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The experimental realization of Bose–Einstein When 𝑎s > 0, the interactions are repulsive. In con-
condensates (BEC) in dilute atomic gases[1−4] has trast, when 𝑎s < 0, the interactions are attractive
prompted much work on the study of the dynam- and a BEC tends to contract to minimize its overall
ics of these condensates. In experiments, the atoms energy. Some experiments on BEC give: 𝑎s = 2.75 nm
were confined in magnetic traps and cooled down for 23 Na, 𝑎s = 5.77 nm for 87 Rb, and 𝑎s = −1.45 nm
to extremely low temperatures. As the temperature for 7 Li.[13] By applying an ac magnetic field may in-
of atoms gets very low, their de Broglie wavelength duce a periodic modulation of 𝑎s , opening a way to
can become greater than the interatomic distance. “Feshbach resonance management”(FRM).[14]
At that point, bosonic atoms will condense into a The value of the energy per particle associated
unique quantum state and become indistinguishable with the wave function Ψ (𝑟) is obtained according
parts of a macroscopic quantum object. It has now to[11−13]
been achieved for all stable alkali atoms,[1−6] as well ∫︁ [︁ 2
~ 𝑈 ]︁
as with hydrogen,[7] metastable helium,[8,9] diatomic 𝐸(Ψ ) = |∇Ψ |2 + 𝑉trap (𝑟)|Ψ |2 + |Ψ |4 𝑑𝑟.
molecules,[10] etc. 2𝑚 2
(2)
In the dilute limit each atom feels the effects of all
For repulsive interactions (𝑎s > 0) the energy func-
surrounding atoms to the first (mean-field) approxi-
tional is convex and its minimum delivers the sta-
mation via an effective potential energy, which is pro-
ble ground state of the gas. For 𝑎s < 0 the ground
portional to the local density of the condensate. In
state exists only at low coupling for limited numbers
addition, the depletion of the condensate due to quan-
of bosons in the trap, as long as the zero-point en-
tum fluctuations is very small. Under these conditions
ergy balances the effect of attractions and prevents
the confined gas at zero temperature is fully charac-
collapse.[15]
terized by the condensate wave function, which is de-
In most cases, the confinement due to the mag-
termined by a nonlinear Schrödinger equation, known
netic trap is well-described by a harmonic oscillator
as the Gross–Pitaevskii equation (GPE)[11−13]
potential
[︁ ~2 2 ]︁
1
− ∇ + 𝑉trap (𝑟) + 𝑈 |Ψ (𝑟)|2 Ψ (𝑟) = 𝜇Ψ (𝑟) (1) 𝑉trap (𝑟) = 𝑚(𝜔𝑥2 𝑥2 + 𝜔𝑦2 𝑦 2 + 𝜔𝑧2 𝑧 2 ) (3)
2𝑚 2
2
∫︀under2 the normalization condition ‖Ψ ‖ = with 𝜔𝑥 , 𝜔𝑦 and 𝜔𝑧 being the trap frequencies in the 𝑥-
|Ψ | 𝑑𝑟 = 1, where 𝑟 = (𝑥, 𝑦, 𝑧) denotes the space , 𝑦-, and 𝑧-directions, respectively. In the disk-shaped
𝜕2 𝜕2 𝜕2
coordinates; ∇2 = 𝜕𝑥 2 + 𝜕𝑦 2 + 𝜕𝑧 2 is the Laplace condensates, i.e., 𝜔𝑥 ≈ 𝜔𝑦 and 𝜔𝑧 ≫ 𝜔𝑥 , the three-
operator, ~ the reduced Planck constant, 𝑚 the mass dimensional (3D) GPE can be reduced to 2D GPE.
of the boson, 𝑉trap a trapping potential spatially In the cigar-shaped condensates, i.e., 𝜔𝑦 ≫ 𝜔𝑥 and
confining the condensate, 𝜇 the chemical potential, 𝜔𝑧 ≫ 𝜔𝑥 , the 3D GPE can be reduced to 1D GPE.
