− 2 2 2 2 2
∗ ∗
O = (σ1 s) (σ ) (σ2 s) (σ ) (σ2p )
2 1 s 2 s z

2 2 ∗2 ∗1
(π = π ) (π = π )
2px 2py 2px 2py

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Chemical Bonding and Molecular Structure JEE Main 2021 (August) Chapter-wise Questions
Hints and Solutions MathonGo

10−7
Bond order = 2
= 1.5

and paramagnetic.

Q7 (3)

For london dispersion forces.


1
E ∝ 6
r

Hence x = −6

Q8 (2)

T-shaped molecule means 3 sigma bond and 2 lone pairs of electron on central atom.

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Chemical Bonding and Molecular Structure JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

Q1 (20 July 2021 Shift 1)

The number of lone pairs of electrons on the central I atom in I is ___


Q2 (20 July 2021 Shift 2)

The hybridisations of the atomic orbitals of nitrogen in NO −

2
, NO
+

2
and NH respectively are.
+

(1) sp 3
, sp
2
and sp

(2) sp, sp and sp


2 3

(3) sp 3
, sp and sp 2

(4) sp 2
, sp and sp 3

Q3 (22 July 2021 Shift 1)

Match List-I with List-II :

Choose the correct answer from the options given below:

(1) (a)-( i), (b)-( ii), (c)-(v) and (d)-(iii)

(2) (a)-(ii), (b)-(i), (c)-(iv) and (d)-(v)


(3) (a)-(iii), (b)-(i), (c)-( v) and (d)-(iv)
(4) (a)-(iv), (b)-(iii), (c)-(ii) and (d)-(v)

Q4 (25 July 2021 Shift 2)

In the following the correct bond order sequence is:

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Chemical Bonding and Molecular Structure JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

(1) O
2− + −
> O > O > O2
2 2 2

(2) O +

2
> O

2
> O
2−

2
> O2

(3) O +

2
> O2 > O

2
> O
2−

(4) O
− 2− +
2 > O > O > O
2 2 2

Q5 (25 July 2021 Shift 2)

Identify the species having one π -bond and maximum number of canonical forms from the
following :

(1) SO 3

(2) O 2

(3) SO 2

(4) CO
2−

Q6 (27 July 2021 Shift 1)

Given below are two statements: One is labelled as Assertion A and the other labelled as Reason R.
Assertion A : Lithium halides are some what
covalent in nature.
Reason R : Lithium possess high polarisation capability.
In the light of the above statements, choose the most appropriate answer from the options given below:

(1) A is true but R is false


(2) A is false but R is true
(3) Both A and R are true but R is NOT the
correct explanation of A
(4) Both A and R are true and R is the correct explanation of A

Q7 (27 July 2021 Shift 1)

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Chemical Bonding and Molecular Structure JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

In gaseous triethyl amine the "-C-N-C-" bond


angle is ______ degree.

Q8 (27 July 2021 Shift 1)

The difference between bond orders of CO and


NO

is x

2
where x =
(Round off to the Nearest Integer)

Q9 (27 July 2021 Shift 2)

The total number of electrons in all bonding

molecular orbitals of O is ........


2−

(Round off to the nearest integer)

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Chemical Bonding and Molecular Structure JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

Answer Key

Q1 (3) Q2 (4) Q3 (3) Q4 (3)

Q5 (4) Q6 (4) Q7 (108) Q8 (0)

Q9 (10)

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Chemical Bonding and Molecular Structure JEE Main 2021 (July) Chapter-wise Questions
Hints and Solutions MathonGo

Q1

I

3
:

The number of lone pairs of electron on the central atom is 3.

