Dropper NEET

MKNY/102 Milestone Test-02 Phase-1

DATE : 30/07/2023

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 1 3 4 2 2 2 1 3 4 3 4 3 3 4 2 1 2 2 2 1
Que. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 2 2 2 1 1 2 3 1 2 4 3 4 2 4 2 2 1 3 4 3
Que. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 4 3 2 2 3 3 2 1 4 3 4 3 1 1 4 2 3 3 1 4
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. 3 4 1 2 4 3 3 2 4 2 4 1 2 1 2 3 3 3 4 1
Que. 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. 3 3 3 3 3 3 3 2 1 2 1 3 3 3 2 2 2 2 4 4
Que. 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. 1 4 1 4 2 1 1 4 2 4 1 2 1 3 4 1 3 1 4 4
Que. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140
Ans. 2 1 1 1 2 4 1 4 3 3 2 3 1 1 4 3 1 1 4 1
Que. 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
Ans. 2 4 3 3 4 3 2 1 1 1 3 3 3 3 2 2 1 3 3 3
Que. 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
Ans. 4 2 2 4 2 4 4 4 3 1 2 4 3 3 1 3 2 3 4 4
Que. 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200
Ans. 2 3 2 3 4 1 3 3 4 3 3 3 1 1 3 3 3 2 2 4

Hints & Solutions

1. (1) 2. (3)
v= x y – direction
dx
1 v2 = u2 + 2as
= (x) 2 22 = u2 – 2g (0.4)
dt
x =x 1 t =t u2 = 12
−
 x 2 dx =   dt u=2 3
x =0 t =0
x uy 2 3 1
 1 tan  = = =
2  x 2  = (t)0t ux 6 3
 
 0  = 30°
2( x ) = t
2
 t 
x = 
 2 
dx 2 2 t
v= =
dt 4
2 t
v=
2
vt

[1]
3. (4) V 2 = 7.5 3  2.5
V = 5.7 m/sec

8. (3)
T cos  = 346
3
T = 346
2
692
T=
3
Now T sin  = w
692 1
 =w
3 2
x + 3x = 8
4x = 8 9. (4)
x=2
( 2 V0 )
2

So, position of 2nd drop from ground is S=

2g
3x = 3 × 2 = 6 m
2 V02
S=
g
4. (2) 10. (3)
5mg − 3mg 2mg g 1
a blocks = = =  ( + )  ( −) U ' = k (14 )
2
5m + 3m 8m 4 2
m a + m2 a 2 1
a cm = 1 1 U = k (7)
2
m1 + m2 2

a cm =
5m g ( 4 ) − 3m (g 4 ) = g U' 196 4
=
U 49 1
=
5m + 3m 16 U' = 4U

5. (2) 11. (4)

6. (2) 12. (3)

Xcm =
 xdm =  xdx
 dm  dx
2
 x(3x + 2)dx
X cm = 0 2
0 (3x + 2)dx
2 2
 x3   x2 
3  + 2  
 3 0  2 0
X c cm = 2
 x2  Apply W.E.T
3   + 2(x)02
 2 0 WfSP + WMg = K
6 1
Xcm = − kx 2 + Mgx = 0
5 2
2Mg
x=
7. (1) k
a cos30° = ac
 3  V2 13. (3)
15   =
 2  R

