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Dirasat, Engineering Sciences, Volume 35, No.

2, 2008

Characterization and Assessment of Treatability of Wastewater


Generated in Amman Slaughterhouse

Ameen Sarairah and Ahmad Jamrah*

ABSTRACT
Slaughterhouse industry can result in serious environmental pollution. Amman slaughterhouse is considered the
largest one in the country and consumes more than 400m3/day. This study aims to characterize slaughterhouse
wastewater generated in Amman, and assessing various suitability of biological treatment and economic
feasibility of wastewater reuse. Composite wastewater samples were collected and analyzed from Amman
slaughterhouse in the period of December 2006 to July 2007. Results of the study indicated the presence of
diurnal differences between the characteristics of the wastewater between summer and winter. Amman
slaughterhouse wastewater is classified as strong wastewater in terms of its content of COD and BOD5. The ratio
of COD/BOD5 indicates applicability of biological treatment. The study also concluded that the organic and
nitrogen contents of the slaughterhouse wastewater are associated significantly with suspended solids indicating
that anaerobic biological treatment could be more efficient for the treatment of this type of wastewater. The
study also showed that direct reuse of slaughterhouse wastewater is acceptable in terms of most of its inorganic
content while direct reuse is not acceptable in terms of its organic content. Finally, yearly cost-benefit analysis
related to the treatment and reuse of Amman slaughterhouse wastewater shows net earning resulting from proper
management of this wastewater.

Keywords: Slaughterhouse, Wastewater, Characterization, Treatability, Reuse, Feasibility.

1. INTRODUCTION Approximately 80% of the country is desert and receives


a precipitation of less than 50 mm annually. Increased
Arid and semi-arid countries like Jordan must population coupled with higher living standards have
employ innovative techniques so that they can arrive at resulted in higher water consumption in most
sound and sustainable management of water resources. communities. Consequently, this resulted in increased
This is mainly due to the fact that water is extremely discharge of untreated wastewater.
essential for socioeconomic development (Al-Kloub et To address water scarcity, the government of Jordan
al., 1998). The reuse of treated wastewater constitutes a considers treated wastewater as a strategic resource that
viable alternative in many cases; as wastewater should be managed and used to lower the stress on fresh
generation rates can be as high as 80% of the total water water resources (WAJ 1997). As a result, Jordan is
consumption (Metcalf and Eddy, 2003). Jordan water reusing more than 70% of the treated wastewater effluents
resources are characterized by vulnerability and generated (Surani, 2003). Reuse of treated wastewater
variability (Bakir, 1999). Due to the variable should not be limited to domestic discharges. In some
topographic features of Jordan, the distribution of cases, industrial wastewater discharges are of significant
rainfall varies considerably with location resulting in quantities and, when treated, should be considered part of
chronic imbalance in the population-water resources the wastewater reuse. One of the most industrial sectors
equation (Shatanawi and AL-Jayyousi, 1995). that produce large quantities of wastewater is the
slaughterhouse sector which often contains high
concentration of biodegradable organic matter.
* Department of Civil Engineering, University of Jordan.
Received on 28/1/2008 and Accepted for Publication on Wastewater discharges generated from
9/6/2008. slaughterhouses typically contain high concentrations of
organics, fat, and proteins (Al-Mutairi et al., 2003).

- 71 - © 2008 DAR Publishers/University of Jordan. All Rights Reserved.


