901-: 3; - 5 4< 58: ; 6; = # ; 2 56 70 - 8- , / 012 - 34

4 -: > +?

./ 0 0 1, 2 3 4 - * * +, = ; @ AB 4 C 2
./ 0 0 1, 2 3 4 - 5 3 5 * +, = < 5
*
99

./ 0 0 1, 2 3 4 - 3 :D 6: ;:E F
./ / 4 63 7 1, 8 9/ 4 : 2 3 4 - * 56: ;:E
52

./ 0 0 1, 2 3 4 - * * +, 56-: E = ,:E
2

H
/< =7-' A 7 3 - B C > ? * =; 3 /< = 7 - / * >8 0 * 5 ? *< 7 @ 3
DOI: 10.22034/jmeut.2022.47924.2979 - ) * +,-. – 182-173 "#$ 1401

A 5 ? 5 0 3 /< = G > @H A> C ? > = /< = 5 C 8 7 - D - E = / > /F

M > 45 5 @ 3 *7 3 J IK> L ,9 0 D / A * >* 5 ?*= . 3 5 @ 3 ' A 7 I= F
/ > /< = 7 - *7 3 J *7 3 C / 4 , I= F A * . 3 5 - N * 4, O 3* C * >
S : 3 T U 6000 * 5 ? * = R> S . 3 >, *= ? P 1 > Q D> > - D
T U 5/07 *7 3 J Y? P *< ZF [ \ . 3 /< = 7 - M 3 > G - U 55 /F 7 - M 3 > G - U 438 0 D *7 3 C
. 3 - * =A ^_3 0 D > ` > *< 0- a K A , > > J /< = G - U = * 7 > M 3
.0 3 A /< = *7 3 C L ,9 0 D *< :5 * 5 , 8;-

Simulation, analysis and optimization of a non-emission process producing power,

hydrogen gas and liquid hydrogen using solar energy and PEM electrolysis

A. Nourbakhsh Saad Abad Department of Mechanical Engineering, Tabriz University , Tabriz, Iran

M. Nami Khalilehdeh Department of Mechanical Engineering, Tabriz University , Tabriz, Iran

S. F. Rangbar Department of Mechanical Engineering, Tabriz University , Tabriz, Iran

S. Faramarzi Department of Mechanical Engineering, West Tehran Branch, Islamic Azad University,
Tehran, Iran

F. Firouzy Department of Mechanical Engineering, Tabriz University, Tabriz, Iran

Abstract
Method of power and hydrogen gas production by solar energy and water electrolysis has received attention in recent years, because
hydrogen and oxygen gases are separated from water without any pollution, the mentioned method has net-zero carbon emissions,
known as green hydrogen. In this study, solar cells are used to supply power for the proton exchange membrane (PEM) electrolysis
and the liquefaction sections. Bandar Abbas city is selected for the proposed process. The novelties of this study are based on two
points, first proposing an integrated process of solar power generation and separation and liquefaction of hydrogen gas without
pollution and with higher efficiency compared to other similar cycles. The capacity of solar arrays is 6,000 kW, while the production
capacity of the electrolysis section is 438 kg/h of oxygen gas and 55 kg/h of hydrogen gas. The specific energy consumption (SEC)
of the liquefaction cycle is 5.07 kWh/kg. The highest rate of exergy destruction goes to the electrolysis section, followed by heat
exchangers as the second rank.
Keywords: Sustainable energy, Proton exchange membrane, Hydrogen separation, Cryogenic process, Green process.

