sase2or7 cueistay— cv SECTION~-A MULTIPLE CHOICE QUESTIONS (MCQ) Q.1-Q.10 carry one mark each. Q.1 ‘The correct order of the boiling points of the compounds is (A) CH, > Si > Sn > Gels (B) Sille> CH,> Gells > Sn, (C) Sn: > GeHs > CHs> Silty (D) Sn. > GeHs > SiH. > CH Q2 Inthe following Latimer diagram, the species that undergoes disproportionation reaction is 1056 a 4 + -025 =156 Mn0¢ 25S vino 22% nino, 228 nino, 215 nino, 275 ain(or = Min (A) Mn. (8) Mn (©) MnOr (D) Mn(OH)> 3. Ayellow precipitate is formed upon addition of aqueous AgNOs to a solution of (A) phosphite (B) pyrophosphate (©) metaphosphate (D) orthophosphate Q4 The compounds having Cs-axis of symmetry are Me 8r Me KR 0 Me“ Me Me “Me Br Br Me" "Me ' " ul v (A) I Mand IV (B)1, Hand ttt (©) land ttt (D) Ill and 1V Q5 ‘The correct order of rate of solvolysis forthe following compounds is Br Br ' im (A) > > 1 (B) > 1> (© >t (D) >> 1 Q6 In the following sequence of reactions, the overall yield (%) of O is 92% yield 78% yield 85% yield L.———> » ——> n——> o (ayer (B85 «4 (D) 68 wv a2am2007 ‘cHewisTRY - CY Q7 Catalytic hydrogenation ofthe following compound produces saturated hydrocarbon(s). The number of stereoisomer(s) formed is Me Me me AA. Me ll (B)2 ©3 (D4 Q8 The number of normal modes of vibration in naphthalene is (a) ss (B54 (48 (D) 49 Q9 The number of degrees of freedom of liquid water in equilibrium with ice is (ayo @)I ©@2 (3 10 4 suite having « slope of ~Y!/pis obtained ina plot between (A) Ink versus T (B) Inke versus T (O)Ink, versus 1/T (D) Ink versus V/T Q.11-Q. 30 carry two marks each. Q.11 Inatypical conductometric titration of a strong acid with a weak base, the curve resembles “ ®) Conductance Conductance | Volume of base ‘Volume of base © ©) conductance conductance Volume of base Volume of base Q.12 The coordination number of Al in crystalline AICI; and liquid AICls, respectively, is (A)4and 4 (B)6and6 (©) 6and4 (D) 3 and 6sasca017 Qu3 Qu Qs Qué Quy Qus Qs cuenasrry - cy ‘The homogeneous catalyst used in water-gas shift reaction is (A) PaCls (B)Cr0s (©) [RhCKPPh)s} (D) [Rule ridyl):] Nitrosyl ligand binds to d-metal atoms in linear and bent fashion and behaves, respectively, as (A) NO* and NO" (B) NO“ and NO“ (C) NO“and NO“ (D) NO and NO* ‘The metal ion (M) in the following reaction is ____ hot cone. HNOs M* + s%* ——» Black precipitate ————*» White precipitate (A) Mn (B) Fe" coce* (0) Cu* ‘The correct order of wavelength of absorption (Zen) of the Cr-complexes is (en = ethylenediamine) (A) [CeFe}*> [Cx(HO)ef* > [Cr(en)sP” > [C(CN).] (B) [Cr(H20)s}”* > [CrFe}> [Cr(en)s]* > [Cr(CN)s}~ (©) [CH(CN)o} > [Cr(en)s]°*> [Cr(H:0)6}”* > [Cre] (D) [Crfen)s]""> [Cr(CN)s}“> [CHO] > [CrP] The correct order of enthalpy of hydration for the transition metal ions is (A) C+ > Mnt* > Co® > Nit (B) Ni? > Co?" > Mn** > Ce (C) Ni? > Co? > Cr" > Ma (D) Cr > Mnt* > Ni?" > Co? ‘Among the following compounds, the pair of enantiomers is, CO HL er H HaN—-H H CH,OH 1 (A) Tand IV (B) Land HL (©) Wand tt (D) Mand IV ‘The number of proton NMR signals for the compounds P and Q, respectively, is rh Ld Me. P Q anJAM 2017 cuenasrey— cv Q.20 The correct set of reagents forthe following conversion is OMe OMe Br CN (A) (i) NaNHs/lig. NH; (ii) NaNOydil. HCI; (iii) CuCN, heat (B) (i) HNOWH,SO4; (ii) Zn/HCI; (iti) ) NaNOz/dil, HCl; (iv) CuCN, heat (©) (i) Mefether, Hs0* ; (i) (Et0):CO; (iii) NH.OH; (iv) PCls (D) (i) Ma/ether, HsO* ; (i) HNOs/H:SOx; (iii) NaNO2/dil, HCI; (iv) CuCN, heat Q21_ The product R in the following reaction is Coe () Ozonolysis R Sore (A) (B) ° ‘eon cy © (D) ° ° : " Beton Ho) s (A) (B) i iO 10 ot x , or © (D) ar saJam2017 Q23 Q24 Q25 ‘cheney cv In the following reaction, the major product T is (i) polyphosphoric acid “ @) Me Me ° oO (0) Me Sle 7 ‘The following conversion is carried out using ov— om (A) hydroboration-oxidation followed by Jones oxidation (B) Wacker oxidation followed by haloform reaction (©) oxymercuration-demercuration followed by Jones oxidation (D) ozonolysis followed by haloform reaction In the following reactions, the major products E and F, respectively, are OH ()NaOHICO, 125°C, 4-7 atm (CHscO)20 = ——+ F (i) H,0* a) ®) on ‘coc, oH 9cocH, CH CO;CHy and and CoH CoH © ©) o# ‘9cocHs oH ococH, CO,H cO3H and and CoH Go,CH, w onsa2007 cHenisrey — cv 26 $ = 2 i, itera eqtion fron (yore (B)eipse (C) bell-shaped curve (D) hyperbola Q27 Value ofthe given determinant is R24 I-10 2) (A)-12 (B)0 6 (D) 12 Q.28 _Ionisation energy of hydrogen atom in ground state is 13.6 eV. The energy released (in eV) for third member of Balmer series is (A) 13.056 (B) 2.856 (©) 0.967 (D) 0.306 Q29 For a first order reaction A(g) -+ 28(g) + C(g), the rate constant in terms of initial pressure (po) and pressure at time ¢ (p,), is given by. 2 py —2P0 1), 3P0 a ©) {ina © {Ine (D) Fin i (A) pin Bpree een PP Q.30_ Fora particle in one-dimensional box of length L with potential energy V(x) © 0 for L > x > 0 and V(x) = 0 for x> L and x < 0, an acceptable wave function consistent with the boundary conditions is, (4, B, Cand D are constants) (A) Acos =) (B) B(x + x?) (©) Cx3(x = L) o— sin) SECTION -B MULTIPLE SELECT QUESTIONS (MSQ) Q.31-Q. 40 carry two marks each. Q31_ The “heme” containing protein(s) is/are (A) cytochrome C—(B) hemocyanin (C) hemerythrin_(D) myoglobin 32 Among the following, the species having see-saw shape is/are (a sF (B)XeFs © cre ©) cre Q33. The indicator(s) appropriate for the determination of end point in the titration of a weak acid with a strong base is/are (A) phenolphthalein (B) thymol blue (©) bromophenol blue (D) methyl orange ee msava017 ‘chewistay cy Q4 Q35 36 Q37 Q38 Q39 Qo wr Jahn-Teller distortion is observed in octahedral complexes with d-electron