Characterization and Assessment… Ameen Sarairah and Ahmad Jamrah

From the environmental engineering point of view, this activities in the slaughterhouse include cattle, sheep and
indicates that their treatment might be more demanding poultry slaughtering. The Amman slaughterhouse
than domestic wastewaters. However, these wastewaters consists of two plants: the cattle and sheep plant and the
may be quiet useful when it comes to wastewater reuse poultry plant. These two plants consume 45% and 55%
for agriculture. As has been reported (Al–Mutairi et al., of the total fresh water; respectively. The total amount of
2004; Al–Mutairi et al., 2003; Quinn and Farlane 1989; fresh water consumed is estimated at more than 400 m3
Sangodoyin and Agbawhe, 1992), slaughterhouse per day (MOGA, 2006). The operations conducted
wastewater is very harmful to the environment. Effluent throughout the slaughterhouse activities include blood
discharges from slaughterhouses can result in the capturing. This operation results in capturing a daily
depletion of oxygen from water bodies, and the average of 15 m3 of pure blood, which is generally
contamination of groundwater. These effluents contain collected and transferred to a nearby biogas plant. This
high levels of organic matter, which generally arise from blood capturing process leads to a reduction in the total
paunch, fecal, fat and lard, undigested food, blood, COD and BOD5 of the waste.
suspended material, urine, loose meat, soluble proteins, Very few studies dealt with the characterization of
excrement, and particles. The pollution potential of slaughterhouse wastewater. Masse and Masse (2000b)
meat-processing and slaughterhouse plants has been characterized wastewater from hog slaughterhouses in
estimated at over 1 million population equivalent in the eastern Canada, and reported that raw wastewater has a
Netherlands (Sayed 1987), and 3 million in France total COD in the range of 2333 to 8627 mg/L, and SS
(Festino and Aubart 1986). Blood, one of the major concentration in the range of 736 and 2099 mg/L. Al–
dissolved pollutants in slaughterhouse wastewater, has a Mutairi and co-workers (2003) characterized and
chemical oxygen demand (COD) of 375,000 mg/L (Tritt investigated the possibility of using contact stabilization
and Schuchardt 1992). Slaughterhouse wastewater also activated sludge process to treat slaughterhouse
contains high concentrations of suspended solids (SS), wastewater generated in Kuwait city. Their results
including pieces of fat, grease, hair, feathers, flesh, indicated that the employed process effectively reduce
manure, grit, and undigested food (Bull et al. 1982). These pollution potential of slaughterhouse wastewater. The
insoluble and slowly biodegradable SS represented 50% COD of slaughterhouse wastewater ranged from 3335 to
of the pollution load in screened (1 mm) slaughterhouse 7580 mg/L, of which approximately 30% was in the
wastewater, while another 25% originated from colloidal form of SS. Reported removal efficiency was 77% for
solids (Sayed and Zeeuw, 1988). soluble COD and 82% for insoluble COD when the
The number of slaughterhouse plants in Jordan is applied volumetric loading rate was 1.8 kg COD/m3.day.
estimated at 32 plants. Among these, 8 are owned by the Many researchers investigated the treatment of
private sector and the rest are owned by municipalities slaughterhouses wastewater (Masse and Masse 2000a,
(MOA, 2006). While fresh water consumption reported Borja et al., 1995, Pozo et al., 2003, Merzouki et al.,
by the private sector stands at 1670 m3 per day, no data 2005, Caixeta et al., 2002, Pozo et al., 2006, Manjunath
is available regarding fresh water consumption by the et al., 2000, Flugaur 2003, Pozo and Diez 2003, Fuchs et
municipalities. The wastewater generated by the private al., 2003, Amuda and Alade 2006, Reginatto et al., 2005,
sector is usually treated using activated sludge biological Ruiz et al., 1997, Pozo et al., 2000, Al-Mutairi et al.,
treatment, and the resulting treated effluent is reused for 2004, Borja et al., 1998). They employed treatment
agricultural purposes. The wastewater generated by techniques ranging from anaerobic sequencing batch
municipal slaughterhouse plants is usually discharged reactor (ASBR), anaerobic fluidized-bed system,
either to municipal sewer system or transferred by anaerobic–anoxic sequencing batch reactor coupled with
tankers to a final liquid disposal site overseen by the fixed-bed nitrification reactor, a three-phase separation
Ministry of Water and Irrigation. system in a UASB reactor, anaerobic fixed-film reactor
The slaughterhouse in the city of Amman is one of (AFFR), upflow anaerobic sludge blanket (UASB)
the largest in the country, and was established in the year process, integrated anaerobic-aerobic fixed-film reactor,
1972, with a surface area of about 20000 m2. The anaerobic treatment using a stirred tank reactor coupled
slaughterhouse serves about 80% of the city’s population with membrane filtration unit, coagulation/flocculation
which is estimated at more than two million people. The process, anaerobic ammonium oxidation, and an upflow

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Dirasat, Engineering Sciences, Volume 35, No. 2, 2008

anaerobic sludge blanket reactor followed by anaerobic samples were collected in duplicates, at a point before
filter. the wastewater is discharged directly to the sewer
On the national level, no significant studies have system. The samples were collected bi-weekly during
been carried out to characterize or investigate the the morning time, from 8 a.m. to 1 p.m. Samples were
wastewater generated from slaughterhouse industry. As collected from the sewer of each of the two plants (cattle
a result, the objectives of this study include: (1) and sheep plant and poultry plant). Two liters were
evaluating the physical, chemical, and biological collected every hour, over a period of five hours to
characterization of the wastewater generated in the ensure that representative composite samples were
Amman slaughterhouse, (2) investigating the diurnal obtained. An overall representative sample was then
changes in the characteristics of the wastewater obtained by mixing 45% of the first plant and 55% of the
generated, and (3) assessing various slaughterhouse second plant.
wastewater management options, including the Parameters selected for analysis during this
suitability of biological treatment and economic investigation were determined based on previous studies
feasibility of wastewater reuse. in this field. Table (1) shows an overview of selected
parameters analyzed during characterization of
2. METHODOLOGY slaughterhouse wastewater as reported in the literature.
The table also shows the parameters selected for this
Composite wastewater samples were collected from study. Prior to analysis, samples were screened using 1-
Amman slaughterhouse in the period of December 2006 mm sieve. Samples were then analyzed in duplicates
to July 2007. This period was chosen to ensure that according to the Standard Methods for the Examination
diurnal changes are reflected by the samples. All of Water and Wastewater (APHA, 2005).

Table 1. An overview of selected parameters analyzed during characterization of slaughterhouse


wastewater as reported in the literature.
Reference Parameters investigated
Masse and Masse TCOD, SCOD, TS, VS, SS, VFA, TKN, NH3-N, protein, P, K, Ca, Na, Mg, S, Fe,
(2000b) Mn, pH, and Alkalinity.
Borja et al. (1995) COD, BOD, TSS, VSS, VFA, pH, Alkalinity, P, NH3-N, TKN, and Protein.
TCOD, SCOD, TBOD, SBOD, TSS, VSS, TKN-N, NH3-N, Total P, Cl, Grease and
Pozo et al. (2003)
Oil, and pH.
Merzouki et al. (2005) TCOD, SCOD, TOC, pH, VFA, NH4-N, TKN, P, and TSS.
Density, pH, Acidity, COD, BOD, Oil and Grease, Turbidity, TSS, VSS, FSS, Org.
Caixeta et al. (2002)
nitrogen, NH3-N, and Total P.
Pozo et al. (2006) COD, TKN, NHx-N, TSS, Total Alkalinity, and pH.
Manjunath et al. (2000) SS, pH, BOD5, Fat, TKN, P, and COD.
Flugaur (2003) BOD5, TSS, TKN, Total P, and Fecal coliform bacteria.
TCOD, SCOD, TBOD5, SBOD5, TKN, C/N, Partial Alkalinity, TSS, and Oil and
Pozo and Diez (2005)
Grease.
Al-Mutairi et al. (2003) TCOD, SCOD, SBOD5, SS, VSS, P, TKN, FOG, and pH.
Fuchs et al. (2003) COD, BOD, SS, pH, VFA, NH4-N, and TKN.
Amuda and Alade (2006) TSS, TDS, TP, BOD5, COD, TKN, FOG, Turbidity, and pH.
Reginatto et al. (2005) NH4-N, NO3⎯-N, NO2⎯-N, COD, and pH.
Ruiz et al. (1997) TCOD, TSS, COD insoluble%, Protein, Fats, P, NH3-N, and pH.
Pozo et al. (2000) BOD5, COD, TSS, TKN, TP, and Grease.
Al-Mutairi et al. (2004) Filterable COD, SS, Turbidity, pH, and TDS.
Borja et al. (1998) pH, COD, BOD5, TOC, TS, VS, Non-volatile solids, P, TKN, and Alkalinity.
TCOD, SCOD, BOD5, TS, TVS, TSS, VSS, VFA, TN, protein, P, K, Ca, Na, Mg,
This study
Mn, S, Fe, EC, HCO3-, NO2-, NO3-, NH4+, NH3, pH, and Alkalinity.