* =; 3 @H A> C ? >* / M > /< = J -1

* (- 3 > C > 3 - B C > ? ( + *< 7 @ 3 *< * =' 7
> /< = 0= 0 3 O 3 A > ` > * , /< = 6c> . 3 bU K * =O 3 / A * > * 5 ?
+ I= ? = ;3 ' A 7 @3 d e f@: g= > C > .[1] > @U K J H
* \ B N 7 0D * 5 ? *< 7 @ 3 > /< = UgC 7 bU K * = * KU- * =7 - I= G 0 7
k .[2] 3 5 /< = * =' 1 > > B h> B * > * 5 ? *< 0D 7 @ 3 /< =
*
s.ranjbar@tabrizu.ac.ir :
00/06/23 : !
00/09/22 :' ( !
A Y? P K / , v . > H 28 ? P 5 O Q > /< = 0 3 /< = ? 5 > /< =
h H 37 w : 3 5 *< 0- a K A I > = M g+ 5 /< = T H A >

D / >
7 @ 3 [8]/ g= 3 . > O 3 h 7 *< 0- a K *= - G 0 3 /< = @H A> C ?
I= * > > (C ?P 2 >a * 5 ? *< -JgC * = O 3 7 5 > A> C ? * /< =

= -
A ?P. 3 > /< = *7 3 J Y? P * - > /< = * ; \e 5 @ 3 A> *

/<
N cn A I 3I * = : ; \e * 5 ? *< 7 @ 3 > C > I= F A . 5
*< 7 @ 3 [9], [10]/ g= h . > 5 - /< = ' A k 3 0 3 /< = m 7 *

@ 3 > / *7 3 J
3 > /< = / * > - A 7 * 5 ? .[3] 3
. n 5 U * = ? 3 7 @ 3 > /< =
* 0D m 1 > Q L ,9 0 D > /< = G > 5 > A> * JgC * =O 3 > 04+

... *< 7
: r ( U3 YC 80 20) A * * * = x 0 04+ o6H [ nc U> B ' A 0 5 ? 5
D > / C 1P U> B O * z ; y5 U> B 2P * JgC * = ? P > /< = g B * =O 3 / g
/< = H 99/99 { U? > (J> 3 > _ 2) ? 3 * = 0= D gM ' A 3 A>
.[11] 3 J 3 = !3 ( H 90 80) D > /F >D> > A> * JgC * = * 1 gc
7 / A * > * 5 ? *< 7 [12]/ g= | c> > = K * JgC h> B A> O P = * Q ' A
*= y y } . @3 L ,9 0 D 2 - I 0 C ? A> H ?P I= > ; 3 P 7
4 * 4 , Y? P . 5 3 >O 3 UgM > bU K *7 3 C * > K> / o6H O 3 7 @ 3 .[4] >
7 0 [13] G D . > H 41/25 *< 0- = 7 > * ;: /< = ' A ; / 7 - 7 /< =
0D 7 @ 3 > 8 7 /< = * > * 5 ? *< O 3/ 0 > D > A> C ?' A 3 p:
1/25 L ,9 0 D S @3 L ,9 7 d e > * -7 3 U> B A> * JgC
. > M3 G - U 7- > 7> K> / o6H O 3 7 [5]/ g= q
5 3 > * > * = I= F /< = * >8 0 O 3 . 5 @ 3 /< = *7 3 J * >J c r
( + J> 7 / A * = : > / a 3 I 3O 3 < I 3I Y? P 7 4 * 4 ,
C O 3 M p 7 /< = *7 3 J A |g= IK> T U 146760 . 5 @ 3 < = / > A
[14] / g= * . 5 3 > 0 I= F A > > G - U 98331 *7 3 J * > I 3 * = : *7 3 ,
A> * J /< = > * / h * >* ?P . 5 @ 3 J /< = M 3
h 5 > O 3 7 v h 5 * 4 , Y? P . 4, 7 - *7 3 ?s ; Q ' A 4> A > C >
/< = *7 3 C 0 D / * =O 3 a3 *7 3 J O 3 8 K 3 / *7 3 J /< =
-* *7 3 J * > >(C I 3 Y? P 8 7 /F /< = * =O 3 Z hg * > g=
J Y? P /F ?3 >/ Z : A> :) /< = *7 3 J A >* > C > .[6] 3
> G - U 3/3 S * * 4 , Y? P . > /< = *7 3 I * =O 3 \ / ( U3 YC 250 @
= 7>. > * A> } > G - U 10 J /< = } 7 /< = 7 - *7 3 J A * 4 I 3 I 3
+ > 3/359 / *< ZF [ \ H 95 ? P *< 0- > g= *7 3 J Y? P I 0 *7 3 4> >
;x > A ?P ? P 7 @ 3 [15] / g= * > * 5 ? *< ( + J 7 @3 >R>A .
7 . 3 > /< = / / 0g= * > L ,9 O 3 *7 3 , IK> * = 3 _g 8 0D O 3
A ?P. 5 @3 A Y? P R123 * ; 3 B cn O 3 M p 7 /< = *7 3 J
8 A g 5I * > 0D 7 / G+ Tc n . 5 = ? 3 > I= F A -
* > / * 5 - de * > * =O 3 * 5 ? *< 7 @ 3 n> 5(- 5
> I k 7 ^ * /< = . 3 0D /< = * >8 0 * =' m /< =
8 T : / 0D . 5 O= d e > de . 5 /< = *7 3 J
7 @ 3 UH > 7 . h /F /< = > / A * > - A 7 * 5 ? *< 7 @3
N > * 5 ? R > 7 @ 3 > /< = * > 0D C 5(- * = ; 3 /< = *= : \
/ * > /< = h 5 > 5 ? ( + *< / h ( + O 3 2 [7] > . 3 >
A 6c> 3 * 5 ? R > ; Q *7 3 ?s / g ( *< * =O 3 >/ O 32 G9 > - P
.[16] 3 7 d e > -7 3 6 *= A Y? P 7 @ 3 > -A 7 * 5 ?
4, < = *7 3 J Y? P [17], [18]/ g= *7 * - ;Q * > = ' - O 3 2 7 5 3 > * 5 ?
7 . >A I 3 I 3 I YU: h 5 *< 0- = 7 > 5 @ 3 = > *= ; < 7 , >

