2 G) Answer any Three questions. (a) ; TA. (i) Separate answer script must be used for answering the questions of PAR (ii) Figures in the right margin indicate marks. esentation. 2.67 What is electrolysis? Show mechanism of electrolysis with schematic representati : (b) (©) (d) (a) (b) (c) (a) (b) (c) a il State Faraday's first lawof electrolysis with its importance Explain Koblrausch's law of ionic mobility. How does it help in determining the > equivalent conductivity of infinite dilution of weak eletrolyte? F Pee An electric current is passed through three cells in series containing respectively — 2 solutions of copper sulphate, silver nitrate and potassium iodide, What weights of silver and iodine will be liberated while 1.25 g of copper is being deposited? Write a short note on“ Relation between Ke and Kp” 4 Explain the effect of addition of inert gas and increase of temperature on the position of equilibrium on an exothermic reaction At 00°C, the reaction between No and Hp to form ammonia has Ke ~ 6.0 « 10. What 2.67 is the numerical value of Kp for the reaction? Discuss the influence of temperature on the rate ofa reaction with the help theory. How is the activation energy of a chemical reaction determined? of Arthenius 5 What do you understand by molecularity and order of a reaction? eee 1.67 Derive the integrated rate equation for the following reaction A —— Products 4 MX C4 es to form B and C and the re, = Compound A decomposes to form B and C eee rate constant for the reaction is 0.450s. What is the half-life of A ay pleat ie How does sol ifr roma ge? Explain" aNSN6F Wiha suitable diagram 2.67 What i Tyndall eee? True solution does 91 sw Tyndatetfetayhy Define colloid. Describe a method for purifying colloidal solutions 2 s and Lyophobie sols 36 What do you mean by Lyophilic sols and’ I-yon! Obie sols? Lyophilic sols are ba than Lyophobic sols-explain. re stable 3,5NB: i ent of Civil Engi , St Year Ist Semester Examination-202 Course ‘Title: Chemistry-I Course No: Ch 1101 > : 3.00 hours (For PARY-A and PART-B) PART-B Pull Marks: 35 ) Answer any Three questions i Separate answer script must be used for answering the questions of PART-B. (iti) Figures in the right margin indicate marks (a) (b) () (a) (b) () (d) (a) (b) (c) (d) (a) (b) (c) Ve the defects of Rutherford’s model of atom. What suggestions were given by Bohr 5 to remove these defects? ate Pauli's exclusion principle and show that the maximum number ofelectrons ina 4.67 given shell is 2n? where n is the principal quantum number of the shell, Define : (a) Absorption —(b) Emission There is a close relationship between clectronic configuration and chemical behaviourof 2.67 elements. Justify this statement giving reasons supported by examples. Discuss Bohr's atomie model with limitations Explain the following with reason: a (i) Atomic radius decreases from left to right of « period and inereases from top to down ofa group. (ii) Electron affinity increases aeross a period and decreases along group from top to down State modem periodic law fi ‘What is meant by an ionic bond? What are the conditions necessary for the formation of 3.5 an ionic bond? Explain intermolecular and intramolecular hydrogen bonding with one example of each. 2.67 Cl, Nfs and 120 have tetrahedral geometry yet their bond angles are different, Why? 4 What is meant by hybridisation? Write the hybridisation involved in 1s (i) Beryllium dichloride (ii) Boron trifloride ion of solids on the basis of bonding and their properties. 35 Discuss classi h Show the paramagnetic character of OXY! What is Lanthanides and Actinides these series. gen with the help of Molecular orbital theory. 25 .) Briefly discuss preparation and propertics of 5.672 a) ») °) a) b ° a) ») ° a) ) contucianes eae ‘conductance. Explain clearly w1 dilution equivalent conductance increases and specific conductance decreases. Sate and explain Faraday"s law of electrolysis. Derive the integrated 2" order king ies equation when the initial concentrations of the two reactants are different, bisa Discuss the influence of temperature on the velocity. How is the activation energy of chemical reaction determined? i — {fa first order reaction is half-complete in 100 seconds. Calculate the time require 99% of the reaction completed Why chemical equilibrium is called a dynamic equilibrium? ve At 500°C, the reaction between No and Hp to form ammonia has K; = 6.0 = 10°. What is ‘the numerical value of K; for the reaction’? What will happen to the formation of ammonia iff the temperature and pressure are increased? State different methods of preparation of colloidal dispersions. Describe Bredig's arc ‘method! in detail What is electrophoresis? How does this phenomenon provide information about the sign of charge on particles? ‘What are emulsions and what is emulsifying agent? Outline briefly Bohr's postulates. Derive an expression fo ofan electron in the Bohr's orbit. What are three quantum numbers used to deseri is described by each quantum number? Write a short note on Pauli’s exclusion principle. the calculation of total energy ibe an orbital? What property of an orbital bonds of compounds are in the limits of pure ionic to pure covale statement with reference to compouinds tom Na o Cl and electroneyetv What are the factors which favor the formation of ionie bond? Explain the term isomorphism, ent”. Explain this What is atomic orbital? Draw diagram to show the ‘of atomic orbitals. Show that Os is paramagnetic according to molecular orbit bond order from this MO diagram of Os. Explain the type of hybridization and geometrical orbital diagram. shapes and orientations of p and d type tal (MO) theory. Caleulate the I shape of PCls molecule with the help off ‘What are s-block elements? How do these elements dite ces main characteristics Prblock elements? Give theie Discuss d-block elements in the following respects. (i) Colored ion formation (i) Magnetic properties Distinguish between transition elements and oj : i in group elements clectronie configuration, ease Glenents in ema their 1% 4% 1% 3% a%er any six questions, ii, Figures in the right margin indicate matks- a) b) °) a) >) °) a) b) ° a) b) °) a) by ¢) Define conductance, specifie conductance, equivalent conductance and conductance, ss \ductance. Establish the relation between specific conductance and equivalent conductance. State and explain Faraday’s law of electrolysis. Derive the Arhenius equation and discuss how it is useful to calculate the energy of activation, Write short notes on: (i) Parallel reactions (ii) Opposing reactions. The rate constant for a first order reaction is 1.54 * 10° sec’!, Calculate its half-tife period. How are Kp and Ke related? What is Le Chatelier's principle? Discuss its applications. Derive the law of mass action for the expression. Discuss the origin of charge on colloidal particles. What is meant by electrical double layers? What is meant by Zeta potential? ‘What is a colloid? Discuss the essential difference between Iyophilic and lyophobic colloids. What are gels? Give examples. ‘What is Pauli Exclusion Principle? How does it govern the distribution of the atoms of IH and Na? Explain the origin of spectra in a hydrogen atom, Draw the sketches of p and d orbitals showing the electrons in directional characteristics, ‘Show that methane and water contain covalent linkages What is a co-ordinate covalent bond? How does it diffe Write a short note on hydrogen bonding. among their respective atoms, from a normal covalent bond? Describe sp*, sp? and sp hybridization of carbon in org: of acetylene and label the bonds as sigma and pi bonds, Nitrogen molecule is diamagnetic while oxygen mo What are the differences between bonding and angi ‘anic molecules. Draw the model lecule is paramay netic. Explain, 'bonding molecular orbitals? What are transition elements? How Many transition elements are - es a S are there in the periodic What is meant by ionization potential? How is it related 4 to elements to form positive or negative of the elements? the tendency of the Discuss how the covalent and ionie Tdi Vary in the ys. '¢s of transition elements,