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Crop Protection
Face-to-Face Performance
• Providing guidance on the functionality, selection and optimal use of Evonik's products
• Developing guideline formulations
• Offering solutions based on a novel package of products and expertise
• Innovative developments for future challenges
• Utilizing our wide network of contacts to Evonik internal and external agricultural experts
• Creating long-term relationships based on trust
2
Evonik Agriculture
Network
www.evonik.com/break-thru
2 Face-to-Face Performance
BREAK-THRU®, SURFYNOL®
and TOMADOL® product groups
6 Spreaders and Penetrants
10 Oil Enhancers
12 Antifoams
14 Dispersing Agents
16 Emulsifiers
3
VIDEO DEMONSTRATING THE ABILITY OF OUR TRISILOXANE SUPER-
SPREADERS TO WET PLANTS AND OTHER HYDROPHOBIC SURFACES.
4
Additives for Crop Protection
SPREADERS AND
PENETRANTS
BREAK-THRU®
Both BREAK-THRU® Spreaders and cuticular penetration and in some cases products improve the deposition and
Penetrants decrease the surface tension stomatal flooding. As a consequence retention of the agrochemical sprays
of pesticide formulations and thereby these surfactants help reduce the spray and facilitate the uptake of the
reduce the tendency of spray droplets to volume required for a particular pesticide pesticide. At the same time they meet
bounce off plant foliage. This effect application, and they allow for better today´s requirements for product
allows for better deposition and reten- targeting and increased pesticide uptake. safety, environmentally friendliness
tion on plant surfaces and maximizes and convenience of handling.
the performance of agricultural chemi- While organo modified siloxanes are BREAK-THRU® SP products are
cals. The BREAK-THRU® portfolio synonymous with super spreadering, outstanding with reference to their
of Spreaders and Penetrants includes Evonik has designed variants of this low foam tendencies.
siloxane based polyethers and more chemistry to produce similar static
recently biodegradable and solid trisilox- surface tensions, but without appreciable BREAK-THRU® SF stands for Spreader
anes and biobased polyglycerolesters spreading to behave mainly as a pene- manufactured by fermentation.
and sophorolipids. trant. Quick penetration can translate BREAK-THRU® SF 420 is a 100%
into rainfastness with many systemic biobased spreader improving wetting
Owing to their ultra low static surface pesticides as delivery of the pesticide and adhesion of plant protection
tensions, BREAK-THRU® Super Spreaders into the plant has been accelerated and products. In addition it also provides
provide superior spray coverage. They are a later rainfall cannot wash it from the dispersing properties for copper
unique among surfactants in their ability plant’s surface. products. The low foaming product
to impart phenomenal spreading charac- is considered for organic farming.
teristics to formulations. These products BREAK-THRU® SP stands for Sticker
can also be instrumental in enabling Penetrant. The BREAK-THRU® SP
5
Properties of BREAK-THRU® Spreaders and Penetrants
TENSION [mN/m]
STATIC SURFACE
STABLE WITHIN
IN X% WATER
DESCRIPTION
APPLICATION
PROPERTIES
CHEMICAL
pH RANGE
PRODUCT
MODE OF
ACTION
Excellent adhesion and retention,
esp. for aqueous formulations
with a high salt content, excellent
Organo modified Super emulsifying properties in methylated
BREAK-THRU® S 200 Trisiloxane Spreader 6–8 22 (0.1%) seed oils
Please refer to our leaflet Overview of BREAK-THRU®, SURFYNOL® and TOMADOL® products for information
regarding labelling, biobased and/or biodegradable material and OMRI listing status of our products.
1)
Very low dynamic surface tension of 31 mN/m measured at 30 ms
6
SURFYNOL®
SURFYNOL® non foaming surfactants SURFYNOL® 104 series surfactants properties such as surface tension reduc-
are especially noted for their ability to are Gemini functional wetting agents tion, foam control, and stabilization.
lower the dynamic surface tension of synthesized to provide high dynamic
aqueous solutions. They improve the surface activity and therefore accelerated SURFYNOL® 400 surfactant series are
degree of surface coverage and penetra- wetting of hydrophobic surfaces. The wetting agents providing compatibility in
tion of a pesticide. unique chemical structures allow these an array of agricultural chemical applica-
products to provide multifunctional tions.