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Characterization and Assessment… Ameen Sarairah and Ahmad Jamrah

3. RESULTS AND DISCUSSIONS for the screened and raw samples ranged from 1.25 to
2.5 and from 1.6 to 2.5; respectively. These numbers are
Wastewater Treatability comparable to those presented by Metcalf and Eddy
As mentioned previously, the slaughterhouse (2003) and Jamrah (1999a). Those researchers stated that
wastewater stream typically contains high levels of the typical COD/BOD5 ratio of domestic wastewater is
organic matters which generally arise from paunch, fecal usually in the range 1.25 to 2.5, and indicated that the
matter, fat, lard, undigested food, suspended materials, proportion of the biodegradable contents is higher than
urine, and loose meat. These contents tend to form a the nonbiodegradable contents. This indicates that the
mixture of suspended solution at the end. As a result, the biological treatment is applicable in case of Amman
collected samples in this study were screened at 1-mm slaughterhouse wastewater treatment.
sieve. The statistical analyses of the results of the study In addition to the organic content, the pH is of
were carried out for the winter (wet) season, summer concern when chemical properties of wastewater are
(dry) season, and for the whole year. Results are being investigated. In the case of biological waste
presented in Table (2). treatment the well-being of treatment microorganisms is
The water authority of Jordan (WAJ), who is of concern. Low pH value may inhibit the growth of
responsible for monitoring and discharge of this microorganisms. The reported pH values of the screened
wastewater, carried out a monitoring program of raw and raw wastewater samples of Amman slaughterhouse
wastewater for the years 2004 to 2006. Unscreened are shown in Tables (2 and 3), and are within the range
samples were collected and analyzed for the TCOD, favored by the bacteria.
BOD5, TS, TSS, TDS, and pH. Results of these analyses The TDS content of the screened wastewater samples
are shown in Table (3). It should be noted that results ranged from 320 to 2560 mg/l with an average of
presented in Table (3) do not include the outlying values 1826.42 mg/l, while the TDS of the raw samples ranges
such as those of the COD data that were obtained prior from 846 to 5444 mg/l with an average of 2401.14 mg/l.
to installation of the blood capturing system. It can also be observed from Tables (2 and 3) that TSS
The characterization of slaughterhouse wastewater is content of the wastewater recorded over the year time
divided generally into physical, chemical, and biological for the screened and raw samples range from 600 to
properties. The interrelation within these properties 1190 mg/l with an average of 863.57 mg/l and from 342
could contribute to selection of the treatment method to 3850 mg/l with an average of 1424.21 mg/l;
that will be applied. Seasonal measurements were respectively. These numbers are extremely significant
conducted in order to emphasize the effect of because suspended solids can lead to the development of
temperature on these properties and its subsequent effect sludge deposits and anaerobic conditions when untreated
on the chemical reactions taking place via the activity of wastewater is discharged in the aquatic environment.
bacteria that is responsible for stabilization of organic The measured TCOD, TDS and TSS results indicate
content of wastewater. It has been observed, as shown in that the wastewater being studied is classified as strong,
Table (2), that the screened samples have slightly low since reported values for wastewater that is classified as
TCOD content in the summer season compared to the strong (Metcalf and Eddy, 2003) show values that are
winter season. lower than those measured.
The summer TCOD content of the wastewater ranges Previous studies on slaughter wastewater as listed in
from 1260 to 2390 mg/l with an average of 1866.57 the text showed most of the researchers conducted their
mg/l, while the winter TCOD content ranges from 1390 works on the treatment rather than characterization. Few
to 3300 mg/l with an average of 2421.42 mg/l. Similar researchers carried out research on slaughterhouse
trend is presented in Table (3) for the TCOD content of wastewater characterization. Those researchers include
raw wastewater samples obtained from WAJ. The Masse and Masse (2000b) and Al–Mutairi and co-
observed winter TCOD for the raw samples ranges from workers (2003). Their findings are reported in Table (4),
2186 to 17968 mg/l with an average of 7644.57 mg/l which also compares those findings to the results of this
while the summer TCOD ranges from 807 to 6518 mg/l study. The table shows that the findings of this study are
with an average of 3664.14 mg/l. very well comparable to those reported in the literature.
The COD/BOD5 ratios recorded over the year time The slight difference between the numbers reported in