174
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. 3 5 @3 N he * 5 ?R > O 3 8K > *= h 7 @3 . 5 @3
> c3 IK>

Q: 4< 4 P * )0 D O;- -2-2 0 A > *= /< = * > a3 : TD c

1
5 > h\ O 3 7 T 1 6 S >/ A * > /< = 7 - * > a3 : c 5A + 5 3 >
* 5 ? * =h h 5 3 5 @ 3 * 5 ?*= / C* > 5 o6H A > -8 -2 > A * = ~?
* 4

T \K, . 3 8 OQ R>/ C h *= : IK> . 3 > / > -q x *=

*< F [ \ 5 *< 0- a K A , > I 3 I
U U?

* 5 ƒ T M6r Y > * 5 ? R > :

2 m 7 ;< 0= > . 3 5 : r [14]/ g= /< = G - U = * 7 > M 3 T U 8/85 ? P h
x3

7. 5 B 11 b 1819 U3; G U= / • * = € 7 A I 3 IK> . > J

. 3 5 - N @H 3 = * - 4C 28 2 = 7 Q , /< * = € 7 I 3 I IK> /< =
+ 7

9/83 5 ;\ / C 39/7 47 > < * = . 5 @ 3 = A> =

/ 3

15/28 4 U3 YC 45 „ : . = _ * 5 ? R > 7 @ 3 > J /< = I= F A *

. 3 H *< h N > - D -E=/ > M > 45
*7

. 3 ; Q *7 3 ?s * > J /< = 7 - > * 5 ? R >

8 0 * > * 5 ? *< / 7 * 4 , Y? P
=

@ 3 /< = *7 3 J : *7 3 , IK> / A
*7

5 A> C ? -E=* 4, + 3 5
* D> *7 3 J Y? P . 3 7 d e > -7 3 6
@3 / h 5(- * 4 , * = 1 >
*=A c ) 5 o6H P > € O 37
* 5 ? *= 7 . 3 ( > , Y? P > ,> -
8 *7 3 C * > L ,9 0 D 7 R>A * >
he / M > x M > 45 . 3 5 @ 3 /< = 7 -
J ? P . 3 5 8K * 4 , * C * > a3
2 0= > /< = *7 3 J * > € *7 3
. 5 @3 * 5 ? R> * > U3 ;
5 3 > ; 3 bU K * = = UgM ‚ A |g=
. 3

