Be 8A, B cong, pie tains 1 mark, 2 4 3 questions of Part a owen be anise fh nd 8 marks questions respectively and book, if answe oF ed in the first two pages of the main answer "ed in any other part of the answer book will not be valued. 8*1=8 marks (a) Define the term entropy, (b) What is system? State Nitrogen rule for Mass Spectrometry, (a) Write the IUPAC name of K3 [Fe(CNyg]. {e) What is complex ion? ff} Calculate EAN of [er(co),]. {g) What is spin-spin coupling? (h) State Franck Condon principle, PART - B * 2=10 marks Answer any FIVE of the following questions : 5x2 (a) Explain the preparation of Fe(CO)s complex. (b) | Write a note on application of complex formation taking extraction of nickel as ) Writ : an example. -(c]_ Derive Cp - Cy = x 10! (a) Calculate the efficiency of heat engine working between 25°C and 1 1 P.T.0,oupling Q.P. Code - 15572 Se (e} What is shielding and deshielding effect in NMR spectroscopy? (Explain Me-Lafferty rearrangement in Mass spectrometry. (g] What are bidendate ligands? Give one example. ae molecules. (h) Write a note on microwave activity of asymmetric top PART -C Answer any FOUR of the following questions : be 8. Derive an expression for isothermal reversible expansion of an ideal gas, 4. Explain instrumentation of mass spectrometty. 5. Write any four applications of microwave spectroscopy. ©. Explain structure and geometry of [MnCl,]?* on the basis of VBT. a Write a note on different types of electronic transition in electronic spectros 8. Calculate the entropy change involved in thermodynamic expansion of 2 mo ideal gas from a (a) volume of 5 litre to a volume of 50 litres and (b) 10 att to 2 atm, pressure at 303 K. PART-D Answer any TWO of the following questions : 2x8=1 9 (a) Describe the factors influencing the stability of complexes. (>) Explain crystal field splitting of octahedral complexes, 10. (a) Discuss the optical isomerism of complexes with coordination number 6 (b) Predict H-NMR spectra of CHsOH and GsH.OH molecules, (b) 11. (@) Derive Kirchotf’s equations. OO: HGP P (b) Write any four comparison between Raman and IR spectroscopy A 12. (a) Explain the theory of NMR spectroscopy. me - a (b) Discuss the factors influencing chemical shift, > “152 agin bees Ps a fae| coDE 15572 osructions (0 the candidates, 1, This paper consists of Fou, R se 2. Section ~ 4, B, © g a Anse, nd D i r all. respectively, contains 1 ‘Sections gover the following in a word, Phrase or i a) State Frank - Condon Principle, b) Write one molecule which is mi «) Define base peak in Mass Spec 4) State 18 ~ electron rule for 8x1=o8 “rowave active, ‘trometry, metal carbonyls, e) What are metal carbonyls? ) Write Born — Oppenheimer approximation, ®) Give one example for spherical top molecule, ) Write the IUPAC name of K[Fe(cw),] ‘complex, SECTION - 5 \nover any FIVE of the following questions: «) What are stokes and antistokes lines in Raman Spectroscopy. ®) Calculate the efficiency of a reversible heat engine Working between the temperatures 80°C and 195°C, ‘) Explain spin — spin Relaxation process. ‘) Write Retro ~ Diel’s Alder reaction, 3x2=10 ©) Define ambidentate ligand and give one example, ') Write methods of preparation of Cobalt carbonyl. | ; 1 :QP CODE 15572 4), Mention the different solvents used in H'— Wj effects. 1). Explain Me-Lafferty Rearrangement in Mass Sp SECTION -C Answer any FOUR of the, following questions: » 4. Derive Krchof?s equation forthe variation of hea constant P and V. Describe Rotational and Vibrational spectra of d Explain the detection of co-ordiantion compou method and pH method. 6. Define Chemical shift and explain the 7. Write a note on microwave activity of sym 8, Discuss the structure and geometry of [ 10. a) Write the H1'— NMRn OW) 14 4q paroarap saxayduros Jo w {SdUT OM ~y JaquinU TOHRU; UT Ww: ~oyduuxo un yea ayn NV axtst ur arg (BZ z ssuoysanb Bumoyof ay) fo TALL Cun somsry SMW OL = 7S ( a - NOILOGS “aL Cum) Fon)20 | so 2ueu svani MeSH {soxojdmoo inds sry ore wy {S9|MOgJOU SANOP oAvA OIDTN ATE UA peat areimapiqure ame eM (9 49 puw do uaamreg drysuonejar ayy uM (p uonouny ares aujaq. 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HONBUTPI005 (1 ssnosiq] Cn +, € esuoysanb Supmopof ays fo YAO kup sowsuy O-NOILOaSDE 15572 Page No... 1 Fifth Semester B.Sc., Degree Examinations SEPTEMBER/OCTOBER 2022 (Semester Scheme) (New Syllabus) (June 2016 Onwards) SSE 251: PAPER - VI: CHEMISTRY jhrs.) [Max. Marks: 50 structions to the candidates: 1. This paper consists of FOUR sections. Answer all sections 2. Section ~ A, B, C & D contain Imark, 2marks, dmarks & 8 marks questions respectivel 3. Write equations and neat diagrams wherever necessary. SECTION - A nywer the following in a word, a phrase or in a sentence: 8x1=08 |. a) Write an expression for heat capacity at constant volume. b) What is meant by path function? ©) State BAN rule 4) What is crystal field stabilization energy? €) What is Retro ~ Deil’s Alder reaction? ) Give the IUPAC name of K,[Fe(CN), NO, | g) Give an example for outer orbital complex. hh) What are stokes and antistokes lines? SECTION -B inswer any FIVE of the following questions: 5x2=10 2, a) Mention the application of microwave spectroscopy. b) What are emission and absorption spectra? ©) What are ambidentate ligands? Give an example. 4) Define the terms i) system and ii) surroundings. €) What are the limitations of {law of thermodynamics? {) Caleulate BAN of [ Fe(CWV), | Contd csr 2CE ————_—_—_— QP CODE 15572 8) Calculate erystal-fields stabilization energy for low spin 4 h) What are the conditions fora molecule to absorb energy in MW ¢, SECTION - C Answer any FOUR of the following questions: 3. Explain the detection of complex formation by i) colour change method. 4. Draw the H'-NMR spectra of CH,QH, C,H,OH and C,H splitting pattern 5. Describe various types of microwave active and inactive molecule, 6. Drive an expression for Kirchof?’s equation. 1. Define Gibbs free energy. Give its significance and how does: and Temperature, 8. Discuss crystal field splitting of d — orbital in octahedral complex SECTION -D Answer any TWO of the following questions: 9. a) Drive an expression for efficiency of Carnot’s heat, temperature T; and 7, b) Write a note on Bom — Oppenheimer approximation 10. a) Discuss the structure and bonding in Fe(CO),. ') Write a note on ionization isomerism and hydrate 11. a) Explain any four factors affecting the chemical shift, b) Write a note on Mc-Lafferty Rearrangement and 12, a) Describe the instrumentation of mass ‘spectroscopy. b) Calculate the entropy change when 2 moles of an from 0.05m°to 0.5m! at 300K. ; teehee