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Dirasat, Engineering Sciences, Volume 35, No. 2, 2008

the table can be attributed to waste type, processing, wastewater shows better correlation compared to
measurements technique, efficiency of blood capturing screened wastewater, indicating association of TCOD
system, amount of consumed water, and other with suspended solids, and to larger extent with solids
slaughterhouse activities. greater than 1-mm in size. Similar observation can be
An attempt at investigating the different inter- made regarding TS and TSS for raw and screened
relationships prevailing among the different wastewater samples. However, the relationship between
characteristics of Amman slaughterhouse wastewater is BOD and TSS for screened wastewater shows better
shown in Table (5). The table shows regression correlation compared to raw wastewater, indicating
relationships obtained between the different parameters association of BOD with suspended solids, and to a lesser
of concern and the TSS content in screened and raw extent with solids greater than 1-mm in size. Additionally,
slaughterhouse wastewater samples. Selected the table clearly shows that some of the organic (including
relationships from this table are also shown in Figures (1 BOD) and nitrogen content of slaughterhouse wastewater
thru 6). The table and figures show positively correlated is associated with suspended solids. The fact that the
relationships between the parameters as indicated by the organic and nitrogen contents of the slaughterhouse
positive coefficients of determination (R2) and wastewater are associated significantly with suspended
correlation coefficients (r). One can conclude important solids indicates that anaerobic biological treatment could
facts about characteristics of slaughterhouse wastewater. be more efficient for the treatment of this type of
The relationship between TCOD and TSS for raw wastewater (Metcalf and Eddy, 2003).
Table 2. Summary of statistical analyses of Amman slaughterhouse wastewater characteristics screened at 1 mm
during winter, summer, and year time. (All units are in mg/1 except pH, and SAR which are dimensionless).
Winter time Summer time Year time
Parameter
Ave. Stdev. Max. Min. Ave. Stdev. Max. Min. Ave. Stdev. Max. Min.
Total COD 2421.42 683.01 3300 1390 1866.57 425.74 2390 1260 2144 617.94 3300.00 1260.0
Soluble COD 1707.14 594.13 2560 690 1547.85 390.31 2040.0 1118 1627.50 489.96 2560.00 690.00
BOD5 1080.42 247.01 1453 729 1389.57 310.90 1798.0 1006 1235 313.85 1798.00 729.00
TS 2677.14 568.46 3200 1510 2702.85 371.97 3210.0 2340 2690 461.72 3210.00 1510.0
TSS 1098.57 418.50 1990 780 742.85 129.09 895 600.0 863.57 191.58 1190.00 600.00
TDS 1692.85 689.26 2420 320 1960 410.36 2560 1460 1826.42 562.32 2560 320
TVS 2067.14 563.66 2550 1060 1823.85 237.46 2025 1340 1945.50 434.28 2550.00 1060.0
TVSS 657.14 274.99 980 300 649.85 62.71 780.0 580 653.50 191.65 980.00 300.00
PH 6.74 .17 7.0 6.5 6.64 .13 6.80 6.40 6.69 .159 7.00 6.40
EC(dS/m) 1.47 .16 1.63 1.14 1.60 .11 1.79 1.48 1.53 .15 1.79 1.41
P as( PO4-3 ) 90.67 47.50 157.9 31.1 98.94 18.40 136.50 78 94.80 34.87 157.90 31.10
Fe .60 .12 .84 .43 .82 .18 1.10 .56 .71 .18 1.10 .43
Mn .20 .03 .28 .17 .20 .06 .31 .10 .20 .05 .31 .10
Ca 43.94 7.12 56.31 35.27 59.27 14.40 78.55 45.3 51.60 13.50 78.55 35.27
Mg 46.85 2.50 50.79 42.53 42.86 8.86 58.33 34.39 44.85 6.58 58.33 34.39
Na 210.29 27.48 243.69 177.08 209.03 14.69 232.81 192.65 209.66 21.18 243.69 177.08
K 66.35 17.51 98.92 44.18 62.60 18.25 85.60 38.00 64.47 17.29 98.92 38.00
Cl 207.0 33.62 252.58 159.53 212.30 42.12 265.89 160.12 209.65 36.72 265.89 159.53
HCO3- 636.11 21.01 671 610.0 512.67 186.56 762.62 253.20 574.39 142.72 762.62 253.20
HCO3-
521.41 17.22 550 500 420.21 152.94 625.10 207.50 470.81 117 625.10 207.50
(as CaCO3)
SO4-2 40.05 45.98 137.6 6.40 153.87 118.19 315.00 24.34 96.96 104.45 315.00 6.40
Total cation 367.44 41.15 422.84 316.9 373.77 17.89 394.26 346.60 370.61 30.66 422.84 316.90
SAR 5.25 .54 5.84 4.67 4.96 .56 6.11 4.45 5.10 .55 6.11 4.45
Alkalinity as 521.42 17.25 550 500 424 156.07 625.00 207.50 472.71 118.04 625.00 207.50

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Characterization and Assessment… Ameen Sarairah and Ahmad Jamrah

Winter time Summer time Year time


Parameter
Ave. Stdev. Max. Min. Ave. Stdev. Max. Min. Ave. Stdev. Max. Min.
CaCO3
NO-2-N 1.19 0.56 2.28 0.75 1.45 0.87 3.06 0.6 1.32 0.72 3.06 0.6
NO-3-N 7.08 0.65 8.13 6.22 7.15 0.65 8.4 6.28 7.12 0.62 8.40 6.22
NH3-N 0.20 0.17 0.51 0.05 0.11 0.04 0.18 0.06 0.16 0.12 0.51 0.05
NH4+-N 63.03 38.49 117 11 53.93 16.93 70 22.36 58.48 28.95 117 11
TKN 156.14 20.81 181 131.5 134.86 26.41 185.46 101 145.50 25.37 185.46 101
Organic-N 92.91 54.73 160.45 15.49 80.91 28.45 119.52 37.83 86.91 42.36 160.45 15.49
TN 164.42 20.59 189 140 143.58 26.30 193.70 110 154 25.14 193.70 110
Protein 581.94 341.07 1003.1 100 505.76 177.77 748.12 237.50 543.85 264.27 1003.12 100
VFA (as acetic
162.16 57.62 248.51 88.54 140.36 47.58 188.51 50.26 151.26 52.01 248.51 50.26
acids)

