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    AIATS-2023 (CF+OYM) Test-7 - Code-A&B - Solutions - 05.02.2023

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    Ton All India Aakash Test Series for NEET - 2023 Baie (Answers) CU TEST - 7 (Code-A) Test Date: 05/02/2023, ANSWERS 1 (1) 41. (1) at. (4) 121. (3) 461. (2) 2 (2) 42. (2) 82. (4) 122. (4) 162. (2) 3. (2) 43, (1) 83. (1) 123. (2) 163, (2) 4 (2) 44. (4) 84. (3) 124. (3) 164. (1) 5. (1) 45. (2) 85. (1) 125. (3) 168. (3) 6. (4) 46. (3) 86. (3) 126. (3) 166, (2) 7 (2) 47. (1) 87. (2) 127. (1) 167. (1) 8. (1) 48. (1) 88. (4) 128. (1) 168. (4) 9 (3) 49. (1) 89, (1) 129. (4) 169. (3) 10. (3) 50. (2) 90. (4) 130. (4) 170. (4) 11. (2) 51. (4) 91. (2) 131. (4) 171, (4) 12. (2) 52. (2) 92. (1) 182, (2) 472. (1) 13. (4) 53. (4) 93. (3) 133. (2) 173. (3) 14. (4) 54. (3) 94, (4) 134. (2) 174, (3) 15. (2) 55. (3) 95. (2) 135. (2) 175. (2) 16. Delete 56. (4) 96. (2) 136. (4) 176. (4) 17. (1) 57. (3) 97. (3) 137. (4) 177. (1) 18. (2) 58. (4) 98. (3) 138. (4) 178. (1) 19. (2) 59. (3) 99. (3) 139. (4) 179, (3) 20. (1) 60. (2) 100. (4) 140. (3) 180. (4) 21, (2) 61, (4) 101. (4) 141. (2) 181. (2) 22. (2) 62. (4) 102. (3) 142. (1) 182. (2) 23. (3) 63. (2) 103. (4) 143. (1) 183. (3) 24. (3) 64, (2) 104. (1) 144. (2) 184, (3) 25. (2) 65. (1) 105. (2) 145. (2) 185. (4) 26. (2) 66. (3) 108. (2) 146. (3) 186. (4) 27. (2) 67. (3) 107. (2) 147, (2) 187. (4) 28. (1) 68. (4) 108. (3) 148. (3) 188. (4) 29, (2) 69. (2) 109. (2) 149. (2) 189. (1) 30. (3) 70. (2) 110. (4) 150, (2) 190. (2) 31. (1) 71. (2) 4111. (3) 151. (4) 191. (2) 32. (2) 72. (1) 112. (2) 152. (3) 192, (2) 33. (2) 73. (2) 113. (1) 153. (3) 193. (2) 34. (3) 74. (3) 114. (2) 154. (2) 194, (1) 35. (2) 75. (1) 115. (3) 185. (4) 195. (1) 36. (1) 76. (1) 116. (1) 156. (2) 196. (1) 37. (1) 77. (3) 117. (4) 157. (3) 497. (3) 38. (2) 78. (4) 118. (2) 158. (1) 198. (3) 39. (2) 79. (3) 4119. (3) 159. (2) 199. (2) 40. (1) 80. (1) 120. (3) 160. (1) 200. (2) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 EUs Ta Ss To HINTS & SOLUTIONS [PHYSICS] SECTION-A 5. Answer (1) Answer (1) Hint: Use conservation of mechanical anergy Sol Ua + Ke= Unis + Keston = 0 -Mm Hint: Potential energy in R OM Ay? 0 -cMm Sol.: Potential energy at the sutace , tye SM, potertial eneray at height, h = R from surface of 2 -GMm_-GMm RiR 2k -GMm _GMm _GMm aR ORR ‘Answer (2) Hint: 7? = Re AU Sol.: For satellite we know that, ‘Answer (2) Hint: Energy required is equals Kina efrgy of revolving sate 216M PR 1 Sol; = KE = mv" ° 2 cum 5 GM oR 89 Re tm Big R aro => KES = maR ‘Answer (2) Hint: Wo = +AU. Sol.: Won = +AU = Ur U; ~GMm -6Mm GMm ou ‘] R 2R R 2) aR Answer (4) Hint: Due to symmetry, the net field at the centre is zero. Sol.: The net field at the centre of hexagon would be zero due to symmetry. Now, when one of the masses is removed then, Ey Ey = 0 Ey = Ey Answer (2) ~V Hint: E Answer (1) Hint: Use conservation of mechanical energy SOl-! Usanie + (KE)cente = Uc + Ke ‘Answer (3) Hint: Use Newton’s law of cooling soi; 2-70 x(seete -30} 10 3 Aso 7 © Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 ieee 10. " 12, 13. (Hints & Solutions) aio, 20280 {7060 39] x25 2) on song “10xt Keds 145 TAO Kaas 738 21-S.7~ 9 minutes 35 Answer (3) Answer (2) Hint: Use law of thermal conduction Sol.: For steady state, heat conduction dQ _KalT-To]-A _Ka(To-T)-A dt T T => Ke (Ts ~ To) = Ka (To~ Te) = Kyl, —KaTo = Kalo ~Kals > ‘Answer (2) Hint: Use Wien’s displacement law Sol. Patt ET and ig: T= C= by -T, RoW has na =h-(1) ofa a la) >= 256 r= 256 Ps o=256 Answer) Hint: There is no change in temperature during phase change, Sol.: The phase change of water into steam is represented by process DE. 14, 16. 16. 7. 