[2]
14. (4) dm
a = a c = r 2
F=v
dt
( )
= 80  103  2 = 16  104 N

2 2
 5  2  5  2 
a =   =   23. (2)
 100 T
  100  0.2 
mv 2
 a = 5 m/s 2 w = mg +
R
24. (1)
15. (2) 25 cos60° = 5(a)
AB a = 2.5
Bcos  =
A T = 2(a)
A.B 12 + 10 + 6 28 T=5N
= =
A 2 2
3 +5 +2 2 38
25. (1)
16. (1)
26. (2)
3
17. (2) w =  fdx
ˆ
Velocity = (speed)  A 0
3
 2iˆ + 2ˆj − kˆ 
v = 6 
(
=  5x 2 − 2x dx )
 3 0
  3
5 
= 4iˆ + 4jˆ − 2kˆ =  x3 − x 2 
3 0
18. (2)
= (45 – 9) – (0)
= 36 J
19. (2)
(Fr) = µmg
27. (3)
= (0.6) × 10 × g = 60 N
28. (1)
20. (1)
aA = gsin
29. (2)
aB = gsin – µgcos
P = F.V
aA gsin 45 2
= = =2+2+1=5
a B gsin 45 − g cos 45 1
1 2 30. (4)
=
1−  1 Work = Area of F.T. curve from x = 3m to x = 6m
1 = 2 – 2µ 1
= 63
2µ = 1 2
1 = 9.0 J
µ=
2
31. (3)
21. (2) FTh − Mg = Ma
60 = (3 + 5 + 7) a dm
a = 4 m/s2 Vrel = M(g + a)
dt
T1 = (5 + 7)a = 12  4 = 48 N dm
1.6  1000 = 800(10 + 6)
T2 = 7 ( a ) = 7  4 = 28N dt
dm
= 8 kg/s
22. (2) dt
dm
= 2 kg/s
dt

[3]
32. (4) 4
Cos  =
5
33. (2) a.b = abcos 
4
34. (4) = 2 × 5 × =8
5
w = k
1 1
 ( 4 + 12 )  10 = ( 0.1) v 2 40. (3)
2 2 mv1 + mv2 + mv3 = 0
160 = (0.1) v 2

v = 40 m/s v3 = − ( v1 + v2 )

35. (2)
(
= − 3iˆ + 2jˆ − ˆi − 4jˆ )
= − ( 2iˆ − 2jˆ )
36. (2)
= −2iˆ + 2jˆ
M  L 
w =  g  
 5   10 
41. (4)
MgL
= mR 2
50 I=
4
37. (1) mR 2
Icm =
1 2 2
mv = mg ( 3h − 2h )
2 mR 2
IP = + mR 2
v2 = 2gh 2
mv 2 3
N= − mg mR 2
h 2
m  2gh 6
= − mg IP = mR 2 = 6I
h 4
= mg
42 (3)
38. (3) R
kd 1
1
S = t2 = 2 =
3 kR R 2
ds 2
v= = t
dt 3 43 (2)
dv 2
a= = 44. (2)
dt 3
F = ma Ms a2 4
= 2
=
2 MP a 
F = 3  = 2N  
3 2
W=FS Ms > Mp
1 Inside square plate
= 2   ( 3)
2

3
= 6J 45 (3)
2  4 − 2  2 = ( 2 + 2) v
39. (4) 4=4v
ab sin  =  v = 1 m/s
2 × 5 sin  = 
3
Sin  =
5

[4]
46. (3) 53. (1)
dy HO 1 4 H
= −2x + 2 = 0
dx 3 2 CF3
x=1
 (R) Configuration
y = 100 – (1)2 + 2(1)
= 100 – 1 + 2 = 101
H 4 1 NH2
HS  (R) Configuration
47. (2) 2 3 COOH
2m = mV1 + 2mV2 ….(1) H 4 3 CH3
v − v1 1 CHO  (R) Configuration
e= 2 = ……(2) 2 1
2 2
v2 – v1 = 1 54. (1)
v1 + 2v 2 = 2
3° 2°
3v 2 = 3 3° 3°
V2 = 1 2° 3° 3°C 5
V1 = 0 2°C 6
2° 3° 2°
2° 2°
48. (1)
m1x1 + m2 x 2 55. (4)
Xcm =
m1 + m2
O

=
( ) (
1 ˆi + 2ˆj + kˆ + 3 −3iˆ − 2ˆj + kˆ ) O–C–CH3
1 2
1+ 3 Cyclohexylethanoate
ˆ ˆ ˆ
−8i − 4 j + 4k
=
4 56. (2)
= −2i − j + kˆ
ˆ ˆ O
49. (4)
O
*
50. (3)
OH
One chiral carbon
51. (4)
NC CN
57. (3)
C=C
H– C Butane-1-amine & Butane-2-amine are position
CN
isomers
O
 bonds = 10 58. (3)
 bonds = 8 H
1 2 H
H2 N C C F
52. (3)
H H
CHO
1
H
H H
2 6
3
5
H F
Br 4
OH NH2
3-Bromo-5-hydroxybenzenecarbaldehyde Most stable due to intramolecular H-bonding

