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Home > Chemistry Letters > List of Issues > Volume 23, Issue 2 > Stereoselective Synthe…

1994, Vol.23, No.2

231-234

Stereoselective Synthesis of (E) and (Z)-

Vinylsilane by the Addition Reaction of
Organometallic Reagent to Silyl-substituted
Fischer-type Carbene Complex
Iwasawa Nobuharu 1 , Saitou Masatoshi 1

https://doi.org/10.1246/cl.1994.231
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Cited by
Toshimichi Asakura, Takuto Kojima, Tomoya Miura, Nobuharu
Iwasawa. (2006) Useful Reactions of Silylated Propargyltungsten or
Propargylmolybdenum Species. Angewandte Chemie International
Edition 45:41, 6874-6877.
Online publication date: 17-Oct-2006.
Toshimichi Asakura, Takuto Kojima, Tomoya Miura, Nobuharu
Iwasawa. (2006) Useful Reactions of Silylated Propargyltungsten or
Propargylmolybdenum Species. Angewandte Chemie 118:41, 7028-
7031.
Online publication date: 17-Oct-2006.
José Barluenga, Iván Pérez‐Sánchez, Marcos G. Suero, Eduardo Rubio,
Josefa Flórez. (2006) Diastereoselective Multicomponent
Cyclizations of Fischer Carbene Complexes, Lithium Enolates, and
Allylmagnesium Bromide Leading to Highly Substituted Five‐ and Six‐
Membered Carbocycles. Chemistry – A European Journal 12:27, 7225-
7235.
Online publication date: 6-Sep-2006.
Kohei Fuchibe, Nobuharu Iwasawa. (2003) Generation of Reactive
Species by One‐Electron Reduction of Fischer‐Type Carbene
Complexes of Group 6 Metals and Their Use for Carbon–Carbon Bond
Formation. Chemistry – A European Journal 9:4, 905-914.
Online publication date: 11-Feb-2003.
Nobuharu Iwasawa, Masatoshi Saitou, Hiroyuki Kusama. (2001)
Reactions of silyl-substituted Fischer-type carbene complexes with
silanes. Journal of Organometallic Chemistry 617-618, 741-743.
Online publication date: 1-Jan-2001.
Mar Gómez-Gallego, Marı́a J Mancheño, Pedro Ramı́rez, Carmen
Piñar, Miguel A Sierra. (2000) On the Reduction of α,β-Unsaturated
(Group 6) Carbene Complexes by NaBH 4 1. Tetrahedron 56:28, 4893-
4905.
Online publication date: 1-Jul-2000.
Björn C. Söderberg, Shannon N. O'Neil, Angela C. Chisnell, Jian Liu.
(2000) A [3.3]Sigmatropic Rearrangement of α,β-Unsaturated Fischer
Chromium Carbenes: Synthesis of Alkynol and Dienol Esters.
Tetrahedron 56:28, 5037-5044.
Online publication date: 1-Jul-2000.
Cecilio Alvarez-Toledano, O. Baldovino, G. Espinoza, R. Alfredo
Toscano, René Gutiérrez-Pérez, Olivia García-Mellado. (1997)
 Reactivity of a two heteroatom stabilized anionic chromium (0)
carbene complex towards a mono- and a disubstituted alkyne: New
synthesis of γ-aminobutenolides and formation of a novel oligomer
chromium (0) complex. Journal of Organometallic Chemistry 540:1-2,
41-49.
Online publication date: 1-Aug-1997.
Björn C. Söderberg, Jian Liu, Thomas W. Ball, Michael J. Turbeville.
(1997) Thermal Decomposition of Pentacarbonyl(1-
acyloxyalkylidene)chromium(0) Complexes: Formation of Z -Enol
Esters. The Journal of Organic Chemistry 62:17, 5945-5952.
Online publication date: 22-Aug-1997.
Louis S. Hegedus. (1996) Transition metals in organic synthesis
highlights for the year 1994. Coordination Chemistry Reviews 147,
443-545.
Online publication date: 1-Jan-1996.
N. IWASAWA, M. SAITOU. (1994) ChemInform Abstract:
Stereoselective Synthesis of (E) and (Z)-Vinylsilane by the Addition
Reaction of Organometallic Reagent to Silyl-Substituted Fischer-Type
Carbene Complex.. ChemInform 25:28, no-no.
Online publication date: 19-Aug-2010.

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