,C- - D -2
@3 N = 4 M<:H K LB+ -1-2
O 3 7 : 5> O 3 7 3 h 5 3 >
7 * 5 ? * =; U3 d3 R > > 5 ? Z h
*7 3 J O 3 7 L ,9 m 7 8 0 D O 3
€ A I 3 I O 3 > 04+ /< =
* M g+ . 3 5 /, c n Y? P : r 1 h 5
R > 5 ? 7 @ 3 > * 5 ? * =; U3 7
R> 5 >/ 7 * Q 5 h IK> >* R>
.5= + D *: 02:E ;4O:R -1 ) 0D : 7 / 1 Q 5 hQ * 3 3
/< = 0 8 0D : . A
. ; 3 2000 , U3 YC 80*
J : d3 5 hQ ?s /0K > /< =
/ , M > 45 . 5 *7 3 J /< = *7 3
1
Grid-connected PV ASPEN HYSYS * = 0 G 7 6c> . 3 o r A * C he
2
Array tilt angle
3
Array azimuth angle 5 @ 3 /< = *7 3 J Y? P *7 3 5 * > MATLAB
4
Open-circuit voltage (VOC)
5
Short circuit current (ISC)

175
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*= > *7 3 , U: 3 4 I 3 IK> 7 /F /< = *7 3 C * > L ,9 m 0 D 7

D / >
* =' 3 > 7 ^ … Qe A . 5 G + 3/1 2/7 2/3 : . 5 @3 OQ R>/ C 7 @3 >* 8
: c 7 ~ ? /< = / C d? *7 3; * > bU K

= -
A 3 v Y > I= F A L ,9 0
7- € * =/ C * > 5 o6H A > -8 -2 > 0D S . 3 5 - N [19]/ g=

/<
' . 3 5 @3 / > -q : c 7 c r U3 YC 80 * > /< = 7 - M 3 > G - U 55/23
. 3 [20] / g= *7 > @3

@ 3 > / *7 3 J
^ 50 >8 E1 / C 2 h 5 …> n . 3
. 5 † ?0 7 3 /< = E6 / C *7 3 C 7
; 4 ; 8- , )0 D -5-2 8 /F h 5 3 E5 0 7 1 C ?/ C
> /< = 7 - ٪25 h 5 3 , /< = = 1 ?s /7 K g3 > C ? /F 3

... *< 7
?3/ > 3 3 T H > / ٪75 T H . 5 0 > 8 :
( ) 3 > /< = c . 5 @- O= gc
K1 > :2 3 ?3 / P 1 >/ * > 8- , 56 70 O;- -4-2
* . 3 > * D > *< 7 3 IK> I 3 I IK> h 5 /< = *7 3 J :
. 3 5 ?3 7 4 ; c : @- / A > x I 3I : . 3 (A I 3) 4
. 3 5 I g : I 3h 5 r 52 C PZ 2 h 5* ?P
Q 3 7 - > ( ) 3 7 /< = - - /< = 7 - * I= Y@ S 3 _g =
- J /< = 7 ,K> / 5 K> ‡M > - A I 3 IK> . U3 YC 190 @ *
* 7 >/ 7 3 > A gc : . 5 …> n 3 / • /< = G U= h 5 * 1 €
A M3/ n 5 ; gM > 5 A [H d = 3 _g - * =A 7 * M g+ 2 h 5
=; * - > h 5 d 5 A . > D> h I4C 2 r 5 2 - *= h =
h = A _3 4C y U> B 3 0 * 5 3 I /< = * 5 - > C
Z h 3 7 I= F A .[21] > /< = . = I= 3 U3 YC 251 @ *7 3 J *
H ; * > h 3 5 @3 > JC > 4 I 3 I 3 I IK> €
4 ;x H 74 G ;x H 47 -I 3 Y? P , „ : . 5 8 K [17]
. > I 0 H 99/99 ; 3 U 330 / , hB : ; 3 U 4200 I 3
; 3 U 1505 , „ : 4 I 3 IK> 3
IK> , I0 . 3 ; 3 U 101 , A O