Table 3. Summary of statistical analyses of Amman slaughterhouse raw wastewater characteristics reported by
water authority of Jordan for the years 2004 to 2006. (All units are in mg/1 except pH).
Winter time Summer time Year time
Parameter
Ave. Stdev. Max. Min. Ave. Stdev. Max. Min. Ave. Stdev. Max. Min.
Total COD 7644.57 6024.39 17968 2186 3664.14 2060.82 6518 807 5654.35 4793.38 17968 807
BOD5 1813.14 1178.56 3828 751 1266.42 502.61 1978 463 1539.78 915.50 3828 463
TDS 2723.85 1596.38 5444 846 2078.42 1228.67 3820 965 2401.14 1408.94 5444 846
TSS 1668.14 1105.97 3850 612 1180.28 635.67 2080 342 1424.21 902.84 3850 342
TS 4392 2147.84 6976 1542 3258.71 1575.28 5373 1396 3825.35 1902.70 6976 1396
PH 6.86 1.22 7.8 4.59 7.04 .49 7.89 6.44 6.95 .90 7.89 4.59

Table 4. A comparison of slaughterhouse wastewater characteristics obtained in this study with those reported by
other researchers (All units are in mg/1 except pH which is dimensionless).

Parameter Masse and Masse (2000b) Al–Mutairi et al. (2003) This study
TCOD 3417 27,000 2144
SCOD 1250 1100 1627
TSS 1431 1500 863
VSS 1149 1650 653
TKN 158 170 145
P (as PO4-3) 80 27 94
pH 6.5 6.8 6.69

Table 5. The regression relationships obtained between the different parameters of concern and the
TSS content in screened and raw slaughterhouse wastewater samples.
Regression formulas R2 r
TCOD (screened)= -66.19*TSS (screened) + 2640.5 0.2008 0.448107
BOD5 (screened)=0.3031*TSS (screened) + 874.16 0.4312 0.656658
TS (screened)= -0.9033*TSS (screened) + 3470.1 0.1405 0.374833
TN (screened)=0.078*TSS (screened) + 86.649 0.3533 0.594390
Organic-N (screened)=0.0822*TSS (screened) + 15.884 0.1383 0.371887
TKN (screened)=0.0783*TSS (screened) + 77.902 0.3493 0.591016
TCOD (raw)=2.3014*TSS (raw) + 1183.2 0.4285 0.654599
BOD5 (raw)=0.6314*TSS (raw) + 640.52 0.3877 0.622655
TS (raw)=1.503*TSS (raw) + 1684.7 0.5086 0.713161

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Dirasat, Engineering Sciences, Volume 35, No. 2, 2008

1400
1200
1000
BOD 5(mg/l)
800
600
400
200
0
0 200 400 600 800 1000 1200
TSS(mg/l)

Figure 1. A plot of TSS versus BOD5 contents of screened slaughterhouse wastewater samples.

250

200
TN(mg/l)

150

100

50

0
0 200 400 600 800 1000 1200 1400
TSS(mg/l)

Figure 2. A plot of TSS versus TN contents of screened slaughterhouse wastewater samples.

200

150
TKN(mg/l)

100

50

0
0 200 400 600 800 1000 1200 1400
TSS(mg/l)

Figure 3. A plot of TSS versus TKN contents of screened slaughterhouse wastewater samples.

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Characterization and Assessment… Ameen Sarairah and Ahmad Jamrah

8000
7000
6000
TCOD(mg/l) 5000
4000
3000
2000
1000
0
0 500 1000 1500 2000 2500
TSS(mg/l)

Figure 4. A plot of TSS versus TCOD contents of raw slaughterhouse wastewater samples.

4500
4000
3500
BOD 5(mg/l)

3000
2500
2000
1500
1000
500
0
0 500 1000 1500 2000 2500 3000 3500 4000 4500
TSS(mg/l)

Figure 5. A plot of TSS versus BOD5 contents of raw slaughterhouse wastewater samples.

8000
7000
6000
5000
TS(mg/l)

4000
3000
2000
1000
0
0 500 1000 1500 2000 2500 3000 3500 4000 4500
TSS(mg/l)

Figure 6. A plot of TSS versus TS contents of raw slaughterhouse wastewater samples.

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Dirasat, Engineering Sciences, Volume 35, No. 2, 2008

Wastewater Reuse used for agricultural purposes, had define the maximum
Wastewater reuse is an important management option allowable concentrations limits required for this purposes
in Jordan due to the limited renewable fresh water (JS 202:2004). Table (6) shows the average values of
resources. Jordan is indirectly reusing most of the treated physical, chemical and biological characteristics of the
wastewater for agricultural purposes. Jordan institute of slaughterhouse wastewater samples and their
standards and metrology (JISM), that is responsible for acceptability for reuse according to the Jordanian
the application of the standards for reclaimed wastewater standards.

Table 6. The average values of physical, chemical and biological characteristics of the slaughterhouse wastewater
samples (sieved at 1 mm sieve) and their acceptability for reuse according to the Jordanian standards. All units are
in mg/l except EC (in dS/m), pH and SAR (unitless).
Average screened Max. allowable limits
Parameter Acceptability
samples results required by (JISM)
TCOD 2144 500 No
BOD5 1235 300 No
TSS 863.57 150 No
TDS 1826.42 2000 Yes
pH 6.69 6-9 Yes
EC 1.53 3 Yes
P 94.80 30 No
Fe .71 5 Yes
Mn .2 .2 Yes
Ca 51.60 230 Yes
Mg 44.85 100 Yes
Na 209.66 230 Yes
-
Cl 209.65 400 Yes
HCO-3 574.39 400 No
-2
SO 4 96.96 500 Yes
SAR 5.1 9 Yes
NO-3 as (N) 7.1 45 Yes
TN 154 70 No

