12 ACH

LAKSHYA Marks : 300

SUBJECT : PHYSICS, CHEMISTRY & MATHS
Rotational Motion, Mechanical Properties of fluids, Oscillations,
Waves and Sound, Wave Optics, Electrostatics, Current Electricity,
Magnetic Fields due to Electric Current (MEEC) Magnetism and
Magnetic Materials, Solutions & Colligative Properties, Transition &

XII-JEE-PCM-MT-1- Inner transition Elements (d & f block elements), Co-ordination

Compounds, General Organic Chemistry (GOC) , Isomerism, Time (mm:ss) : 180:00
SET-B (23-24)
Reagents & Mechanism, Haloalkanes and Haloarenes , Alcohols,
Phenols & Ethers, Pair of Straight Lines, Vectors, Lines & Planes,
Indefinite Integration, Dedinite Integration

PHYSICS - Single Correct Answer 80

1) A capillary tube of internal radius 2 × 10–3m immersed vertically in a beaker containg a liquid. If the weight of the
liquid vision is the capillary tube is 9 × 10–5kg, the surface tension of the liquid is

a) 70 N/m

b) 7 N/m

c) 0.7 N/m

d) 0.07N/m

2) The terminal velocity of a copper ball of radius 2.0 mm falling through a tank of oil at 20oc is 6.5 cms-1. Compute
the viscocity of the oil at 20oc. Density of oil is 1.5 × 10+3 kgm-3. Density of copper is 8.9 × 103 kgm-3

a) 100 kg/ms

b) 9.9 × 10–1 kg/ms

c) 1000 kg m

d) None of the above

3) Two boys weighing 40 kg and 50 kg are sitting on either side of a wooden plank at distance 4.5m and 1.5m
respectively from the fulcrum coinciding with centre of gravity of the plank. Where must a third boy weighing 35
kg it to secure balance?

a) 3m

b) 5m

c) 6m

d) 8m
4) A rod of length L is hinged from one end. It is brought to a horizontal position and released. The angular velocity of the rod when it
is in vertical position is :
−−−−
a) √2g/L

b)

−−−−
c) √g/2L

−−−
d) √g/L

5)

Time elapsed between P and Q is

a)
5T

12

b)
7T

12

c)
2T

d)
4T

6) If a spring is cut into 3 equal parts then new spring constant of one part becomes.

a) K

b)
K

c) 3K

d)
K

2
7) The B-H curve for a ferromagnet is shown in the figure. The ferromagnet is placed inside a long solenoid with
1000 turns/cm. The current that should be passed in the solenoid to demagnetise the ferromagnet completely is :

a) 1 mA

b) 2 mA

c) 20 μ A

d) 40 μ A

8) A solenoid has a core of a material with relative permeability 50. The winding of the solenoid are insulated from
the core and carry a current of 5A. If number of turns per unit length is 500/meter then the magnetisation
intensity (I) in core is

a) 12.25 × 10
−4
A/m

b) 12.25 × 10
−3
A/m

c) 11.25 × 10 A/m
4

d) 12.25 × 10 A/m
4

9) Two equal charges as separated by a distance d. A third charge placed on a perpendicular bisector at x distance
from centre will experience maximum coulomb force, when
d
a) x =
√2

b)
d
x =
2

d
c) x =
2√2

d
d) x =
2√3
10) The resistance in the two arms of the meter bridge are 5 , respectively. When the
Ω and R Ω

resistance R is shunted with an equal resistance, the new balance point is at 1.6ℓ1 . The resistance ‘R’
is :

a) 10 Ω

b) 15 Ω

c) 20 Ω

d) 25 Ω

11) The resistance Rt of a conductor varies with temperature t as shown in the figure. If the variation is represented
by Rt = R0 [1 + αt + βt2 ], then

a) α and β are both negative

b) α and β are both positive

c) α is positive and β is negative

d) α is negative and β is positive

12) A circular loop of radius R is moved with a velocity v as shown in the diagram. The force needed to maintain its
velocity constant is

μ IvR
a) 0

2πa

μ IvR
b)
0

2π(a+R)