176
'
> c3 IK>
* 4
U U?
x3
+ 7
/ 3
*7
=
*7

.* 5 ? *< 0D 7 @3 >J /< = * 4, ? PG - -2 h 5

3/119 101 80 0/015 E6(H2)

1/17 101 23/44 0/234 MR5.0
174/53 4200 20 0/596 MR11
84/33 101 80 0/032 E4(H2O)
56/48 2000 26/85 0/015 .[22]; - 4 ; X3 O = 8- , V4 34 A0; 2 -3 )
E9
177/19 130 -251 0/015 LH2 K U:E -6-2
.[23] 3 0 P , C h *< T y •
D W; A -7-2 T U 30 -*= , •
*7 3 5 v Q Y > p : I= F M I+ 3 .[5] 3 5 - N T U 50 =
h 5 [25] / g= * > + v > 0D IK> YC 8 1 1I1 nQ 0 * hB : •
bU K Q ,9 h 4 h 5 3 5 G+ 4 - N -*= U3
/ , p : I= F [25] / g= * * > / C 1P .[5] 3 5
*7 3 5 a3 B Z = /, v Q . 3 5 80 = 3 _g 2 > = 7 > [24]/ g= A Y >
IK> *7 3 5 ' + 3 M . 3 I= F A 0D N H 80 =ˆg H 85 = d A> H
* 4 , ? P T \K, Q > p: /< = *7 3 J . 5 -
; C . 3 5 G + 3E 2U> 5 d3 5 ƒ 2
> ? P *7 3 5 v Q +3 M v 2 . @3 N = 4 02:E 5 , 0: K LB+ -1 V-
. 3 5 [26]JC p : I= F ' 7 @ 3 , > / CG
*< 0-
U ) * C ) G-U )
(T U )
(; 3 ( U3 ( } >

29/06 101 80 0/1218 E2(O2)

2
PRICO ®
3 1
Black & Veatch Pinch point

177
 A > 7 *< 0- * ( ,- > Y 3 e 4C ? Yn>
/ C *< 0- Ex i Ex o / - B @3

D / >
/ C *< 0- Ex Qo Ex Q i =* C ?

= -
* 5 G+ * e W sh C ? * * -;Q

/<
. 5> A > 7 *< 0- * ( ,- > I d3

@ 3 > / *7 3 J
4 -: > +? 901-: 3; -9-2
A>OQ R >/ C7 @3 >8 0
I . 5 C O= 7 L ,9 2 d3 5 G+
- 5- 40 * [0 0 J = :U O A,-. X"$ -4 )
: 5 G + 7 n> … r

... *< 7
. 4 -: > +? 901-: 3; 5;: [25] ; ,
1
H 2 O ( liquid ) + E electrical → H 2 ( g ) + O2 ( g ) (5)
2
- A,-. \0; = = # ; 56 70 C- [0 D W; -2 V-
n> . 3 0 D 7 *< E electrical .4 0: 5 <:H K LB+ D " = [26]7 :
:[1] 3 5 7 0D * > ^ - *<
∆ G = ∆H − T ∆ S (6 ) p : I= F [26] JC ? P T \K,