configuration of (A)d-high spin (B)d* low spin (©) d’-high spin (D) a*- tow spin Among the following, the correct statement(s) is/are (A) Guanine isa purine nucleobase (B) Glycine and proline are achiral amino acids (©) DNA contains glycosidic bonds and pentose sugars (D) Sucrose is a non-reducing sugar ‘The INCORRECT statement(s) among the following is/are (A) [4x+ 2] cycloaddition reactions are carried out in presence of light (B) [2x+2n] cycloaddition reaction between a keto group and an alkene is photochemically allowed (C)_ [4x + 2x] cycloaddition reactions are thermally allowed (D) Transoid dienes undergo Diels-Alder reactions ‘The following conversion is an example of os Heat a SS Meh Me ud (A) oxy-Cope rearrangement (B) sigmatropic rearrangement (C) Claisen rearrangement (D) pericyclic reaction IR active molecule(s) is/are (A) COr (B) CS: (Qocs (D)Nz Intensive variable(s) is/are (A) temperature (B) volume (©) pressure (D) density Wave nature of electromagnetic radiation is observed in (A) diffraction (B) interference (C) photoelectric effect (D) Compton scattering asane2017 ‘cuewistRY - CY SECTION -C NUMERICAL ANSWER TYPE (NAT) Q.41-Q. 50 carry one mark each, Q41_ The number of isomeric structures of di-substituted borazine (B:NsHsX2) Q42__ The number of S-S bones) in tetrathionate ion is Q43._ Thenumber of unpaired electron(s) in K:NiFe is Q44 The number of reducing sugars among the following is Que OH OH OH OOH OH Otome HO ‘OH CH,OH 9, ronson ee Ho OH Ho OH Q45_ The maximum number of dipeptides that could be obtained by reaction of phenylalanine with leucine is Q46 Among the following, the number of aromatic compound(s) is s Ocrogsos o yhe BRS Q47 _At.an operating frequency of 350 MHz, the shift (in Hz) of resonance from TMS (teramethylsilane) of a proton with chemical shift of2 ppm is w omQs Qs Q50 ccuienasrey — cy ‘At 298 K and 1 atm, the molar enthalpies of combustion of cyclopropane and propene are =2091 kJ mol and ~2058 kI mol", respectively. The enthalpy change (in kJ mot) for the conversion of one mole of propene to one mole of cyclopropane is, For a cell reaction, Pb(s) + HgzCla(s) > PbCIa(s) + 2Hg(D, (SE) is 1.45104 VK~. The ? entropy change (in J mol" K") for the reaction is [Given: 1 F = 96500 C mot] For a reaction 2A + B > C+D, of C (in mot L's“) is rate of consumption of 4 is 0.1 mol L™s", the rate of production Q.51-Q. 60 carry two marks each. Qst Qs2 Qs3 Qs4 Qs5 ‘The standard reduction potentials of Ce"/Ce"" and Fe"/Fe" are 1.44 and 0.77 V, respectively. The logiok (K is the equilibrium constant) value forthe following reaction is (inal answer should be rounded off to two decimal places) Cots Fe? = Co Fe [Given: RT/F = 0.0257 V] A radioactive element undergoes 80% radioactive decay in 300 min. The half-life for this species in minutes is _ Silver crystallizes in a face-centered cubic lattice, The lattice parameter of silver (in picometer) is [Given: Avogadro's number 6,023 x 10 mol, molar mass of silver = 107.87 g mol" and density of crystal = 10.5 gem") ‘The amount of bromine (atomic wt.= 80) required (in gram) for the estimation of 42.3 g of phenol (molecular wt. = 94 g mol") is The total number of pair of enantiomers possible with molecular formula CsH1:0 is vo1avs2017 Q56 Qs7 Qs8 59 Q.60 w cHeMIsray— cv In 200 g of water, 0.01 mole of NaC! and 0.02 mole of sucrose are dissolved. Assuming solution to be ideal, the depression in freezing point of water (in °C) will be (final answer should be rounded off to two decimal places) (Given: K;(H20) = 1.86 K kg mot} ‘The adsorption of a gas follows the Langmuir isotherm with K'= 1.25 kPa! at 25 °C. The pressure (in Pa) at which surface coverage is 0.2 is ‘The separation of 123 planes (in nm) in an orthorhombic cell with a = 0.25 nm, 6 = 0.5 nm and = 0.75 nm (Final answer should be rounded off to two decimal places) ‘A vessel contains a mixture of Hz and No gas. The density of this gas mixture is 0.2 g L~! at 300 K and 1 atm, Assuming that both the gases behave ideally, the mole fraction of No (g) in the vessel (inal answer should be rounded off to two decimal places) [Given: R= 0.082 L atm mot” K-', atomic wt, of hydrogen = 1.0 and atomic wt. of nitrogen = 14.0] Consider an isothermal reversible compression of one mole of an ideal gas in which the pressure of the system is increased from 5 atm to 30 atm at 300 K. The entropy change of the surroundings (in dK) is (inal answer should be rounded off to two decimal places) [Given: R = 8.314 J mol"! K-!] END OF THE QUESTION PAPER hanJAM 2018; CHEMISTRY CY SECTION-A MULTIPLE CHOICE QUESTIONS (MCQ) Q. 1-Q.10 carry one mark each. QI Onhydrolysis, aluminium carbide produces (A) CHs (B) CoH. (OCH (D) CoH Q.2 Carbonic anhydrase is an example of (A) Hydrolysis enzyme (B) Redox enzyme (©) Oe transport protein (D) Heme protein Q3 The CORRECT order of melting points of group 15 trifluorides is (A) PF) < ASF) < SbF) < Bis (B) BiFs < SbFs < PFs < AsFs (C) PFs < SbFs < ASPs < Bil (D) BiFs < ASF) < SbF: < PF: Q4 NaF, KF, MgO and CaO are crystalline solids. They have NaC! structure, Their lattice energies vary in the order (A) NaF < KF < MgO < C20 (B) KF < NaF < CaO 0 > Cl (B) First ionisation energy order is A> Mg > K (©) Atomic radius order is N > P > As (D) Ionic radius order is K* > Ca®* > Mg” orJAM 2018; Qu Qus Qu4 CHEMISTRY - CY Which plot represents a spectrophotometric titration, where the titrant alone absorbs light in the visible region? (A) (B) A A ee $B] endpoint £2| endpoint Ee 52 \ 3: | 2 a Volume of tran Volume ofirant © (D) A A cd point be | Be end point 2 — Volume of titrant Volume of titrant Among the following metal carbonyl species, the one with the highest metal-carbon back bonding (A) [Ti(CO)a (B) [V(CO}- (C)CHCO)«, (D) [Mn(CO).