Pr

oyec
ciones
,Vol
.13 No.2,Oc
tubr
ede2015

!"#$%&'()!(*+,-'%$#(!'(*./*("!)%*'0!("*0!+%*1!,()!(
2*3#($#,0#(4(,!./+*()%,5#,%$%&'(6'*1
Jorge Martín Meichtry 1, Elizabeth Graciela De Seta 1,2, Fernando Damián
Reina1, Fernando Isaac Mugrabi1 y Esteban José Domingo 1,3
7'%8!+,%)*)(9!$'#1&.%$*(:*$%#'*1;(<*$/10*)( !.%#'*1(=/!'#,(>%+!,;(?!5*+0*"!'0#()!(@'.!'%!+A*(
B/A"%$*1;(7?=CB/A"%$*(2;(?!5*+0*"!'0#(@'.!'%!+A*(D%8%13;(E!)+*'#(FGH(IDHHJF>>BK;(
D%/)*)(>/0&'#"*()!(=/!'#,(>%+!,;(>+.!'0%'*(

"!%$L0+4M$'!*N.#8N*+
!$%2%)#(!1(HO()!("*4#()!(PQHG;(*5+#2*)#(!1(HR()!(3/1%#()!(PQHG

Resumen

S!( !,0/)%&( 1*( $*5*$%)*)( )!( +!"#$%&'( )!( *+,-'%$#( "!)%*'0!( *),#+$%&'( 4T #( $#C5+!$%5%0*$%&'(
!"51!*')#("*0!+%*1!,(!$#'&"%$#,($#"#(*+$%11*('*0/+*1(4(L%!++#($!+#8*1!'0!(I<!IQKK($#"!+-
$%*1;( "%$+#5*+0%$/1*)#( 4( $#"#( 8%+/0*N( S!( +!*1%U*+#'( !V5!+%"!'0#,( )!( +!"#$%&'( )!( >,I@@@K( 4(
>,IWK(5+!,!'0!(!'(,#1/$%#'!,(*$/#,*,(IX >,Y 0
(Z(G(".([ -1
;(5\(JK;(!"51!*')#($#'$!'0+*$%#'!,(
8*+%*21!,()!(*+$%11*(4(<!IQK] (5*+*(!1($*,#()!(1*(*+$%11*;(,!(!,0/)%&(1*($%'-0%$*()!(+!"#$%&'(4(!1(
!^!$0#()!1(5\(IG;G(_(5\(_(`;GKN(9*"2%-'(,!(!,0/)%&(1*(1%V %8%*$%&'()!1(>,(+!0!'%)#(!'(1#,(+!,%-
)/#,(.!'!+*)#,;(1#,($/*1!,(^ /!+#'(,#"!0%)#,(5+!8%*"!'0!(*()%,0%'0#,(0+*0*"%!'0#,(0-+"%$#,N(
S!()!0!+"%'&(a/!(,#'('!$!,*+%*,($#'$!'0+*$%#'!,()!(P;Gb("T 8()!(*+$%11*(#(Q;QGb("T 8()!(
<!IQK(5*+*(1#.+*+(/'*(+!"#$%&'(c(FGb(5*+*(*"2*,(!,5!$%!,()!(>,N([ #,(!,0/)%#,()!(+!"#$%&'(
$#'(*+$%11*(%')%$*+#'(a/!(1*($%'-0%$*()!(*),#+$%&'()!(>,I@@@K(4(>,IWK(+!,5#')%&(*(/'($#"5#+-
0*"%!'0#(2%C!V 5#'!'$%*1(4(a/!(1*(+!"#$%&'()!(>,IWK(5#+(*+$%11*(!,("*4#+(*(8*1#+!,(d$%)#,;(
"%!'0+*,(a/!(1*(5+!,!'$%*()!("*0!+%*(#+.d'%$*(Id$%)#($A0+%$#K()%,"%'/4!(1*(+!"#$%&'N(e'(0#)#,(
1#,($*,#,;(,!(#2,!+8&(/'*(1%V %8%*$%&'()!,5+!$%*21!(5*+*(>,IWK;("%!'0+*,(a/!(5*+*(>,I@@@K(!,(
%'^!+%#+(*1(Ob()!1(>,(0#0*1(+!"#8%)#N

PALABRAS CLAVE: (> Sf:@Dg(h( eEgD@i:(C(> D@[[

>S(:>97 >[eS(h(\@e g(De gW>-
[e:9e(C([@j@W@>D@i:(?e(> Sf:@Dg

Abstract
9L!(#23!$0%8!(#^ (0L%,(k#+l(k*,(0#(,0/)4(0L!(*+,!'%$(+!"#8*1($*5*$%04(#^ (1#k($#,0("*0!+%*1,;(,/$L(
*,('*0/+*1($1*4(#+(U !+#8*1!'0(%+#'(I<!IQKK;(2#0L(*,("%$+#5*+0%$/1*0!)("*0!+%*1(#+(*,(%+#'(k##1N( !-
"#8*1(!V5!+%"!'0,(^ #+(>,I@@@K(*')(>,IWK(IX >,Y0
(Z(G(".([ -1
;(5\(JK(k%0L(8*+4%'.($#'$!'0+*0%#',(#^ (
$1*4(*')(<!IQK(k!+!(5!+^ #+"!)N(<#+($1*4;(0L!(l%'!0%$,(#^(+!"#8*1(*')(0L!(!^ ^
!$0(#^(5\(I5\(_(GNG(_(
`NGK(k*,(,0/)%!)N(>,(1!*$L%'.(#^ (0L!(,#1%)(k*,0!,(.!'!+*0!)(*')(5+!8%#/,14(,/23!$0!)(0#()%^ ^!+!'0(
L!*0(0+!*0"!'0,(k*,(*1,#(,0/)%!)N
9L!(+!,/10,(#20*%'!)(%')%$*0!(0L*0($#'$!'0+*0%#',(#^ (PNGb("T 8(^
#+($1*4(#+(QNQGb("T 8(^
#+(2#0L(<!IQK(
"*0!+%*1,(*+!(+!a/%+!)(^ #+(>,(+!"#8*1,(L%.L!+(0L*'(FGb(^ #+(2#0L(>,IWK(*')(>,I@@@KN(9L!(,0/)%!,(#^ (
*+,!'%$(+!"#8*1(k%0L($1*4(%')%$*0!)(0L*0(0L!(*),#+50%#'(l%'!0%$(600!)(*(2%C!V5#'!'0%*1("#)!1(*')(
0L*0(>,IWK(+!"#8*1(k*,(L%.L!+(*0(1#k(5\(8*1/!,;(kL%1!(%0(k*,(%'L%2%0!)(%'(0L!(5+!,!'$!(#^ (#+.*'%$(
"*00!+(I$%0+%$(*$%)KN(@'(*11($*,!,;(*('!.1%.%21!(>,IWK(1!*$L%'.(k*,(#2,!+8!);(kL!+!*,(^ #+(>,I@@@K(%0(
k*,(1!,,(0L*'(Ob(#^ (0#0*1(>,(+!"#8!)N