Y >. = [6 ? ∆S _ [6 ? ∆H
N 0D IK> I= F A T 6 [1]/ g= 3 3 0 * hB :
* /F / C /< = / C ‚ . 3 , - YC ) -
:[30] 3 > 7 n> 7 L ,9 0 D ( U3

J 0/280 0/281 T U ) *< F [ \

N& H 2 , out = = N& H 2O , reacted (7) (J 7 - G - U > M 3
2F
J
N& O2 , out = (8) 58 9/; - 58: ; ) " -8-2
4F
2 3 * =h Ue m 7 *< h Ue
n> … r 0D < . 3 / C 1P J * >} F
7 5 3 > g T H > *7 3 J *< [ \
. 3 > 7 1
*< F [ \ =~? 5 a B / > 4> N
E el = EX = JV (9)
el G-U 2 * 7 > *7 3 J Y? P \ > > >
V =V 0 +V act,c +V act,a +V ohm (10) G+ c n h *< 0- h Ue . 3 J /< =
*< 0- ; Q 7 / N [ H > =/ C *< 0- 3 5
V0 0 D > * *< 0- E el * *< E el
3
:[27] 5 - N 7T H >h , C
> 3 n> 7 @3 > c h
Ex = Ex ph
+ Ex ch (1 )
*7 3 ; c Y p h V act,c . 3 > [30]/ g=
Ex ph
= h − h0 −T (S − S 0 ) (2 )
. 3 g= h V ohm *7 3 ; c Y p h V act,a
Ex ch =  x Ex ch + RT  x ln x (3 )
mixture i i 0 j j
i j
[0 -3 N [H h> B c n I= F * g 5 *< 0-
5 4< 5 , 0; 2 -1-3 g5I > *= h 0D 7
*= de * 5 ? I> A 1 Q 5h 5 Q 3 n> 7 @ 3 > =/ C g 5 *< 0- . C
O 3 Q3 * > N 45) M > 45 ; 3 bU K . 5 3e [28] 8 5 ƒ 3 *< 0-
Q A I > ,4 . 5 I g (* 4 , … r T 0 4+ *< 0- 7 Y c 7 @ 3 > *< 0- a K
: 3 5 = , I> Q A O s I> :[28], [29] 5 3 e 7 n>
R@ * A O d e * A I>
Ex i + Ex Qi = Ex o + Ex Qo +W sh + I (4 )
. 3

2
Faraday constant
3 1
Nernst equation Specific energy consumption (SEC)

178
 . 56 D 4 -: > +? 901-: 3; K LB+ -3 V-
_04 A ]3 ^

Q 0D \K,

; 3 U 101 ‫ﻓﺷﺎﺭ ﺟﺭﻳﺎﻥ ﺍﮐﺳﻳژﻥ ﺗﻭﻟﻳﺩی ﺩﺭ‬

‫ﺍﻟﮑﺗﺭﻭﻻﻳﺯﺭ‬
M

* /< = / C ,
; 3 U 101
0D

76( kJ/mol ) ( E act,a ) *7 3; c *<

18( kJ/mol ) ( E act,c ) *7 3; c *<

`+ ;=

100 ‫ﺿﺧﺎﻣﺕ ﻏﺷﺎء‬

4 \0; a #N3) 90:D

2
: )V 5, =f " 5 =- 4< A \ ` -3 )
170000( A/m ) J aref
.(g DW
460000( A/m 2 ) J cref
96486 ( C/mol ) (F ) * >}
*< Q > 3 > >* 5 ? *= UgM ‚
- JC : O 3 * *< > O 37 C ?
; )0 E =

- * 5 ? *= UgM ‚ 6 h 5 .
56 70 <:H 58 9/; - 58: ; 9 3 2 -3-3
* UgM ‚ A 4> . 5 / , ; 3 bU K * =
(=4+ cdO 3

