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! University*of*Santo*Tomas!
COLLEGE*OF*SCIENCE!
Certificate)in)Science)Teaching)

EXERCISES'
A.!INTERMOLECULAR!FORCES!!
1.!Classify!each!of!the!following!compounds!as!hydrogen!bond,!dipoleJdipole,!Van!der!Waals/London!
!!!!dispersion!force!or!ionJdipole:!
!!!!a.!CH3OH!and!H2O! b.!Br2!and!C6H6! ! c.!CCl4!and!C6H6! ! d.!KCl!and!H2O!
2.!Arrange!the!following!compounds!according!to!increasing!boiling!point.!
!!!!a.!NH3!! ! b.!MgCl2!! ! c.!H2O! ! ! d.!CH3OH!
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B.!PHASE!CHANGE!
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1.!Dimethyl!sulfoxide!(DMSO),!a!controversial!painJkilling!drug!has!a!boiling!point!of!189 C.!Is!it!more!or!
!!!!!less!volatile!than!water?!Explain.!
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2.!At!760mmHg,!water!boils!at!100 C.!Explain!why!as!the!external!pressure!decreases,!water’s!boiling!point!also!
decreases.!
3.!Consider!the!ff.!equilibrium!existing!in!a!sealed!container:!
!!!!!! alcohol!(l)!!+!!∆!!!!!!!!!!!!!!!!!!!!alcohol!(g)!
!!!!!a.!In!which!direction!will!the!equilibrium!shift!if!alcohol!vapor!can!be!removed!from!the!container?!!!!!!!!
!!!!!b.!If!the!system!is!cooled,!in!what!way!will!the!equilibrium!be!affected?!
4.!Which!of!the!following!is!a!surfactant?!Explain!why!water!forms!“beads”!on!a!waxy!surface!but!!!!!!
!!!!!spreads!out!with!the!help!of!a!surfactant?!
J +!
!!!!!a)!NaOH! ! b)!H3PO4! ! c)!CH3(CH2)14CO2 Na ! d)!all!of!these!!
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C.!CHEMICAL!REACTIONS!
!!!!Complete!and!balance!the!following!equations!and!identify!the!type!of!reaction!involved.!!
1.!Ca(HCO3)2!!!→!!_____!!+!!CO2!!+!!H2O!
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2.!Mg(OH)2!!+!!_____!!!→!!Mg3(PO4)2!!+!!H2O!
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3.!Ba(NO3)2!!+!!!_____!!→!!BaSO4!!+!!KNO3!!!!
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4.!Na2CO3Q10!H2O!!→!!_____!!+!!_____!
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5.!Fe!!+!!H2SO4!!→!!_____!!+!!H2!
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