μ IvR
c)
0 R+a
ln ( ]
2π R

d) Zero

13) A charged particle enters a uniform magnetic field with velocity vector at an angle of 450
with the magnetic field. The pitch of the helical path is p. The radius of the helix will be
p
a) π

p
b) 2π

c) √2p

d) 2√π

14) In an ammeter 4% of the main current is passing through the galvanometer. If shunt resistance is 5Ωthen resistance of
galvanometer will be

a) 60Ω

b) 240Ω

c) 120Ω

d) 480Ω
15) A pulse moves in a string as indicated in the sketch. At the end of a string is a ring that can slide without friction on
a post. On reflection, the pulses would most nearly be represented by

a) 1

b) 2

c) 3

d) 4

16) Find the change in the volume of 1 Litre kerosene when it is subjected to an extra
pressure of 2 × 105 N/m2 from the following data. Density of kerosene is 800 kg/m3
and speed of sound in kerosene is 1330 m/s.

a) 0.28 cm3

b) 0.42 cm3

c) 0.14 cm3

d) 0.70 cm3

17) In a YDSE experiment, the coherent sources are at 2d distance from each other and screen is placed a distance D
from the slits. If nth bright fringe is formed on the screen exactly opposite to a slit, the value of n must be
2

a) d

4λD

b) d

λD

c) 2d

λD

d) d

2λD
18) In a Young’s double-slit experiment (figure), the angular position (θ) of a bright fringe having intensity one fourth
of the maximum intensity is given by:

a) sin
−1
(λ/4d)

b) sin
−1
(λ/3d)

c) sin
−1
(λ/2d)

d) sin
−1
(λ/d)
19) All identical capacitor plates each of area A are arranged such that adjacent plates are at d distance
apart. Plates are connected to a source of emf V volts as shown in figure.
Match the quantities in List-I with their respective answer in List-II. (dielectric constant in each shaded
region is k = 2)

List-I List-II

Total charge o plates numbered

P. i) 4/3
(3)

The heat rejected by the system

Q. 13ε0 AV
2
ii) 1
(multiple of )
d

Equivalent capacitance between

R. iii) 1/3
AB(multiple
13Aε0
of )
d

Potential difference between the

S. iv) 2/3
plates 6 and 7 (multiple of V/2)

v) 5/3

a) P (iv); Q (iii); R(i); S(v

b) P (v); Q (ii); R(iv); S(iii)

c) P (iv); Q (v); R(i); S(ii)

d) P (v); Q (i i i ); R(i v); S(i)

20) A charged bead (charge + 4 μC) is threaded on fixed smooth circular ring of radius 2m in gravity free
space. Another charge +4μC is fixed at 1m from centre as shown. The bead is projected with just
sufficient velocity to complete the circular path. If mass of bead is 100 gm, what is initial speed v0?

a) 80√3 cm/s

b) 40√2 cm/s

c) 10 m/s

d) 4√5 m/s

PHYSICS - Integer Type Questions (Attempt Any Five) 20

21) Two beams of light having intensities I and 4I interfere to produce a fringe pattern on a screen. The phase
difference between the beams is 2 at point A and π at point B. The ratio of the resultant intensities at A and B is
π

………

22) In a Young’s double slit experiment, an angular width of the fringe is 0.35° on a screen placed at 2 m away for
particular wavelength of 450 nm. The angular width of the fringe, when whole system is immersed in a medium of
refractive index 7/5, is . The value of α is __________
1

23) A particle of mass 0.10 kg has its velocity varying according to the relation v= −4π sin (πt+
π
) m/sec [T ake π 2
=10]
4

What is the maximum kinetic energy ? (in J)

24) A tiny ball of mass 100 g and density 2g/cm3 is dropped in a tall gar oil of density 0.8 g/cm3. When the ball
acquires terminal velocity, the magnitude of the viscous force acting on it in dyne is ______.

25) Let ‘M’ be the mass and ‘L’ be the length of a thin uniform rod. In first case, axis of rotation is passing through
centre and perpendicular to the length of the rod. In second case, axis of rotation is passing through one end and
perpendicular to the length of the rod. The ratio of radius of gyration in second case to first case is____.