18. CUT 023, Answer (4) Hint and Sol.: At the triple point all the 3 phases co-exist and triple point of water is identified at particular temperature and pressure. Water cannot exist as quid below triple point. Answer (2) Hint: Thermal resistance, R= + KA Sol: Hint, =P __ Constant UP-LP Sol: 100-30 1-30 t-30_ 70 1590 , 1230 _ 70 |, ¢-30 36 100 60 80 100 t=65"c Answer (1) Hints mg = 2-nr Teos0 —> mr Sol: > 7-4 Lom, =25¢ mt L 2 Answer (2) Hint: b= 2S. Rog Sol: na 28 sn. Rac ohRaW-R oR =tR Reg nr Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 CUI eed 19. 20. 24 22. 23, 24. 26. Fractional change 4 (h_.) W Answer (2) Hint & Sol.: Bernoull’s theorem is based upon the conservation of energy. Answer (1) Hint: P Sol. onthe : rower 2) Hint: Body will finaly attain terminal velocity Sol.: When the body is dropped in a viscous fluid with a velocity greater than terminal velocity then the viscous force acts on the body opposing motion and the speed decreases and. finally achieve terminal velocity Vv ‘Answer (2) Hint and Sol.: The buoyant force acting on the: body is due to the pressure differences. Answer (3) Hint: Prtim = Pgh Sol. pg -9-Py = Pay = py = APA For same pressure at the bottom level, the density of liquid A wil be greater than that of B Answer (3) Hint: Rate of flow = Area x velocity Sol.: Rate of flow = cross-sectional area * velocity vx Re ‘Answer (2) Sol.: Coefficient of viscosity Shearing stress Strain rate 26. 27. 28. 29. 30. foe To Shear stress = n x shear strain rate Shear strain rate =~ Shear stress = yx = 4210" 8 r 10 =2%102N m2 ‘Answer (2) Hint: Centre of buoyancy is centroid of displaced volume of fluid. Sol. == 5 Cento of buoyancy ying at conte of dspace velume of fue ‘Answer (2) Hint: Elongation = SL ”Y Sol: Elongatior Answer (1) Hint: For brittle materials yield point and fracture pointiies close to each other. Sol.: Material is said to be brittle when yield point and fracture point are close to each other, ‘Answer (2) Hint: Breaking stress for the material remains ‘same S01: gg, = 1000 «25x10 r 1000 Perrot Fx25x10 = 71000 2 =T, ON ‘Answer (3) Hint: fe = 0.8 then there fs no change in volume Sol: V= art aV_2ar ab vor e Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 34 32, 33, 34, Answer (1) Hint: Energy stored per unit volume = + x (strain)? « Young's modulus Sol.: Elastic potential energy per unit volume = x stress * strain ; % (Young's modulus) * strain x strain 1 2 =A x (strain Fe¥ (stain) (oe a8 10" x64<107 100) “2 = 1.6 x 108 Jim? Answer (2) = 15x10" 2 a dint: gy <9] & af Ry BR, 3\_g 4 J gg = 9)" Sols gy =9)t- FR] > Weight = mg, aw 200 soy 44 ‘Answer (2) Hint: 9 dt Sol: The angular momentum of the planet remains constant as it goes around the sun, Answer (3) ; 36, 36. 37. 38, CUT 023, Answer (2) Hint: Change in potential is independent of reference point. Sol.: When potential was zero at OM Vasco 2R Now potential made zero at centre, -3GM 36M Vente om FF SECTIONS Answer (1) Hint: Angulaf momentum of a satelite remains constant Sol. M-V4-2R=m-Vp-4R => Vp =2Ve Maximum kinetic energy willbe atthe point A Hiny2 Mm 1 ,,2_GMm 28 aR 28 aR fv,’ _GMm | GMm 2| 4k“ R 1 2 A ed 2 °° 4 aR AR Answer (1) Hint: B = SMm 2r Sol.: (8-€), GMm:2_GMm 22 Or => Hence the ratio is 1:1 ‘Answer (2) Hint: y= 3a Sol: y=3% 2% 10-4=6 x 104, (BE Don (2) Pa =Po[t- AT] Fractional change Po=Po _ Pe. Po Po Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 CUI eed = 88 = 6x 10-4«50 Po = 300 x 104 =3%102=0.03 39. Answer (2) Hint: Use law of heat conduction 2K AAT, since at ae conductivity of first half is less as compared to second half, its thermal resistance will be more. Hence for steady state heat transfer, the temperature drop would be more for first haf. 40. Answer (1) Hint: Use Wien’s displacement law Sol. the thermal Sol: hy -T=C-4 2g = 22-4, 5-8 aT g 41. Answer (1) Hint: Use Stefan’ law E= 0 AT! Sol.: Total radiated power = 0-4nR.T* Total radiated power por unit area’ o-4aR3-Tt _ TAR 4nR? Re at distance, R 42. Answer (2) Hint: Heat required to convert = mL Sols Semagxh= mathe = 45.6 km 43. Answer (1) Hint and Sol.: Thermal strai ou AT = 1.7% 10-5 «102 7x 10-= 0.0017 44, Answer (4) Hint and Sol.: An ideal fluid should be non- viscous, incompressible in nature and shear stress developed is zero, longitudinal strain 45, 46. 