KEYWORDS:> Se:@D(h( eEgW>[

C(:>97 >[(D[
>mS(C(ne g(W>[e:9(@ g:(C(> Se:@D([e>D\@:o

\*'(5*+0%$%5*)#()!(1*(!1*2#+*$%&'()!(!,0!(0+*2*3#p
(E*%*(?*'*(D*,0%.1%*(1;([
/%,(e/.!'%#([
*' 1,2 47
 Introducción retenidoenes tosr esi
duosr es ultaf undamental
5*+*()!0!+"%'*+(*10!+'*0%8*,(5*+*(,/()%,5#,%$%&'(
q#+(+*U #'!,(.!#1&.%$*,('*0/+*1!,(!1(*./*(,/20!- 6'*1;(4*(a/!(/'*(1%V%8%*$%&'("*4#+(*(1#,(1A"%0!,(
++d'!*( 5/!)!( $#'0!'!+( !1!8*)*,( $#'$!'0+*$%#- 63*)#,(%"51%$*(a/!(1#,(+!,%)/#,()!2!+d'()%,5#-
'!,()!(*+,-'%$#(%'#+.d'%$#;(L*$%-')#1*('#(*50*( '!+,!($#"#(+!,%)/#,(5!1%.+#,#,N
5*+*(!1($#',/"#(L/"*'#N(e,0*(,%0/*$%&'(,!(5+!-
,!'0*(!'()%8!+,*,(U #'*,()!(1*( !5r21%$*(>+.!'- e,0!( 0+*2*3#( !,0/)%&( 1*( +!"#$%&'( )!( >,IWK( 4(
0%'*(4(*^!$0*(!,5!$%*1"!'0!(*(+!.%#'!,(+/+*1!,(#( >,I@@@K( )!( )%8!+,*,( "*0+%$!,( *$/#,*,;( "!)%*'-
'r$1!#,()!(5#21*$%&'()%,5!+,*;('#($#'!$0*)*(*( te pr oces os de ads orc
ión y c o-precipitaci
ón
+!)!,( )!( *./*( 5#0*21!N( e1( *./*( !,( 1*( 5+%'$%5*1( conmater ialesec onómicos ,c omoar ci
llasnatu-
+/0*()!(!V5#,%$%&'()!(1*,(5!+,#'*,(*1(*+,-'%$#;( +*1!,( 4( L%!++#( $!+#8*1!'0!N( >)!"d,( ,!( !,0/)%&(
4*(,!*(*(0+*8-,()!(1*(%'.!,0*()%+!$0*(#(*(0+*8-,( !1( !^ !$0#( !'( 1*( +!"#$%&'( )!( )%8!+,*,( 8*+%*21!,(
)!(*1%"!'0#,($/10%8*)#,($#'(!,0*(*./*N !V5!+%"!'0*1!,($#"#(1*(*$%)!U (I5\K()!1("!)%#(
4(1*(5+!,!'$%*()!("*0!+%*(#+.d'%$*;(!"51!*')#(
e1(*+,-'%$#(!,(*$/"/1*21!(!'(!1(#+.*'%,"#(5#+( d$%)#($A0+%$#(ID%0K($#"#($#"5/!,0#("#)!1#N(S!(
!V5#,%$%&'($+&'%$*;(5/)%!')#(#$*,%#'*+(\%)+#*+- model ól ac apac idadder emoc ióndel osdi s
tin-
,!'%$%,"#(D+&'%$#( !.%#'*1(e')-"%$#(I\>D eK( 0#,("*0!+%*1!,(*,A($#"#(0*"2%-'(1*($%'-0%$*()!(
*,A($#"#(0*"2%-'()%8!+,#,(0%5#,()!($d'$!+N([*( *),#+$%&'()!(>,IWK(4(>,I@@@K(!'(*+$%11*N(q#+(r1-
$#'$!'0+*$%&'("dV%"*(5!+"%,%21!(5*+*(*+,-'%$#( 0%"#;( ,!( !8*1/&( 1*( !,0*2%1%)*)( )!( 1#,( +!,%)/#,(
!'(*./*;(!,0*21!$%)*(5#+(1*(g+.*'%U *$%&'(E/'- ,&1%)#,(.!'!+*)#,(5#+(!1(/,#()!(*+$%11*('*0/+*1!,(
)%*1()!(1*(S*1/)(4(!1(D&)%.#(>1%"!'0*+%#(>+.!'- "!)%*'0!(!,0/)%#,()!(1%V%8%*$%&'()!(*+,-'%$#N(
0%'#;(!,()!(HQ(s.([ -1
(IgES;(PQQ`K;(ID>>;PQQJKN
Parte experimental
eV%,0!'( )%8!+,#,( 5+#$!,#,( 5*+*( 1#.+*+( !1( *2*0%-
mi entodear s énico.Lael ecci
óndeunodeel los Materiales y métodos
)!5!')!+d()!()%,0%'0#,(^ *$0#+!,p ($#'$!'0+*$%&'(
)!( *+,-'%$#( 4( )!( #0+#,( %#'!,( !'( !1( *./*;( 0%5#( [*( *+$%11*( '*0/+*1( I1*0!+%0*K( /0%1%U
*)*( !'( 1#,( !V
-
)!(^ /!'0!;(.!#.+*^ A*()!1(1/.*+;()%,5#'%2%1%)*)(4( 5!+%"!'0#,(^ /!(!V0+*%)*()!(1*(q+#8%'$%*()!(E%-
$#,0#( )!( 1#,( %',/"#,;( 5#21*$%&'( *( ,!+8%+;( !0$N( ,%#'!,] (5+!8%#(*(,/(/0%1%U *$%&'(^ /!(5+#$!,*)*(!'(
e'0+!( 1#,( "-0#)#,( *51%$*21!,( !'( !,0#,( $*,#,( *( "#+0!+#(4(0*"%U *)*(!'(/'(610+#()!("*11*(PQ(I0*-
1*( +!"!)%*$%&'( )!( >,( I[%00!+( 4( $#1*2#+*)#+!,;( "*v#()!(5*+0A$/1*(%'^ !+%#+(*(Q;`w(""KN(
PQHQK( 5/!)!'( "!'$%#'*+,!p ( *K( 5+#$!,#,( )!(
$#*./1*$%&'C5+!$%5%0*$%&'( $#'( ,*1!,( )!( *1/"%- S!( !"51!*+#'( )#,( "*0!+%*1!,( )!( L%!++#( $!-
'%#(#(L%!++#] (2K(*),#+$%&'($#'($*+2&'(*$0%8*)#;( +#8*1!'0!( I<!IQKKp ( HK( L%!++#( "%$+#5*+0%$/1*)#(
*1r"%'*(*$0%8*)*;(*+!'*;(*+$%11*,(4(($#"5/!,0#,( Is<!IQKK( )!( *10*( 5/+!U *( IxFF;`bK;( $#'( /'( 0*-
)!(L%!++#(I%'$1/4!')#(!1(<!($!+#8*1!'0!K;(,%!')#( "*v#( )!( 5*+0A$/1*( $#"5+!')%)#( "*4#+%0*+%*-
!,0#,(r10%"#,(1#,("d,(!6$%!'0!,] ($K(+!,%'*,()!( "!'0!( Ix( FGbK( !'0+!( "*11*( PQ( IQ;`w( ""K( 4(
%'0!+$*"2%#(%&'%$#] ()K(610+*$%&'(5#+("!"2+*'*,( "*11*(PQQ(IQ;QJw(""K] (PK(8%+/0*()!(L%!++#($#-
I!,5!$%*1"!'0!( r0%1( $/*')#( !1( >,( ,!( !'$/!'0+*( "!+$%*1(I8<!IQKKN(
!'(^ #+"*(5*+0%$/1*)*K(4(&,"#,%,(%'8!+,*(ISL*+-
"*(4(S#L';(PQQFK(I:!k$#"2!(4(E#11!+;(PQQtK( [#,(+!*$0%8#,(!"51!*)#,(^ /!+#'()!($*1%)*)(*'*-
I:#/2*$0!5(4($#1*2#+*)#+!,;(PQHQK 1A0%$*](4(!1(>./*()!,0%1*)*;(!"51!*)*(5*+*(5+!-
par arlass oluci
onesc onteniendoAsatr atar,de
e'( d+!*,( +/+*1!,( ,!( 8%!'!'( )!,*++#11*')#( ,%,- 2*3*($#')/$0%8%)*)N
0!"*,( )!( *2*0%"%!'0#( )!( *+,-'%$#( /0%1%U *')#(
*+$%11*,( '*0/+*1!,( 1#.+*')#( +!"#$%#'!,( "*- e'(1#,(!V5!+%"!'0#,(+!*1%U *)#,()/+*'0!(0+!,(L#-
4#+!,( *1( FGb( I?!( e,5*+U *;( u#'.( )!( E!)%'*;( +*,(#("!'#,(,!(!"51!&(*.%0*$%&';(5+#8%,0*("!-
HFF`KN(e,0#,(0+*0*"%!'0#,(0%!'!'(1*(8!'0*3*()!( )%*'0!(/'(*.%0*)#+(#+2%0*1($#'($*1!^
*$$%&'(<!+$*N(
,/(2*3#($#,0#(4(,%"51%$%)*)()!(*51%$*$%&';(5!+#( Parati emposmay oresatr eshor asnos eus ó
+!a/%!+!'(.+*')!,()#,%,()!(*+$%11*(5*+*(+!)/$%+( *.%0*$%&'(!'(1#,(!V5!+%"!'0#,N
1*( $#'$!'0+*$%&'( )!( *+,-'%$#( *( 8*1#+!,( %./*1!,(
#(%'^ !+%#+!,(*(1#,(+!$#"!')*)#,(5#+(1*(gES;(1#( Caracterización de la arcilla
a/!(*(,/(8!U (%"51%$*(1*(.!'!+*$%&'()!(.+*')!,(
$*'0%)*)!,( )!( +!,%)/#,( ,&1%)#,( a/!( 1/!.#( )!- Lac ompos icióndel aar cill
as edeter minóme-
2!'( ,!+( )%,5/!,0#,] ( 1*( !,0*2%1%)*)( )!1( *+,-'%$#( )%*'0!( *'d1%,%,( !1!"!'0*1( 5#+( @DqCgeS;( 5+!8%*(
PROYECCIONES - Publicación de investigación y posgrado de la Facultad Regional Buenos Aires