−−
26) Electric potential at any point is V = 5x + 3y + √15 z, then the magnitude of intensity of electric field is
27) A current of 6 A enters one corner P of an equilateral triangle PQR having 3 wires of resistance 2Ω each and
leaves by the corner R. The currents il in ampere is _______.

28) The coercivity of a small magnet, where the ferromagnetic gets demagnetized is 3 × 103 A/m. The current (in A)
required to be passed in a solenoid of length 10 cm and number of turns 100, so that the magnet gets
demagnetized when inside the solenoid is

29) Two long strings A and B each having linear mass density 1.2 kg/m are stretched by
× 10
−2

different tensions 4.8N and 7.5 N respectively and are kept parallel to each other with their left ends
at x = 0. Wave pulses are produced on left ends at t = 0 on A and t = 20 ms on B. If n × 10
−2
s is
the time required to meet, then find n.

30) A charged particle enters a uniform magnetic field with velocity vector at an angle of 450
with the magnetic field. The pitch of the helical path is p. The radius of the helix will be (n) × p/π . Find 1/n

CHEMISTRY - Single Correct Answer 80

31) The freezing point of a diluted milk sample is found to be -0.20C, while it should have been -0.50C for pure milk.
How much water has been added to pure milk to make the diluted sample ?

a) 2 cups of water to 3 cups of pure milk

b) 1 cup of water to 3 cups of pure milk

c) 3 cups of water to 2 cups of pure milk

d) 1 cup of water to 2 cups of pure milk

32) Which of the following binary liquid solutions would exhibit negative deviation from Raoult’s law?

a) Acetone + chloroform

b) Benzene + toluene

c) Diethyl ether + acetone

d) Ethanol + acetone

33) The mass of a non-volatile, non-electrolyte solute (molar mass = 50 g mol-1) needed to be dissolved in
114 g octane to reduce its vapour pressure by 75 percent is :

a) 37.5 g

b) 75 g

c) 150 g

d) 50 g

34) K 2 HgI4 is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is :-

a) 1.8

b) 2.2

c) 2.0

d) 1.6

35) Molecules of benzoic acid (C6H5COOH) dimerise in benzene. 'w' g of the acid dissolved
in 30 g of benzene shows a depression in freezing point equal to 2K. If the percentage
association of the acid to form dimer in the solution is 80, then w is : (Given that Kf = 5 K kg mol-1, Molar mass of
benzoic acid = 122 g mol-1)

a) 1.8 g

b) 2.4 g

c) 1.0 g

d) 1.5 g

36) Elevation in the boiling point for 1 molal solution of glucose is 2 K. The depression in the freezing point of 2 molal
solutions of glucose in the same solvent is 2 K. The relation between Kb and Kf is :

a) K b = 0.5 K f

b) Kb = 2 Kf

c) K b = 1.5 K f

d) Kb = Kf
37) Identify the compound amongst the following of which 0.1 M aqueous solution has highest boiling point.

a) Glucose

b) Sodium chloride

c) Calcium chloride

d) Ferric chloride

38) The equation that represents van’t Hoff general solution equation is

a)
n
π = RT
V

b) π = nRT

c)
V
π = RT
n

d) π = nV RT

39) Due to lanthanoids contraction:

a) Fe, Co, Ni have equal size

b) Zr and Hf have equal size

c) All f- block ions have equal size

d) All isoelectronic ions have equal size

40) Why is HCl not used to make the medium acidic in oxidation reactions of KMnO4 in acidic medium?

a) Both HCl and KMnO4 act as oxidising agents.

b) KMnO4 oxidises HCl into Cl2 which is also an oxidising agent.

c) KMnO4 is a weaker oxidising agent than HCl.

d) KMnO4 acts as a reducing agent in the presence of HCl.