47, 4g, 49, 50, 7 (Code-A)_(Hints & Solutions) ‘Answer (2) Hint: Use Bernoull’s theorem Sol.: Neglecting height difference, 1 ye 12 P+dpv? =P, + Apu} 2° 2 1p te P,-P, =Apv3 -Apv? = 30V8-5F 1 800(3? - 7?) 2 1 a = 3200 Nim? Answer (3) 800%8 Lateral strain Hint: - —L#teral strain _ Longitudinal strain (Poisson's ratio) Sol.: Longitudinal strain = , since the ratio of longitudinal strain)is same and the material is same. Hence, Ratio of lateral strain = 1: 1 ‘Answer (1) Hint: & AVIV Sol.: Fractional change in volume = ‘Answer (1) Hint and Sol.: For closed orbits total mechanical energy is always negative ‘Answer (1) Hint: Work done = surface tension Increase in surface area So: w ‘Answer (2) tint = [a q is flow velocity in > de pipe Sol: vy = [2290-4 % ~ fee Ps 9 ps Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 51 52. 53, 54. 56. (Hints & Solutions) All India Aakash Test Series for NEET-2023 [CHEMISTRY] SECTION-A Sol: ‘Answer (4) Hint: 2FeC,0, +Cr,0F +1444" > 2Fe®* +2Cr** + 400, +7H,0 Sol.: *: 2 moles FeCz0s requires 1 mol Cr,0%- 4 mol FeC20s requires %4 mol Cr,0}- ‘Answer (2) Hint: Sum of all the oxidation state of elements in an ion is equal to charge on ion, Sol ton Oxidation state PO, 6 so, +6 noe 7 our “1 Answer (4) Hint: Disproportionation reactions are those in which the atom of same element oxidizes as well as reduces. 42 o Sol.: (1) 2XeF; +2H,0 > 2Xe + 4HF4O, 4 eed (2) 6X@F, + 12H,0 + 4Xe + 2X00, + 26HF +30, ° 3 “4 (3) Py + 3NaOH+ 3H,O > PH, + 3NaH,PO, 2a (4) 2H,02 > 2H,0 +0, ‘Answer (3) Hint: n-factors for MnO and F are § and 1 respectively. Sol.: Balanced chemical reaction is 2MnOg +107 + 16H* —> 2Mn?* + Sip + 8H,0 Answer (3) Hint: Element undergoing oxidation is reducing agent. 56. 87. 58. 59. 60, e ° 14H «Gh0F + 3Ni > 2cr8* 4 aNPP + 7H,0 Oxdizng Reducing ‘agent agent ‘Answer (4) Hint: Oxidation number of carbonyl group is zero Sol.: ‘Compound Oxidation state of Fo FexOs +3. Ke{Fe(CN)e] +2. FeSOq(NH:)SO+6H:0 42 Fe(CO)s 0 ‘Answer (3) Hint: H202 will be oxidised in the reaction in which itis acting as reducing agent. Sol.: > >. ° I + HjO,4 20H > 2m + 2H,0+ 02 (Roaicing oer) fo a | 4 (1) ) 0 HO, + Ag,0 —> Ag+ HO + 0, ‘Reducing agent) b ‘Answer (4) Hint: Change in oxidation number per atom provides number of electrons involved 15. Sol: 10,7 +607 > Answer (3) Hint: Metal displaced by another metal from its compound is known as metal displacement reaction. Sol.: Zn displaced copper from copper sulphate. So itis metal displacement reaction Answer (2) Hint: The oxidation number of sulphur in SO2 is 4 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 CUI eed Sol. [eee 4 6 SO, + Cl —> SO,Cl, ‘Oxidation number of sulphur changes from +4 to +6. 61 62. 63. 64. 66. Answer (4) Hint: Higher the standard reduction potential of metal, more willbe its oxidising power Sol: EapiC>A>B Since Ejap of Cis maximum, ithas more oxidising power. Answer (4) Hint: Smaller the size of hydrated ion, higher will be its ionic mobility in aqueous medium Sol; Due to more hydration of Li, effective size of ion increases and hence ionic mobility decreases. Answer (2) Hint: Thermal stability increases with inérease in cation size Sol.: Thermal stability: MgCOs < CaC0s < SrCOs NaHiCOs + NHAC! + 2NaHCOs —4-+ NazCOs + H20 + COz Answer (1) Hint: Be and Al resembles in properties due to diagonal relation. Sol: Duo to high ionisation energy of beryium, a large amount of energy requires for excitation of the electrons. Answer (3) 66. Hint: A brine solution is electrolysed using a mercury cathode and carbon anode. Sol.: Electrolysis of brine solution in Castner Kellner cell produces NaOH. 67. 