}* ‘The CORRECT order of As (the octahedral crystal field splitting of d orbitals) values for the following anionic metal complexes is (A) [Ir(CN) gf < [Rh(CN)6} < (Rll < [Coley (B) [Cole}* < [Rhlo}® < [Rh(CN)o}* < [Ir(CN)oF* (©) [Cole] < [Rh(CN)o]* < [Rho] < [Ir(CN) oI (D) [In(CN)eI* < [Cole}*-< [Rh(CN)e}* < [RhT] ‘The decay modes of '4C and “40 are (A) Bedecay (B) positron emission (C) B decay and positron emission, respectively (D) positron emission and B decay, respectively x wssav 2018 curemusTay cy Q.16 Consider the following four xenon compounds: XeF2, XeF:, XeFsand XeO3 ‘The pair of xenon compounds expected to have non-zero dipole moment is (A) XeF, and XeFe (B) XeP, and XeF, (C) XeF,and XeO3 (D) XeFe and XeOs Q.17 The CORRECT order of stability for the following carbocations is lo ma oS " u v (A)I: Ces “a CO2CH3, ®) .CO2CHs © (D) CO;CH, CO,CHy oe aaJAM 2018; CHEMISTRY - CY Q.22. The major products ¥ and Z in the following reaction sequence are wi “en (excess) 4) Et0Na, then HO" 2) NaOH, then H;0", heat “ H ® (oo. cy = ze © H (@) Q23 The CORRECT order of carbonyl stretching frequencies for the following compounds is ° ° ° ©. 7 cl N H or Crore 1 " um Vv (yii Products, follows first-order kinetics. If [A] represents the concentration of reactant at time f, the INCORRECT variation is shown in “ ®) a) > \ te — © oy =A loglAl = = xJAM 2018; CHEMISTRY CY Q28 Q29 Q30 ‘The behavior of Clz is closest to ideal gas behavior at (A) 100°C and 10.0 atm (B)0°C and 0.50atm (C) 200°C and 0.50 atm (D) =100°C and — 10.0 atm A vector A = 7+ x7 + 32 is rotated through an angle and is also doubled in magnitude resulting in B= 4¢+ (4x —2)j + 2k. An acceptable value of x is at B)2 ©3 () 4/3 With reference to the variation of molar conductivity (Am) with concentration for a strong. electrolyte in an aqueous solution, the CORRECT statement is (A) The asymmetry effect contributes to decrease Ay, whereas the electrophoretic effect contributes to increase Amy (B) The asymmetry effect contributes to increase Aj, whereas the electrophoretic effect contributes to decrease Ay, (©) Both asymmetry effect and electrophoretic effect contribute to decrease Ayy (D) Both asymmetry effect and electrophoretic effect contribute to increase Ayy SECTION -B MULTIPLE SELECT QUESTIONS (MSQ) Q.31-Q. 40 carry two marks each. Q3i Q32 Q33 Which of the following metal(s) is(are) extracted from its(their) sulfide ore(s) by self-reduction/air reduction method? (acu (B) AL (au (D) Pb In a saturated calomel electrode, the saturation is with respect to (KCl (B) Hach. (© Bech (D) AgCl Consider the following six solid binary oxides: Ca, AlLOs, PbO, Cs:0, SiO2 and Sb.Os. ‘The pair(s) of ionic oxides is(are) (A) CaO and AO; (B)CaO and PbO (C) Cs:0 and Al; (D) SiO2 and Sb:0s x mmsJAM 2018; CHEMISTRY CY Q34 Q35 Q36 Choose the CORRECT answer(s) with respect to the magnesium-EDTA titration carried out in the pH range 7 — 10.5, using Solochrome black as indicator (A) Magnesium-indicator complex is more stable than the magnesium-EDTA complex (B) Atthe end point, the colour changes from red to blue (C) After the end point, the colour of the solution is due to the indicator (D) pH range of 7- 10. necessary for observing the specific colour change On reaction with NaNO, and HCl, which of the following amino alcohol(s) will yield compound P? "CHO “ NH, ® sl pr det. - OH © se o NH oo OH ‘The CORRECT statement(s) about carbene is(are) (A) Carbene is a neutral species (B) Carbene is an intermediate in the Curtius rearrangement (C) Carbene can insert into both o and a-bonds (D) Carbene is generated from amines on reaction with nitrous acid ‘The compound(s) that shows(show) positive haloform test is(are) Oo ce om oe HC ° © SCH (A) © HyC" x TosJAM 2018; CHEMISTRY CY Q38 Q39 Q4o ‘Tetrapeptide(s) that gives(give) the following product on reaction with Sanger’s reagent followed by hydrolysis is(are) NO2 ,, N_COH on CH (A) Ala-Gly-Leu-Phe (B) Asp-Phe-Leu-Pro (©) Asp-Gly-Tyr-Phe (D) Ala-Phe-Tyr-Pro of the following set(s) of quantum numbers is(are) NOT allowed? (B)n=4,1=0, m, ‘The CORRECT expression(s) for isothermal expansion of 1 mol of an ideal gas is(are) (a) AA = RT in at (8) AG = RT in ust (© AM = RT In weae () AS = R In wLnee Vena Vina SECTION -C NUMERICAL ANSWER TYPE (NAT) Q. 41 —Q. 50 carry one mark each. Q4l Q42 Qs ‘The number of possible isomers for [Pt(py)(NHs)BrCl] is . (py is pyridine) ‘The volume of 0.3 M ferrous ammonium sulphate solution required for the completion of redox. titration with 20 mL of 0.1 M potassium dichromate solution is mL. Among the following hydrocarbon(s), how many of them would give rise to three groups of proton NMR peaks with 2:2:3 integration ratio? Aw an OY x TasJAM 2018; CHEMISTRY CY Qa Q45 Q46 Qa7 Q.48 Q49 Q50 ‘The number of stereoisomers possible for the following compound is, Ph-CH-CH-Ph OH OH ‘The number of hydrogen bond(s) present in a guanine-cytosine base pair is ‘The time for 50% completion of a zero order reaction is 30 min, Time for 80% completion of this reaction is min, Consider the reaction CO(g) + 5 02(g) —> €02(g) ‘The value of AU for the reaction at 300 K is -281.8 kJ mol". The value of AH at same temperature is kJ mol ' (rounded up to the first decimal place). [R=833K' mol] ‘The nuclear spin quantum number (1) of a nucleus is. When placed in an external magnetic field, the number of possible spin energy states it can occupy is The value of Cy for 1 mol of Nz gas predicted from the principle of equipartition of energy, ignoring vibrational contribution, is, 101" (rounded up to two decimal places). [R = 8.3 JK ‘mol "] Assuming ideal gas behavior, the density of O2 gas at 300 K and 1.0 atm is up to two decimal places), [R = 