Q2

Q3

(a) SF 4− sp 3
d hybridisation
(b) IF 5 − sp
3
d
2
hybridisation
(c) NO +

2
− sp hybridisation

(d) NH +

4
− sp
3
hybridisation

Q4

O2 (16 electrons) σ 2
1s

∗2
1s

2
2s

∗2
2s

2
2p2

2 2 ∗1 ∗1 ∗
π = π ,π = π ,σ
2px 2py 2p 2py 2p
y x y p

Bond order of O 2 ⇒ 2

Bond order of O −

2
⇒ 1.5

Bond order of O
2−

2
⇒ 1

Bond order of O
+

2
⇒ 2.5

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Chemical Bonding and Molecular Structure JEE Main 2021 (July) Chapter-wise Questions
Hints and Solutions MathonGo

Q5

Among SO 3, O2 , SO2 and CO , only O and


2−

3
2

has only one π -bond


2−
CO
3

Q6

Lithium due to small size has very high


polarization capability and thus increases covalent nature in Halides.

Q7

In gaseous triethyl amine the "-C-N-C-" bond


angle is 108 degree.

Q8

Bond order of CO = 3

Bond order of NO +
= 3

Difference = 0 =
x

x = 0

Q9

M. O. Configuration of O 2−

2
( (18e )
¯
¯¯

2 2 2 2 2 2 2
σ1 s σ1 s σ2 s σ2 s σ2pz π2px = π2py

2 2
π2px = π2py

Total B.M.O electrons = 10

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Chemical Bonding and Molecular Structure JEE Main 2021 (March)
Questions with Answer Keys MathonGo

Q1: 16 March (Shift 1) - Single Correct

Given below are two statements: one is labelled as Assertion A and the other is labelled as

Reason R :

Assertion A : The H − O − H bond angle in water molecule is 104.5 ∘

Reason R : The lone pair − lone pair repulsion of electrons is higher than the bond pair - bond pair repulsion.

(1) A is false but R is true

(2) Both A and R are true, but R is not the correct correct explanation of A

(3) A is true but R is false


(4) Both A and R are true, and R is the correct explanation of A

Q2: 17 March (Shift 1) - Single Correct

A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The shape of this

molecule is:

(1) see-saw

(2) planar triangular


(3) T-shaped

(4) trigonal pyramidal

Q3: 17 March (Shift 2) - Single Correct

Amongst the following, the linear species is:

(1) NO 2

(2) Cl 2O

(3) O 3

(4) N −

Q4: 18 March (Shift 1) - Numerical

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Chemical Bonding and Molecular Structure JEE Main 2021 (March)
Questions with Answer Keys MathonGo

AX is a covalent diatomic molecule where A


and X are second row elements of periodic table. Based on Molecular orbital theory, the bond order of AX is
25 . The total number of electrons in AX is____( Round off to the

Nearest Integer).

Q5: 18 March (Shift 2) - Single Correct

The oxide that shows magnetic property is :

(1) SiO 2

(2) Mn 3 O4

(3) Na 2O

(4) MgO

Q6: 18 March (Shift 2) - Single Correct

In the following molecules,

Hybridisation of carbon a, b and c respectively


are :

(1) sp 3
, sp, sp

(2) sp 3 2
, sp , sp

(3) sp 3 2
, sp , sp
2

(4) sp 3
, sp, sp
2

Q7: 18 March (Shift 2) - Numerical

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Chemical Bonding and Molecular Structure JEE Main 2021 (March)
Questions with Answer Keys MathonGo

The number of species below that have two


lone pairs of electrons in their central atom is_______
(Round off to the Nearest integer)

SF4 , BF , CIF3 , AsF3 , PCl5 , BrF5 , XeF4 , SF6
4

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Chemical Bonding and Molecular Structure JEE Main 2021 (March)
Questions with Answer Keys MathonGo

Answer Key

Q1 (4) Q2 (3) Q3 (4) Q4 (15)

Q5 (2) Q6 (3) Q7 (2)

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Chemical Bonding JEE Main 2021 (February)
Questions with Answer Keys MathonGo

Q1: 24 Feb (Shift 1) - Single Correct

Which of the following are isostructural pairs?

