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Chapter 6
Neutralizing the Threat of Acid Rain
A proton is an H+.
Remember that you must balance the equation and have proper charges on the ions.
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Chapter 6-Neutralizing the Threat of Acid Rain
4. When dissolved in water, hydrogen bromide (HBr) forms hydrobromic acid. Determine
the hydroxide ion concentration in a 4,500 mL solution containing 3.78 g hydrogen
bromide; Kw = 1.00 × 10¯14.
A. 0.0001
B. 0.001
C. 0.429
D. 10,000
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Chapter 6-Neutralizing the Threat of Acid Rain
A. nitrogen
B. ozone
C. oxygen
D. carbon dioxide
A. carbon oxides
B. phosphoric acid and hydrochloric acid
C. ozone and carbon monoxide
D. nitrogen oxides and sulfur oxides
8. Coal is not a pure chemical compound, but its elemental composition can be
approximated by the formula C135H96NO9S. What is the approximate percentage by
mass of sulfur in coal?
A. 0.413%
B. 1.68%
C. 3.11%
D. 42.8%
Remember to take the total mass of carbon divided by the total mass of the molecule.
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Chapter 6-Neutralizing the Threat of Acid Rain
9. Calculate the amount of sulfur dioxide produced annually by a power plant that burns
7.5 million metric tons (t) of coal over a year. Assume that the coal is 2.4% sulfur by
mass. 1 metric ton (t) = 1000 kg.
A. 3.6 × 108 kg
B. 3.6 × 108 t
C. 1.8 × 1011 kg
D. 7.5 × 1012 g
Each sulfur combines with two oxygens doubling the mass of the sulfur in the coal.
10. Sulfur oxides have been implicated as important contributors to the problem of acid
rain. What is the principal anthropogenic source of these compounds?
A. transportation
B. coal fired power plants
C. lightning
D. volcanoes
11. The formation of nitric oxide (NO, a precursor to nitric acid) from oxygen and nitrogen
is ordinarily a very slow process. What accounts for its more rapid formation in
automobile exhaust?
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Chapter 6-Neutralizing the Threat of Acid Rain
12. A proton released by an acid in aqueous solution quickly reacts with water to form a
hydronium ion. What product is formed when a proton reacts with ammonia (NH3)?
A. NH3+
B. NH4
C. NH2¯
D. NH4+
Just add the hydrogen and its charge to the ammonia molecule.
13. The hydronium ion concentration in a solution with pH 10 is __________ than the
hydronium ion concentration in a solution with pH 13.
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Chapter 6-Neutralizing the Threat of Acid Rain
A. 0.017
B. 1.77
C. 9.22
D. 12.23
Find the hydroxide ion concentration, then the pOH then take 14 - pOH = pH
15. The pH of lemon juice is approximately 2.40. At this pH, the hydronium ion
concentration is closest to which concentration?
A. 2.5 × 10¯12 M
B. 4.0 × 10¯3 M
C. 0.38 M
D. 5.6 × 10¯4 M
A. converting oil or natural gas power plants to coal because coal is cheaper.
B. pulverizing coal in order to make it burn more efficiently.
C. converting coal power plants to oil or natural gas to reduce SOx emissions.
D. using coal with a lower sulfur content to reduce SOx emissions.
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Chapter 6-Neutralizing the Threat of Acid Rain
17. The Clean Air Act Amendments of 1990 authorize the assignment of permits to
corporations allowing a predetermined level of sulfur dioxide emissions. Permit holders
that keep emissions below the permit level may
A. orange juice
B. rain
C. a sulfuric acid solution
D. a lye solution
19. Which reaction most accurately represents the dissociation of nitrous acid (HNO2) in
water?
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Chapter 6-Neutralizing the Threat of Acid Rain
A. KNO3 + H2O
B. KNO2 + H2O2
C. KH + HNO4
D. KO4 + H2N
A. I only
B. II only
C. I and III only
D. II and III only
22. The acid neutralizing capacity of a lake or stream most often derives from the presence
of _______ in the surrounding soil or rock.
A. CaCO3
B. HNO3
C. NaCl
D. Sr(OH)2
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Chapter 6-Neutralizing the Threat of Acid Rain
23. One of the functions of an automobile catalytic converter contributes to the battle
against acid rain. Which reaction represents this function as carried out by a catalytic
converter?