0.082 L atm mot K", molar mass of O: = 32] gL" (rounded Q.51- Q. 60 carry two marks each. Q51 How many of the following interhalogen species have 2 lone pairs of electrons on the central atom? CIFs, CIF, CIFs and ICl* Na decays to one-fourth of its initial amount in 29.8 hours. Its decay constant is, hour (rounded up to four decimal places). ‘The magnitude of crystal field stabilization energy (CFSE) of octahedral [Ti(H2O)«]* complex is 7680 cm”. The wavelength at the maximum absorption (max) of this complex is om (rounded up to the nearest integer). x TasJAM 2018; CHEMISTRY CY Qs4 Q55 Q56 Qs7 Q59 Q.60 Elemental analysis of an organic compound containing C, H and O gives percentage composition C: 39.9 % and H: 6.7 %. If the molecular weight of the compound is 180, the number of carbon atoms present in the molecule is, ‘The number of compounds having S-configuration among the following is HyCH,C, CH,CHs H, ig ‘c=0= Hon go“O=e, er H. Hc bs BC CH NG Ct, Hj 4 The emf of a standard cadmium cell is 1.02 V at 300 K. The temperature coefficient of the cell is -5.0x10 V K™, The value of AH® for the cell is KJ mol" (rounded up to two decimal places). [1 F = 96500 C mot} For the reaction H2(g) + 5 02(g) —> Hz0(\), the following information is given T=300K AH? = ~285 kJ mol 58,(g) = 204.3 K mot! 5f,0(0) = 70.3 K mot! 5f,(g) = 130 K+ mot ASSniverse for the reaction is JK" mor, For Hb molecule, the fundamental vibrational frequency (8) can be taken as 4400 cm”. The zero- point energy of the molecule KJ mol (rounded up to two decimal places). [h= 6.610 J 5, ¢ = 310° ms, Ny = 6x10" mot!] ‘The solubility of PbI2 in 0.10 M KI(aq) is x10" M (rounded up to two decimal places). [The solubility product, Ky) = 7.1x10°] ‘The electron of a hydrogen atom is in its n Bohr orbit having de Broglie wavelength of 13.4 A. ‘The value of m i (rounded up to the nearest integer). [Radius of n'” Bobr orbit = 0.53n A, x= 3.14] END OF THE QUESTION PAPER x TasSECTION -A MULTIPLE CHOICE QUESTIONS (MCQ) Q. 1-Q.10 carry one mark each, QI Fora reaction of the type A + B > Products, the unit of the rate constant is mol L~! s“ The overall order of the reaction is (Ayo (By (2 (D)3 Q2__ The thermodynamic criterion for spontaneity of a process in a system under constant volume and temperature and in the absence of any work other than expansion work (if any) is (A) change in entropy is positive (B) change in enthalpy is negative (C) change in Helmholtz free energy is negative (D) change in Gibbs free energy is negative Q3__ The number of vibrational mode(s) of a carbon dioxide molecule that can be detected using, infrared spectroscopy is (ay (B)2 (3 (D4 Q4 For three non-coplanar vectors a, b and ¢, the expression a (b X ¢) can be written as (A) @xb)-e (B) (ax): (axe) (©) (ab) x (ac) (D)(a-b) xc Q.5 Correct trend in the bond order is (A) Of > 03" > OF (B) 07 > OF > OF- (©) 03" > 07 > OF (D) Of > OF > 03- Q6 The correct option for the metal ion present in the active site of myoglobin, hemocyanin and vitamin Bip, respectively, is (A) iron, iron and zine (B) molybdenum, iron and copper (C) iton, copper and cobalt (D) molybdenum, copper and cobalt SO asQ7 The correct order of wavelength (max) of the halide to metal charge-transfer band of [Co(NHs)sCIP* (1), [Co(NHs)sBr}?" (II) and [Co(NHs)sIP* (11D, is (A)II in their ground state is (A) NO, Bs, and C2 are paramagnetic (B) Bz, Op and NO are paramagnetic (C) 02, C2 and NO are paramagnetic (D) O2, Bp and C2 are paramagnetic Q.20 The observed magnetic moments of octahedral Mn**, Fe™* and Co complexes are 4.95, 6.06 and 0.00 BM, respectively. The correct option for the electronic configuration of Mn**, Fe** and Co metal ions in these complexes, respectively, is (A) thee. geg and they (B) tlgeh tized and tSget (O)thged thgog and thet (D) tage «gee and tigey Q.21 Among the following compounds, the one having the lowest boiling point is (A) SnCly (B) GeCly (C) SiCl (D) CCl Q.22 The correct option having one complex from each of the following pairs which is more reactive towards the oxidative addition reaction by hydrogen molecule is Pair I: InCl(PMes)s (1) and IrCl(CO)(PMes)2 (ID) Pair 2: IrCl(CO)(PPhs)2 (IIT) and IrCl3(PPhs) (IV) (A) (1) and (IIT) (B) (I) and (IV) (C) (ID) and (11) (D) (11) and (TV) Q.23. Among the following, the correct statement is a (A) The density follows the order, Cs > Rb > Li> Na. (B) The solubility in water follows the order, Cs2CO3 > KaCO3> NagCO3> LizCOs. (C) The first ionization potential follows the order, Li> K > Na> Cs. (D) The melting point follows the order, MgCl:> BeCl > CaCh> StCh. oussant 2019 cuenstey cv Q.24 The major product of the following reaction is Me; ny “pegten ‘mete-chioroperbenzoic acid (A) (B) ak ; ‘OH ‘Me L (c) (D) Me- Me Me- Me ; In 'H NMR spectrum of the given molecule, the correct order of chemical shifts of the labelled protons (H*, HY, H?) is z ss x oH HOW (A) H> BS > HY (B) Hé> HY > HX (C)IR> HY > Ht (D) HY > HX> He SO ms2.26 Q27 a In the following reaction of (D)-Glucose, a product P is formed. 