68, 69, 70. nm 7 (Code-A)_(Hints & Solutions) Cathode : Na* +e"! sNa (amalgam) 2Na (amalgam) + 2H20 -> 2NaOH + 2Hg + He Anode : CI -» Ach, +e7 2 Answer (3) Hint: Sodium in quid ammonia gives ammoniated electrons, Sol.: When sodium is dissolved in liquid ammonia, ammoniated electrons are produced which are responsible for blue colour solution, conductivity land selective reducing agent. + In concentrated solution, it becomes diamagnetic. ‘Answer (4) Hint : All alkali metals and few alkaline earth metals gives characteristic colour to oxidising flame. Sol.: Metal | Colour of flame ui Crimson red Na Yellow Ba Apple green Mg No colour ‘Answer (2) Hint: Mik of lime reacts with chlorine to form hypochlorite. Sol.: Ca(OH) +2Cl, +» CaCl, + Ca(OCl), + Bleaching powder 2H,0 Answer (2) Hint: Higher the hydration enthalpy, higher will be solubility in water. Sol.: MgSO has higher hydration energy, so ithas higher solubility. Down the groups, solubility of alkaline earth metal sulphates decrease. ‘Answer (2) Hint: Higher the polarising power of cation, more will be covalent character. Sol.: BeH is covalent and polymeric in nature as itis electron deficient. Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 ieee 72. 73, 74 75. 76. 77. (Hints & Solutions) ‘Answer (1) Hint : Density generally increases down the group. Sol. Metal Density (g cm) ui 0.53 Na 0.97 K 0.86 Rb 1.53 ‘Answer (2) Hint : Lime water is the clear aqueous solution of slaked lime. Sol.: Suspension of slaked lime in water is known as milk of lime. ‘Answer (3) Hint: Compounds in which oxygen has oxidation state are superoxide. Sol.: LitO —> Oxide NazO2 -> Peroxide KO2 > Superoxide BaQ2 > Peroxide Answer (1) Hint & Sol: 2eethylanthraquinol 222» Taira H:02 + oxidised product Answer (1) Hint: Chlorides and sulphates of Mg and Ca is responsible for permanent hardness Sol.: Temporary hardness is due to MgHCOs (Magnesium bicarbonate) and CaHCOs (Calcium bicarbonate) Answer (3) Hint: In CuSO«5H:0, four HzO molecules are present inside the coordination sphere. Sol.: Only one HO molecule is hydrogen bonded in CuSO+-5H20 78. 79. 80. at 82, 83, 84, 85, 86. ‘Answer (4) Hint: 020 is heavy water Sol.: CaCe + D20 > CaD2 + Ca(ODe Answer (3) Hint and Sol: Due to cage like structure, density of ice is less than water. Answer (1) Hint: Extent of solvation depends on dielectric constant, Sol.: Dielectric constant of 020 is less than HzO. Answer (4) Hint : lonic hydrides and formed by most of the s-block element. Sol.: NaH — lonie hydride CHi > Electron precise hydride BiHs > Electron deficient hydride NHy-> Electron rich hydride ‘Answer (4) Hint: Volume strength = 11.2 x molarity Soli: Volume strength = 11.2 * 3 = 33.6 V ‘Answer (1) Hint: Water is reduced at cathode and oxidised at anode, Electrolysis Traces ofacd Sol.: 2,00) 2H(9)+ O29) ‘Answer (3) Hint : Calgon is sodium hexametaphosphate, Sol.: Hydrated sodium aluminium silicate is zeolite or permutt Answer (1) Hint: Water gas is mixture of CO and Ha Sol: C(s) + steam —2/0K SECTION-B > CO(g) + Hala) Answer (3) Hint: Permanent hardness is due to chlorides and sulphates of Ca and Mg Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 CUI eed a7. 88, 89, 90. 