(A) SO 2−

4
and CrO 2−

(B) SiCl and TiCl 4 4

(c) NH and NO
3

(D) BCl and BrCl 3 3

(1) A and C only

(2) A and B only


(3) B and C only

(4) C and D only

Q2: 24 Feb (Shift 2) - Single Correct

The correct shape and I-I-I bond angles respectively in I ion are :

(1) Trigonal planar; 120 ∘

(2) Distorted trigonal planar; 135 and 90 ∘ ∘

(3) Linear; 180 ∘

(4) T-shaped; 180 and 90 ∘ ∘

Q3: 25 Feb (Shift 1) - Single Correct

According to molecular orbital theory, the species among the following that does not exist is:

(1) He −

(2) He 2
+

(3) O 2−

(4) Be 2

Q4: 25 Feb (Shift 2) - Single Correct

Which among the following species has unequal bond lengths ?

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Chemical Bonding JEE Main 2021 (February)
Questions with Answer Keys MathonGo

(1) XeF 4

(2) SiF 4

(3) BF 4

(4) SF 4

Q5: 26 Feb (Shift 1) - Single Correct

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : Dipole-dipole interactions are the only non-covalent interactions, resulting in hydrogen bond
formation
Reason R : Fluorine is the most electronegative element and hydrogen bonds in HF are symmetrical In the
light of the above statements, choose the most appropriate answer from the options given below :

(1) A is false but R is true


(2) Both A and R are true and R is the correct explanation of A
(3) A is true but R is false
(4) Both A and R are true and R is not the correct explanation of A

Q6: 26 Feb (Shift 2) - Single Correct

Match List-I with List-II.

Choose the correct answer from the options given below:

(1) (a) − (iii), (b) − (iv), (c) − (i), (d) − (iii)


(2) (a) − (i), (b) − (ii), (c) − (iii), (d) − (iv)
(3) (a) − (ii), (b) − (i), (c) − (iv), (d) − (iii)

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Chemical Bonding JEE Main 2021 (February)
Questions with Answer Keys MathonGo

(4) (a) − (iv), (b) − (iii), (c) − (ii), (d) − (i)

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Chemical Bonding JEE Main 2021 (February)
Questions with Answer Keys MathonGo

Answer Key

Q1 (2) Q2 (3) Q3 (4) Q4 (4)

Q5 (3) Q6 (1)

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Chemical Bonding JEE Mains 2020 Jan Chapter wise Question Bank

JEE Mains 2020 Jan Chapter wise Question Bank

Chemical Bonding

Q1

7th Jan Morning

Sol

Q2

7th Jan Morning

Sol

Q3
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Chemical Bonding JEE Mains 2020 Jan Chapter wise Question Bank

7th Jan Evening

Sol

Q4

8th Jan Morning

Sol

Q5

8th Jan Evening

Sol

Q6

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Chemical Bonding JEE Mains 2020 Jan Chapter wise Question Bank
8th Jan Evening

Sol

Q7

9th Jan Morning

Sol

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BITSAT & other competitive exams. All the subjects are included. Tap on the banner.

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question papers from our website. Visit www.mathongo.com now!
Chemical Bonding JEE Mains 2019 Chapter wise Question Bank

JEE Mains 2019 Chapter wise Question Bank


Chemical Bonding - Questions

Q1

9 April Morning

Q6

9 Jan Morning

Q2
9 April Evening

Q7

9 Jan Evening 10 April Morning

Q3 Q8

10 Jan Morning

Q4 12 April Morning

8 April Evening

Q5

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Chemical Bonding JEE Mains 2019 Chapter wise Question Bank

JEE Mains 2019 Chapter wise Question Bank


Chemical Bonding - Solutions

Q1
Q4

9 Jan Morning

Q2
8 April Evening

Q5

9 Jan Evening

Q3

9 April Morning

Q6

10 Jan Morning
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Chemical Bonding JEE Mains 2019 Chapter wise Question Bank

9 April Evening

Q7

10 April Morning

Q8

12 April Morning

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