1, BraftH,0 (Glucose ——= + p 2. H2O2, Fe{SO«)s Among the following compounds, the one which will give the same product (P) under identical reaction conditions is (A) 8) HO H-on Ho: HO--H HO: HOH Ht HO--H Ht CH,OH The major product of the following reaction is ° Me Trituoroacetic anhydride/H,O. HO" me (A) (B) Me ud Me COOH (D) CH,Q28 Q29 SO The correct option for the product(s) of the following reaction is 5 [ Ss NaNH2 Nn? Nes () (A) e QO HANT ON’ (@) oO : « — 0O:-a 7 (D) The increasing order of acidity of the given molecules in aqueous media is OH 9° ec, FCH,COOH CH,OH 1 " um wv (a) (B) we are paramagnetic, (B) NOb is paramagnetic and NO>* is diamagnetic (C) Both CO and NO2" have linear geometry. (D) CO» and NO» are isoelectronic. tosQ37 Q38 Q39 a ‘The compound(s) formed as intermediate(s) in the following reaction sequence is/are OMe OH 1) Li, NH, THE 2) O», MeOH. HS. 3) NaBH, EtOH SMe te _4)t0syl chloride (TSC, pyridine he 5) LiAlHs, EO (a) (B) © ©) OMe OMe OMe OMe ‘0 (~cHO ‘0 WA_OTs CHO WALO Me Me H Me Me The correct statement(s) among the following is/are (A) Secondary structure of a polypeptide describes the number and type of amino acid residues, (B) Uracil is a pyrimidine nucleobase. (C) Natural fatty acids have odd number of carbon atoms, (D) Reaction of (D)-glucose with Ca(OH)2 gives a product mixture containing (D)- fructose, (D)-mannose, and (D)-glucose. The diastereomeric pair(s) among the following option(s) is/are ) Ph Et Pho we oH weet (B) 8r er or kt “eu ‘Bu © owes “er Br (D) oH OH ° Q HO. ‘OH oH OH unsQ40 The reaction(s) that result(s) in the formation of aromatic species is/are (A) [cl + spcls. ——~ (B) Os + AgBE, ——> © Ph, Pproom + a Pa (D) a. SECTION -C NUMERICAL ANSWER TYPE (NAT) Q. 41 -Q. 50 carry one mark each. Qt Q42 Q43 a The bond order of Nf ion is (Round off to one decimal place) One liter of a buffer solution contains 0,004 mole of acetic acid (pKg = 4.76) and 0.4 mole of sodium acetate. The pH of the solution is, (Round off to two decimal places) The limiting molar conductivity of La** and Cl ions in aqueous medium at 298 K are 209.10 x 10-4 and 76.35 x 10S m? mol, respectively. The transport number of Clin an infinitely dilute aqueous solution of LaCh at 298 K is - (Round off to two decimal places) isJas.2019 cuenstey cv Q44 The magnetic field strength required to excite an isolated proton to its higher spin state with an electromagnetic radiation of 300 MHz is Tesla (T). (Round off to two decimal places) [Magnetogyric ratio of proton is 26.75 x 107 rad T! s*'] QA5_ The value of n for the complex [Fe(CO)s(SiMes)}* satisfying the 18-electron rule is Q.46 In the structure of PsOjo, the number of P-O-P bond(s) is Q47 Number of vertices in an icosahedral closo-borane is Q48__ Based on the information given below, the isoelectric point (p/) of lysine is, (Round off to one decimal place) ha 9 tm bs NHs © @ OH Wary te ° 30° PK, =2.2 2 440° | OH NH, ° So oe eas ° H:0 Q.49 (R)-2-methyl-1-butanol has a specific rotation of +13.5°. The specific rotation of 2-methyl- 1 -butanol containing 40% of the (S)-enantiomer is ®. (Round off to one decimal place) SO usQ.50 ‘The number of gauche-butane interaction(s) in the following compound is, CH Ldn Q. 51 - Q. 60 carry two marks each. a Qsi Qs2 Qs4 The ionization energy of hydrogen atom is 13.6 eV and the first ionization energy of sodium atom is 5.1 eV. The effective nuclear charge experienced by the valance electron of sodium atom is (Round off to one decimal place) One mole of an ideal gas is subjected to an isothermal increase in pressure from 100 kPa to 1000 kPa at 300 K. The change in Gibbs free energy of the system is kJ mol! (Round off to one decimal place) [Given: Gas constant (R) = 8.3 JK! mol] One liter of an aqueous urea solution contains 6 g of urea, The osmotic pressure of the solution at 300 K (assuming an ideal behavior) is kPa, (Round off to one decimal place) [Given: Molecular weight of urea is 60, gas constant (R) is 8.3 J K-! mol] A first order reflection of X-ray from {220} plane of copper crystal is observed at a glancing angle of 22°. The wavelength of the X-ray used is pm. (Round off to one decimal place) [Given: Copper forms fee crystal with unit cell edge length of 361 pm.] The collision flux of a monoatomic gas on copper surface is 3.0 x 10! m? s"!. Note that copper surface forms a square lattice with lattice constant of 210 pm. Ifthe sticking coefficient of the atom with copper is 1.0, the time taken by the gas to form a complete monolayer on the surface is, (Round off to one decimal place) wasQ.56 The tumover frequency (TOF) for the catalytic reaction, Catalyst (0.01 mol (1 mo) Hest : S hours with 90% yield of the product is hour”, (Round off to the nearest integer) Q57_ A radioactive sample decays to 10% of its initial amount in 4600 minutes. The rate constant of this process is hour”, (Round off to two decimal places) Q58_ Given that the radius of the first Bohr orbit of hydrogen atom is 53 pm, the radius of its third Bohr orbit is pm. (Round off to the nearest integer) Q59 5.3 g of benzaldehyde was reacted with an excess of acetophenone to produce 5.2 g of the enone product as per the reaction shown below. The yield of the reaction is %. (Round off to the nearest integer) ° ° ° NaQEt ork ter hon or hon Mw= 108 MW= 120 Mw = 208 (MW = Molecular weight) Q.60. Assume that the reaction of MeMgBr with ethylacetate proceeds with 100% conversion to a give fert-butanol, The volume of 0.2 M solution of MeMgBr required to convert 10 mL of a 0,025 M solution of ethylacetate to tert-butanol is mL, (Round off to one decimal place) END OF THE QUESTION PAPER isssant cueustay cy SECTION - A MULTIPLE CHOICE QUESTIONS (MCQ) Q. 1-Q.10 carry one mark each. Qu The graph that represents the temperature (T) ~ entropy (S) variation of a Camot cycle is (A) 4 (B) : r s © 4 (D) 1 1 — s Q2 For the radical chain reaction below, the correct classification for step 2 and step 3 is, respectively, Step 1: Brp+M —=2Bre + M Step 2; Bret Hp === HBr + H+ Step3: Ht + Bry —> HBr+ Bre (A) chain propagating, chain terminating (B) chain branching, chain terminating (©) chain propagating, chain propagating (D) chain propagating, chain branching wJas 2020 CHEMISTRY -cY Q3 Q4 Qs Q6 ‘The salt bridge in a galvanic cell allows the flow of (A) ions but NOT electrons (B) BOTH ions and electrons (©) electrons but NOT ions (D) NEITHER ions NOR electrons ‘The nucleobase NOT