Excel file for the calculation of DIC in seawater with infrared detection and uncertainties by the K

Please cite as: Bernal C., Sanchez-Cabeza J.A., Gómez M., Perez, E., Herrera J., Ruiz G., & Cartas H. (2021) Excel file for the calc
infrared detection and uncertainties by the Kragten method. Red de Investigación de Estresores Marinos - Costeros en Latinoa
Santa Marta, Colombia. https://remarco.org/manual-ao/

This work follows the procedures published by REMARCO (https://remarco.org/manual-ao/)

Please read the manual
Written by Cesar A. Bernal, INVEMAR, 2021-10-23
Revised by Prof. Joan-Albert Sanchez-Cabeza, 2021-10-24
Sheet Input: sample data and measurements. This is the only sheet where the user enters information
Sheet Results: final results are presented
Sheet Kragten-DIC (occult): the Kragten method is used for uncertainty calculations
To avoid accidental changes of calculation cells, only the worksheet Input is unlocked
To unlock, the password is remarco (lowercase)

Please, send your comments to Cesar Bernal <cesar.bernal@invemar.org.co>

This work was supported by the International Atomic Energy Agency - IAEA, through the project RLA/7/025 entitled "Streng
Coastal Environments Using Nuclear and Isotopic Techniques".
 uncertainties by the Kragten method
H. (2021) Excel file for the calculation of DIC in seawater with
Marinos - Costeros en Latinoamérica y El Caribe – REMARCO.

ct RLA/7/025 entitled "Strengthening Capacities in Marine and

pic Techniques".
crm.code crm.info crm.temperature crm.area sample.code
batch.171 crm.dic 2029.19 25.99 27411 invemar.1
crm.dic.u 0.29 27415
crm.salinity 33.434
crm.sal.resolution 0.001
crm.volume.ml 2.00000
crm.vol.resolution 0.00005
crm.tem.resolution 0.01
crm.area.resolution 1
sam.info sam.sal sam.tem.ana sam.area sam.sal.repetitions
sam.sal.resolution 0.1 33.5 25.87 28349 33.5
sam.tem.ana.resolution 0.01 28370 33.4
sam.volume.ml 2.00000 33.4
sam.vol.resolution 0.00005 33.5
sam.area.resolution 1 33.5
33.5
33.5
33.4
33.5
33.5
tem.ana.repetitions area.repetitions volume.repetitions dic.repetitions repetibilities
25.82 26293.00 1946.35 sal.repetibility
25.77 26266.00 1949.95 vol.repetibility
25.74 26259.00 1952.61 tem.ana.repetibility
25.80 26268.00 1951.81 area.repetibility
25.40 26291.00 1953.30 dic.repetibility
25.23 26293.00 1948.86
25.78 26252.00 1949.19
25.12 26263.00 1947.43
26.12 26249.00 1952.01
25.43 26278.00 1951.12
0.000085
SUMMARY
DIC = 2099.07
u(DIC) = 0.98
ue(DIC) = 1.96 K=2
Quality index = 66.67 %

UNCERTAINTIES crm.dic crm.sal crm.tem sample.sal sample.tem

Numbers:
n sample 1 1 1
n repetitions 10 10 10
n repetibility 0 0 0

Repetibility:
Sample 0.0000 0.0000 0.0000
Repetitions 0.0984 0.0153 0.0984
Repetibility 0.0000 0.0000 0.0000

Uncertainties:
Mean 2029.19 33.4340 25.9900 33.5000 25.8700
u(repetibility) 0.0984 0.0153 0.0984
u(resolution) 0.0003 0.0029 0.02887 0.00289
u(combined) 0.2900 0.0003 0.0984 0.0327 0.0984

Quality index:
Maximum 3 3 3
Value 2 2 2
 UNCERTAINTY BUDGET (PLOT)

60

sample.area crm.area sample.volume crm.volume dic 50

40

2 2 1 1 0 30
10 10 0 0 10

Variance (%)
0 0 1 1 0 20

10

0.0000 0.0000 0.0000 0.0000 0.0000 0

)
5.2743 5.2743 0.0000 0.0000 0.7262 SU
(P
0.0000 0.0000 0.0001 0.0001 0.0000 M
CR e
ity ur
lin rat
Sa pe
m
Te
28359.5000 27413.0000 2.0000 2.0000
5.2743 5.2743 0.0001 0.0001 0.7262
0.2887 0.2886751 0.0000150 0.0000150
5.2822 5.2822 0.0001 0.0001 0.7262

3 3 2 2 2 21 Maximum value
2 2 1 1 2 14 Sum
67 % Quality index
 NCERTAINTY BUDGET (PLOT)

Uncertainty budget
60

50

40

30
Variance (%)

20

10

0
) ) U) ) e L) L) g) C
SU (°C PS (°C pl CR
M
(m (m l/K DI
(P M ( re a m a a o
M CR ity tu S
Ar
e tr
CR
M m
CR e lin e ra rea m (µ
ity ur S a p A e e M
lin rat m lu
m lu
m
CR
Sa pe Te Vo Vo
m
Te

Maximum value

uality index