48
)%,#1/$%&'( !"51!*')#( /'( L#+'#( )%.!,0#+( )!(
"%$+##')*,(>:9g:(q>> (E/10%k*8!(OQQQ(,!-
.r'( !1( 5+#$!)%"%!'0#( )!,$+%0#( !'( 1*,( '#+"*,(
7SCeq>( OQGH( 4( OQGP( I>.*U U%( 4( q%+#1*;( PQQQK]
( e'(1#,(!V5!+%"!'0#,(!"51!*')#(*+$%11*,;(/'*(8!U (
1#,( 5+%'$%5*1!,( !1!"!'0#,( %'8#1/$+*)#,( !'( 1*(
+!"#$%&'()!(>,(,!($/*'0%6$*+#'(5#+(!1("-0#)#(
)!(!,0d')*+(!V 0!+'#;($#'(/'(!,5!$0+&"!0+#()!(
!"%,%&'(&50%$*(5#+(51*,"*(%')/$0%8*"!'0!(*$#-
51*)#(I@DqCgeSK("*+$*(qe y@:(e[ Ee ("#)!1#(
Opti ma2000 DV .
>)!"d,( ,!( +!*1%U &( /'( !,0/)%#( )!( $*+*$0!+%U
*-
$%&'( )!( 1*( *+$%11*( "!)%*'0!( D*1#+%"!0+A*( ?%^!-
+!'$%*1()!(=*++%)#(I?SDK;(!"51!*')#(/'(!a/%5#(
BPQ("*+$*(9>(@',0+/"!'0,N(q*+*(!11#(,!(5!,&(
*5+#V N( P( ".( )!( "/!,0+*( !'( $d5,/1*( L!+"-0%-
$*(4(,!(+!*1%U *+&(/'*($#++%)*(*(HQ(z DT"%';($#'(
atmós feradeN2;( $#'( /'( {/3#( )!( GQ( "1T "%';(
)!,)!(0!"5!+*0/+*(*"2%!'0!(L*,0*(GGQ(z DN
[*(^+*$$%&'()!(,&1%)#,(8#1d0%1!,()!(1*(*+$%11*(,!(
deter minómedi antec al
cinac i
óndel asmues tra
*(JQQ(RD()/+*'0!(G(L#+*,(!'(*%+!;($#'(/'(L#+'#(
!1-$0+%$#("*+$*(g [ ;("#)!1#(\(JQH([ N
Ensayos de remoción de As
D#'(!1(#23!0#()!(!8*1/*+(1*($*5*$%)*)()!(+!"#-
$%&'()!(>,IWK()!(/'*(,#1/$%&'(*$/#,*;(,!(+!*-
1%U*+#'(!V 5!+%"!'0#,($#'($#'$!'0+*$%&'(%'%$%*1(
)!(>,IWK($#',0*'0!(4($#'$!'0+*$%#'!,(8*+%*21!,(
)!(*+$%11*;(s<!IQK;(8<!IQK;(4("!U $1*,()!(*+$%11*(
4( s<!IQK;( !'( !+1!'"!4!+,( )!( PGQ( "1N( PQQ( "1(
)!(,#1/$%&'()!(>,(I$#'$!'0+*$%&'Z(G(".([ -1
K(,!(
$#1#$*+#'(!'(/'(e+1!'"!4!+(4(,!(*3/,0&(*1(5\(
r equer idoempl eandos oluc i
onesc onc entradas
)!( \D1( #( :*g\( IQ;H( EK] ( /'*( 8!U ( *3/,0*)#( !1(
5\;( ,!( 0#"&( /'*( "/!,0+*( I8*1#+( %'%$%*1K( 4( 6-
'*1"!'0!(,!(*.+!.&(1*("*,*('!$!,*+%*()!("*-
0!+%*1( $#"#( ,&1%)#;( )!0!+"%'*)*( 5+!8%*"!'0!(
"!)%*'0!(5!,*)*;(2*3#(^ /!+0!(*.%0*$%&'N(S!(0#-
mar onmues trasper iódic asde5mL ,lasc ual es
^/!+#'(610+*)*,(*(0+*8-,()!(/'(610+#()!('%0+*0#(
)!( $!1/1#,*( IQ;PP( s"( )!( 5#+#K( 4( PG( ""( )!(
)%d"!0+#;( 5*+*( *'*1%U *+( !1( .+*)#( )!( +!"#$%&'(
)!(>,IWK(4T #(>,(0#0*1N([#,(!',*4#,(,!(+!*1%U *+#'(
*(0!"5!+*0/+*(*"2%!'0!;(!'0+!(Ht(4(PQ(RD(4(!1(
tiempoder eac ciónempl eadof uede24 hpar
1*(*+$%11*(4(Ht`(L,(5*+*(!1(<!IQK(4(1*,("!U $1*,(
)!(*+$%11*(4(<!IQKN
7'*(8!U ()!0!+"%'*)*(1*($#'$!'0+*$%&'("A'%"*(
'!$!,*+%*( )!( "*0!+%*1( *2,#+2!'0!( 5*+*( 1#.+*+(
/'*(+!"#$%&'("*4#+(*1(FGb()!1(>,(%'%$%*1"!'-
0!(5+!,!'0!;(,!(!,0/)%&(!1(!^ !$0#()!1(5\()!(1*(
,#1/$%&'(*(0+*0*+(IG;G(_(5\(_(`;GK(!'(1*(+!"#-
$%&'()!(>,IWK(4(>,I@@@KN((
6'*1%U*)#(!1(!',*4#(,!(,!5*+&(!1(,&1%)#("!)%*'0!(
,#1/$%&'(4(1/!.#(^
/!(,#"!0%)#(*(!',*4#,()!()!,-
orción.
!"#$%&'"'%(#)*+),-).)/+
[*( $/*'0%6$*$%&'( )!( *+,-'%$#( 4( L%!++#( )%,/!10#,(
!'(1*,(,#1/$%#'!,(0+*0*)*,;(1/!.#()!1(5!+A#)#()!(
!V5#,%$%&'(*(1#,("%,"#;(,!(+!*1%U &("!)%*'0!(!,-
5!$0+#^#0#"!0+A*()!(*2,#+$%&'("#1!$/1*+(I!,5!$-
0+#^#0#"!0+A*( 7WCW%,%21!K;( $#'( /'( !,5!$0+#^ #0&-
"!0+#()!()#21!(L*U (SL%"*)U /;("#)!1#(7WCHJQQ;(
!a/%5*)#($#'($!1)*,()!($/*+U #()!(H($"()!(5*,#(
óptico.
La téc ni ca empl eada en l a deter minac ión de
>,IWK( ,!( 2*,&( !'( 1*( '#+"*( @Sg( t`J`CH( 5*+*( 1*(
)!0!+"%'*$%&'()!(^ #,^ *0#,(!'(*./*(I>^'#+;(HFFJK((
"#)%6$*)*(5#+([!'#21!(4($#1*2#+*)#+!,(IPQQOKN(
[*()!0!+"%'*$%&'()!(>,I@@@K(,!(+!*1%U &("!)%*'0!(
)!0!+"%'*$%&'()!(>,(0#0*1(5#+(#V%)*$%&'(5+!8%*()!1(
>,I@@@K( $#'( 5!+"*'.*'*0#( )!( 5#0*,%#( IyE'g4K;(
,!.r'([!'#21!(4($#1*2#+*)#+!,(IPQQOKN(
[*($#'$!'0+*$%&'()!(<!I@@K(,!()!0!+"%'&((5#+(^ #+-
"*$%&'( )!1( $#"51!3#( $#'( #C^!'*'0+#1%'*( IS$L%10;(
HFtFKN([*($#'$!'0+*$%&'()!(<!I@@@K(,!(+!*1%U &(5#+(
^#+"*$%&'( )!1( $#"51!3#( $#'( !1( *'%&'( 0%#$%*'*0#(
Iu##),;(HFwHKN
Estudio de desorción de As
[#,( +!,%)/#,( ,&1%)#,( #20!'%)#,( 1/!.#( )!1( 0+*0*-
"%!'0#()!(>,IWK(4(>,I@@@K($#'(*+$%11*(^/!+#'(,#"!-
0%)#,(*()%,0%'0#,(0+*0*"%!'0#,(0-+"%$#,p (HK(,!$*)#(
!'(!,0/^ *(*(OQ(zD(5#+(Ht`(L] (PK(,!$*)#(!'(!,0/^ *(
*(HQQ(zD(5#+(Ht`(L;(4(OK($*1$%'*$%&'(!'(L#+'#(*(
JQQ(zD(5#+(G(LN(>($#'0%'/*$%&';(!,0*,("/!,0+*,(
^/!+#'( ,#"!0%)*,( *( !V5!+%"!'0#,( )!( 1%V%8%*$%&'(
$#',%,0!'0!,(!'(1*(,/,5!',%&'(!'(*./*()!,0%1*)*(*(
5\(J()!(/'*($#'$!'0+*$%&'()!(w(b("T 8()!(*+$%11*(
)/+*'0!(J()A*,(*(0!"5!+*0/+*(*"2%!'0!(IHt(h(PQ(
zDK(4(2*3#(*.%0*$%&'N([/!.#(,!(0#"*+#'("/!,0+*,(
a 4(,!(*'*1%U &(1*($#'$!'0+*$%&'()!(>,IWK(4(>,I@@@K(
empl eandol osmétodosdes cri
tosanter i
or mente.
Resultados y discusión
Caracterización de la arcilla
Lac
onc
entr
aci
ón del
osel
ementosal
umi
nioy