found in DNA is (A) Thymine (B) Uracil (C) Guanine (D) Adenine The correct statement for the following structures is i Hi yon Sy yo oy at let | y< NY Nay NS’ oH 1 2 3 (A) 1, 2 and 3 are resonance structures (B) Land 2 are resonance structures, whereas 3 is an isomer of 1 and 2 (C) Land 3 are resonance structures, whereas 2 is an isomer of 1 and 3 (D) 1, 2 and 3 are constitutional isomers ‘The correct order of boiling points of compounds I-IV is ee es 1 ul WL IV (A> 1> mI > IV @®u>m>1r>IVv (©l>m>Wv>l (I> WV >il> 0Jas 2020 CHEMISTRY -cY Q7 Qs Qo Q10 ‘One of the products of the hydrolysis of calcium phosphide at 25° C is (A) phosphine (B) phosphoric acid (C) phosphorus pentoxide (D) white phosphorus ‘Treatment of formic acid with concentrated sulfuric acid gives (A) CO +H: (B) COp + Hp (C) HCHO +% (D) no product (no reaction) The d-orbitals involved in the hybridization to form square planar and trigonal bipyramidal geometries are, respectively, (a) d_2 and d,2z (8) dy, and dz (©) d,2_y2 and d,2 (D) d,2_y2 and dy, ‘The amino acid with R configuration is (A) CO2H (B) CO2H HoN——H HoN—]—H CH2CH CH2SH © CO2H (D) CO:H HoN——H H.N——H CH2Ph (CH2CH2SCH3Jas 2020 CHEMISTRY -cY Q. 11- Q. 30 carry two marks each. QH1 At constant pressure, the [tT diagram for a pure substance that sublimes is (5 = solid, = liquid and g = gas) (A) (B) g Ch Temperature (T) > Temperature (T) > © ©) gi Temperat Q.12_ The force constant for H*°CI and D*Cl are the same and both can be considered as harmonic oscillators. H*°C! has a fundamental vibrational transition at 2886 cmr!. The ratio of the zero-point energy of HCl to that of D*°Clis (A) 0.515 (B)0.717 (© 1.395 (D) 1.946Jas 2020 CHEMISTRY -cY Q13 The correct statement regarding the determinants (Det) of matrices R, S and Tis Qi4 324) 234) 341 n=|tsy s-fa7] r= [253] 138] 318) 478. (A) Det(R) = Det(S) # Det(7) (B) Det(R) = Det(T) # Det(S) (©) Det(R) = Det(S) = Det(7) (D) Det(R), Det(S), Det(7) are all different The Boyle temperature (Tj) is defined as the temperature at which the properties of a real ‘gas coincide with those of an ideal gas in the low pressure limit. The graph that shows the pressure dependence of the compression factor (Z) for a real gas at Ty is (A) (B) © Pressure (bar) 1000 : © ©) Pressure (bar) 1000 1.09] 7000 ° Oressure bar) Pressure (bar) 1000Jas 2020 CHEMISTRY -cY QI5_ The major product formed in the following reaction sequence is Oo i. EtMgBr, Et,0 it. C10, CH2Cle il, PhyP=CH, THE “ @) | © ) Q16 The geometries of the species [Br3]*, [Bra]” and [BrF] are, respectively, (A) linear, trigonal bipyramidal and trigonal bipyramidal (B) linear, linear and trigonal planar (©) tetrahedral, trigonal bipyramidal and trigonal bipyramidal (D) tetrahedral, trigonal pyramidal and trigonal planar QLI7_ The cage — type structure adopted by boron hydride, [BsHy1}, is (A) closo (B) nido (© hypo (D) arachnoJas 2020 CHEMISTRY -cY w Qs Quo Q20 The order of the M-C bond strength in the following species is (Atomic number for Cr = 24, Mn = 25, Ti = 22, Co = 27) [Cr(CO)e] — [Mn(CO)gJ* —[T(CO)g]* — [Co(CO).F I Wl m1 Iv (A> 1> IV > (@®I>M>>IV (Mm >IWV>r>0 MM >1>1>IV ‘The number of non-bonding electrons present in the frontier molecular orbitals of HF is (A) 10 (B)4 (6 @)s ‘The coordination number of aluminum ion and the number of bridging hydrogen atoms in [AI(BHy))” are, respectively, (A) 8and 8 (B) 6 and 6 (©) 4 and 6 (D) Sand 12 ‘The complex which does NOT obey 18-electron rule is (atomic number for Mn = 25, Fe = 26, Co = 27, Ru = 44) (A) [Cox(CO)s] (B) [Fe(CO).]> (©) [HMn(CO)s] (D) [7 -C: s)RuCK(CO)(PPh:)}JAM 2020, CHEMISTRY -cY w Q22 ‘The solid state structure of HF is A) @ yor. seen HF Ht () ‘The number of d-d transition(s) expected for the complex [Cu(NH3)2(H:0)s}** is (al (B)2 ©3 (D4JAM 2020, CHEMISTRY -cY Q.24 The plot showing the magnetic behavior of oxy- (solid line) and deoxy-haemoglobin (dashed line) is, (ayy molar magnetic susceptibility, T = temperature) (A) (B) as ao ie, 7 33 > = = 4 M £ e & & a! 5 5, See 100 200 300 a oe T(K) T(K) © () a4 ik S3p-------- = M, = L 5 1 Xo 100 200 300 100 200 300 T(K) T(K) w 021Jas 2020 CHEMISTRY -cY Q.25. The major product formed in the following reaction is O° mA NaOMe, MeOH Me Br ay B: Ph “a Ph. OMe 2 Yr Me 7 OMe Me 8 6 © Me ©) co mh ma A A, Q.26 The rate of solvolysis of I-IV follows po see Br’ I ML Vv (A)L> > I> IV (BM >>> (mM>U>1r>IV @MIV>1>0> 0 eS natJas 2020 CHEMISTRY -cY Q.27. The more stable species in each pair of conformers are sd oe I " oN me OO 20. Ml Iv OH ox Yo = OH Lo yo v VI (A) IL, IV and V (B)I, IV and V (C) Tl, M1 and V (D) I, TV and VI Q28 The major product formed in the following reaction sequence is OMe i. TiCls, Cu-Zn SCHOO Phy ii, HCI/ HO “A 9 ° ( B) ° er AAP oO © 10 ©) ° ery fo}JAM 2020, CHEMISTRY -cY Q29. For the Diels-Alder reactions I-IV, the activation barriers follow the order Oo he ALS é (A) I> I> I> IV (B)I> I> IV>0 (QM>IV>n>1 (D)IV> I> > Q.30. The major product formed in the following reaction is COpH lp, NaHCO3 H20 “ oS ) ° 9 9 ' © ©) eS 321aa M2020 CHEMISTRY -cY SECTION -B MULTIPLE SELECT QUESTIONS (MSQ) Q.31-Q. 40 carry two marks each. eS Q31 Q32 Q33 For the reaction shown in Scheme 1, the concentration profiles of different species are provided. Scheme 1 s a R - AN, a (FI ef Concentration (al Time — Based on this graph, the correct condition(s) regarding the rate constants is(are) (A) kp > ky (B) k3 > ki Ok>k Mk = ko W(X,Y,Z) describes the wavefunction of a particle, The probability of finding the particle between x and x + dx, yand y + dy, zand z + dz, can be expressed as (A YWY.2Z) WOY.Z) (B) |yxy,z)? dx dy dz COyw*(y.z) wOny,z)dx dy dz ©) Jo dx [dy [2 dz y*ey.2) Wosy.2) In water, the enthalpy of a protein in its folded state (He) is lower than that in its unfolded state (Hur). The entropies of the folded and unfolded states are Sp and Sur, respectively. The condition(s) under which this protein spontaneously folds in water at a temperature T, is(are) (A) Sur < Se (B) Sup = 0 (C) Sur = Se (D) (Sp — Sup) > (He — Hue)/T watJas 2020 CHEMISTRY -cY Q34 Q35 Q36 Q37 ‘The soft Lewis base(s) is(are) (a) I> (B) CO (© Ho (D) CH3NC ‘The boron adduct(s), which show(s) three signals in 'H NMR spectrum with the intensity ratio 1:2:3 is(are) (A) (CHs)sB:N(CH3)s (B) (CH3CH2)3B:N(CH2CH)s (©) HsB:N(CH2CHs)s (D) (CH3CHs)sB:NHs, The transition metal complex(es) with zero magnetic moment, zero dipole moment and CFSE of -2.4 As is(are) (A) [Mn(CO)s(CH3)] (B) [rrans-Ni(ethylene diamine):Clo] (©) [trans-Co(CN).