8- , . R@ s
= 7>. 3 5 / , T 0 4+ *< 0- = 7 > 7 h 5
/ C * = g 9 8 h 5 . 3 H 42 h *< 0-
* hB : Q - Z * > G- 3
. 5 I g U3 YC 1 U3 YC 3/4 0
1 0 * hB : 3 ~K, 9 8 h 5 7 n g=
2 0 1 >G- 3 *= g U3 YC
5 -Z *< 0- a K I= aC =
; Šn3 > 7 7 3 * ‰ 0> Z > † :
Z ? 3 , > Y 0= / Y+ * I>* -
0 * hB : Y 4> Q A A > > 3 -
5;: V 5, =5 4< 5 , 0; 2 =: W h: -6 )
} 7 3 g= 0ƒ : > - *= : r
.A,-. \0; = = # ; = 4 i
? 3 Y 0= = *< 0- a K Q >OQ
Q [32]/ g= 5 > [24]/ g= A . =/
2 - *= * > 0 * hB : Y 4> 4 -: > +? 901-: 3; -2-3
5 c U3 YC 1 hB : /< = *7 3 J Y? P I= F A @3 L ,9 0 D T \K,
N U3 YC 1 Q hB : 0 I= F A 3 A @3 0D : r. 3 5 3; C
. 3 5 - 3 5 G + [19]/ g= A 3 > I= F
0D m > C > . 3 C J> A I > T \K,
? 3) [31] 1 3 * = =[ m 7 I= F A
L ,9 * = 0 D 7 3 = =[ 3
3 100 ; c : * 0D h3 = 3 (/< =
h3 39 * 0D 3 NL/h 20 ‚ J>
* > A |g= 3 /< = M 3 > G - U 54 S >
Q A ,> 2/2 h3 = < A , > 0 D h3 =
*7 3 ; c *< 100 L ,9 Kp > 207 * ,
. 3 ; > ; < U 18 76 a >
. 8- , 56 70 O;- K;9 58 9/; ,=6 -4 )

1
Fraunhofer Institute for Solar Energy Systems ISE

179
 > - *= T \K, 4 ; C
h UgM a p . 3 5 / , /< = *7 3J Y? P

D / >
. 3 H 65 O 3

= -
.56 70 O;- 0 :/ 5 , * 3= D K LB+ -4 V-

/<
LMTD 5 hQ * - * hB : A G
YC ) (T U ) YC ) 0 -

@ 3 > / *7 3 J
( U3 ( U3

17/3 73118 1 HexM1

5/3 2651 2/2 HexC1.0

.k B 5 , ` = = 58 9/; ]0:B $ = -10 )

... *< 7
1/4 21609 1/1 HexC11

6/2 1393 3/9 HexC2.0

O 3 * > *< 0- † ? / C 11 h 5
1/3 19588 1 HexC21
*= IK> * / . 3 5 /, c n
5/9 1687 2/4 HexC3.0
. 3 5 - N * *< 0- / M > * 5 ?
1/5 14301 1/2 HexC31

6/5 367 3/3 HexC4.0

5/6 10157 3/2 HexC4.1

.5= + i 6; -:< - 5=- - 58 9/; 0: ;=4 -11 )

A0 : A O;- 0 :/ \* 3= D j:/ - =: D *: ;=4 -8 )