𝑈 = 4𝜋~2 𝑁 𝑎s /𝑚, 𝑁 the total number of particles There are many numerical methods, such as
in the condensate, 𝑎s the s-wave scattering length. the imaginary-time propagation (ITP) method,[15−18]
* Supported by the National Natural Science Foundation under Grant No 11047010, and the Key Project Foundation of the
110302-1
CHIN. PHYS. LETT. Vol. 29, No. 11 (2012) 110302
𝜕2
the Galerkin spectral method,[19,20] the time-splitting with the linear operator 𝐻ˆ0 = − 21 𝜕𝑥 1 2
2 + 2𝑥 . Here
Fourier transformation method,[21,22] and so on, for 𝑞 ∈ [0, 1] is the embedding parameter and 𝑐0 is the
solving the GPE. Many researchers have investigated convergence-control parameter. When 𝑞 = 0, Eq. (6)
the GPEs analytically,[23−31] but most works are fo- becomes
cused on the case that the trapping potential is not
harmonic or the coefficient of the atom-atom interac- 1 𝜕 2 Φ(𝑥, 0) 1 2
− + 𝑥 Φ(𝑥, 0) = 𝑀 (0)Φ(𝑥, 0). (7)
tion is not a constant. In fact, it is challenging to 2 𝜕𝑥2 2
find the exact analytical solutions to Eq. (1) with a Equation (7) is a linear Schrödinger equation with
harmonic oscillator potential and a constant interac- harmonic potential for stationary state. Consider-
tion coefficient. In this Letter, an analytical approach ing that we seek the ground state solutions of the
based on the homotopy analysis method (HAM)[32−38] 1D GPE, Φ(𝑥, 0) can be chosen as Φ(𝑥, 0) ∝ 𝑒−𝑥 /2
2
of the first equation (𝑘 = 0) can be obtained easily al- The coefficient 𝑐10 can not be determined now. With-
though all the equations are linearized. It is rather dif- out loss of generality, one can adopt 𝑐10 = 0 because it
ficult to obtain the exact solutions for 𝜓𝑘 when 𝑘 > 0. can be combined with 𝑐00 and determined by the nor-
We now use the Galerkin spectral method to find the malization condition of Ψ (𝑥). For the same reason,
approximate analytical solutions for 𝜓𝑘 of Eq. (10). we take 𝑐𝑘0 = 0 (𝑘 > 0).
For a given 𝑘, suppose that 𝜓𝑗 and 𝜇𝑗 (𝑗 = A similar way can be used to find 𝜓𝑘 and 𝜇𝑘 (𝑘 >
0, 1, . . . , 𝑘 − 1) are known and we will seek 𝜓𝑘 and 𝜇𝑘 . 1). As 𝑘 and 𝒩 increase, however, the computational
Let us consider a basis set of functions, {𝜑𝑛 (𝑥)|𝑛 = quantity will increase rapidly. Fortunately, the proce-
0, 1, . . . , 𝒩 }, perhaps satisfying some set of boundary dure described above can be implemented easily with
conditions over the interval (−∞, +∞), which is com- the aid of symbol calculation software, such as Maple
plete enough for expanding the unknown function over or Mathematica. Finally, at the 𝐾th order approxi-
that interval to sufficient accuracy. For simplicity we mation we have the analytical solution
assume that these functions form an orthonormal ba-
sis for the space. Hermite polynomials are a natural 𝐾
∑︁
choice for this problem, as they are the eigenfunc- Ψ (𝑥) ≈ Ψ 𝐾 (𝑥) = 𝜓0 (𝑥) + 𝜓𝑘 (𝑥),
tions of the linearized GPE in harmonic traps and 𝑘=1
consequently satisfy the proper boundary conditions 𝐾
∑︁
by construction. Thus, we take 𝜇 ≈ 𝜇𝐾 = 𝜇0 + 𝜇𝑘 . (19)
𝑘=1
√
√︁
2
𝜑𝑛 (𝑥) = 𝑒−𝑥 /2 𝐻𝑛 (𝑥)/ 2𝑛 𝑛! 𝜋, 𝑛 = 0, 1, . . . , 𝒩 ,
(11) The zeroth-order approximation for Ψ (𝑥) is
where 𝐻𝑛 (𝑥) is the Hermite polynomial with order 𝑛
𝑑𝑛 −𝑥2
2 1 −𝑥2 /2
𝐻𝑛 (𝑥) = (−1)𝑛 𝑒𝑥 𝑒 . (12) Ψ (𝑥) ≈ Ψ 0 (𝑥) = 𝑐00 𝜑0 (𝑥) = √ 𝑒 ,
𝑑𝑥𝑛 4
𝜋
The basis functions {𝜑𝑛 |𝑛 = 0, 1, . . . , 𝒩 } form an or- 𝜇 ≈ 𝜇0 = 0.5. (20)
thonormal set which satisfies
∫︁ +∞
This is just the Gaussian profile, which can be re-
⟨𝜑𝑛 |𝜑𝑗 ⟩ = 𝜑𝑛 (𝑥)𝜑𝑗 (𝑥)𝑑𝑥 = 𝛿𝑛𝑗 , (13) garded as an approximate solution to Eq. (4) only
−∞
ˆ 0 𝜑𝑛 (𝑥) = (𝑛 + 1/2)𝜑𝑛 (𝑥). for the case that the atom-atom interaction is rather
𝐻 (14)
weakly, i.e., the value of 𝑔 is very small.