( !"#$%&'()!(*+,-'%$#(!'(*./*("!)%*'0!NNN
J.M.Meichtry et al.-

49
 Tabla 1.Composición química de la arcilla

L%!++#;(5+%'$%5*1!,(!1!"!'0#,($#',0%0/0%8#,()!(1*( *(1*()!,L%)+#V%1*$%&'()!(1#,(.+/5#,(L%)+#V%1#()!(
*+$%11*( %'8#1/$+*)#,( !'( 1*( +!"#$%&'( )!( >,( I?!( 1*( *+$%11*;( ,!.r'( e,$*1!+*( E!3%*( IPQHOK;( $#'6+-
W%0+!( 4( $#1*2#+*)#+!,;( HFFH] ( S/11%8*'( 4( >11!;( "*')#(1*(5+!,!'$%*()!(&V%)#,()!(>1N
HFFtK;(,!("/!,0+*'(!'(1*(9*21*(HN
Capacidad de remoción
[*,( $#'$!'0+*$%#'!,( )!( >1( 4( <!( !'( 1*( "/!,0+*(
)!( *+$%11*( "%,%#'!+*( I1*0!+%0*K( !"51!*)*( $#"#( e1(*'d1%,%,()!(1*($*5*$%)*)()!(+!"#$%&'()!(>,IWK(
"*0!+%*1( *),#+2!'0!;( ,#'( )!( %./*1( #+)!'( *( 1*,( !"51!*')#(*+$%11*;(L%!++#($!+#8*1!'0!(#(,/("!U -
obteni daspar amues tr
asdes uel osmi sioner os $1*(,!(+!*1%U &(!"51!*')#()%,0%'0*,($#'$!'0+*$%#-
!'( #0+#,( !,0/)%#,( .!#1&.%$#,( +!1*$%#'*)#,( $#'( '!,( )!( !,0#,( "*0!+%*1!,( ,%./%!')#( !1( 5+#$!)%-
elabati mi entodear s éni co,dondepr edomi nan "%!'0#( )!,$+%0#( !'( 1*( ,!$$%&'( !V5!+%"!'0*1N( >(
1*( $*#1%'%0*( 4( 2!%)!11%0*( I*"2#,( "%'!+*1!,( +%$#,( $#'0%'/*$%&';( 1*( "!U $1*( ,!( )!3&( 2*3#( *.%0*$%&'(
enAl O
2 3
K($#"#($#"5#'!'0!("*4#+%0*+%#;(3/'0#( y se toma ron muestra sper iódic ashas taqueno
*( &V%)#,( )!( ,%1%$%#;( L%!++#( 4( #0+#,( $#',0%0/4!'- ,!(#2,!+8*+#'($*"2%#,(!'(1*($#'$!'0+*$%&'()!(
0!,("!'#+!,(I<!+'*')!U (9/+%!1(4($#1*2#+*)#+!,;( >,(!'("/!,0+*,(,/$!,%8*,N(S!($#',%)!+&(*()%$L*(
PQQGKN conc entrac i
ón l ac orr espondi ente alequi li
br i
o
dels istema.Par alasmues tr
asdear ci
llaes ta
[#,( ,&1%)#,( 8#1d0%1!,;( )!0!+"%'*)#,( 5#+( 5!,*- $#'$!'0+*$%&'()!(!a/%1%2+%#(,!(*1$*'U &(*(1*,(Pw(
)*(*'0!,(4()!,5/-,()!(1*($*1$%'*$%&'(*(JQQ(z D( L;("%!'0+*,(a/!(5*+*(1*,("/!,0+*,()!(<!IQK(!,0!(
$#',0%0/4!'(!1(Jb("T "()!1(0#0*1()!(1*("/!,0+*N ti empof uede168h.Losr esul tadosobteni dos
,!(%')%$*'(!'(1*(<%./+*(PN
e1(0!+"#.+*"*($#++!,5#')%!'0!(*(1*(*+$%11*(!"-
51!*)*($#"#("*0!+%*1(*),#+2!'0!(I<%./+*(HK(5+!- S!( 5/!)!( *5+!$%*+( a/!( 5*+*( /'*( +!"#$%&'( )!(
,!'0*(P(!')#0!+"*,($*+*$0!+A,0%$#,N(e1(5+%"!+#;( >,IWK( c( FGb( ,!( +!a/%!+!( X *+$%11*Y( c( P;Gb;(
a/!(,!(!V0%!')!(!'0+!(1#,(GQ(4(*(HQQ(RD;(!,()!- X s<!IQKY ( c( Q;QGb( 4( X8<!IQKY ( c( Q;Gb;( 5#+( 1#(
2%)#(*(1*(!8*5#+*$%&'()!(1*(L/"!)*)(*),#+2%)*N( a/!(5/!)!($#'$1/%+,!(a/!(!1("*0!+%*1("d,(!6-
e'(,!./')#;($#'("dV%"#(!'((GQtNtP(RD(,!()!2!( $%!'0!(!,(!1(s<!IQKN(e'(0#)#,(1#,($*,#,(,!(#2-

Fig.1.Calorimetría Dif
erencial de Barrido (
DSC)de arcilla misionera
PROYECCIONES - Publicación de investigación y posgrado de la Facultad Regional Buenos Aires

50
Fig.2.Ef ecto de la masa de adsorbente en la concentración de As( V)en solución.
D#')%$%#'!,p(X>,IWKYQ(Z(G(".([ -1
;(5\(J(I$0!NK;(9(Z(PQ(RDN(9%!"5#()!(+!*$$%&'p(Pw(L(5*+*(*+$%11*;(Ht`(
L(5*+*(s<!IQK(4(8<!IQKN([A'!*,(,&1%)*,p (*3/,0!()!(1#,(+!,/10*)#,(!V5!+%"!'0*1!,(*(1*(!$/*$%&'(IHK

,!+8&(/'*(+!1*$%&'(!'0+!(1*($#'$!'0+*$%&'()!( 1*(9*21*(PN
>,IWK(+!"*'!'0!(!'(,#1/$%&'(4(1*($#'$!'0+*-
$%&'()!("*0!+%*1(/0%1%U
*)#;(1*($/*1(,!(*3/,0*2*( q*+*(0#)#,(1#,("*0!+%*1!,(!,0/)%*)#,;(X >,IWKY |(
,!.r'(1*(!$/*$%&'(IHKp Z(Q(4(X >,IWKY(Z(G(".([ -1
,l
oquei ndic aque
conunac onc entr ac ióndemater i
aladec uada
!,(5#,%21!(1#.+*+(/'*(+!"#$%&'()!(>,IWK("*-
4#+( #( %./*1( *( FGbN( 9*"2%-'( ,!( #2,!+8*( a/!(
( ( ( ( ( IHK !1( "*4#+( 8*1#+( )!( ( $#++!,5#')!( *( s<!IQK;(
?#')!p ( %')%$*')#( a/!( !,0!( "*0!+%*1( !,( $*,%( HQQ( 8!-
X >,IWKYS
(+!5+!,!'0*(1*($#'$!'0+*$%&'()!(>,IWK( $!,("d,(!6$%!'0!(a/!(1*(*+$%11*(5*+*(+!"#8!+(
ens oluc i
ón, >,IWKN(?!2!($#',%)!+*+,!(a/!(1*(+!"#$%&'()!(
X >,IWKY(1*($#'$!'0+*$%&'()!(>,IWK(+!"#8%21!( >,IWK(!"51!*')#(<!IQK(0%!'!(1/.*+(!'(,/,(5+#-
porads or ción, duc tosdec orr osión,s i
endoes teproc es oelli-
esunac onstantedepr imerordenquei ndica "%0*'0!(!'(1*(8!1#$%)*)()!(+!"#$%&'(IE#+.*)*(
1*(!6$%!'$%*()!($*)*(*),#+2!'0!(4(X >,IWKY|
re- 4([ %00!+;(PQHQK] (!1(0%!"5#()!(+!*$$%&'(#20!'%)#(
5+!,!'0*(*1(>,IWK('#(+!"#8%21!(5#+(*),#+$%&'N(( IHt`(LK('#(%"51%$*('!$!,*+%*"!'0!(/'(0%!"5#(
der es i
denc iadelpr oc
eso,y aqueespos ibl
e
[ #,(5*+d"!0+#,()!(*3/,0!()!(1#,(+!,/10*)#,()!( obtenerunac or ros ión5+!8%*()!1(<!IQKN
1*(<%./+*(P($#'(1*(!$/*$%&'(IHK(,!("/!,0+*'(!'(