,C- :`0= 5= + i 0 J -4-3 .g4 M =3 0=9 5 = )^; O
I= F A 3 > Y? P T \K, 5 ; C
. 3 5 Q [30]/ g= [5]/ g= q >
< I 3 I O 3 7 [5]/ g= q
7 @ 3 . 5 @ 3 /< = 7 - > / > I 3 O 3
IK> I 3 7 ,K> A * > J c r 7- > 7> O 3
q * 4 , Y? P S. 5 @3 < I 3I
YC -251 * > J /< = 7 A 300 [5] / g=
*7 3 J ? P . > ; 3 U 130 , U3
/ > 5/07 *< ZF [ \ * p : I= F @3
> 5 A * 5 ? *= d3 / 7
7 * 4> UgM 11/05 Q > [5]/ g= q A0 : A O;- 0 :/ \* 3= D j:/ - =: D *: ;=4 -9 )
.g4 M =1 0=9 5 = )^; O
I= aC 3 5 @3 € 7 p : I= F
* 4 , Y? P . 5 -*= *< 0- a K
1 > bU K * = 1 3 *< 0- a K H 10 h 5
/ : h 5 * * [30]/ g=
0D 3 ~K, 10 h 5 7 n g= . 5 Q
7- > /< = *7 3 J Y? P B > 0D
-*= : *< 0- a K A , >
A : Z 5 / 7 3 > / ; \e /< =
. O 3 h *< 0- a K D > O43 0 =
> C ? /< = p : I= F : . 3 5 @3

180
 7 A 1/29 S * *7 3 J : • * 5 ? *= : 5 / 7 3 J T H
_04 A ]3 ^

0 * hB : . 3 5/07 *< F [ \ . 3 5 @3
1 Z7 > - * =A I1 nQ
IK> . 3 5 - N U3 YC 3 - :U O A,-. = = # ; = 4 D *: i =: W -3 V-
A I> * - * =A *7 3 J
M

. [30] ; ,- - [5] ; ,-l 05 , *

h : > *< 0- a K [30] [5] p : I= F O 3 T \K,
a K A I>0 : * 4,
0D / o6H 0D *7 3 C O 3
. *< 0- 1
L ,9 K> L ,9 /< =
`+ ;=

A ?P R >Y 5 *= R >A '

,= -5
4 \0; a #N3) 90:D

*3 3 * 5 ? O 3 \
U1 Oƒ6M
(kW) *< 0- Ex J IK> /< = € IK> € m
*7 3 *7 3 J
(kW) g 5 *< 0- Ex ch
; )0 E =

ph *< ZF [ \
(kW) 0 *7 0- Ex J IK>
11/05 5/07 *7 3 J IK>
*7 3
I
(=4+ cdO 3

(kW) *< 0- a K /< =

(J /mol) ^ - 7 *< G
5 7 -4
(kJ/kg) _ H
* > 0D * 5 ? *< 7 @ 3 I= F A
(K) T „ . 3 5 3 > - D - E = / > /< =
(kJ/kg K) S \ / 5(- 5 ƒ /< = *7 3 J * = ? P
> - D * 5 A = 7 /< = 7 -
(kW) -;Q 7 5 *< 0- Ex Qi
O 3 > /< = *7 3 J Y? P 2 a > Q A
(kW) * e W sh 3 5 4, * m g+ 0 3 /< =
N& H 2 ,out U3 YC 251 @ * J /< = / C ?
(mol/s) /< =/ C >
7 † ? 7 / A > *7 3 ; 3 U 101 ,
(mol/s) 8 / C > N& H 2O ,reacted
A * 5 ? *= : 7 / 7 / O 3
(A/m 2 ) ‫ﭼﮕﺎﻟﯽ ﺟﺭﻳﺎﻥ‬ J @H I= F A * 4, A> C ? 6c> 5
(C/mol) ‫ﺛﺎﺑﺕ ﻓﺎﺭﺍﺩی‬ F * 5 ? *< a3 A / h > M > 45 . 3
A |g= /< = *7 3 C * > 7 8 A |g=
(mol/s) /F / C > N& O 2 ,out
* 4, * C * > 7 * =8 > 3 3
(kW) 0 D \ *< E el
. 3 5 4, 3 >
(v) 0 D < V 121 7 - S > L ,9 0 D 7 •
80 * /< = 7 - G - 15 /F 7-G -
7 ;: -6 * > ; 3 U 101 , U3 YC
0D . 3 5 @ 3 8 *7 3 C
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