Conditions that adversely affect irrigation water Sucoff et al. (1975) reported that chloride and sodium can
quality include elevated levels of dissolved solids, accumulate in the plant needle (leaves). The influence of
presence of toxic compounds, and salt water (Metcalf and sodium, measured as sodium-adsorption ratio (SAR), can
Eddy, 2003). Salinity is important in determining the be explained by high and low SAR levels that can be
suitability of water for irrigation, and irrigated crops translated into deterioration of the physical condition of
accordingly. As has been stated by other investigators soil and reduction of infiltration rate (Ayers and Westcot,
(Metcalf and Eddy, 2003, Jamrah, 1999b), the presence 1985). Investigation of Table (6) indicates that the
of salts can have osmotic effects on plant growth, along numbers related to chloride, sodium, magnesium,
with ion toxicity and soil dispersion. This ultimately can calcium, SAR, and pH are acceptable for irrigation based
affect crop water availability. on specific ion toxicity. Similar conclusion can be
Analyzing the contents of table (6) indicates that the reached for other nutrients which include sulpher,
numbers related to EC and TDS of Amman potassium, and nitrate. The organic content reported in
slaughterhouse wastewater effluents screened using 1- this study as TCOD, BOD5, and TN as shown in Table
mm sieve are well within the limits allowing their reuse (6) indicates that the concentrations of these parameters
in agriculture. Chloride and sodium are among the ions generally exceed the limits required by JISM. This
that are of concern in terms of specific ion toxicity. emphasizes the need for proper biological treatment to

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Characterization and Assessment… Ameen Sarairah and Ahmad Jamrah

reduce this organic content so that these requirements are Additionally, the treatment of the 300 m3/day
adhered to. Similar conclusion can be reached when the (constituting 75% of fresh water consumption (Viessman
bicarbonate and phosphorus concentrations are et al., 2005)) of slaughterhouse wastewater generated in
considered. Amman can be estimated at 60 JD (US $90) per day
(HAL, 2007), including capital, operational and
Economical Feasibility of Treatment and Reuse maintenance costs during a 15 years of the project life
Any applied treatment technology should be cycle. Furthermore, the WAJ imposes a treatment charge
applicable, cost effective, and environmentally sounds. to the Amman slaughterhouse based on the following
Tankers belonging to MOGA have transported more than surcharge equation (WAJ, 2007):
80,000 m3 of fresh water in the year 2006 for agricultural
× (COD − 1500)
Q
Surcharege Fee ( J .D) = 0.05 ×
purposes. This water constitutes a small portion of all 1000
fresh water consumed by MOGA to irrigate parks and Where, Q refers to amount of fresh water
gardens throughout the city. The estimated cost of tanker consumption. Accordingly, based on 300 working days
water stands at 1.0 JD (US $1.4) per cubic meter per year, 400 m3 of daily water consumption, and an
(MOGA, 2006). average yearly COD concentration of raw wastewater of
As stated earlier, the blood capturing system handles 5,654 mg/l, it can be estimated that a total of cost of
about 15 m3 of blood per day, with a COD concentration 140,000 J.D (US $200,000) should be incurred for the
of 375,000 mg/l. Management of the captured blood by disposal of wastewater. A summary of the yearly cost-
anaerobic digestion costs MOGA 20 JD (US $28) per m3, benefit analysis related to the treatment and reuse of
and results in generation of biogas and electricity with a Amman slaughterhouse wastewater shows a net earning
payback of 50 JD (US $70) (JBO, 2007). of 87,000 J.D. (US $138,000), as presented in Table (7).

Table 7. Annual cost-benefit analysis related to the treatment and reuse of


Amman slaughterhouse wastewater.
Item Quantity (m3) Cost (J.D.) Earning (J.D.)
Fresh water 120,000 120,000 --------------
Wastewater 90,000 18,000 90,000
Blood capturing 4,500 90,000 225,000
Total 228,000 315,000

4. CONCLUSIONS (JISM) requirements related to the reuse of reclaimed


wastewater for the agricultural purposes, while the
The study concluded that the Amman slaughterhouse concentration of (TDS, pH, EC, Fe, Mn, Ca, Mg, Na, Cl-,
wastewater effluents are biologically treatable, SO-24, SAR, and NO-3 as N) parameters are acceptable.
preferentially by using anaerobic biological treatment. Screening the effluent for solid removal proved to be
The TSS concentration contributes significantly to the significant in reducing the biological loads. The captured
organic composition of the raw samples compared to blood and suspended solids are feasible enough to be
screened samples. The concentration of (TCOD, BOD5, treated by anaerobic biological treatment. The treatment
TSS, P, HCO-3, and TN) parameters of the screened and reuse of Amman slaughterhouse for agricultural
samples exceed the maximum allowable limits based on purposes are adequate.

NOMENCLATURE

MOGA: Municipality of Greater Amman


JISM: Jordan Institute of Standards and Meteorology
WAJ” Water Authority of Jordan
BOD5: 5-day biochemical oxygen demand (mg/l)
EC: electric conductivity (dS/m)

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Dirasat, Engineering Sciences, Volume 35, No. 2, 2008

NH3-N: ammonia as nitrogen (mg/l)


NH+4-N: ammonium as nitrogen (mg/l)
NO-2-N: nitrite as nitrogen (mg/l)
NO-3-N: nitrate as nitrogen (mg/l)
ON: organic nitrogen (mg/l)
SAR: sodium- adsorption ratio
SCOD: soluble chemical oxygen demand (mg/l)
TCOD: total chemical oxygen demand (mg/l)
TDS: total dissolved solids (mg/l)
TKN: total kjeldahl nitrogen (mg/l)
TS: total solids (mg/l)
TSS: total suspended solids (mg/l)
TVS: total volatile solids (mg/l)
TVSS: total volatile suspended solids (mg/l)
VFA: volatile fatty acids (mg/l)