SURFACE TENSION
DESCRIPTION
APPLICATION
6 b/s (mN/m)
AT 0.1 wt %,
PROPERTIES
CHEMICAL
DYNAMIC
PRODUCT
MODE OF
ACTION
RANGE
Ethoxylated Acetylenic
diol, average degree of
SURFYNOL® 440 ethoxylation 3.8 moles Wetter 4 – 10 35.3 Low foaming wetting agent
Ethoxylated Acetylenic
diol, average degree of
SURFYNOL® 485 ethoxylation 22 – 23 moles Wetter 4 – 10 53 Low foaming wetting agent
Please refer to our leaflet Overview of BREAK-THRU®, SURFYNOL® and TOMADOL® products for information
regarding labelling, biobased and/or biodegradable material and OMRI listing status of our products.
*
Static surface tension (mN/m) 0.5% in water
7
Mode of action:
• Improved spreading
• Improved penetration
• Inhibits crystallization of larger agglomerates
BENEFITS OF BREAK-THRU®
OIL ENHANCERS:
CHEMICAL
PRODUCT DESCRIPTION APPLICATION PROPERTIES
Improved penetration of actives in oil and water based formulations, stable within a pH
BREAK-THRU® Organo modified range of 3–11, spreader esp. for methylated vegetable oils, antidust agent in WDG & for
OE 446 Siloxane seeds treatments
Please refer to our leaflet Overview of BREAK-THRU®, SURFYNOL® and TOMADOL® products for information
regarding labelling, biobased and/or biodegradable material and OMRI listing status of our products.
8
Additives for Crop Protection
OIL ENHANCERS
Many pesticides exhibit limited water and compositions vary globally, the soluble, it can be used in aqueous formu-
solubility, so mineral and vegetable BREAK-THRU® OE comprise a series of lations. BREAK-THRU® OE 446 has been
oils often serve as the carriers to deliver products designed for a broad spectrum found to prevent agglomeration of solid
these actives to plants or pests. of oils and formulation types. These prod- particles and inhibit their crystallization.
BREAK-THRU® Oil Enhancer are unique ucts are suitable for use in EC, EW, SC, It can be also applied in seed treatments
additives designed to improve the perfor- WDG and OD crop protection formula- to reduce abrasion and dust creation.
mance of oil based crop protection tions as well as in crop and mineral oil.
formulations. They work by lowering the
surface tension of oils and solvents, BREAK-THRU® OE 446 is easy to apply
thus enabling faster and more complete and versatile as it is both an oil and water
leaf coverage and penetration into the soluble adjuvant. BREAK-THRU® OE
plant. Added in small amounts, they 446 is particularly suitable for formula-
enhance the efficacy of oil based pesti- tions based on methylated vegetable oils
cides formulations. As oil preferences and some solvents. As it is also water
9
Additives for Crop Protection
ANTIFOAMS
• Highly efficient
• Highly compatible with concentrates
• Minimum influence on shelf life of dilutions
• Suitable for water and oil based formulations
• Benign toxicological profile
In agrochemical formulations, a variaty increases processing times, and leads to taining the efficiency and low dose rates
of surface active chemistries are used as possible loss of product due to overflow. typical of silicone oils. BREAK-THRU®
wetting agents, emulsifiers, dispersants, BREAK-THRU® Antifoams are added AF offers long term stability and superior
compatibilizers and even solvents. Many directly into the agricultural formulation compatibility in both water and oil based
of them tend to generate and stabilize to allow an easy and safe handling of the formulations. Since individual
foam. formulations. formulations contain different active
ingredients, solvents and surfactants,
Foam formation can occur during manu- BREAK-THRU® AF products have a a universal solution to foaming issues
facture and packaging of formulations, benign toxicological profile. These does not exist. BREAK-THRU® anti-
but also during field application. Foam- siloxane products are modified with foam agents are very robust in their per-
ing poses serious problems as it inter- organic groups and are tailor-made to formance and are used in a variety of
feres with efficient filling of containers, overcome incompatibility, while main- applications.
10
Properties of BREAK-THRU® Antifoams
ACTIVE VISCOSITY @
PRODUCT CHEMICAL BASE CONTENT 25 °C [mPas] APPLICATION PROPERTIES
Please refer to our leaflet Overview of BREAK-THRU®, SURFYNOL® and TOMADOL® products for
information regarding labelling, biobased and/or biodegradable material and OMRI listing status of our products.