[5]
59. (1) COOH
Me
CH3 (4) H OH
* CH2OH
*
(D)
*
(P) (Q) 63. (1)
Me Cl Br

Me Me * Cl CH3
* *  sp3 carbon has same groups so does not show
G.I
(R) (S)
64. (2)
60. (4)
CH3
3 1
CH3–C–CN
2

CH2=C=CH–CH3 CH2=CH–CH=CH2
CH3 CHC–CH2–CH3 CH3–CC–CH3
Common Name by system (I)
t-butyl cyanide
65. (4)
Common name by system (II)
All are chiral molecules because POS & COS
Neovaleronitrile
both are absent so optically active.
IUPAC name
2 2-Dimethylpropanenitrile
66. (3)
I → Open chain compound
61. (3)
CH3 HO 1 CH2CH3 II → Ring compound
H 3
2
4 C & C So both are Ring-Chain isomers
4
1 2 CH2CH3 3 CH3
HO H 67. (3)
S S I → 2-chloropentane
Homomers or Identical II → 3-chloropentane
So both are structure isomers
62. (4) (Position isomers)
CH3 CHO 68. (2)
180º rotation Isotone means same number of neutrons
(1) H OH HO H
Number of neutrons =
CHO CH3 Mass number – Atomic number
(L) Number of neutron in Ge = 76 – 32 = 44
CH3 COOH Number of neutron in As = 77 – 33 = 44
180º rotation
(2) H NH2 H2N H
69. (4)
COOH CH3 Number of electrons = 2n2 (n = shell number)
(L) For 4th shell = 2 × (4)2 = 32 electrons
COOH
70. (2)
(3) H2 N H Number of radial nodes = (n – l – 1)
For 4s n = 4 l = 0 (4 − 0 − 1) = 3
CH2OH 
For 3p n = 3 l = 1 (3 − 1 − 1) = 1
(L)

[6]
71. (4) 83. (3)
1 1 1 4.2
= RH  2 − 2  Total number of moles = = 0.3 mol
 2 3  14
1 5 1 mol of N3– have electrons = 10 × NA.
= RH  Number of e– in 0.3 mol
 36
= 0.3 × 10 × NA = 3 NA
72. (1)
84. (3)
420 = n = 4
Mn +2 → MnO 2
⎯⎯
 = 2 (d)
n=2
m = 0 d z 2 = 4d z2
M
 Eq. wt. =
73. (2) 2
2r = n
n=3 85. (3)
nh
mvr = (n = number of shell)
74. (1) 2
On the base of (n + l) rule. Angular momentum
6h 3h
for 6th shell = =
75. (2) 2 
m = – l to +l, through zero thus for l = 2, values
of m will be – 2, –1, 0, + 1, + 2. 86. (3)
DU = number of  bonds + number of rings
76. (3) =4+3
=7
77. (3)
The graph is depicted as follows 87. (3)
H3C CH3 H CH3
C=C C=C
H H H3C H
P
T1 Cis Trans
T2 Stability:
T3
Trans > cis due to less steric
V
hinderence in trans.
Applying Gay Lussac's law, at constant volume,
Solubility:
as pressure increases, temperature should also
Cis > trans due to more dipole
increase.
moment in cis
 T1 > T2 > T3
Dipole moment:
Cis > trans because the bond
78. (3)
moments of two bonds
Critical temperature of a gas is related to van der
to alkyl groups are
Waals constants as
opposed and cancel in
8a trans.
Tc =
27Rb Melting point:
Trans > cis Trans structure is
79. (4) symmetrical therefore
Gases with same molar mass will effuse at the it will be more closely
same rate. packed.
Melting point 
80. (1) packing efficiency