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Disposal, Reuse; New York, McGraw-Hill Inc. Sucoff, E, R. Feller, and D. Kanton. 1975. Deicing salt (sodium
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aerobic conditions. Journal of Chemical Technology and Viessman, W.; Hammer, M. Water Supply and Pollution
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fixed-film reactor for slaughterhouse wastewater treatment. Water Authority in Jordan, Ministry of Water and Irrigation.
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Pozo, R., D., Diez, V., Salazar, G. and Espinosa, J. 2006. The

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‫‪Dirasat, Engineering Sciences, Volume 35, No. 2, 2008‬‬

‫ﺘﺤﺩﻴﺩ ﻤﻜﻭﻨﺎﺕ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ ﺍﻟﻨﺎﺘﺠﺔ ﻋﻥ ﺃﻨﺸﻁﺔ ﺍﻟﻤﺴﺎﻟﺦ ﻓﻲ ﻋﻤ‪‬ﺎﻥ‬


‫ﻭﺘﻘﻴﻴﻡ ﻤﺩﻯ ﺇﻤﻜﺎﻨﻴﺔ ﻤﻌﺎﻟﺠﺘﻬﺎ‬

‫ﺃﻤﻴﻥ ﺍﻟﺼﺭﺍﻴﺭﺓ ﻭﺃﺤﻤﺩ ﺠﻤﺭﻩ*‬

‫ﻤﻠﺨـﺹ‬
‫ﺘﻌ ‪‬ﺩ ﺃﻨﺸﻁﺔ ﺍﻟﻤﺴﺎﻟﺦ ﻤﻥ ﺃﻜﺜﺭ ﺍﻟﺼﻨﺎﻋﺎﺕ ﺍﻟﺘﻲ ﻴﻨﺘﺞ ﻋﻨﻬﺎ ﺍﻟﻜﺜﻴﺭ ﻤﻥ ﺍﻟﺘﻠﻭﺙ ﺍﻟﺒﻴﺌﻲ ﺍﻟﺨﻁﻴﺭ‪ ،‬ﻭﻤﺴﻠﺦ ﺃﻤﺎﻨﺔ ﻋﻤﺎﻥ ﻤﻥ ﺍﻜﺒﺭ ﺍﻟﻤﺴﺎﻟﺦ‬
‫ﻓﻲ ﺍﻷﺭﺩﻥ ﻭﻴﺴﺘﻬﻠﻙ ﺃﻜﺜﺭ ﻤﻥ )‪ 400‬ﻡ‪ (3‬ﻴﻭﻤﻴﺎ ﻤﻥ ﺍﻟﻤﻴﺎﻩ ﺍﻟﺼﺎﻟﺤﺔ ﻟﻠﺸﺭﺏ‪.‬‬
‫ﺘﻬﺩﻑ ﻫﺫﻩ ﺍﻟﺩﺭﺍﺴﺔ ﺇﻟﻰ ﺘﺤﺩﻴﺩ ﻤﻜﻭﻨﺎﺕ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ ﺍﻟﻨﺎﺘﺠﺔ ﻋﻥ ﺃﻨﺸﻁﺔ ﻤﺴﻠﺦ ﺃﻤﺎﻨﺔ ﻋﻤﺎﻥ ﻭﺘﻘﻴﻴﻡ ﻤﺩﻯ ﺇﻤﻜﺎﻨﻴﺔ ﻤﻌﺎﻟﺠﺘﻬﺎ‬
‫ﺒﻴﻭﻟﻭﺠﻴﺎ ﻭﺘﻘﻴﻴﻡ ﺍﻟﺠﺩﻭﻯ ﺍﻻﻗﺘﺼﺎﺩﻴﻪ ﻹﻋﺎﺩﺓ ﺍﺴﺘﻌﻤﺎل ﺍﻟﻤﻴﺎﻩ ﺍﻟﻤﺴﺘﺼﻠﺤﺔ ﻓﻲ ﺍﻟﺭﻱ‪.‬‬
‫ﻤﺠﻤﻭﻋﺔ ﻤﻥ ﻋﻴﻨﺎﺕ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ ﺍﻟﻨﺎﺘﺠﺔ ﻤﻥ ﻨﺸﺎﻁ ﺍﻟﻤﺴﻠﺦ ﺘﻡ ﺠﻤﻌﻬﺎ ﺤﺴﺏ ﻁﺭﻴﻘﺔ ﺍﻟﻌﻴﻨﺔ ﺍﻟﻤﺭﻜﺒﺔ ﻭﺫﻟﻙ ﺨﻼل ﺍﻟﻔﺘﺭﺓ ﻤﻥ‬