1 92. Sol. + Bolling of hard water and Clark's method can bbe used to remove temporary hardness of water. + Ion exchange, synthetic resin and treatment with sodium carbonate methods are used to remove permanent hardness of water. ‘Answer (2) Hint: H02 has open book like structure Sol. H202 is polar and non-planar compound. Answer (4) Hint: Orthoboric acid is a Lewis acid Sol. + HaBOs is a weak monobasic acid HBO, + H,0 > B(OH),~ +H" + Hybridisation of boron in HsBOs is sp? Answer (1) Hint: Concentrated HzSOx is a dehydrating agent cone. Sol: aso. HCOOH > CO+H,0 ‘Answer (4) Hint: Compound having vacant orbital act as Lewis acid Sol.: In BFi- octet of boron is complete, hence cannot act as Lewis acid, while BrHs, AICls and BeF2 have vacant orbital so behave as Lewis acid. ‘Answer (2) Hint: Compounds showing back bonding has higher bond strength and lesser bond length. Sol.: Due to back bonding in BFs, 8-F bond strength increases and bond length decreases. Answer (1) Hint: The compound in which central atom has. vacant orbital will undergo hydrolysis easily. 93, 94, 95, 96. 97. 98. 7 (Code-A)_(Hints & Solutions) Sol.: In Ck, carbon does not have vacant orbital hence does not hydrolyse in aqueous medium, Answer (3) Hint: Cyclic silicates shared two oxygen atom per tetrahedral unit Sol.: Out of four oxygen atom, two oxygen atom of sllicate unit are shared in cyclic silicate ‘Answer (4) Hint: Borax is NazB:Or-10H.0 Sol: + Borax contains tetranuclear unit [BsOs(OH)s)> + NazB:Or + 7H:0 > 2NaOH + 4H:B03 + Two boron atoms in borax are sp? hybridised while other two are sp® hybridised. ‘Answer (2) Hint:.In diamond there is no free electrons for ‘conduction Sol: Graphite shows delocalised electrons conductivity due to Potassium. and sodium have electrons to show conductivity free valence Answer (2) Hint: Due to electron deficiency BHs dimerises to Bie. Sol: Nee ra »‘, Hay py ett H K + Two 3c-2e- bonds (Banana bond) are present in diborane. Answer (3) Hint: Catenation power decreases with increase in atomic size. Sol.: Increasing order of catenation GeRe r AV Bar, aL Vor et 7. Answer (2) Hint: Breaking stress for the material remains same Sol: The angular momentum of the planet = 1000 remains constant as it goes around the sun. 225x104 ‘Answer (2) 4 T 1000 Zxtxto4 2x25x10 Faretot Fx26x10 37-1000 7 -40N es Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 10. 1" 12. 13. Cie) ‘Answer (1) Hint: For brittle materials yield point and fracture point lies close to each other. Sol.: Material is said to be brittle when yield point and fracture point are close to each other. ‘Answer (2) fe AY Hint: Elongation Ftp (u-Way Sol.: Elongation a T Lok 4 ‘Answer (2) Hint: Centre of buoyancy is centroid of displaced volume of fluid, Sol. ==>, conte oftuoyancy of dspace velume of fue Answer (2) Sol.: Coefficient of viscosity Shearing stress Strain rate | Shear stress =» shear strain rate ‘Shear strain rate Shear stress = nx 2% 109 Nm? Answer (3) Hint: Rate of flow = Area x velocity Sol.: Rate of flow = vx aR? Answer (3) ross-sectional area x velocity Hint: Poosom = Pgh Paba ha SOL: p4:9-Pa = Pa -9-he > Py = For same pressure at the bottom level, the density of liquid A will be greater than that of B. 14, 16. 16. 7 18, 19. 20. CUT 023, Answer (2) Hint and Sol: The buoyant force acting on the body is due to the pressure differences. Answer (2) Hint: Body wil finaly attain terminal velocity Sol.: When the body is dropped in a viscous fluid with a velocity greater than terminal velocity then the viscous force acts on the body opposing motion and the speed decreases and finally achieve terminal velocity. v Answer (1) Hint: P= pa Sol: pdag=p.gh ahaha m1 Answer (2) Hint & Sol: Bernoull’s theorem is based upon the ‘conservation of energy. ‘Answer (2) no 2S gh. R=6 Sh-R=W- RR’ Rog Fractional change Answer (1) Hint: mg = 2 ar Teos0 => m =r Sol: > Zt Delete Hint: —f=1-P —_ Constant U-P-L-P Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 EUs 24 22. 