41) The IUPAC name of the complex [Pt(NH3)2Cl(NH2CH3)]Cl is :

a) Diamminechlorido (methanamine) platinum (II) chloride

b) Diammine (methanamine) chlorido platinum (II) chloride

c) Diamminechlorido (aminomethane) platinum (II) chloride

d) Bisammine (methanamine) chlorido platinum (II) chloride

42) Which of following is not capable of existing enantiomers

a) 1, 3-dichloro butane

b) 1, 2-dibromo propane

c) 1, 4-dichloro pentane

d) 3-ethyl pentane

43) The pair of molecules shown are

a) enantiomers

b) diastereomers

c) constitutional isomers

d) two conformations of the same molecule

44) How many structures are possible for a compound with the molecular formula C6H12O which can give both
iodoform and 2,4-DNP test?

a) 1

b) 3

c) 2

d) 4

45) The best method for the preparation of 2,2-dimethylbutane is via the reaction of:

a) Me3CBr and MeCH2Br in Na/ether

b) (Me3C)2CuLi and MeCH2Br

c) (Me3CH)2CuLi and Me3CH2CBr

d) Me3CMgl and MeCH2l

46) A compound A has molecular formula C2Cl3OH.It reduces Fehling’s solution and oxidation gives a monocarboxylic
acid. A is obtained by the action of C l2 on ethyl alcohol. The compound A is

a) chloroform

b) chloral

c) trichloro ethanol

d) trichloro acetic acid

47) An organic compound A (C6H6O) gives dark green colouration with ferric chloride. On treatment with CHCl3 and
KOH, followed by acidification gives compound B. Compound B can also be obtained from compound C on
reaction with pyridinium chlorochromate (PCC). Identify A, B and C.

a)

b)

c)

d)

48) An organic compound C 4 H10 O(X) on reaction with I2 /red−P gives C 4 H9 I which on further reaction with
AgN O2 gives C 4 H9 N O2 (Y ). Y on treatment with H N O2 forms a blue solution which turns to red on making

solution slightly alkaline. The possible identity of X is

a) 1-butanol

b) 2-methyl-1-pentanol

c) 2-butanol

d) Either (1) or (2)

49) Correct increasing order for the wavelengths of absorption in the visible region the complexes of
Co3+ is :

a) [Co(H2O)6]3+, [Co(en)3]3+, [Co(NH3)6]3+

b) [Co(H2O)6]3+, [Co(NH3)6]3+, [Co(en)3]3+

c) [Co(NH3)6]3+, [Co(en)3]3+, [Co(H2O6)6]3+

d) [Co(en)3]3+, [Co(NH3)6]3+, [Co(H2O)6]3+

50) The IUPAC name for K2[Cr(CN)2O2(O2)NH3] is :

a) Potassium amminedicyanotetraoxo chromium (III)

b) Potassium amminedicyanodioxygendioxo chromate (IV)

c) Potassium amminedicyanosuperoxoperoxo chromate (III)

d) Potassium amminedicyanodioxoperoxo chromate (VI)

CHEMISTRY - Integer Type Questions (Attempt Any Five) 20

51) Oxidation number of manganese in manganite ion is _________.

52) The electronic configuration of Ce (Z = 58) is [Xe]4fx 5dx 6sy. The value of ‘x’ is ______.

53) How many among the following are amphoteric oxides?

CrO3, V2O5, V2O3, CrO, Cr2O3

54) 2 molal solution of a weak acid HA has a freezing point of 3.885°C.

The degree of dissociation of this acid is _____ ×10−3 .
(Round off to the Nearest Integer).
[Given : Molal depression constant of water = 1.85 K kg mol-1 Freezing point of pure water = 0°C]

55) 1 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the solution at 1 atm is _______
K. (Rounded-off to the nearest integer)
[Given Kb for (H2O) = 0.52 K kg mol–1]

56) The number of stereoisomers possible for [Co(ox)2(Br)(NH3)]2- is _______.

[ox = oxalate]

57) How many ethers are possible for the formula C5H12O including stereoisomers?

58)

x and y mole consumed. Value of x + y_______.

59) An unknown compound (A) (molar mass = 180) on acylation gives a product (molar mass = 390) than find the
number of hydroxyl group present in compound (A) is_____.

60) The total number of C–C sigma bond/s in mesityl oxide

MATHS - Single Correct Answer 80

61) If the volume of parallelepiped determined by vectors 2 (ā
¯¯
¯¯ ¯¯
× b) , 3 ( b × ¯c
¯
) and 5 (¯c
¯ ¯¯
× ā ) is equal to the

volume of the parallelepiped determined by vectors 5 (ā then find the

¯¯ ¯¯
¯¯
+ b) , 6 ( b + ¯c
¯
) and 2 (¯c
¯ ¯¯
+ ā ),

volume of parallelepiped determined by vectors ā in cubic units.