All the unknown functions 𝜓𝑘 (𝑘 = 0, 1, . . .) now can The first-order approximation for Ψ (𝑥) is
be expressed as the linear combination of the basis
functions Ψ (𝑥) ≈ Ψ 1 (𝑥) = 𝑐00 𝜑0 (𝑥)
𝒩
[𝒩 /2]
𝑐0 𝑔𝑐3 ∑︁ (−1)𝑛 (2𝑛 − 1)!!
∑︁
𝜓𝑘 (𝑥) = 𝑐𝑘𝑛 𝜑𝑛 (𝑥), (𝑘 = 0, 1, . . .) (15) + √ 00 √︀ 𝜑2𝑛 (𝑥)
𝑛=0 2𝜋 𝑛=1 2𝑛 22𝑛 (2𝑛)! (21)
where 𝑐𝑘𝑛 are expansion coefficients.
For the case of 𝑘 = 0, we can choose 𝜓0 (𝑥) = 𝑐 𝑔𝑐2
𝑐00 𝜑0 (𝑥) with 𝑐0𝑛 = 0(𝑛 > 1) and 𝜇0 = 1/2. The co- with 𝜇 ≈ 𝜇0 +𝜇1 = 12 − √ 0 00
2𝜋
, where [𝒩 /2] denotes the
efficient 𝑐00 can be determined by the normalization integer part of 𝒩 /2, 𝑐00 should be determined by the
condition of the order parameter Ψ (𝑥). For 𝑘 = 1, we normalization condition. We will discuss how to de-
have termine the adjustable parameter 𝑐0 later. It is worth
noting that the Gauss-Hermite quadrature, employed
(𝑛 + 1/2)𝑐1𝑛 − 𝜇0 𝑐1𝑛 − 𝜇1 𝑐00 ⟨𝜑0 |𝜑𝑛 ⟩
in Refs. [19,20], is also used, which makes our method
= 𝑐0 𝑔𝑐300 ⟨𝜑30 |𝜑𝑛 ⟩, (𝑛 = 0, 1, . . . , 𝒩 ) (16) more efficient to implement using computer algebraic
from which one can obtain software.
Using 23 Na as an example, 𝑚 ≈ 3.8194 × 10−26 kg,
𝑐0 𝑔𝑐2
𝜇1 = −𝑐0 𝑔𝑐200 ⟨𝜑30 |𝜑0 ⟩ = − √ 00 , (17) ~ ≈ 1.05457 × 10−34 J·s, 𝑎s = 10𝑎B ≈ 0.52917 nm,
2𝜋 where 𝑎B ≈ 0.052917 nm is the Bohr radius. The
and frequencies of the external magnetic potential are
𝑐0 𝑔𝑐300 3 adopted as 𝜔𝑥 = 2𝜋×40 Hz, 𝜔𝑦 = 𝜔𝑧 = 2𝜋×130 Hz.[40]
𝑐1𝑛 = ⟨𝜑0 |𝜑𝑛 ⟩ Then we have 𝑔 ≈ 1.04 × 10−3 N. The value of 𝑔
{︃ 𝑛 is about 1 when 𝑁 = 103 and it is about 10 as
0, 𝑛 is odd,
= 𝑐0 𝑔𝑐300 (−1)𝑛/2 (𝑛−1)!! 𝑁 = 104 . Obviously, the atom-atom interaction in-
√
2𝜋
√
𝑛 2𝑛 𝑛!
, 𝑛 is even, creases as the total number of particles increases. If
𝑛 = 1, 2, . . . , 𝒩 . (18) we take the 7 Li as an example, 𝑚 ≈ 1.1624×10−26 kg,
110302-3
CHIN. PHYS. LETT. Vol. 29, No. 11 (2012) 110302
𝑎s = −18𝑎B ≈ −0.9525 nm, then 𝑔 ≈ −1 when choose an appropriate range for 𝑐0 which ensures the
𝑁 = 103 . convergence of the series. In practice, we take 𝐾 = 10
In the framework of the HAM, the solution is ex- and 𝒩 = 8. Figure 1 shows the chemical potential 𝜇
pressed as a series of basis functions. Note that the versus 𝑐0 for different values of 𝑔. We can see from
solution contains the adjustable parameter 𝑐0 , which Fig. 1 that there exists an appropriate range for 𝑐0 to
provides us with a simply way to adjust and control get convergent solution of 𝜇. It is clear that as 𝑔 in-
the convergence of the solution series. In general, by creases, the interval of convergence becomes smaller
means of the so-called 𝑐0 -curve, it is straightforward to and smaller. It fails to converge as 𝑔 is large enough.