81. (3)

82. (3)

[7]
88. (2)  For He  −1312
 → E6 =  (2) 2
* Pseudo chiral carbon 
 z = 2  (6) 2
CH3–CH–CH–CH–CH3
Br OH Br 1312 −1312
=− 4 =
36 9
89. (1) Corresponding energy level for
Br Li 2 + 1312 1312
= − 2  (3)2 = −
(z = 3) n 9

Cl n2 = 81
n=9
Cl
In He n = 4;
The corresponding energy level in Li2+ ions
Br For He  1312 1312
E4 = − 4 =
POS → ✓ z=2 ( 4)
2
4
COS → ✓ Corresponding energy level for
Li  −1312 1312
90. (2) = 2
 (3) 2 = −
(z = 3) n 4
Only II shows G.I.
2
Et n = 36 n=6
Et
Shortcut
&
1 1 1
Et Et = R  (2)2  2 − 2  ...(1)
(trans) (cis)  He2+ 4 6 
1 1 1
91. (1) = R  (3)2  2 − 2  ...(2)
 Li2+ n
 1 n 2
Optical active because POS & COS both are
For same energy equation (1) must be equal to
absent.
equation (2) which only possible when
(2) POS → Present, so optically inactive
n1 = 6 and n2 = 9
(3) COS → Present, so optically inactive
95. (2)
92. (3)
Orbital angular momentum
Molecular formula → Same
h
Structure formula → Same = l (l + 1) = l (l + 1)
2
Configuration → Different
For p-electron value of l = 1
So, (II) & (III) are stereoisomers
 Orbital angular momentum
= 1(1 + 1) = 2
93. (3)
CH3
96. (2)
I CH3 –– C –– CH3
5 95 V1
CH3 V2 = V1 −  V1 =
100 100
2,2-Dimethylpropane Let initial pressure be P1
II CH3––CH––CH2 –CH3 And final pressure be P2
CH3  Applying Boyle’s law,
2-Methylbutane P1V1 = P2V2
Both have different IUPAC name so they are 95 V1
P1 V2 95
constitutional isomers. or, = = 100 =
P2 V1 V1 100
94. (3) Percentage increase in pressure
In He; n = 6 the corresponding energy level in
Li2+ ion will be

[8]
 P2 − P1 P  101. (1)
= 100 =  2 − 1 100 NCERT Page No. 19
P1  P1 
P 100 102. (4)
 2=
P1 95 NCERT Page No. 16
 Percentage increase in pressure 103. (1)
 100  5 500 NCERT Page No. 17
= − 1  100 = 100 = = 5.26%
 95  95 95
104. (4)
NCERT Page No. 17
97. (2)
According to Charles’ law. 105. (2)
VT NCERT Page No. 19
 V = kT
106. (1)
1
or V × =k NCERT Page No. 20
T
1 107. (1)
 V versus gives a hyperbolic graph i.e.,
T NCERT Page No. 21

108. (4)
v NCERT Page No. 21, 22

109. (2)
1 NCERT Page No. 23
T
110. (4)
98. (2) NCERT Page No. 23
NH3 and HCl mixture would not follow Dalton's
law of partial pressure as they react to form 111. (1)
NH4Cl NCERT Page No. 24
NH3(g) + HCl(g) → NH4Cl(s) 112. (2)
NCERT Page No. 24
99. (4)
2C6H6(l) + 15O2(g) → 12CO2(g) + 6H2O(g) 113. (1)
2 × 78 g 15 × 22.4 L NCERT Page No. 167
From equation 15 × 22.4 L of O2 is required for
114. (3)
= 156 g of benzene
NCERT Page No. 26
i.e., 156 g benzene for complete combustion
required O2 (STP) = 15 × 22.4 L 115. (4)
39 g benzene for complete combustion required NCERT Page No. 27
15  22.4
O2 (STP) = × 39 = 84 L of O2 116. (1)
156
NCERT Page No. 30

100. (4) 117. (3)