¯¯
¯¯
, b and ¯c
¯

a) 1

b) 2

c) 3

d) 4

62) 2
∧ ∧ ∧ ∧
2
∧ ∧

The number of distinct real values of λ, for which the vectors −λ i + j + k, i − λ j + k

∧ ∧ ∧
2
and i + j − λ k are coplanar, is :

a) Zero

b) One

c) Two

d) three

63) Let u⃗ , v ⃗ , w ⃗ be such that |u⃗ | = 1, |v ⃗ | = 2, |w ⃗ | = 3.

If the projection v ⃗ along u⃗ is equal to

that of w ⃗ along u⃗ and v ⃗ , w ⃗ are perpendicular to each other, then

|u⃗ − v ⃗ + w ⃗ | are equals

a) 2

b) √7

−−
c) √14

d) 14

64) Let A⃗ , B⃗ , C⃗ be vectors of length 3, 4 and 5 respectively. Let A⃗ be perpendicular to

⃗ ⃗
B + C , B
⃗ to C⃗ ⃗
+ A, and C
⃗
to A⃗ ⃗
+ B. Then length of the vector, A⃗ , B⃗ , C⃗ is :

a) −5√2

b) √2

c) 5√2

d) None of these
65) Consider the lines
x+1 y+2 z+1
L1 : = =
3 1 2

x−2 y+2 z−3

L2 : = =
1 2 3

The distance of the point (1, 1, 1) from the plane passing through the point (-1, -2, -1) and whose normal is
perpendicular to both the lines L1 and L2 is :
2
a) √75

7
b) √75

13
c) √75

23
d) √75

66) Let L be a line obtained from the intersection

of two planes x + 2y + z = 6 and y + 2z = 4.
If point P (α, β, γ) is the foot of perpendicular from
(3, 2, 1) on L, then the value of 21 (α + β + γ) equals:

a) 68

b) 102

c) 142

d) 136

67) The distance of the point (1, 1, 9) from the point of intersection of the line x−3
=
y−4
=
z−5
and the plane x + y
1 2 2

+ z = 17 is :

−−
a) 2√19

b) 19√2

c) 38
−−
d) √38

68) The equation of the plane passing through (1, 1, 1) and (1, -1, -1) and perpendicular to 2x - y + z + 5 = 0 is

a) 2x + 5y + z - 8 = 0

b) x+y-z-1=0

c) 2x + 5y + z + 4 = 0

d) x-y+z-1=0
69) The point of intersection of the lines x − 5
=
y − 7
=
z + 2
,
x + 3
=
y − 3
=
z − 6
is
3 −1 1 −36 2 4

a)
5 10
(21, , )
3 3

b) (2, 10, 4)

c) (-3, 3, 6)

d) (5, 7, -2)

70) The shortest distance between the lines x−3

=
y−8
=
z−3
and
x+3
=
y+7
=
z−6
is
3 −1 1 −3 2 4

−−
a) √30

−−
b) 2√30

−−
c) 5√30

−−
d) 3√30

71) The co-ordinates of the foot of perpendicular drawn from point P (1, 0, 3) to the join of points A (4, 7, 1) and B (3, 5,
3) is :

a) (5, 7, 1)

b) (5/3, 7/3, 17/3)

c) (2/3, 5/3, 7/3)

d) (5/3, 2/3, 7/3)

72)
2
sec x
The integral ∫ dx equals to (for some arbitrary constant c)
9

(sec x+tan x) 2

−1 1 1 2

a) 11
{
11
−
7
(sec x + tan x) } + c
(sec x+tan x) 2

1 1 1 2

b) 11
{
11
−
7
(sec x + tan x) } + c

(sec x+tan x) 2

−1 1 1 2

c) 11
{
11
+
7
(sec x + tan x) } + c
(sec x+tan x) 2

1 1 1 2

d) 11
{
11
+
7
(sec x + tan x) } + c
(sec x+tan x) 2

73) If ∫ dx
=
1
log 2
∣ √x +1−√3 ∣
−
1
tan
−1 −−−−−
√x + 1 + c then k equals
2
(x −4)√x +1 k ∣ √x +1+√3 ∣ 2