23, 24 Ta Sol. 100-30 100 1= 65°C Answer (2) Hint: Thermal resistance, R= KA Sol. Kan? rd Answer (4) Hint and Sol.: At the triple point all the 3 phases) co-exist and triple point of water is identified. at particular temperature and pressure, . Water ‘cannot exist as liquid below triple point ‘Answer (4) Hint: There is no change in temperature during) phase change. Sol.: The phase change of water into steam is represented by process DE. Answer (2) Hint: Use Wien's displacement law Sol. Pot! qh Tz pray 28-(1) fp 2 pla] 256 = 256 P1 ca= 256 Ss To 25. Answer (2) Hint: Use law of thermal conduction Sol.: For steady state, heat conduction dQ _KalTi=To]-A _Ka(To-To)-A at => Ka (Ts — To) = Ke (To — Ta) = Kal ~Kaly = Kalo ~ Kal 2 Hala 1, 26. Answer (3) Sol.: We know that, pl_tye_ ye axel"? *] 3p lad 52K ate 27. Answer (3) Hint: Use Newton's law of cooling 80-70 _ (80470 mm “| 2 Sol: -20] fo aon eds...( 5 70-60 _,{70+60 also, | +80 30 |- «x6 ...(2) On solving, a 1xt_Kxa5_t_ 45 710 -Kx35~ 7 35 =1-Sx7- ominutes 35 28. Answer (1) Hint: Use conservation of mechanical energy Us Ke SOL Uceite + (KE)oen -3GMm 1,2 mv’ 2 R 2 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 al o ieee 29. 20. 34 32. 33, 34, (Hints & Solutions) ‘Answer (2) ~v Hint: Sol: E= ‘Answer (4) Hint: Due to symmetry, the net field at the centre Sol.: The net field at the centre of hexagon would be zero due to symmetry. Now, when one of the masses is removed then, Ey + Ey =0 = Eoyy ou ‘Answer (1) Hint: Use conservation of mechanical energy 0 Uo Ke= Vee + Kata _ 6m 4 ne atom SMO PE R z Answer (2) Hint We = 8 Answer (2) Hint.: Energy required is equal to kinetic energy of revolving satelite Sol: = KE = 4 my 2 Gum 4 4 SM 2R R Beg. e —POF rR 2 Answer) Hints Te Sol: For satlto we know tat, 35, 36. 37, 38. 39, 40, Answer) -sm = R from surface of potential energy at height, SECTIONS, Answer (2) Hint: v, = Peas is flow velocity in pipe ol vy =, [22297 pro ay"? — 2 Page Sols v= JPR [10 a" = Pad ‘Answer (1) Hint: Work done = surface tension * Increase in surface area ‘Answer (1) Hint and Sol.: For closed orbits total mechanical energy is always negative, ‘Answer (1) Hint: 8-——" aviv Sol. Fractional change in volume = SY ~ ole Answer (3) Lateral strain Longitudinal strain Hint: (Poisson's ratio) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 CUI eed 44 42. 43. 44 48, 46. Sol.: Longitudinal strain = since the ratio of AY longitudinal strain is same and the material is same. Hence, Ratio of lateral strain Answer (2) Hint: Use Bernoull’s theorem Sol.: Neglecting height difference, 1a P+ tovi 3ov 1 2p 37 800(3*-*) = 1 800%8 2 3200 Nim? Answer (4) Hint and Sol.: An ideal fluid should be non viscous, incompressible in nature and shear stress developed is zero, ‘Answer (1) Hint and Sol.: Thermal strain = Longitudinal strain 7 * 10-5 «102 0.0017 ‘Answer (2) Hint: Heat required to convert = mL bl 489.4108 3x98 Sol. 3 demagxh=mxb-2h= mg a = 45.6 km Answer (1) Hint: Use Stofan's law E Sol.: Total radiated power Total radiated power per unit area o-4aR?-T! oT'RE 4nR? Re at distance, R Answer (1) Hint: Use Wien’s displacement law a7. 48. 49, 50, Answer (2) Hint: Use iaw of heat conduction sol: 22-K-AAT, since the thermal at ar conductivity of first half is less as compared to second half, its thermal resistance will be more, Hence for steady state heat transfer, the temperature drop would be more for first half ‘Answer (2) [1-147] Fractional change =-AT Sol.: (B-E),, = (1) ( @Mm-2_GMm B-E),,,- 2) Edm Zap ar) =+ Hence the rato is 1:1 Answer (1) Hint: Angular momentum of a satelite remains constant Sol.: m-v,-2R=m-Vg-4R > V4 = 2vp Maximum kinetic energy will be at the point A 1 2_GMm_1 2 GMm aR aR sri 3m timy2 1m .J¥a fh _GMm GM 2/7 aR aR GMm 12 GMm J inv3 = GM aR > 4 4R 2 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005: Phone : 01147623456 51 52. 53, 54, 56. 56. 87. 58. 