Tabla 2.Parámetros de aj
uste de la ecuación (
1)a los datos de la Figura 1

( !"#$%&'()!(*+,-'%$#(!'(*./*("!)%*'0!NNN
J.M.Meichtry et al.-

51
 Fig.3.Capacidad de remoción de As de la arcilla y de Fe( 0)microparticulado
D#')%$%#'!,p (X>,IWKY0
(Z(G(".([ -1
;(5\(J(I$0!NK;(9(Z(PQ(RDN(9%!"5#()!(+!*$$%&'p (Ht`(LN(>,IWK;(tw`(
L,(>,I@@@KN(=*++*,('!.+*,p(!V5!+%"!'0#,($#'(>,IWK] (2*++*,(.+%,!,p
(!V5!+%"!'0#,($#'(>,I@@@K(I2*++*,(
.+%,!,(1%,*,(+!5+!,!'0*'(!1(>,I@@@K(+!"*'!'0!;(1*(2*++*(.+%,(*(+*4*,(+!5+!,!'0*(!1(>,IWK(!'(,#1/$%&'(
^#+"*)#(5#+(#V%)*$%&'()!(>,I@@@KKN

>( $#'0%'/*$%&';( ,!( +!*1%U *+#'( !',*4#,( )!( +!- )*)( )!( +!"#$%&'( )!( >,IWK( 4( >,I@@@K( !'( )%^
!-
"#$%&'( )!( >,IWK( 4( >,I@@@K( $#"2%'*')#( *+$%- rentesc oncentracionesdear c i
ll
ademues tran
11*( 4( s<!IQK( !'( 1*,( $#'$!'0+*$%#'!,( &50%"*,( a/!(1*(!8#1/$%&'(0!"5#+*1()!(1*($#'$!'0+*$%&'(
#20!'%)*,( *'0!+%#+"!'0!] ( 0*"2%-'( ,!( *'*1%U&( )!(>,(!'(,#1/$%&'(,!(*3/,0*(*(/'("#)!1#(2%!V -
elpos i
bleef ectodel apr es enciademater i
a 5#'!'$%*1;(,!.r'(1*(!$/*$%&'(IPK
#+.d'%$*(!"51!*')#(d$%)#($A0+%$#($#"#($#"-
5/!,0#( "#)!1#] ( 1*( $#'$!'0+*$%&'( )!( >,( $#-
++!,5#')!( *1( 8*1#+( )!( 5,!/)#C!a/%1%2+%#( IHt`(
4(tw`(L,()!(+!*$$%&'(5*+*(>,IWK(4(>,I@@@K;(+!,- (( ( ( ( ( IPK
5!$0%8*"!'0!KN( [ #,( +!,/10*)#,( ,!( %')%$*'( !'(
1*(<%./+*(ON ?#')!p
[As ]S
representa lac onc entr ac
ión de Asen
9*1( $#"#( ,!( "#,0+&( !'( 1*( <%./+*( P( 4( !'( 1*( sol uc i
ón,
9*21*(P;(1*,("*4#+!,(+!"#$%#'!,(,!(*1$*'U *'( A1 yA2 +!5+!,!'0*'( !1( ( >,( +!"#8%)#( 5#+( 1#,(
$#'( s<!IQK;( 11!.d')#,!( *( 8*1#+!,( 5#+( )!2*3#( pr oces os1 y2,
)!1(1A"%0!()!()!0!$$%&'(!'(!1($*,#()!(>,IWK] (,/( t1 yt2( ,#'( 1#,( 0%!"5#,( $*+*$0!+A,0%$#,( )!( 1#,(
combi nac i
ónc onar cil
lanoaumentadef or ma pr oces os1 y2,y
,%.'%6$*0%8*( 1*( +!"#$%&'( 0#0*1N( [
*( *+$%11*( ,#1*( [As ]|
( +!5+!,!'0*( *1( >,( '#( +!"#8%21!( 5#+( *)-
!,(!^ !$0%8*(!'(+!"#8!+(>,;(5!+#(,/($*5*$%)*)( sor ción.
esi nferi
oryr equi ereunamas adeads or ben-
0!( ,%.'%6$*0%8*"!'0!( "*4#+N( S!( #2,!+8*( /'*( e,0!("#)!1#(5+#5#'!(1*(!V %,0!'$%*()!()#,(0%-
0+*',^ #+"*$%&'(5*+$%*1()!1(>,I@@@K(*(>,IWK;(5#- posdistintosdes i
tiosdeads or c
ióndeAs ,uno
siblementedebi doalaac c óndelO2 delai
i re. a/!(*),#+2!("d,(+d5%)*"!'0!;()!6'%)#($#"#(
e'('%'.r'($*,#(,!()!0!$0&(1*(5+!,!'$%*()!(<!( 5+#$!,#( H;( 4( #0+#( "d,( 1!'0#( )!6'%)#( $#"#(
!'(,#1/$%&';(4*(,!*($#"#(<!I@@K(#(<!I@@@KN proceso2.

Cinética de adsorción de As en arcilla Losr esultadosobteni doss

emues
tran en l
a
9*21*(O(4(!'(1*(<%./+*(wN
[
#,(!,0/)%#,($%'-0%$#,(5*+*(!8*1/*+(1*(8!1#$%-
PROYECCIONES - Publicación de investigación y posgrado de la Facultad Regional Buenos Aires

52
Fig.4.Cinética de adsorción de As( V)y As( III)en arcilla
D#')%$%#'!,p
(X>,IWKY
Q(Z(G(".([
-1
;(5\(J(I$0!NK;(9(Z(PQ(RDN(

Tabla 3.Parámetros de aj
uste de la ec.(
2)a los datos de la Figura 3

[ #,("%,"#,(,!(*3/,0*'(*(1*(!$/*$%&'(P;()#'- 0+*0*"%!'0#(*5+#5%*)#()!(/'(*./*($#'0!'%!'-
des eapr eci
anc lar amentedospr oces osc on )#(H(".([ -1
()!(>,(I$#'$!'0+*$%&'("dV %"*()!(
0%!"5#,( $*+*$0!+A,0%$#,( 01 yt2( ;( a/!( )%6!+!'( >,(!'(1*(.+*'("*4#+A*()!(1*,(^ /!'0!,()!(*./*(
!'( "d,( )!( H( #+)!'( )!( "*.'%0/)N( >,%"%,"#( '#+"*1"!'0!(/0%1%U *)*,K;(%')!5!')%!'0!"!'0!(
,!( #2,!+8*( a/!( *1( %'$+!"!'0*+,!( 1*( $#'$!'- )!(1*(!,5!$%!(a/A"%$*()!(>,N
trac i
óndear c i
ll
aaumental apr opor cióndel
>,(+!"#8%)#(5#+(!1(5+#$!,#(+d5%)#(I>HKN(e,- q+#$!,#,(!a/%8*1!'0!,()!(*),#+$%&'()!(>,IWK(
tosr esultadosi ndi can quepuedeas umi r
se !'( ,/!1#,( L*'( ,%)#( +!5#+0*)#,( 5+!8%*"!'0!(
a/!(!V %,0!'(P(0%5#,()!(,%0%#,(!'(1*(*+$%11*;(/'#( 5#+( nL*'.( 4( S!1%"( IPQQGK( 4( S"%0L( 4( :*%)/(
"d,( ^ d$%1"!'0!( *$$!,%21!( *,#$%*)#( $#'( !1( IPQQFK;($#'(/'*(!0*5*(%'%$%*1(+d5%)*(a/!(!,(,!-
pr oceso1,yotr omenosac ces ibleas ociado ./%)*()!(/'(5+#$!,#('#0#+%*"!'0!("d,(1!'0#N(
c onelpr oceso2. nL*'.( 4( S!1%"( *,%.'*'( !,0!( $#"5#+0*"%!'0#(
*(1*(5+!,!'$%*()!("r10%51!,(!a/%1%2+%#,($#'(0+!,(
[#,(8*1#+!,()!(01(,#'("*4#+!,(5*+*(>,I@@@K;(1#( siti
osde ads orción di sti
ntos ,l o que r esulta
a/!(5/!)!(+!1*$%#'*+,!($#'(/'*("!'#+(*6'%- !'( /'( "#)!1#( $%'-0%$#( "d,( $#"51!3#( a/!( 1*(
)*)()!(!,0*(!,5!$%!(5#+(1#,(&V %)#,()!(>1(4(<!( !$/*$%&'(IPK] (5#+(,/(5*+0!;(S"%0L(4(:*%)/('#(
)!( 1*( *+$%11*;( L*$%!')#( "d,( 1!'0#( !1( 5+#$!,#( *3/,0*'( ,/,( +!,/10*)#,( !V5!+%"!'0*1!,( *( '%'-
deads or ción. .r'(0%5#()!($%'-0%$*N([ *()!$%,%&'()!(!"51!*+(!1(
"#)!1#($%'-0%$#()!(1*(!$/*$%&'(IPK(,!(3/,0%6$*(
Debedes tacars
eque,par atodasl asc ondi - 5#+(,/("*4#+(,%"51%$%)*)(4(!V $!1!'0!(*3/,0!(*(
$%#'!,(!,0/)%*)*,;(1#,(8*1#+!,()!(01 obteni dos 1#,(+!,/10*)#,(!V 5!+%"!'0*1!,(#20!'%)#,N((
%')%$*'(a/!;(/0%1%U*')#(/'*($#'$!'0+*$%&'()!(
*+$%11*( *)!$/*)*;( 5#)+A*( 1#.+*+,!( !'( O( L( /'( [
#,( 8*1#+!,( )!( >|;( ,%( 2%!'( ,#'( ,/5!+%#+!,( *1(