a) 2√3

b) 4√3

1
c)
4√3

1
d) 3√3
74)
2

3
b
(2x−3)
If ∫ then ab =
2x−3
dx = a( ) + c
8
4x+5
(4x+5) 3

a)
1

b)
1

10

c)
1

11

d)
1

22

75) ∫
5 cos x + 4 sin x
dx = ax + b log (3 sin x + 2 cos x) + c, then (a, b) ≡
3 sin x + 2 cos x

a)
22 −7
( , )
12 13

b)
23 −7
( , )
12 12

c)
−22 −7
( , )
13 13

d)
22 7
( , )
13 13

76) x
log t
For x > 0, if f(x) dt, then f(e) is equal to:
e 1
= ∫ + f( )
(1 + t) e
1

a) 1

b)
1

c) 0

d) -1

77) 3

The value of the integral,∫ [x

2
- 2x - 2] dx, where [x] denotes the greatest integer less than or equal to x, is :
1

a) - √2 - √3 + 1

b) - √2 - √3 - 1

c) -5

d) -4

78) 1

The value of , where [t] denotes the greatest integer ≤ t, is :

3
2 [x ]
∫ x e dx
−1

a)
e−1

3e

b)
e+1

c)
e+1

3e

d)
1

3e
79) If the slope of one of the lines given by 4x2 + kxy + y2 = 0 is 4 times the other, then value of k is

a) ±6

b) ±4

c) ±5

d) ±3

80) If one of the lines given by 6x2 − xy + 4ky

2
= 0 is 3x + 4y = 0, then k =

a) 1

b) -1

c) 2

d) -3

MATHS - Integer Type Questions (Attempt Any Five) 20

81) If the angle between the two lines x2 - 3xy + λy

2
+ 3x - 5y + 2k = 0, λ ≥ 0, is tan−1 (
1
), then : λ =
3

82) The value of the integral

10 2
[x ] dx
∫
2 2
where [x] denotes the greatest integer less than or equal to x, is :
,
[x −28x+196]+[x ]
4

83) 1

If ∫ e
{2x}
d {2x} = m (e − 1) , where { } denotes the fractional part, then find the value ofm.
−1

84) If ∫
2

log |sin x – cos x|+ 8 (sin 2x+ cos 2x) +C then A is equal to
cos x sin x A 1
dx=
sin x− cos x 16

85) If ∫
x −x

then |4 A| = ………. .
4e +6e 2x
x −x
dx=Ax+B log(9e −4)+C ,
9e −4e

86) If S is the cirum centre and O is the other centre of ΔABC, ¯OA
¯¯¯¯¯¯¯ ¯¯¯¯¯¯¯¯
+ OB + OC
¯¯¯¯¯¯¯¯ ¯¯¯¯¯¯¯
= λ OS then λ= _____

87) If (ā
¯¯
¯¯
× b)× ¯c
¯
=
1 ∣¯¯∣
|¯c
¯ ¯¯
| ā and θ is the angle between
¯¯
b , ¯c
¯
. Find 9 sin2 θ = _______
3 ∣ b∣

88) Let u⃗ , v ⃗ , w⃗ be the vectors such that u⃗ + v⃗ + w⃗ = 0 , if |u⃗ | = 3, |v ⃗ | = 4 and |w ⃗ | = 5 then find the
value of |u⃗ . v⃗ + v ⃗ . w⃗ + w ⃗ . u⃗ |
89) ∧ ∧ ∧ ∧ ∧ ∧

If the shortest distance between the lines r ⃗ = αi + 2j + 2k + λ ( i − 2j + 2k ) , λ ∈ R

∧ ∧ ∧ ∧

α > 0 and r ⃗ = −4 i − k + μ (j − 2k ) , μ ∈ R is 9, then is α is equal to _.

90) If the equation of plane passing through the mirror image of a point (2, 3, 1) with respect to line
y−3 1−y
and containing the line is αx , then α is
x+1 z+2 x−2 z+1
= = = = + βy + γz = 24 + β + γ
2 1 −1 3 2 1

equal to :

*ALL THE BEST*