Scribd Logo
Upload

Welcome to Scribd!

  • CHY412 Problem-2

    Uploaded by

    PARVATHY ANIL
    4 views2 pages
    This document outlines 9 problems for an advanced organic chemistry problem set assigned by Dr. Basudev Sahoo at IISER TVM. The problems involve drawing reaction products with proper stereochemistry and proposing mechanisms for the reactions. Hints are provided that refer to class notes, textbooks, and journal articles to aid students in solving the problems.

    Original Description:

    Original Title

    CHY412_Problem-2

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    This document outlines 9 problems for an advanced organic chemistry problem set assigned by Dr. Basudev Sahoo at IISER TVM. The problems involve drawing reaction products with proper stereochemistry and proposing mechanisms for the reactions. Hints are provided that refer to class notes, textbooks, and journal articles to aid students in solving the problems.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    4 views2 pages

    CHY412 Problem-2

    Uploaded by

    PARVATHY ANIL
    This document outlines 9 problems for an advanced organic chemistry problem set assigned by Dr. Basudev Sahoo at IISER TVM. The problems involve drawing reaction products with proper stereochemistry and proposing mechanisms for the reactions. Hints are provided that refer to class notes, textbooks, and journal articles to aid students in solving the problems.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 2

    CHY412: Advanced Organic Chemistry

    Instructor: Dr. Basudev Sahoo (SoC, IISER TVM)


    Problem Set-2

    Problem-1: Write the structures of the product A, B and C with proper


    stereochemistry. Write the mechanism for the product B and C formation.

    [Hint: Class note; Enders Tetrahedron 2002, 58, 2253]


    Problem-2: Write the structures of the product A, B and C with proper
    stereochemistry. Write the mechanism for the product B and C formation.

    [Hint: Enders Tetrahedron 2002, 58, 2253]


    Problem-3: Select the suitable hydrazine-based auxiliary for (R)-Lilial synthesis. Write
    the structures of the product A and C with proper stereochemistry. Write the
    mechanism for the 2nd and 3rd steps.

    [Hint: Enders Tetrahedron 2002, 58, 2253]


    Problem-4: Write the structures of the product A and B with proper stereochemistry.
    Write the mechanism for the product A formation.

    [Hint: Class note]


    Problem-5: Write the structures of the product A and B with proper stereochemistry.
    Write the mechanism for the product A and B formation.

    [Hint: Class note; Organic Chemistry Book - Clayden]


    CHY412: Advanced Organic Chemistry
    Instructor: Dr. Basudev Sahoo (SoC, IISER TVM)
    Problem Set-2

    Problem-6: Write the structures of the product A and B with proper stereochemistry.
    Write the mechanism for the product A formation.

    [Hint: Class note for similar DA reaction; Organic Chemistry Book - Clayden]
    Problem-7: Write the structures of the compound A and B with proper stereochemistry
    and explain the origin of stereoselectivity.

    [Hint: Class note for similar alkylation reaction; Organic Chemistry Book - Clayden]
    Problem-8: Write the structures of the product I with proper stereochemistry and
    explain the origin of stereoselectivity.

    [Hint: Class note; Oppolzer, Pure & Appl. Chem. 1990, 62, 1241]
    Problem-9: Write the structures of the product A with proper stereochemistry and
    explain the origin of stereoselectivity.

    [Hint: Class note]


    -------------------------------------------------------------------------------------------------------------------------

    You might also like