11
BENEFITS OF BREAK-THRU®
DISPERSING AGENTS:
• Improved stabilization
• Better biological efficacy
• Show good emulsifying properties
• No need for co-wetting agents in
the dispersion process
• Low foaming
• Improved milling efficiency
• Benign toxicological profile
Non-ionic
BREAK-THRU® organically Particularly effective in SC formulations, for sensi-
DA 675 modified polymer low 40% tive active ingredients
Please refer to our leaflet Overview of BREAK-THRU®, SURFYNOL® and TOMADOL® products for information
regarding labelling, biobased and/or biodegradable material and OMRI listing status of our products.
12
Additives for Crop Protection
DISPERSING AGENTS
BREAK-THRU® DA products are dispers- This increases milling efficiency. The BREAK-THRU® DA products can be
ing agents which ease the incorporation resulting small particle size enables a applied in SC and OD formulations.
of solid active ingredients in liquid better pesticide uptake. BREAK-THRU® They promote stable dispersions without
formulations and prevent their settling DA products finely disperse the particles settling and syneresis in the dispersing
and re-agglomeration. The dispersing which leads to a long term stability of medium. BREAK-THRU® DA products
agents are adsorbed onto the surface of the formulations. are m
ulti-functional additives often
the particles leading to wetting of the providing also emulsification properties
particles and coverage of the surface. The benefits are a higher biological effi- useful in OD formulations. In addition
By adsorbing on newly created surfaces cacy and enhanced storage stability of they have benign toxicological profiles.
during milling, they reduce interactions the formulations, even under extreme
and re-agglomeration of the particles. conditions.
13
Additives for Crop Protection
EMULSIFIERS
BREAK-THRU® Emulsifiers include to the needs of different applications. They increase the blooming effect of
primary and secondary emulsifiers that To emulsify a specific oil, the precisely formulations in water and enhance the
are based on renewable resources such adjusted HLB values of BREAK-THRU®
1)
wetting of hydrophobic surfaces.
as sorbitol, fatty acids and glycerol. EM products are needed. The required
HLB value can be adjusted by selected TOMADOL® 1-5 at 0.1% promotes
BREAK-THRU® EM products are non- blending. BREAK-THRU® EM products excellent wetting of hydrophobic
ionic, hydrophilic or lipophilic organic also provide dispersing, solubilizing and substrates by reducing the static surface
surfactants used for the preparation wetting properties. tension to 26 mN/m. Also, at 0.015%
and stabilization of both oil-in-water and in water the contact angle measures 18°.
water-in-oil emulsions. BREAK-THRU® EM The TOMADOL® ethoxylated alcohols TOMADOL® 1-5 is a good emulsifier for
products balance hydrophilic and lipo- surfactants have a dual function in for- aromatic and dearomatized hydrocarbon
philic properties to allow for adjustment mulations. solvents. It is readily biodegradable.
14
Benefits of BREAK-THRU® Emulsifiers:
PEG2) (20) Glyceryl for vegetable oil – also for naturally derived
BREAK-THRU® EM V 20 Oleoricinoleate 8.4 liquid pesticidal oils
paste,
melting
point
TEGIN® OV Glycerol mono/dioleate 3.3 ~30°C as co-emulsifier for BREAK-THRU® EM V 20
Please refer to our leaflet Overview of BREAK-THRU®, SURFYNOL® and TOMADOL® products for information
regarding labelling, biobased and/or biodegradable material and OMRI listing status of our products.
1)
HLB = hydrophilic-lipophilic-balance 2)
Polyethyleneglycol
15
Additives for Crop Protection
FORMULATIONS AND
FIELD PERFORMANCE
The BREAK-THRU® product portfolio in Confocal Laser Scanning Microscope) active (Imidacloprid) in liquid formula-
combination with the expertise of the we are able to visualize the mode of tion without solvent. To create a stable,
technical service of Evonik enables our action of our products. In addition we effective and environmental friendly for-
customers to differentiate their formula- use our competence in agronomy to mulation we used our BREAK-THRU®
tions in the market. design and conduct glasshouse and field DA 675 and BREAK-THRU® DA 647.
trials globally to evaluate the perfor-
TECHNICAL EXPERTISE mance of our products and formulations. With both BREAK-THRU® Dispersing
Evonik has expertise in preparing solid Agents we achieve excellent and stable
and liquid formulations like OD, SC, EC, EVONIK SERVICE formulations with good dispersibilities in
SL, WDG and WP and has the equipment Our aim is to give you the ability to water and with low foaming tendencies.