+2 − 2 +6
NCERT Page No. 32
FeS → Fe+3 + SO3
n-factor of FeS = 1  (3 − 2) + 1  (6 − (−2)) 118. (1)
Fe S NCERT Page No. 32, 33
=1+8=9
M M 119. (4)
E= = NCERT Page No. 36
n factor 9
120. (4)
NCERT Page No. 37

[9]
121. (2) 141. (2)
NCERT Page No. 36 NCERT Page No. 170

122. (1) 142. (4)

NCERT Page No. 36 NCERT Page No. 168

123. (1) 143. (3)

NCERT Page No. 36 NCERT Page No. 167

124. (1) 144. (3)

NCERT Page No. 38 NCERT Page No. 167, 170

125. (2) 145. (4)

NCERT Page No. 38 NCERT Page No. 11

126. (4) 146. (3)

NCERT Page No. 38 NCERT Page No. 13

127. (1) 147. (2)

NCERT Page No. 39 NCERT Page No. 30

128. (4*) 148. (1)

NCERT Page No. 36, 38 NCERT Page No. 25

129. (3) 149. (1)

NCERT Page No. 40 NCERT Page No. 20, 21, 22

130. (3) 150. (1)

NCERT Page No. 40 NCERT Page No. 31

131. (2) 151. (3)

NCERT Page No. 37
(NCERT Pg 101)
132. (3)
NCERT Page No. 42, 43 152. (3)
(NCERT Pg 101)
133. (1)
NCERT Page No. 129
153. (3)
(NCERT Pg 101)
134. (1)
NCERT Page No. 137
154. (3)
135. (4) (NCERT Pg 102)
NCERT Page No. 135
155. (2)
136. (3)
NCERT Page No. 126, 129 (NCERT Pg 102)

137. (1) 156. (2)

NCERT Page No. 133, 134, 135 (NCERT Pg 104)

138. (1) 157. (1)

NCERT Page No. 132, 136, 138
(NCERT Pg 105)
139. (4)
NCERT Page No. 136, 137 158. (3)
(NCERT Pg 112)
140. (1)
NCERT Page No. 166

[10]
159. (3) 175. (1)
(NCERT Pg 112) (NCERT Pg 279)

160. (3) 176. (3)

(NCERT Pg 113) (NCERT Pg 279)

161. (4) 177. (2)

(NCERT Pg 114) (NCERT Pg 280)

162. (2) 178. (3)

(NCERT Pg 114) (NCERT Pg 281)

163. (2) 179. (4)

(NCERT Pg 275) (NCERT Pg 296)
164. (4)
(NCERT Pg 268) 180. (4)
(NCERT Pg 293)
165. (2)
(NCERT Pg 269) 181. (2)
(NCERT Pg 293)
166. (4)
(NCERT Pg 270) 182. (3)
(NCERT Pg 294)

167. (4) 183. (2)

(NCERT Pg 272) (NCERT Pg 304)

168. (4) 184. (3)

(NCERT Pg 272) (NCERT Pg 304)

169. (3) 185. (4)

(NCERT Pg 273) (NCERT 305)

186. (1)
170. (1)
(NCERT Pg 305)
(NCERT Pg 274)

187. (3)
171. (2)
(NCERT Pg 305)
(NCERT Pg 274)

172. (4) 188. (3)

(NCERT Pg 275) (NCERT Pg 306)

173. (3) 189. (4)

(NCERT Pg 275) (NCERT Pg 308)

174. (3) 190. (3)

(NCERT Pg 279) (NCERT Pg 312)

[11]
191. (3) 196. (3)
(NCERT Pg 312) (NCERT Pg 285)

197. (3)
192. (3)
(NCERT Pg 288)
(NCERT Pg 307)
198. (2)
193. (1)
(NCERT Pg 293)
(NCERT Pg 311)
199. (2)
194. (1)
(NCERT Pg 294)
(NCERT Pg 286)
200. (4)
195. (3) (NCERT Pg 296)
(NCERT different chapters)

[12]