24. Cars and trucks produce most of the NOx emissions and they also suffer the deleterious
effects of acid rain. Which negative effects of acid rain affect cars and trucks?
I. decreased gas mileage
II. damage to the paint and finish
III. increased susceptibility to rust
IV. reduced radio reception
A. I and II only
B. I and IV only
C. II and III only
D. III and IV only
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Chapter 6-Neutralizing the Threat of Acid Rain
A. CH2O3
B. CO
C. CH2O
D. CHO2
A. OH¯
B. NO2¯
C. Cl¯
D. SO3¯
Remember that acid and base make water and salt in a neutralization.
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Chapter 6-Neutralizing the Threat of Acid Rain
28. Why have efforts to reduce sulfur oxide emissions met with greater success than those
directed at nitrogen oxide emissions reductions?
A. H2S
B. H2SO4
C. H2SO3
D. SO2
30. What is the current expert consensus concerning the role of acid rain on the health of
forests?
A. Acid rain is indisputably responsible for the declining health of many forests.
B. Acid rain is not responsible for any of the decline observed in many forests.
C. Acid rain weakens trees and the surrounding soil, leaving them susceptible to
disease and insects.
D. There is not sufficient evidence that acid rain has caused an appreciable decline in
the health of any forests.
There are many factors at play and acid rain is a large factor.
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Chapter 6-Neutralizing the Threat of Acid Rain
31. Which statement(s) concerning SOx and NOx emissions are true?
I. Automobiles produce NOx but very little SOx.
II. Power plants produce only SOx.
III. Diesel powered vehicles produce only SOx.
IV. The high concentration of nitrogen compounds in gasoline accounts for the
formation of NOx by automobiles and trucks.
A. I only
B. I and II only
C. II and IV only
D. I, II, III, and IV
Remember that nitrogen oxides occur any time there are high temperatures and air.
A. the mid-1750s.
B. the mid-1850s.
C. 1900.
D. the mid-1950s.
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Chapter 6-Neutralizing the Threat of Acid Rain
33. Sulfur dioxide, the primary product of sulfur combustion, further reacts with oxygen as
shown.
2 SO2 + O2 → 2 SO3
What is the final step in the formation of the acidic aerosol?
A. MOH¯ = 0.0065 M
B. MH+ = 1.27 × 10¯9 M
C. MH+ = 5.79 × 10¯10 M
D. MOH¯ = 1.77 × 10¯10 M
A. NO
B. NaNO2
C. N2
D. NH3
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Chapter 6-Neutralizing the Threat of Acid Rain
A. conversion of NO to NO2
B. conversion of nitrogen oxides to nitric acid
C. conversion of N2 to NO2¯
D. conversion of NH4+to NO3¯
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Chapter 6-Neutralizing the Threat of Acid Rain
39. Why did the industrial-scale production of ammonia from nitrogen and hydrogen
present a difficult challenge?
A. Ammonia is explosive.
B. Nitrogen is difficult to purify.
C. Nitrogen is unreactive.
D. Hydrogen is unreactive.
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Chapter 6-Neutralizing the Threat of Acid Rain
40. Calculate the percentage decease in NOx emissions after clean coal technology was
installed at the Milliken power station.
A. 0.39%
B. 39%
C. 61%
D. 156%
This is not over 100% and can be found by taking the difference in levels divided by
the original level.
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Chapter 6-Neutralizing the Threat of Acid Rain
41. What is the source of the nitrogen in the NOx emitted from fossil fuel combustion?
A. the atmosphere
B. coal
C. natural gas
D. oil
42. In addition to fossil fuel combustion, what other facet of modern industrial society
contributes to the formation of acid rain?
43. The pH of rain water falling through an unpolluted atmosphere is closest to:
A. 4.7
B. 5.4
C. 7.0
D. 8.7
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Chapter 6-Neutralizing the Threat of Acid Rain
44. If acids are compounds that release protons (H+), how is it that SOx and NOx cause acid
rain?
45. Which reaction illustrates how acid rain causes the decomposition of marble
monuments?
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Chapter 6-Neutralizing the Threat of Acid Rain
46. Nationally, the greatest amounts of NOx in the atmosphere are produced by which of
these?
I. transporation sources (motor vehicles, aircraft, trains)
II. combustion of fuel in electrical utility plants and industry releases
III. nitrification in farm fields
A. I and II only
B. I and III only
C. II and III only
D. I, II, and III
Think about which would cause interaction with water in the atmosphere.