to do so (e.g., Dyno®-Mill, Speed- differentiate your formulation in the In addition the formulations have excel-
Mixer™, solid extruders). We test the market. We not only offer superior lent biological efficacies.
quality, stability and foam properties of agrochemical products, but also the
these formulations by established CIPAC service to develop guideline formulations As shown in the chart below, the Imida-
(Collaborative international pesticides in partnership with our customers. With cloprid 20% SC formulation prepared
analytical council) methods. We have an customer supplied actives, we use our with BREAK-THRU® Dispersing Agent
in-depth understanding of the interfacial broad portfolio of high performance and Oil Enhancer afforded better efficacy
behavior of our products as evidenced by adjuvants and additives for In-Can appli- than a commercial product. In a field test
our testing equipment for the physico- cations to develop guide formulations. for control of cotton aphids the guideline
chemical evaluations, e.g., Bubble Pres- So please contact us to discuss your formulation with reduced active ingre-
sure Tensiometers (SITA and LAUDA), specific application. dient content exceeded the effect of the
Pendant Drop Tensiometer (DATA commercial product at full rate.
PHYSICS), Turbiscan™ LAB, Beckman EXAMPLES FOR FORMULATIONS
Coulter LS 230, Anton Paar Rheometer AND THEIR FIELD PERFORMANCE OD formulations require unique
Physica MCR 301. Moreover with our Two formulation recipes are shown here dispersing agents and emulsifiers to
spectroscopic equipment (e.g., Hitachi with our BREAK-THRU® products. The suspend active components in oils. Our
Scanning Electron Microscope, LEICA SC formulation is designed to deliver the BREAK-THRU® Dispersing Agents
16
Imidacloprid 20% SC formulation
BREAK-THRU® DA 675 or
5.0 BREAK-THRU® DA 647 Dispersing Agent
1)
registered trademark of Evonik Resource Efficiency GmbH 2)
registered trademark of Thor GmbH 3)
registered trademark of ExxonMobil Chemical
17
support the fine milling of the solid Our example for a Nicosulfuron OD for- active ingredient content results with the
particles. In addition our OD formulation mulation proved to be a formulation with guideline formulation nearly matched
benefits from Evonik AEROSIL® fumed high stability and excellent dispersibility performance with the higher dosage in
silica which is an effective network in water. The Nicosulfuron 45 g/L OD the commercial product.
builder in both mineral and natural oils. formulation prepared with
They lead to thixotrophic properties of BREAK-THRU® Dispersing Agent and Oil
the formulation and to an excellent sta- Enhancer afforded better efficacy than
bility of the formulation with extended the commercial product in the glasshouse
shelf life. trial on Poa pratensis. Even at reduced
Emulsification behavior of the Evonik formulation (left) compared to a commercial standard (right)
18
RESULT OF FIELD TEST WITH IMIDACLOPRID 20% SC FORMULATION ON COTTON APHIDS
(number of aphids per 20 leaves / ai = active ingredient / DAT = day after treatment)
800
700
600
500
400
300
200
100
0
Commercial Commercial Evonik Formulation
Check
(70 g ai/ha) (35 g ai/ha) (35 g ai/ha)
100
80
60
40
20
0
Commercial standard Commercial standard Evonik´s Formulation Evonik´s Formulation
(10 g ai/ha) (2.5 g ai/ha) (10 g ai/ha) (2.5 g ai/ha)
20 DAT 30 DAT
19
Inv.-Nr.: 49-2020
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technical or otherwise, are presented in good
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Evonik Operations GmbH prepared. Recipients of this information and
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Phone +49 201 173-2665 In no event shall Evonik assume liability for
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www.evonik.com result from the use of or reliance upon this in-
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SUCH PURPOSE) WITH RESPECT TO ANY
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INFORMATION AND RECOMMENDATIONS
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PROVIDED. Reference to any trade names
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Phone +86 21 6119-1125 used by other companies is neither a recom-
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sponding product, and does not imply that
similar products could not be used. Evonik
reserves the right to make any changes to the
information and/or recommendations at any
The Americas time, without prior or subsequent notice.
Evonik Corporation
P.O. Box 34628
Richmond, VA 23234
USA
Phone +1 804 727-0700
Fax +1 804 727-0855 www.evonik.com/break-thru