(H20)2- (D) [trans-Fe(CN)xCh}> Achiral stereoisomer(s) is(are) possible for rc) YL (B) HOC Br =c=\ ‘Br COH © OH On ) Hoy ‘CO;H OH tsaJas 2020 CHEMISTRY -cY Q.38 Q39 ‘The compound(s) which will have only two signals in the 'H NMR spectrum in 3:2 ratio. is(are) A) B “ c _ ° ° © ° © 6 ° ‘The correct sequence of reactions for the synthesis of the following molecule is(are) OH Oy (A) (i) 4-lodophenol, Mg, ether ) Cyclopropane carboxaldehyde, THF (iii) CSCO, Mel, THE (B) (i) Cyclopropyl bromide, Mg, ether (ii) 4-Hydroxybenzaldehyde, THF (iii) CSCOs, Mel, THF (©) @ 4-lodophenol, CsCOs, Mel, THF ii) Mg, ether (iii) Cyclopropane carboxaldehyde, THF (D) (i) Cyclopropyl bromide, Mg, ether ii) Methyl 4-methoxybenzoate, THF 1621JAM 2020, CHEMISTRY -cY Q40_ The organometallic reagent(s) among the following is(are) (A) Lithium divinylcuprate (B) Lithium diisopropylamide (©) Potassium rert-butoxide (D) Isopropyl magnesiumiodide eS vaiJas 2020 CHEMISTRY -cY Q.41- Ql Qa Q44 Qas Q.46 Qa Q.48 Qa4o SECTION -C NUMERICAL ANSWER TYPE (NAT) Q. 50 carry one mark each. ‘The function x*e~2/? (for x > 0) has a maximum at a value of x equal to (Round off to two decimal places) The longest wavelength of light absorbed by a hydrogen-like atom is 2.48 nm. The nuclear charge (Z) of the atom is __ (Round off to nearest integer) (Rydberg constant Ri = 109700 em") Fullerene (Coo) crystallizes in an FCC unit cell (edge length = 14.14 A) with one Cao centered at each lattice point. The smallest distance (in A) between the centers of two Ca molecules is (Round off to two decimal places) A film of stearic acid partially covers the water surface in a container. The work needed to decrease this coverage by 1 cm? is 25.0 x 10°? J. The surface tension (in Nm) of the film is (Round off to three decimal places) (Surface tension of pure water is 0.072 N/m) ‘The value of ‘n’ in [PaOrs]* is ‘The total number of all possible isomers of [Co(H2NCH2CH:NHs):Ch] and [Co(H2NCH2CH2NH2)3]** together i ‘The number of lone pairs present in phosphonic acid (phosphorus acid) is ‘Total number of cons tutional isomers possible for trimethyl cyclohexane is ‘The dihedral (torsional) angle (in degrees) between the two methyl groups in the most stable conformation of n-butane is (Round off to nearest integer) i821Jas 2020 CHEMISTRY -cY Q50 Q.51- Qsi Q52 Q53 The degree of unsaturation (double bond equivalent) for a compound with molecular formula CiHi20> is Q. 60 carry two marks each. ‘The heat of formation of MgO at 300 K and 1 bar pressure is ~600.60 kJ mol. The free energy (in kJ mol") of formation of MgO at 280 K is, (Round off to nearest integer) Given: In the range 280-300 K, the constant pressure heat capacities (Cp) and molar entropies (Sy) are: Mg 0: MgO Co (in J mot! K) 249 29.4 21.0 Sm (in J mol K") 0 205.2 0 Sea water containing 1 M NaCI has to be desalinated at 300 K using a membrane permeable only to water. The minimum pressure (in bars) required on the sea-water side of the membrane is __ (Round off to one decimal place) (R Jmol! K"!, 1 bar = 10° N/m?) A bacterial colony grows via cell division where each mother bacterium independently produces two daughter cells in 20 minutes. If the concentration of bacteria is 10¢ cm’, the colony becomes harmful. Starting from a colony with an initial concentration of 5 cmv’, the time taken (in minutes) for the colony to become harmful is (Round off to nearest integer) oatJas 2020 Q54 Q57 CHEMISTRY -cY ‘The Maxwell distribution of speeds of a gas at 300 K is given below 3 : 0 250 500 750 1000 1250 Speed (ms) ‘The molar mass (in g mol) of this gas is (Round off to one decimal place) (R=8.3J mol" K") Ata certain wavelength, liquid P transmits 70%, whereas liquid Q transmits 30% of the incident light when separately placed in a spectrophotometric cell (path length = 1 em). In a binary mixture of liquids P and Q (assume non-interacting liquids), the absorbance in the same cell is 0.25. The volume fraction of liquid P in the binary mixture is (Round off to two decimal places) ‘The mean ionic activity coefficient for a 0.01 M aqueous solution of Cas(PO.) is (Round off to three decimal places) (Given: logyg ys. =— 0.509 z4|z-| VT ) For the reaction, CuSO,(aq) + Zn(s) > ZnSO«(aq) + Cu(s), the value of AG? (in kJ mol") is (Round off to the nearest integer) (Reduction potential: Cu?