10-5

{
a) [ kzcrou ] =
5- M 1000 :
1

CROÚ ZAGT #
-

→ 5×10-5
+
Agzcroy
'
[ Grout ] [ ] 10-8 M
kps =

Agt =
5.
10-5
10-12 5. [
Agi ]2 T
= .

PRECIPTARÁ kce

[Ag -13=1142.10-4
←

ABANS

[ KU] =
5. 10-8 M

Agt
-

ce + a
Aga

kps =
[ cé ] [ Aj ]
10-97 =
5.10-8 .
[
Acj]
[Aj] =
3199.10-3 M

{
b) [ kzcrór] = 5- 10-2 M 1000 1 :

'

kps [ GOY J [
Aj] 10-2
-

5. ✗ =

[
Ag -13=4147.10-6 M
10-5
=
5. M
T
CKCL] = 5.10-514 KU

KPS = [ cé ] [
Agt]
10°
Agt ]
3.99
[ M ←
PRECIPITARÁ
-

ABANS
 gente

a) Casi
S
+ SÓÍ
S
= casar 5=111
y
/L ✗
# =
8109.10-314

kps [ casi ] [ 5042 ]

-

=
S -

= 52
?
= (8109.10-3)

KPS =
6154 .
10-5

¥-2105
"
CAZ -1
-

+
ZF te Cafz 5=01016 / L IÓ M
g
✗ .

S 2s

[ Cart ] [ f- j
Kps =

'
=
S .

CZS )

= 453
= 4-2105.10-43
"
14ps =
3145 .

IÓ

b) V -250mL
0102 Mob Nazsou quien precipitaría primer
si siaddiciona Calla ?
0103 moho NAF

0102 NAF 0103

NAZSOY → = 0108M →
= 0112M
0125 ☒

"
SOE "
-

Era + -
Casoy Ca +
⇐ → cafz

kps =
[Ca
"
] [ 504
"
] kps
=
[ casi ] [ f- Í
"

6154 .

10-5 =
[Cari] .

0108 3145 IÓ .

[Cat ] .

01122

[ Caz] =
8118.10-4 M [Caz] = 214 -

10-9 M

9
pp primer cata
 Casi -12-5 Cat CZOYZ
-

Cats
-

I + I Caczoy

kps =
[ cara] [ F- } kps = [ casi] [ CZÓÜI
10-14 =
[ Galt ] .

01012 10-817 =
Ccaa] .

011

[ Cazt ] =
1.10 -10M [ CAZT] =
1199 .
10-8 M

① a
pp primer

② miro la concentración pp primer las condiciones

que
en

del el
segon precipitar quau segon comuna .

2n : [ Ca
"
] =
1199 .
10-5 M

'

lr :

kps
=
[Casi ] [ f- ]
10-14 =
1199.10-8 . [ F- 32
5103 .
10-7 =
[ f- ja

[ F- ] -

VÉ
[ F- ] =
7109 . 10-4 M

③ miren si es
quautrtatin
7109 .

10-4
✗ 100 = ← NO ÉS QUANMTATN
0,01

d
HAURIA
DE SER

f 011%
 " "

CUCOH )2
- -

a) Cu + OH → Mu + OH → MUCOHIZ

"
[ Cu ] [ OH ] kps [ Mui ] COTT ]
kps
= =

418-10-20=0105 .

[OH ] -

2.10-13 = 0104 .

[ OIÍ ]

[Ott ] 916 10-19 M

[01-5]=5 10-12
=
M
.
.

T T
el aire
pp primer más soluble

b) kps [ cura] [ OH ]
'

418.10-20 =
[ Curt ] .

5. 10-12

[ Cut ] =
916 -

10-9 M

C) 916 .
10-9 ✗ 100 =
010000192% 011% 2- Si EI
0105 QUANTTATIUA
 5-
"

Agas Te
ZAG +

S
[1-1-1]=1 M

2s

-
[ se]
[
Ag ]
"

kps =

=
SI -

=
453

① 10-4912 =
4g
}

% s

5- 2151 .
10-17

② quam
teuim Ht calculen ✗ cres

'
Kps kps ✗
= -

✗ SCH ] =
1.1020

Kps
'
= 10-4912 .

1.1020

'
6131 10-30
ILPS
=
.

Kps
'
= 453

¿ =
= 1116.10-10 M
 -1
CDZ + 5- → Cdsti
?
ÓINE 0101 ✗ 99%
10-4 µ

] [ 5) el
"
Kps =
[Cd

[Elle =
KPS = 7-10-2314
[cdzy

✗ =
[ 52-704
[ 5- JII

= 1143.1021

101319 [ Ht ] 101319.10+102 [ 1++32 1143.1021

¥-1
-1
.

+ .
=

[1-1-1]=1131 M →
PH = -
0112 ←
DONDE TENEMOS

EL 99% EL Cd

"

zn + Si → 2ns tu
0101 ✗ 1% ? 0101×99
Tu

Kps =
[ 2h2-1] [ F) el

[5- ] el =
3-10-2014

[ 5- ] ' 04 'S
✗ = = =
3133-10
[52-311 3.10-20

✗ 5- [ znzi) = -
- =
333-1018 → [tí] =
010633M

↳ 112
pH =
 Nim + g- →
Nis
10-2M -011% 011.9919%

E- Ti
 '
moh mvls ML ni
-

ni son
peq
:
=
pH

inicial PSCN [ SCN ] 111

-10g
-

O = =

V. M V. M 8. 10-2
log
= -

50-8.10-2 10-2 [ SCN ] 117

abanspeq
-

V 4.
PSCN log
=

50
.
= -
=

-10g 0102

V-100mlf-p.eq-p.iq → 100

i.su
dsppeq 110
faltan 2

:{
10-2

{
8.
01004 malo
-

50mL SCN × = SCN

-

yooo
/ muy
4. 10-2 mots
50mL UÍ ✗ = 01002 Cut ←
limitar
pooom ,

{
01002
01002 uevls SCN [ SCN ] 0102 M
- -

=
→
FINAL
=
0105 -1010g
Ouruls leí
 010214mm
47 mL KSCN ×
1000mL
×
µ = 010010058 mol
Agt

107188 0110842524
010010058 mal
Agt ×
lmol
=
g Agt

0110842524 G 8716 % Agt

-

✗ noo =

011238T
012386 g
CNAQI KBR) + H2O →
MOHR 4814mL AGNO 30104837M

Ná

i-N03-KBr-AGN03.es
NaCl
AGNÓS ←
Agudo
+ +

AGBRL

✗
g Nace
GRKBR
=

f-

✗+ 012386
y =

010483 mol
4814mL
2143.10-3 malo Ag NOS
AGNO }
=
✗
1000mL
T
TOTAL

✗+ 012386 ✗
✗ y
-
=
-

↳ KBR
✗
+ = 2134.10-3 y
=
012g
53144 ,

Amol 79199 1
012g KBR ×

119g
×
¡ ×

Andá
×
012386
✗ "°

= 5613% Br
 ( Klloasi inert )
0175g + 50mL
AGNO} 011225M

d
916mL KSCN 011080M

011225^01
50mL AGNÓS ✗ = 01006125 mols
Ag NOS TOTACS
1000mL

mal
µ
01080
916mL KSCN × × =
010010368 mols Aguas
1000mL
EXCEÍ

T -

E =
01006125 -

010010368 =
010050882 malo AGNÓS
REACCIONATS

1mV K 03 59
122 >
'

010050882 malo
AGNO } ✗
016236g
=
✗

lueol Amol
AGNO } KU 03

016236
✗ 100 =
83114-1 .

KU 03
0175