59, Cie) CUT [CHEMISTRY] ‘SECTION-A ‘Answer (1) Hint: Water gas is mixture of CO and Ho. Sol.: C{s) + steam —2K , coig) + Haig) ‘Answer (3) Hint : Calgon is sodium hexametaphosphate. Sol.: Hydrated sodium aluminium silicate is zeolite or permutit Answer (1) Hint: Water is reduced at cathode and oxidised at anode. Electrolysis Sol.: 24,0() —EPASHES + 2H (9) + 02(9) ‘Answer (4) Hint: Volume strength = 11.2 x molarity Sol.: Volume strength = 11.2* 3 = ‘Answer (4) Hint : lonic hydrides and formed by most of the s-block element. Sol.: NaH 3.6 V > Tonic hydride CHa — Electron precise hydride Bie Electron deficient hydride NHs— Electron rich hydride Answer (1) Hint: Extent of solvation depends on dielectric constant, Sol.: Dielectric constant of D0 is less than H20, Answer (3) Hint and Sol: Due to cage like structure, density of ice is less than water. Answer (4) Hint: D20 is heavy water Sol.: CaCs + D20 > C2De + Ca(OD)e Answer (3) Hint: In CuSOs5H:0, four H:0 molecules are present inside the coordination sphere. Sol.: Only one H:0 molecule is hydrogen bonded in CuSO«SH:0 60. 61 62. 63, 64, ‘Answer (1) Hint: Chlorides and sulphates of Mg and Ca is responsible for permanent hardness Sol.: Temporary hardness is due to MgHCOs (Magnesium bicarbonate) and CaHCOs (Calcium, bicarbonate) Answer (1) Hint & Sol. ota) 2-ethylanthraquinel 22> TiiPa H:02 + oxidised product ‘Answer (3) Hint: Compounds in which oxygen has oxidation state are superoxide. Sol.: LitO > Oxide NaeO2 > Peroxide KO2 ~> Superoxide BaQ2 > Peroxide Answer (2) Hint : Lime water is the clear aqueous solution of slaked lime. Sol.: Suspension of slaked lime in water is known as milk of ime. Answer (1) Hint : Density generally increases down the group. Sol.: Metal Density (g em) ui 0.53 Na 0.97 K 0.86 Rb 1.53 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 CUI eed 65. Answer (2) Hint: Higher the polarising power of cation, more will be covalent character. Sol.: Bel. is covalent and polymeric in nature as itis electron deficient. ‘Answer (2) Hint: Higher the hydration enthalpy, higher will be solubility in water, Sol.: MgSO. has higher hydration energy, soithas higher solubility. Down the groups, solubility of alkaline earth metal sulphates decrease. 66. 67. ‘Answer (2) Hint: Mik of lime reacts with chlorine to form hypochlorite. Sol. Ca{OH)p +2Cly > CaCly +Ca(OCI), + 2H,0 powder”? ‘Answer (4) 68. Hint : All alkali metals and few alkaline earth metals gives characteristic colour, to oxidising flame, Sol. Metal | Colour of flame Li Crimson red Na Yellow Ba Apple green Mg No colour Answer (3) 69, Hint: Sodium in iquid ammonia gives ammoniated electrons. Sol.: When sodium is dissolved in liquid ammonia, ammoniated electrons are produced which are responsible for blue colour solution, conductivity and selective reducing agent. + In concentrated solution, it diamagnetic. Answer (3) Hint: A brine solution is electrolysed using a mercury cathode and carbon anode. Sol.: Electrolysis of brine solution in Castner Kellner cell produces NaOH. becomes 70. Cathode : Na* +e"! 5Na (amalgam) 2.Na (amalgam) + 2H:0 —> 2NaOH + 2Hg + He n 72 73, 74, 7. 76, 7 (Code-B)_(Hints & Solutions) 1 Anode: Cr > Ac, +e~ zee Answer (1) Hint: Be and Al resembles in properties due to diagonal relation, Sol.: Due to high ionisation energy of beryllium, a large amount of energy requires for excitation of the electrons. ‘Answer (2) Hint: Solvay process is used to manufacture sodium carbonate Sol.: In Solvay's process, steps involved. + 2NHs + HzO + CO2 > (NHs)COs + (NH4)2COs + Hs + COz—> 2NHsHCOs + NHsHCOs + NaCl > NaHCOs + NHiCI + 2NaHCO3 —*-> NaxCO3 + H0 + CO» Answer (2) Hint: Thermal stability increases with increase in cationic size. Sol.: Thermal stability: MgCO3 < CaCOa < SrCO3 A>B Since Ep of Cis maximum, ithas more oxidising power. Answer (2) Hint: The oxidation number of sulphur in SO2 is +4 Sol.: [eee 6 — so,cl, Oxidation number of sulphur changes from +4 to +6. “4 SO, + Cl, Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 78. 