47. Which reaction accounts for the fact that the pH of rain is naturally slightly acidic?
Remember which gas is always found in the atmosphere, even without any pollution.
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Chapter 6-Neutralizing the Threat of Acid Rain
48. Which reactive nitrogen compound is produced using the Haber-Bosch process?
A. NaNO3
B. KNO3
C. NH3
D. NO2
This can be a gas and is often found dissolved in water for cleaning.
49. The amounts of SO2 and NOx emissions from anthropogenic sources are ______ those
from natural sources.
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Chapter 6-Neutralizing the Threat of Acid Rain
50. Scrubbers installed on coal fired power plants remove acidic emissions by the
following reaction:
If a plant burns 2.4 million metric tons of coal (1 t = 1000 kg) containing 1.3% sulfur,
how much limestone (CaCO3) will be consumed neutralizing the resulting acid?
Assume that all of the sulfur is converted to sulfuric acid and that the acid is
completely converted to calcium sulfate.
A. 2.4 × 109 kg
B. 1.3 × 108 kg
C. 3.1 × 107 kg
D. 9.7 × 107 kg
The mass of sulfur released divided by 32 g/mol will get the amount of sulfuric acid
and moles of calcium carbonate needed. Calcium carbonate has a mass of 100.1 g/mol.
51. Bases are substances that increase the hydroxide ion concentration in aqueous solution.
Why does ammonia (NH3), which does not contain a hydroxide group, act as a base?
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Chapter 6-Neutralizing the Threat of Acid Rain
52. An acidic fog in Pasadena was found to have a pH of 2.50. Which expression
represents this pH measurement?
A. 3 LiH + (OH)3PO4
B. 3 H + 3 O2 + H3Li3
C. Li3PO4 + 3 H2O
D. Li3P + 2 H2O + H3O5
Acid/base neutralizations make salt and water. Be sure to balance the equation.
54. Most aquatic life in lakes cannot survive in water with a pH less than
A. 9.
B. 8.
C. 6.
D. 5.
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Chapter 6-Neutralizing the Threat of Acid Rain
56. The production of nickel and copper metals from their ores involves sulfur dioxide
emissions because
A. the ores of these elements are composed primarily of NiSO2 and CuSO2.
B. the ores of these elements are composed primarily of NiS and CuS.
C. to release the metals from their ores, the ores are heated with sulfur-containing coal.
D. the release of metals from their ores involves the reaction of SO3 with the ore.
Remember that combustion reactions are vigorous combinations with oxygen gas.
57. In the early 1990s, glass manufacturers developed a green chemistry solution to
reducing NO emissions and energy consumption. This involved
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Chapter 6-Neutralizing the Threat of Acid Rain
58. Iron, an important component of the steel used in the construction of buildings, bridges,
and railroads, combines with oxygen to form Fe2O3, which we recognize as rust. At
room temperature, iron
A. HCl
B. NaOH
C. NH3
D. LiOH
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Chapter 6-Neutralizing the Threat of Acid Rain
60. What is the concentration of hydroxide ions in an aqueous solution containing [H+] = 1
x 10-5 M?
A. 1 x 10-5 M
B. 1 x 10-7 M
C. 1 x 10-9 M
D. 1 x 10-14 M
A. an increase in acidity.
B. 10 times more hydrogen ions in solution.
C. 10 times less hydrogen ions in solution.
D. none of the above.
FALSE
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Chapter 6-Neutralizing the Threat of Acid Rain
63. Scientists predict that shells of some ocean creatures will start to dissolve after how
many more years of ocean acidification?
A. 40 years
B. 150 years
C. 300 years
D. 85 years
64. Why are mountaintops more susceptible than grassy plains to acid deposition?
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Chapter 6-Neutralizing the Threat of Acid Rain
A. Calcium carbonate
B. Ammonium nitrate
C. Sodium hydroxide
D. All of the above
66. Why are automobiles a contributor to acid rain when there is no sulfur in gasoline to
make SOx?
Remember that there are two causes of acid rain, not only SOx.
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Chapter 6-Neutralizing the Threat of Acid Rain
68. Which of the following countries is the largest consumer of coal (by total mass)?
A. China
B. United States
C. India
D. Indonesia
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