‫)ﻜﺎﻨﻭﻥ ﺃﻭل( ‪ 2006‬ﺇﻟﻰ )ﺘﻤﻭﺯ( ‪.2007‬‬
‫ﺩﻟﺕ ﻨﺘﺎﺌﺞ ﺍﻟﺩﺭﺍﺴﺔ ﻋﻠﻰ ﻭﺠﻭﺩ ﺘﺒﺎﻴﻥ ﻓﻲ ﻤﺤﺘﻭﻴﺎﺕ ﻫﺫﻩ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ ﺨﻼل ﻓﺼﻠﻲ ﺍﻟﺼﻴﻑ ﻭﺍﻟﺸﺘﺎﺀ‪.‬‬
‫ﺘﺼﻨﻑ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ ﺍﻟﻨﺎﺘﺠﺔ ﻋﻥ ﻤﺴﻠﺦ ﻋﻤﺎﻥ ﺒﺄﻨﻬﺎ ﻗﻭﻴﺔ ﺍﻟﺘﺭﻜﻴﺯ ﻓﻴﻤﺎ ﻴﺘﻌﻠﻕ ﺒﻤﺤﺘﻭﻴﺎﺘﻬﺎ ﻤﻥ ﺍﻟﻁﻠﺏ ﺍﻟﻜﻴﻤﺎﻭﻱ ﻋﻠﻰ ﺍﻷﻜﺴﺠﻴﻥ‬
‫)‪ (COD‬ﻭﺍﻟﻁﻠﺏ ﺍﻟﺤﻴﻭﻱ ﻋﻠﻰ ﺍﻷﻜﺴﺠﻴﻥ )‪.(BOD5‬‬
‫ﺃﻅﻬﺭﺕ ﻨﺘﺎﺌﺞ ﺍﻟﺘﺤﺎﻟﻴل ﺒﺄﻥ ﻨﺴﺒﺔ ﺍﻟﻁﻠﺏ ﺍﻟﻜﻴﻤﺎﻭﻱ ﻋﻠﻰ ﺍﻷﻜﺴﺠﻴﻥ ﺇﻟﻰ ﻨﺴﺒﺔ ﺍﻟﻁﻠﺏ ﺍﻟﺤﻴﻭﻱ ﻋﻠﻰ ﺍﻷﻜﺴﺠﻴﻥ )‪(COD/BOD5‬‬
‫ﻜﺎﻨﺕ ﻋﺎﻟﻴﺔ ﺘﺸﻴﺭ ﺇﻟﻰ ﺇﻤﻜﺎﻨﻴﺔ ﺍﻟﻤﻌﺎﻟﺠﺔ ﺃﻟﺒﻴﻭﻟﻭﺠﻴﺔ ﻟﻬﺫﻩ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ‪.‬‬
‫ﺩﻟﺕ ﺍﻟﺩﺭﺍﺴﺔ ﻋﻠﻰ ﻭﺠﻭﺩ ﻨﺴﺏ ﻋﺎﻟﻴﺔ ﻤﻥ ﻤﺤﺘﻭﻴﺎﺕ ﺍﻟﻤﻭﺍﺩ ﺍﻟﻌﻀﻭﻴﺔ ﻭﺍﻟﻨﻴﺘﺭﻭﺠﻴﻨﻴﺔ ﻭﺍﻟﺘﻲ ﺍﺭﺘﺒﻁﺕ ﺒﺸﻜل ﻤﺒﺎﺸﺭ ﺒﺴﺒﺏ ﻭﺠﻭﺩ‬
‫ﺍﻟﻤﻭﺍﺩ ﺍﻟﺼﻠﺒﺔ ﺍﻟﻌﺎﻟﻘﺔ ﻤﻤﺎ ﻴﺸﻴﺭ ﺇﻟﻰ ﺇﻤﻜﺎﻨﻴﺔ ﺍﻟﻤﻌﺎﻟﺠﺔ ﺍﻟﺒﻴﻭﻟﻭﺠﻴﺔ ﺍﻟﻼﻫﻭﺍﺌﻴﺔ ﻟﻬﺫﺍ ﺍﻟﻨﻭﻉ ﻤﻥ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ ﻭﺒﻜﻔﺎﺀﺓ ﻋﺎﻟﻴﺔ‪.‬‬
‫ﺃﻅﻬﺭﺕ ﺍﻟﺩﺭﺍﺴﺔ ﺒﺄﻥ ﺍﻻﺴﺘﻌﻤﺎل ﺍﻟﻤﺒﺎﺸﺭ ﻟﻬﺫﻩ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ ﻷﻏﺭﺍﺽ ﺍﻟﺭﻱ ﻤﻼﺌﻡ ﻓﻴﻤﺎ ﻴﺘﻌﻠﻕ ﺒﻤﺤﺘﻭﺍﻫﺎ ﻏﻴﺭ ﺍﻟﻌﻀﻭﻱ ﻭﻏﻴﺭ‬
‫ﺍﻟﻤﻼﺌﻡ ﻓﻴﻤﺎ ﻴﺘﻌﻠﻕ ﺒﻤﺤﺘﻭﺍﻫﺎ ﺍﻟﻌﻀﻭﻱ‪.‬‬
‫ﺃﺨﻴﺭﺍ‪ ،‬ﺃﻅﻬﺭﺕ ﺍﻟﺘﺤﺎﻟﻴل ﺒﺄﻥ ﻤﻌﺎﻟﺠﺔ ﻤﻴﺎﻩ ﺍﻟﻤﺴﻠﺦ ﻭﺇﻋﺎﺩﺓ ﺍﺴﺘﻌﻤﺎﻟﻬﺎ ﻷﻏﺭﺍﺽ ﺍﻟﺭﻱ ﻤﺠﺩﻴﺔ ﻤﻥ ﺍﻟﻨﺎﺤﻴﺔ ﺍﻻﻗﺘﺼﺎﺩﻴﺔ ﻋﻨﺩ ﺘﻁﺒﻴﻕ‬
‫ﺍﻹﺩﺍﺭﺓ ﺍﻟﺠﻴﺩﺓ‪.‬‬
‫ﺍﻟﻜﻠﻤـﺎﺕ ﺍﻟﺩﺍﻟـﺔ‪ :‬ﺍﻟﻤﺴﺎﻟﺦ‪ ،‬ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ‪ ،‬ﻤﻌﺎﻟﺠﺔ ﺍﻟﻤﻴﺎﻩ ﺍﻟﻌﺎﺩﻤﺔ‪.‬‬

‫________________________________________________‬
‫* ﻗﺴﻡ ﺍﻟﻬﻨﺩﺴﺔ ﺍﻟﻤﺩﻨﻴ‪‬ﺔ‪ ،‬ﺍﻟﺠﺎﻤﻌﺔ ﺍﻷﺭﺩﻨﻴﺔ‪ .‬ﺘﺎﺭﻴﺦ ﺍﺴﺘﻼﻡ ﺍﻟﺒﺤﺙ ‪ ،2008/1/28‬ﻭﺘﺎﺭﻴﺦ ﻗﺒﻭﻟﻪ ‪.2008/6/9‬‬

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