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Half equations
Cathode reactions
Positively charged ions gain electrons at the cathode. These are half equations for
some reactions at the cathode:
Na+ + e- → Na
Pb2+ + 2e- → Pb
2H+ + 2e- → H2
Example
Balance the half equation for the formation of aluminium during electrolysis:
Al3+ + e- → Al.
The balanced half equation is: Al3+ + 3e- → Al (because three negatively charged
electrons are needed to balance the three positive charges on the aluminium ion).
Question
Write a balanced half equation for the formation of calcium from a calcium ion, Ca2+.
Anode reactions
1
Write a balanced half equation for the formation of bromine, Br 2,
from bromide ions, Br-.