Table 1. Comparison of the analytical results with the numerical results of chemical potential 𝜇 and energy 𝐸 for different values
of 𝑔. The subscript n and a denote the numerical result and analytical result, respectively.
𝑔 𝜇n 𝜇a 𝐸n 𝐸a 𝑒a ‖𝜖‖2 𝑐0
0.0 0.5 0.5 0.5 0.5 0 0
1.0 0.869940 0.869944 0.689486 0.689487 −2×10−6 5×10−7 −0.90
2.0 1.194849 1.194859 0.862485 0.862487 −1×10−5 2×10−5 −0.85
4.0 1.758700 1.758664 1.173482 1.173484 −1×10−4 2×10−5 −0.75
6.0 2.250211 2.250073 1.452032 1.452036 −4×10−4 5×10−5 −0.60
8.0 2.695244 2.693612 1.708006 1.708026 −3×10−3 2×10−4 −0.55
10.0 3.107240 3.100232 1.947127 1.947176 −1×10−2 3×10−4 −0.50
−0.5 0.291641 0.291657 0.397353 0.397358 −7×10−5 5×10−5 −1.00
−1.0 0.062754 0.062979 0.288220 0.288270 −6×10−4 5×10−4 −1.05
0.8
3.0 =10.0 =-1 Numerical result
1
Analytical result
0.6 5
10
2.0 15
0.4
| |
1.0
0.2
0.0 0.0
-1.2 -0.9 -0.6 -0.3 0.0 -4 -2 0 2 4
Fig. 1. The chemical potential 𝜇 versus 𝑐0 for different Fig. 2. Profile of wave function |Ψ| for different values of
value of 𝑔. 𝑔.
We can define the residual error Table 1 lists the numerical values of the chemical
potential 𝜇 and the energy 𝐸 per particle, given by the
ˆ 0 Ψ 𝐾 (𝑥) + 𝑔(Ψ 𝐾 (𝑥))3 − 𝜇𝐾 Ψ 𝐾 (𝑥)
𝜖(𝑥) = 𝐻 (22) ITP method, and the analytical results obtained by
the HAM described previously, for different values of
to measure the accuracy of the 𝐾th-order approxi- 𝑔. The value of 𝑐0 we choose can ensure that the series
mate solution we derived. The squared norm of 𝜖 can are convergent. In Table 1, 𝑒a = 2𝐸kin − 2𝐸pot + 𝐸int ,
be defined as where 𝐸kin , 𝐸pot , 𝐸int are the dimensionless kinetic
energy, potential energy and interaction energy, re-
∫︁ +∞
‖𝜖‖2 = 𝜖(𝑥)2 𝑑𝑥. (23) spectively. From the Virial theorem we know that
−∞ 2𝐸kin − 2𝐸pot + 𝐸int = 0 for the steady state of the
BEC system we are considering. Differences between
Obviously, Ψ (𝑥) = Ψ 𝐾 (𝑥) is an exact solution for the 𝐸n (numerical result) and 𝐸a (analytical result)
Eq. (4) when ‖𝜖‖ = 0. In general, the fact is that are very small (∼10−6 ), which means that the corre-
‖𝜖‖ ≠ 0. We think that the smaller the value of ‖𝜖‖2 , sponding wave function we derived is a good approxi-
the more precise the solution is. This implies another mation for the ground state of the BEC system. It is
way to determine the value of 𝑐0 is by minimizing clear that the analytical results agree very well with
the squared norm of ‖𝜖‖2 theoretically. However, it the numerical results as |𝑔| is not too large. It also
is rather complicated to perform such a computation can be seen that the error increases as the value of |𝑔|
in practice. We still prefer the former method, via increases. Although we can decrease the error by in-
observing the so-called 𝑐0 curve, to select an appro- creasing 𝐾 or 𝒩 , but the computational quantity will
priated value for 𝑐0 . increase rapidly, which indicates that our method is
110302-4
CHIN. PHYS. LETT. Vol. 29, No. 11 (2012) 110302
suitable for solving GPE that the atomic interaction [13] Dalfovo F, Giorgini S, Pitaevskii L P and Stringari S 1999
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[14] Kevrekidis P G, Theocharis G, Frantzeskakis D J and Mal-
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