( !"#$%&'()!(*+,-'%$#(!'(*./*("!)%*'0!NNN
J.M.Meichtry et al.-

53
 Fig.5.Cinética de adsorción de As( v)con µFe( 0)
D#')%$%#'!,(!V5!+%"!'0*1!,p
(X>,IWKY
Q(Z(G(".([
-1
;(5\(J;(9(Z(PQ(RD(I$0!NK;($#'(*.%0*$%&'(#+2%0*1N(

Fig.6.Cinética de adsorción de As( V)con viruta de Fe( 0)comercial

D#')%$%#'!,(!V5!+%"!'0*1!,p
(X>,IWKY
Q(Z(G(".([
-1
;(5\(J;(9(Z(PQ(RD(I$0!NK;($#'(*.%0*$%&'(#+2%0*1N
1A"%0!(+!$#"!')*)#(5#+(1*(gES;(,!(!'$/!'0+*'( )!(+!"#$%&'()!(>,IWK($#'()%^ !+!'0!,($#'$!'-
)!'0+#()!1(!++#+()!(1*(0-$'%$*(*'*1A0%$*(!"51!*- 0+*$%#'!,()!(s<!IQK(4(8<!IQK()!"/!,0+*'(a/!(
)*] ( )!2!( "!'$%#'*+,!( a/!( 0*"2%-'( !,( 5#,%21!( 1*(!8#1/$%&'(0!"5#+*1()!(1*($#'$!'0+*$%&'()!(
/'( *5#+0!( )!( qIWK( )!( 1*( *+$%11*( 5#+( )!,51*U
*- >,(!'(,#1/$%&'(,!(*3/,0*(*(/'("#)!1#("#'#-
"%!'0#( )!( !,0!( *'%&'( )!( 5*+0!( )!1( >,IWK( !"#$ !V 5#'!'$%*1;(,!.r'(1*(!$/*$%&'(IOK
%&'() *+,"-'&.+/00/1+pr oduc iendouner rorpor
!V $!,#(!'(1*()!0!+"%'*$%&'()!(>,IWK(4(>,(0#0*1N ( ( ( ( ( IOK

Cinética de la remoción de As( V)con Fe( 0) [ #,( 5*+d"!0+#,( )!( 1*( !$/*$%&'( IOK( 0%!'!'( !1(
"%,"#(,%.'%6$*)#(a/!(1#,()!(1*(!$/*$%&'(IPKN(
[#,(!,0/)%#,($%'-0%$#,(5*+*(!8*1/*+(1*(8!1#$%)*)( [#,( +!,/10*)#,( )!( 1#,( !V
5!+%"!'0#,( $%'-0%$#,(

PROYECCIONES - Publicación de investigación y posgrado de la Facultad Regional Buenos Aires

54
Tabla 4.Parámetros de aj
uste de la ecuación (
3)a los datos de las Figuras 5y 6
Tabla 5.Ef
ecto del pH en la remoción de As(
V)por tratamiento con arcilla
,!("/!,0+*'(!'(1*,(<%./+*,(G(I5*+*(s<!IQKK(4(
t(I5*+*(8<!IQKK;(/0%1%U
*')#()%^!+!'0!,($#'$!'-
0+*$%#'!,()!(<!IQKN(e'(1*(9*21*(w(,!("/!,0+*'(
1#,(*3/,0!,()!(!,0#,(+!,/10*)#,(*(1*(!$/*$%&'(
IOKN
e'( *"2#,( $*,#,( 1*( +!"#$%&'( !,( +d5%)*( 4( ,/(
8!1#$%)*)(*/"!'0*($#'(1*("*,*()!(L%!++#(/0%-
1%U
*)*($#"#("*0!+%*1(*),#+2!'0!N(
eV $!50#(5*+*(8<!IQK(Q;QGb;(5*+*(*"2#,("*-
0!+%*1!,( ,!( #2,!+8*( /'*( +!"#$%&'( $#"51!0*(
)!(>,IWK(!'(0#)*,(1*,($#')%$%#!',(!V 5!+%"!'-
0*1!,(!,0/)%*)*,N(>(2*3*,($#'$!'0+*$%#'!,()!(
<!IQK(I_Q;HQ(bK;(,!(#2,!+8*(a/!(1*(+!"#$%&'(
!,("d,(+d5%)*($#'(s<!IQK(I"!'#+(01K;(1#(a/!(
5/!)!( *,#$%*+,!( $#'( 1*( "*4#+( d+!*( ,/5!+6-
$%*1()!(!,0!("*0!+%*1] (*(*10*,($#'$!'0+*$%#'!,(
)!(<!IQK(!,0*(8!'0*3*()!,*5*+!$!;(4(1#,("*-
0!+%*1!,( 5+!,!'0*'( 8!1#$%)*)!,( )!( +!"#$%&'(
simi l
ares .
[
*( 9*21*( G( "/!,0+*( 1#,( +!,/10*)#,( #20!'%)#,(
J.M.Meichtry et al.-
*1(!8*1/*+(!1(!^ !$0#()!1(5\(!'(1*($*5*$%)*)()!(
1*(*+$%11*;((*(/'*($#'$!'0+*$%&'()!(P;Gb;(5*+*(
+!"#8!+(>,IWK(1/!.#()!(Pw(L()!(+!*$$%&'N(
S!(!8%)!'$%*("*4#+(+!"#$%&'(*("!'#+(5\;(!,(
)!$%+;(!'("!)%#(d$%)#;(5#,%21!"!'0!()!2%)#(*1(
!^!$0#( )!( /'*( "*4#+( *0+*$$%&'( !1!$0+#,0d0%$*(
!'0+!( !1( *'%&'( \P>,gw( 5+!,!'0!( "*4#+%0*+%*-
"!'0!(*(G;G(}(5\(}(t;Q;(4(*(1#,(.+/5#,(#V #-
L%)+&V %)#,("!0d1%$#,()!(1*(*+$%11*(I<!;(>1K(+!,-
pons ablesdel ar emoc ióndeAsporads orción
I[%00!+(4($#1*2#+*)#+!,;(PQHQKN(e,0!(!^ !$0#()!1(
5\( !'( 1*( +!"#$%&'( )!( >,IWK( !'( "#'0"#+%1#-
nita,c aolinitaei ll
ita,mi neralesnor mal mente
pres entesenar c
il
las,has i
dor epor tadopr e-
8%*"!'0!(Io#1)2!+.;(PQQPKN(q/!)!()!,0*$*+,!(
a/!(1*(*+$%11*($#'0+%2/4!(*('!/0+*1%U*+(!1(5\()!1(
*./*(0+*0*)*N
e'(1*(9*21*(t(,!("/!,0+*'(1#,(+!,/10*)#,()!(!V -
5!+%"!'0#,(!a/%8*1!'0!,(+!*1%U *)#,($#'(>,I@@@K(
4( 1*( $#'$!'0+*$%&'( )!( >,IWK( ^
#+"*)#( *( 5*+0%+(
)!(1*(#V %)*$%&'(5*+$%*1()!1(>,I@@@KN
( !"#$%&'()!(*+,-'%$#(!'(*./*("!)%*'0!NNN
55
 Tabla 6.Ef
ecto del pH en la remoción de As(
III)por tratamiento con arcilla
Ladependenc i
adel ac apac idaddeads orción )!(1*(!,5!$%!(>,IWKN
)!( >,I@@@K( $#'( !1( 5\( ,%./!( 1*( "%,"*( 0!')!'-
$%*( #2,!+8*)*( 5*+*( >,IWK;( $#'( /'*( )%,"%'/- [ *()!,#+$%&'()!(>,IWK(!'(1*,("/!,0+*,(,!$*)*,(
$%&'(!'(!1(>,I@@@K(*),#+2%)#(*1(*/"!'0*+,!(!1( *(OQ(4(HQQ(RD(!,(5+d$0%$*"!'0!()!,5+!$%*21!(
5\;(1#($/*1(0*"2%-'(5/!)!(*,%.'*+,!(*("!'#+( mi entrasque en l asmues trasc alci
nadass e
*6'%)*)( !'0+!( 1*( ,/5!+6$%!( $#'( $*+.*( !1-$0+%- )!0!$0*(/'("*4#+(5#+$!'0*3!()!,#+2%)#N(e,0!(
$*($+!$%!'0!"!'0!('!.*0%8*()!(1#,(&V %)#,(4(!1( */"!'0#(5#)+A*(*0+%2/%+,!(*(/'*("#)%6$*$%&'(
>,I@@@K(I'!/0+#(*(8*1#+!,()!(5\(%'^ !+%#+!,(*(F;P( ,/5!+6$%*1( !'( 1*( *+$%11*( 4T
#( *( 1*( )!,#+$%&'( )!(
I=/'),$L/L(4($#1*2#+*)#+!,;(PQQ`KN( !,5!$%!,( )!( qIWK( 5+#$!)!'0!,( )!( 1*( "*0!+%*(
#+.d'%$*( $*1$%'*)*;( 1*,( $/*1!,( %'0!+6!+!'( !'(
S!(#2,!+8*(0*"2%-'(/'*("*4#+($#'$!'0+*$%&'( 1*(0-$'%$*(*'*1A0%$*(!"51!*)*(I[ !'#21!;(PQQOKN(
)!( >,IWK( +!"*'!'0!( *( 5\( *1$*1%'#,;( 1#( $/*1( S!( #2,!+8*( 0*"2%-';( a/!( 1*( )!,#+$%&'( !'( 1*,(
pueder el
ac ionar seconl ades or
c i
ónporads or- "/!,0+*,( )!( +!,%)/#( *+$%11#,#( $#'( >,I@@@K( ( !,(
$%&'($#"5!0%0%8*()!(%#'!,(L%)+&V %)#()!1(>,IWK( may orys eenc uentr amay oritar iamentel i
be-
^#+"*)#()!(1*(#V %)*$%&'()!1(>,I@@@K(*),#+2%)#( +*)#($#"#(>,IWKN
!'(1*(*+$%11*(I~
*$l ,#'(4(E%11!+;(PQQQK] (1*(5#,%21!(
#V %)*$%&'(()!1(>,I@@@K(5#+(!1(#V A.!'#()%,/!10#( Conclusiones
puededes car
tar sedebi doal al entac inética
)!(!,0*(+!*$$%&'(I=/'),$L/L(4($#1*2#+*)#+!,;( S!($*+*$0!+%U &(1*(*+$%11*(!"51!*)*($#"#(*),#+-
PQQ`K;(IS"!)!14(4(y%''%2/+.L;(PQQPKN 2!'0!;( %)!'0%6$*')#( *1/"%'%#( 4( L%!++#( $#"#(
"*0!+%*1(*$0%8#(!'(1*(+!"#$%&'()!1(*+,-'%$#N
Estabilidad del As( V)adsorbido en los
materiales Losmodel osde c apac idad de r emoc i
ón de
>,IWK(!'(^/'$%&'()!("*,*()!(*),#+2!'0!(#20!-
Losr es ultadosobteni dosen l osens ayosde '%)#,(5*+*(*+$%11*;(s<!IQK(4(8<!IQK(5!+"%0%!+#'(
des orcióndelAsads orbidoenl asar cil
las,s e )!0!+"%'*+( a/!( !1( s<!IQK( !,( !1( "*0!+%*1( "d,(
"/!,0+*'(!1(1*(9*21*(J;()#')!(1#,(8*1#+!,()!(b( !^ !$0%8#N
)!( 1%V
%8%*)#( ,!( !V5+!,*'( $#"#( $#'$!'0+*$%&'(