*(aq)/Cu(s) = + 0.34 V; Zn**(aq)/Zn(s) =~ 0.76 V) (Faraday constant = 96485 C mol") Titanium tetrachloride (TiCly) reacts with THF to form an octahedral complex X under inert atmosphere at 25 °C. If 5.0 g of TiCly is used and the yield is 80%, the amount of X (in grams) formed is (Round off to one decimal place) (Use atomic weights: Ti 8, Cl = 35.5,O = 16, C= 12, and H= 1) 2mJAM 2020, CHEMISTRY -cY Q.59. The total number of tautomers possible for I and IL together is _ Ce Pho yePh H H I Q.60. The total number of head to tail isoprene linkages in the following molecule is. Me Me Me M Meo Ss SS le Me Me Me ND OF THE QUESTION PAPER eS aa1aM2021 couenustey -cy SECTION - A ‘MULTIPLE CHOICE QUESTIONS (MCQ) Q. 1-Q.10 carry one mark each. Qi The CORRECT order of pX;, for the compounds I to IV in water at 298 K is HC0(CO), — HCo(CO);(PPhy)_ HCo(CO);(P(OPh)s)_—- HCo(CO),(PPhs)2 1 ul mm (A) [> I> I> IV (B)IV> I> > (QIV>M>m>1 (D) I> M> > IV Q2. For Na‘, Mg”, Al and F>, the CORRECT order of ionic radit SS We Sy (A) AP* > Mg? > Na* > F (B) APY Na’ > MSF PO Se (C) F-> Na*> Mg” > APY O) E> ABY Q3_— Spin-only magnetic moments (in BM) of [ ?Pha)2] and [Mn(NCS)6I*~, respectively, are (A) 0.00 and 5.92 (B) 2.83 and 1.89 (C) 0.00 and 1.89 (D) 2.83 and 5.92 Q4 Two sets mbers with the same number of radial nodes are and n= 1=0;m: =0 and n=2;/=1;m:=0 and n=2;1=1;m)=0 and 1;m; =0 a zaiJaM2021 CHEMISTRY -CY Q5 The major product formed in the following reaction is Hyco. 88 CF{COOHIH;O — sco CHC, 0°C, 1h 0,CHEMISTRY -CY 1aM2021 Q7 — Acompound shows 'H NMR peaks at d-values (in ppm) 7.31 (2H), 7.21 (2H), 4.5 (2H) and 2.3 (3H). The structure of the compound is cl Me cl a) @) ~ S cl © bb Q8 The major product formed in the following reaction is 170°C LA (A) “ ‘ waJaM2021 CHEMISTRY -CY Q9 A pure substance M has lesser density in solid state than in liquid state. The AStusion of M is +25 J K mol!. The CORRECT representative Pressure-Temperature diagram for the fusion of M is ‘ g 2 3 3 w 8 we 8 & = ______, ‘Temperature _ 2@ 3 © 8 : -_____, ‘Temperature Q.10 Among the following, the Fron-zero determinant are 10 00 1 00 10 00 12 3 1 pot 0 200 2200 of ¢j23 42 “jo 0 1 00 3 0 3.13 0 “|3 4 13 00 1 00 04 43 14 4124 P,Q (B) P, Rand S (C) P,Qand S (D) Q, Rand S$ a sarJaM2021 CHEMISTRY -CY Q. 11 Q. 30 carry two marks each. QI Reaction of BCI with NHsCI at 140 °C produces compound P. Further, P reacts with NaBH, to give a colorless liquid Q. The reaction of Q with HO at 100 °C produces compound R and a diatomic gas 8. Among the following, the CORRECT statement is (A) P is ByNGHs, (B) R is [B(OH)NH]s (© Qis [BCINH]s (D) Sis Ch Q.12 The complex that does NOT obey the 18-electron rule is (Given: Atomic numbers of Ti, Mn, Ta and Irare 22, 25, 73 and 77, respée (A) [Gf-CsHs)T(CO)sT (B) [Mn(SnPhs): or : (C) [P-CsHs)In(CH2)(PMes)] (D) [TaCk (PEE)2 (CHCM@) < > Q.13 Hybridization of the central atoms in Is, CIF3 (A) sp*d, sp? and dsp? spd and dsp (©) sp°d, sp'd and sp'a © ) sp, sp? and spd Q.14 Reaction of [Ni(CN)]R> with complex E. The geo dn lic potassium in liquid ammonia at ~33 °C yields ignetic behavior of E, respectively, are (A) Square planar agnetic (B) Tetrahedral and diamagnetic (©) Oc jaramagnetic (D) Square pyramidal and paramagnetic \ QIS The dberesing order of C=C bond length in the following complexes is AICIPUCH;=CH)P— [CIsPUC(CN)-C(CN),)-— [ClPACF:-CH)- [ClyP(CF,=CF,) I t mm IV © (A) I> I> Ive (B)IV>1> MST (©U>IV> >I (D)IV> > 1> 1 a warJaM2021 CHEMISTRY -CY Q.16 The CORRECT combination for metalloenzymes given in Column I with their catalytic reactions in Column II is Column I Column IL (@ Cytochrome P-450 (K) 2H,0, —» 2H,0 +0, (ii) Catalase (L) R-CH,OH + 0, —» R-CHO + H,0) (R= alkyl or aryl) & (iii) Galactose oxidase S (M) y+ 4H" + de> ——» 2H;0 N° S (iv) Cytochrome ¢ oxidase oS xe (N) R-H+0)+2e7+2H* —— “ROH + RO (R = alkyl or aryl) ae e PF SS (A) -OD; (iN); Gi); iv) LB) CN): GOAL): Gg 3: ivy (My x (C) GAN); (ii)-(K); (iii) (L); (iv) 4M) ) Hews AK yi); (iv)-(N) & Q.17 According to the crystal field theory, d- (A) Laporte forbidden and spin gS iporte allowed and spin forbidden (C) Laporte allowed and spi (D) Laporte forbidden and spin allowed ed in [Ti(H2O)o]** is a TarJaM2021 CHEMISTRY -CY Q.18 The major product formed in the following reaction sequence is \ sv . 2. (CHg)2NH av 3. LIAM, x 4, BF5, HCHO ww oH ‘OH (A) ~S N~ OH OH OH Ole ca UyJaM2021 CHEMISTRY -CY Q.19 The products P, Q, R and S formed in the following reactions are 1. HBr 2. CuCN ~S~on ———» P + a 3.Cone.HCl major minor 1. HBr OH 2. CUCN eq 3. Conc. HCl major minor COOH eRe eS es (A) P=R= #SScoon and @=8= [7 a oaJaM2021 CHEMISTRY -CY Q.20 The major products E and F formed in the following reactions are Bro {\ +e NY EtoH, 0° EtOH, 0°C Br (A) E= orl er and F= || > H N’ o SF WP F (B) E= Oe and F= el s Fs N ner x¥ Sst f hss ¥ se BL Br Br Os © & v { and F= SS s N (2 H N Br Br 0) & ol by tee Bole q brJaM2021 CHEMISTRY -CY Q21 The reaction that produces the following as a major product is ° H3CO. CHO a t-BuOK ) i * phgpt aa ° 1. BuLi 2. HCO. -~_-cHo Oo oO ®) OL ee 3 3. PhcOCI 4. NalHg 4.110 °C Q22 The major r in the following reaction is 1 Cosmweneon MeOH le 2. . a TarJaM2021 CHEMISTRY -CY Q.23 The major product formed in the following reaction is ° Me 100°C, toluene, 96 h “2 a Meo’ ° icp a) Meo’ ° HL Me © Meo J Q.24 In the following reaction, compound Q i CHs NaOEt — EtOH CHU (only pr ¢ ot sel a) ®) CH(CHS)> CH @) , “Cl CH(CH,)JaM2021 CHEMISTRY -CY Q25 Monochromatic X-rays having energy 2.8 x 10°! J diffracted (first order) from (200) plane of a cubic crystal at an angle 8.5°. The length of unit cell in A of the crystal (rounded off to one decimal place) is (Given: Planck’s constant, h = 6.626 x 10° s; c= 3.0 10 ms“) (A) 24 (B)34 © 48 (D) 9.8 Q26 For a > 0, the value of the integral *"" xe~™* dx is w fe ve ©o () 1 Q.27 The volume correction factor for a non-ideal gas in tetms RTe 27R2T 2 (A) ~ oo ars Q.28 Half-life (t/2) of a chemic: i ‘ies with the initial concentration of reactant (Ao) as given below: A, (mol L*!) x 107 3x 107 hp 450 600 The reaction is (A) (B) 1 (2 (D)3 The\CORRECT statement regarding the molecules BF; and CHs is © (A) Both BF; and CH, are microwave active (B) Both BF; and CHs are infrared active (© CHL is microwave active and infrared inactive (D) BF is microwave active and infrared active a Tai