79, 80. at 82. Cie) ‘Answer (3) Hint: Metal displaced by another metal from its ‘compound reaction. Sol.: Zn displaced copper from copper sulphate. So it is metal displacement reaction. ‘Answer (4) Hint: Change in oxidation number per atom provides number of electrons involved. is known as metal displacement sols Toy +8631 Answer (3) Hint: H:02 will be oxidised in the reaction in which itis acting as reducing agent. Sol. |, +H,0,+20H — 2f +2H,0+02 io (01 4 1) 0) 0 H,0, + Ag,O —> Ag+ H,0 + 0, Reducing agent) s ‘Answer (4) Hint: Oxidation number of carbonyl group is Zero. Sol. Compound Oxidation state of Fe Fe:0s +3 KalFe(CN)el 42 FeSO.(NHs):SO«-6H20 42 Fe(CO)s 0 Answer (3) Hint: Element undergoing oxidation is reducing agent. Sol. Eo. ON 3+ 3N2 14H + C107 + 3Ni > 2Cr3* 4 3Ni?* + 7H, Oxiding Reducing ‘agent agent ‘Answer (3) Hint: n-factors for MnO. and + are 5 and 1 respectively. CUT 023, Sol.: Balanced chemical reaction is 2MnOj +101 + 16H* > 2Mn?* = Sly = BHO 83, Answer (4) Hint: Disproportionation reactions are those in which the atom of same element oxidizes as well as reduces. 2 ° Sol.: (1) 2XeF +2H,0 — 2Xe + 4HF +0, “4 os (2) 6XeF, +12H,0 + 4Xe +2Xe0g +24HF +302 ° 3 “ (3) P, + 3NaOQH+3H,0 > PHy + 3NaH,PO. “1 20 (4) 2H,0, » 2H,0 + O, 84, Answer (2) Hint: Sum of all the oxidation state of elements in an ion is equal to charge on ion. Sol Ton Oxidation state ae 6 »* “6 W. 7 7 a 85: Answer (4) Hint: 2FeC,04 + 61,03 14H? > Fe + 2Cr°* + 4CO, +7H,0 Sol.: «» 2 moles FeC20s requires 1 mol Cr,03- 1 mol FeCsO+ requires % mol Cr,0%- SECTIONS 86, Answer (4) Hint & Sol: Nature of oxide COz_| Acidic InOs | Basic co | Neutral PbO2 | Amphoteric Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 CUI eed 87. Answer (3) Hint: AIC dimerises to AlbCls to acquire stability, Sol. + INAICl molecule octet is incomplete. + Itdimerises to complete its octet. + There is no second period element present in AICls, so no back bonding. + AbCls has two 3c-4e- bonds. 88. Answer (3) Hint: (BN). is known as inorganic graphite. Sol.: Boron nitride has hexagonal layer type structure which is similar to graphite. 89. Answer (3) Hint: Catenation power decreases with increase in atomic size. Sol.: Increasing order of catenation Ge 2NaOH + 443803 + Two boron atoms in borax are sp? hybridised while other two are sp? hybridised 93, 94, 965, 96. 97. 98, 99, foe ‘Answer (3) Hint: Cyclic silicates shared two oxygen atom per tetrahedral unit. Sol.: Out of four oxygen atom, two oxygen atom of silicate unit are shared in cyclic silicate. Answer (1) Hint: The compound in which central atom has vacant orbital will undergo hydrolysis easily. Sol.: In CC, carbon does not have vacant orbital hence does not hydrolyse in aqueous medium. ‘Answer (2) Hint: Compounds showing back bonding has higher bond strength and lesser bond length. Sol.: Due to back bonding in BF2, B-F bond strength increases and bond length decreases. ‘Answer (4) Hint: Compound having vacant orbital act as Lewis acid Sol.: In BF octet of boron is complete, hence cannot act as Lewis acid, while BaHe, AICls and BeF2 have vacant orbital so behave as Lewis acid Answer (1) Hint: Concentrated HzSOx is a dehydrating agent one. HoOOH See Sol >» CO+H,0 Answer (4) Hint: Orthoboric acid is a Lewis acid Sol + HsB0s is a weak monobasic acid HBO, +H,0 > B(OH), + Hybridisation of boron in HsBOs is sp? ‘Answer (2) Hint: H2O2 has open book like structure Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 101 102. 103. 104. 108. 108, 107. (Hints & Solutions) Ue Sol: 4100. Answer (3) Hint: Permanent hardness is due to chlorides and sulphates of Ca and Mig Sol: + Boiling of hard water and Clark’s method can be used to remove temporary hardness of water. + Ion exchange, synthetic resin and treatment with sodium carbonate methods are used to - remove permanent hardness of water. H02's polar and non-planar compound [BOTANY] SECTION-A Sol: Biyophytes have main plant body as Answer (2)

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