Tabla 7.Estudio de desorción de As de arcilla

PROYECCIONES - Publicación de investigación y posgrado de la Facultad Regional Buenos Aires

56
e,0/)%#,(,%"%1*+!,(+!*1%U
*)#,($#'(>,I@@@K(%')%-
cana/!(,/(+!"#$%&'(!,("!'#,(!6$%!'0!(a/!(1*(
)!(>,IWK('!$!,%0d')#,!()!(/'*(#V%)*$%&'(5+!8%*(
*(>,(IWK(5*+*($#"51!0*+(!1(5+#$!,#N
!,("*4#+(*1(*/"!'0*+(1*(*$%)!U ()!1(*./*(0+*0*)*;(
5#,%21!"!'0!( )!2%)#( *( /'*( "*4#+( *6'%)*)( )!(
!,0*,(!,5!$%!,(5#+(1#,(&V%)#,(a/!($#',0%0/4!'(1#,(
$#"5#'!'0!,(*$0%8#,()!(1*(*+$%11*N(

e1( $#"5#+0*"%!'0#( )!( 0%5#( 2%C!V5#'!'$%*1( #2- Lades or cióndeAsdear cil

,!+8*)#( !'( 1*( $%'-0%$*( )!( *),#+$%&'( !'( *+$%11*(
5*+*( *"2*,( !,5!$%!,( )!( *+,-'%$#( 5#)+A*( !,0*+(
*,#$%*)#(*()#,(0%5#,()!(,%0%#,()!(*),#+$%&'N(S!(
!8%)!'$%*;(*)!"d,;(/'(5!+A#)#()!(%')/$$%&'(%'%-
$%*1(5*+*(!1($*,#()!(>,I@@@K;(a/!(5#)+A*()!2!+,!(
*(1*('!$!,%)*)()!(/'*(#V%)*$%&'(5*+$%*1(5+!8%*(
*(1*(*),#+$%&'N([*(+!"#$%&'(>,IWK(4(>,I@@@K()!(
sol uci
onesac uos asempl eandoar c i
ll
ami sioner a
lasempl eadaspr e-
8%*"!'0!( 5*+*( *),#+2!+( >,IWK( )!( ,#1/$%#'!,(
*$/#,*,(!,()!,5+!$%*21!N(:#(*,A(!'(*+$%11*,($#'(
>,I@@@K( *),#+2%)#( !'( !0*5*,( )!( *2*0%"%!'0#( )!(
solucionesac uos as,dondel ac onc entraciónde
>,(5#+()!,#+$%&'(!,(!1!8*)*N(Ed,(!,0/)%#,(,#'(
'!$!,*+%#,(5*+*(!8*1/*+(,%(1*(!,5!$%!()!,#+2%)*(
)!(1*(*+$%11*($*1$%'*)*(!,(>,IWK(#(qIWKN

