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Aim Theory Materials Required Apparatus Setup Procedure Observations Calculations Results and Discussion
The titration of potassium permanganate (KMnO4) against Mohr salt is an example of redox titration. In close proximity to the endpoint, the action
of the indicator is analogous to the other types of visual colour titrations in oxidation-reduction (redox) titrations.
Aim:
To determine the strength of a given potassium permanganate solution against a standard ferrous ammonium sulfate (Mohr’s salt) solution.
Theory:
Potassium permanganate is a strong oxidant in the presence of sulfuric acid. Mohr salt is a double salt forming a single crystalline structure
(https://byjus.com/chemistry/crystal-structure/) having the formula FeSO4.(NH4)2SO4.6H2O. The chemical name for Mohr’s salt is ferrous
ammonium sulfate.
In this titration Mohr salt acts as a reducing agent and potassium permanganate acts as an oxidising agent. So, the reaction between Mohr’s salt
and potassium permanganate is a redox reaction. In this redox reaction, ferrous ion from Mohr’s salt gets oxidised and pink coloured of
manganese present in potassium permanganate, which is in the +7 oxidation state gets reduced to colourless Mn2+ state.
The chemical reaction and the molecular chemical equation (https://byjus.com/chemistry/chemical-equation/) is given below.
Overall reaction –
This titration is based upon oxidation-reduction titrations. When ferrous ammonium sulfate solution is titrated against potassium permanganate
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(https://byjus.com/chemistry/manganese-dioxide/). Here KMnO4 acts as a self indicator and this titration is called permanganate titration.
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Materials Required:
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1. Mohr’s salt (ferrous ammonium sulfate)
4. Chemical balance
5. Burette
6. Burette stand
7. Pipette
8. Conical flask
9. Funnel
13. Burnet
Apparatus Setup:
1. In burette – KMnO4 solution
2. In Conical flask – 10ml of Ferrous Ammonium Sulfate (Mohr’s salt) + Sulfuric acid
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Procedure:
(a) Preparation of 0.05M standard solution of ferrous ammonium sulfate:
The quantity of Mohr’s salt required for the 250ml of the solution having a normality of 0.05N can be calculated as follows.
For preparing 250ml of N/20 Mohr’s salt solution, Mohr salt required
= (19.6/1000) x 250 = 4.9 gm
3. With the help of a funnel, transfer the Mohr’s salt into the measuring flask.
4. Now wash the funnel with distilled water without removing the funnel from the flask.
5. Make the solution up to the marked point with distilled water and make sure the Mohr’s salt is fully dissolved.
(b) Titration of potassium permanganate solution against standard ferrous ammonium sulfate (Mohr’s salt) solution:
1. Wash and rinse the burette and pipette with distilled water and then rinse with the corresponding solution to be filled in them.
Play2. Rinse the burette with the potassium permanganate solution and fill the burette with potassium permanganate solution.
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Win3. Fix the burette in the burette stand and place the white tile below the burette in order to find the endpoint correctly.
4. Rinse the pipette and conical flask with standard ferrous sulfate (https://byjus.com/chemistry/ferrous-sulfate/) solution.
5. Pipette out 10ml of 0.05N standard Mohr’s salt solution into the conical flask.
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test tube full of sulfuric acid in order to prevent oxidation of manganese to form manganese dioxide.
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7. Note down the initial reading in the burette before starting the titration.
8. Now start the titration, titrate against potassium permanganate solution and simultaneously swirl the solution in the flask gently.
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9. Initially, the purple colour of KMnO4 is discharged with ferrous ammonium sulfate. The appearance of a permanent pink colour reveals the
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endpoint.
12. Record the reading in the observation table given below in order to calculate the molarity of KMnO4 given.
Observations:
S.No Volume of ferrous ammonium sulfate (Mohr’s salt) used Burette Reading Volume(V) of KMnO4 used
V = (y-x)ml
Initial(x) Final(y)
Calculations:
(a) Normality of KMnO4 solution:
Consider y ml of given KMnO4 solution is equivalent to 20ml of N/10 Mohr’s salt solution.
N 1 V 1 = N 2V 2
1/10 x 20 = N2 x y
N2 = 2/y
= 158/5
= 31.6
N=Mx5
The strength of and molarity of given KMnO4 solution is found out as 2/y x 31.6 g/l and N/5 moles/liter, respectively.
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3. Use dilute sulfuric acid for acidifying the potassium permanganate.
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4. Clean all the apparatus with distilled water before starting the experiment and then rinse with the solution to be taken in them.
5. Take accurate readings once it reaches the endpoint and doesn’t go with average readings.
7. Use the antiparallel card or auto parallax card while taking the burette readings.
8. The strength of the unknown solution should be taken up to two decimal places only.
Also Read:
The titre of a solution is the weight of a substance that reacts with 1 mL of the solution, such as a titrant.
KMnO4 acts as a good oxidising agent in acidic medium. If acid is not used KMnO4 may be oxidised to MnO2 giving a brown precipitate.
A standard solution is a solution whose concentration is known. The normality and molarity of the solution is known.
Permanganate titration
Complexometric titration
Precipitation titration
Acid-base titration
Redox titration
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