Ref
erencias

><:g ;(IHFFJKN(?!0!+"%'*0%#'()!(1*($#'$!'0+*0%#'(!'(5L#,5L*0!(C(>""#'%/"("#142)*0!(,5!$0+#"!0+%$(
"!0L#)N(:#+"*(@Sg(t`J`CHp HF`t;(9#"#(O;(PtGhPFQ;(q*+A,;(<+*'$%*N
>o>nn@;(>N] (q@ g[ >;(DN;(IPQQQKN(</')*"!'0*1,("!0L#)(*')(^ /0/+!(0+!'),(#^ (!'8%+#'"!'0*1("%$+#k*8!(
,*"51!(5+!5*+*0%#'N(E%$+#$L!"%$*1(~ #/+'*1(tJ;(OOJCOwH
=7:?SD\7\;(~ N(]
(qe en(D> e >;(>N(4([@99e ;(EN@N;(IPQQ`KN(?%,0+%2/$%&'()!1(*+,-'%$#(!'(1*,(+!.%#'!,(
@2-+%$*(!(@2!+#*"!+%$*'*N(@=e g> Se:(Dm9e?(Ie)NKN(@S=:p (HO(FJ`C`wCFtQPOCtHCH
D>>( ID&)%.#( >1%"!'0*+%#( >+.!'0%'#K;( IPQQJKN( E#)%6$*$%&'( )!( 1#,( >+0A$/1#,( F`P( 4( F`O;( =/!'#,( >%+!,;(
>+.!'0%'*N
?e(eSq> n>;(EN([N(4(ug:o(?e(Ee?@:>;(EN;(IHFF`KN(>2*0%"%!'0#()!(*+,-'%$#(!'(*./*,(,/20!++d'!*,(
5*+*(U #'*,(+/+*1!,N(jjW@(D#'.+!,#(@'0!+*"!+%$*'#()!(@'.!'%!+A*(S*'%0*+%*(4(>"2%!'0*1;(Deq@ST gqSN
?%,5#'%21!(!'p (L005p TTkkkN28,)!N5*L#N#+.T *$+#2*0T 5!+$$*QPN5)^
?e(W@9 e;( N(] (=e[n@[e;(:N(4(9eSS@e ;(>N;(IHFFHKN(S5!$%*0%#'(*')(*),#+50%#'(#^ (*+,!'%$(#'()%*.!'!0%$(
%+#'(#V4L4)+#V%)!,N([%"'#1N(g$!*'#.N(Ot;(Hw`QhHw`G] (
eSD>[e >(Ee~ @>;(eN;(IPQHOKN( DL*+*$0!+%U *0%#'(#^(S#"!(:*0/+*1(*')(S4'0L!0%$(E*0!+%*1,(u%0L(S%1%$*0!(
S0+/$0/+!,€ N( [/1!(7'%8!+,%04( #^ ( 9!$L'#1#.4;( ?!5*+0"!'0( #^ ( e'.%'!!+%'.( S$%!'$!,( *')( E*0L!"*0%$,N(
q+%'0!)(24(7'%8!+,%0!0,0+4$l !+%!0;([/1!N(@SS:p (HwQPCHJGJ;(@S=:(FJ`CFHCJwOFCGGOCP
<e :‚:?en(97 @e[;(~ N([N](q> >?>(EN(>N(4(o@Ee:g(9g e:9e;(?N;(IPQQGKN(>+,-'%$#(!'(*./*,p (#+%.!';(
"#8%1%)*)(4(0+*0*"%!'0#N(9*11!+N(@@(S!"%'*+%#(\%,5*'#(1*0%'#*"!+%$*'#(,#2+!(0!"*,(*$0/*1!,()!(L%)+#1#-
.A*(,/20!++d'!*(@W N
D#'.+!,#(\%)+#.!#1&.%$#(>+.!'0%'#;( A#(D/*+0#N(>+.!'0%'*N(e)N(o*1%')#;(H`P(55N(@S=:(F`JQGQQG`JN
og[?=e o;(SN;(IPQQPKN(D#"5!0%0%8!(*),#+50%#'(#^ (*+,!'*0!(*')(*+,!'%0!(#'(#V%)!,(*')($1*4("%'!+*1,N(
S#%1(S$%N(S#$N(>"N(~ N(tt;(wHOhwPHN((((
\g[[;(uN(4([@99e (EN;(IPQHQKN( g$/++!'$%*(a/A"%$*()!1(*+,-'%$#(!'(*./*,N(S/"*+%#()!(0!$'#1#.A*,()!(
+!"#$%&'()!(*+,-'%$#()!(*./*,N(@=e g> Se:(Dm9e?(Ie)NKN(?%,0+%2/$%&'()!1(*+,-'%$#(!'(1*,(+!.%#'!,(
Ibér i
caeI ber oamer icana.
@S=:p (FJ`C`wCFtQPOCJwCHN
~ >DySg:;(=N(q N(4(E@[[e ;(uN(q N;(IPQQQKN(e^ ^
!$0%8!'!,,(#^ (qL#,5L*0!(*')(\4)+#V%)!(^ #+(?!,#+50%#'(#^ (
>+,!'%$(*')(S!1!'%/"(S5!$%!,(^ +#"(@+#'(gV%)!,N(S#%1(S$%N(S#$N(>"N(~ N(tw;(HtHthHtPPN
[e:g=[e;(W N](?e[7D\>9;(W N](Se q>7?;(=N(4(=g[[@:oe ;(~ NDN;(IPQQOKN(>+,!'%0!(#V%)*0%#'(*')(*+,!'*0!(
)!0!+"%'*0%#'(24(0L!("#142)!'!(21/!("!0L#)N(9*1*'0*(tH;(PtJhPJtN
[@99e ;(EN(@N] (Eg o>?>;(EN(eN(4(=7:?SD\7\;(~ N;(IPQHQKN(q#,,%21!(0+!*0"!'0,(^ #+(*+,!'%$(+!"#8*1(%'(
[*0%'(>"!+%$*'(k*0!+,(^ #+(L/"*'($#',/"50%#';N(e'8%+#'N(q#11/0N(HG`;(HHQGCHHH`] (
[@99e ;(EN(@N] (S>:D\>;(>N(EN(4(@:o>[[@:e[[ >;(>N(EN;(IPQHQKN(9!$'#1#.A*,(e$#'&"%$*,(5*+*(!1(>2*0%-
"%!'0#()!(>+,-'%$#(!'(>./*,N(@=e g> Se:;(Dm9e?(I!)NK;(>+.!'0%'*] (=L*00*$L*+4*;(q N;(u!1$L;(>N(\N;(
S0#11!'k!+l;(yN(oN;(E$[*/.L1%';(EN(~ N;(=/'),$L/L;(~ N;(q*'*/11*L;(oN;(PQQJN(>+,!'%$(%'(0L!(!'8%+#'"!'0p (
=%#1#.4(*')(DL!"%,0+4N(S$%N(9#0*1(e'8%+#'N(OJF;(HQFhHPQN
Eg o>?>;(EN(eN(4([@99e (EN;(IPQHQKN( 9!$'#1#.A*,(^ #0#a/A"%$*,(4(,#1*+!,(5*+*(1*(+!"#$%&'()!(*+,-'%-
$#()!(,#1/$%#'!,(*$/#,*,N(e,0*)#()!(*+0!€ N(@=e g> Se:(Dm9e?(Ie)NKN(?%,0+%2/$%&'()!1(*+,-'%$#(!'(1*,(

( !"#$%&'()!(*+,-'%$#(!'(*./*("!)%*'0!NNN
J.M.Meichtry et al.-

57
 +!.%#'!,(@2-+%$*(!(@2!+#*"!+%$*'*N(@S=:p (FJ`C`wCFtQPOCJwCHN
:euDgE=e;( N([N4(Eƒ[[e ;(oN;(IPQQtKN(>+,!'%$( !"#8*1(^ +#"(?+%'l%'.(u*0!+p (>( !8%!kN(=1/!(u*0!+(
9!$L'#1#.%!,;(@'$N(\*4)!';(@?N
:g7=>D9eq ;(DN](D> f;(SN](9go7eCy>Eo>;(<N] (SD\ƒ:e ;(>N(4(ug><g;(q ;N(IPQHQKN(eV0!')%'.(,!+8%$!(1%^
!(
#^ (L#/,!L#1)(k*0!+(610!+,(24("%V%'.("!0*11%$(%+#'(k%0L(,*')N(D[e>:(h(S#%1;(>%+(*')(u*0!+(O`;(FGHhFGFN
gES(Ig+.*'%U *$%&'(E/')%*1()!(1*(S*1/)K;(IPQQ`KN(o/%)!1%'!,(^ #+(?+%'l%'.Ck*0!+(B/*1%04;(O+*(!)N(u\g(
I!)NK;(o%'!2+*;(S/%U *N
>EgS( N(IPQHQKN( </')*"!'0#,()!(*),#+$%&'(!'(,%,0!"*,(1Aa/%)#(,&1%)#€ (@=e g> Se:(Dm9e?(Ie)NKN(
?%,0+%2/$%&'()!1(*+,-'%$#(!'(1*,(+!.%#'!,(@2-+%$*(!(@2!+#*"!+%$*'*N(@S=:p (FJ`C`wCFtQPOCJwCHN
SD\@[ 9;(>N(>N;(IHFtFKN(>'*140%$*1(*551%$*0%#',(#^ (H;HQC5L!'*'0L+#1%'!(*')(+!1*0!)($#"5#/'),;(H+*(!)N(
q!+.*"#'(I!)NK;(gV^ #+);(o+*'(=+!0*v*N
S\> E>;(W N(yN(4(Sg\:;(EN;(IPQQFKN(>a/*0%$(*+,!'%$p (9#V%$%04;(,5!$%*0%#';(0+*',^ #+"*0%#',;(*')(+!"!)%*-
0%#';(e'8%+#'N(@'0!+'N(OG;(JwOhJGFN(
SEe?[em ;(q N([N(4(y@::@=7 o\;(?N(oN(IPQQPKN(>(+!8%!k(#^ (0L!(,#/+$!;(2!L*8%#+(*')()%,0+%2/0%#'(#^ (*+,!-
'%$(%'('*0/+*1(k*0!+,N(>551N(o!#$L!"N(HJ;(GHJhGt`N
SE@9\;(eN(4(:>@?7;( N;(IPQQFKN(DL!"%,0+4(#^ (%'#+.*'%$(*+,!'%$(%'(,#%1,p (l%'!0%$,(#^(*+,!'%$(*),#+50%#'h
)!,#+50%#'N(e'8%+#'N(o!#$L!"N(\!*10L(OH;(wFhGFN
S7[[@W>:;(yN>N(4(>[[e;( NDN;(IHFFtKN(?%*.!'!0%$($4$1%'.(#^ (*+,!'%$(%'(>"*U #'(,L!1^
(,!)%"!'0,N(o!#$L%"N(
D#,"#$L%"N(>$0*(tQ;(HwtGhHwJJN
W@g[ >:9e;(>N(4(q@o:>;(EN;(IPQQPKN(D#"5!0%0%8!(,#+50%#'(#^ (*+,!'*0!(*')(5L#,5L*0!(#'()%^ ^!+!'0($1*4(
"%'!+*1,(*')(,#%1,N(S#%1(S$%N(S#$N(>"N(~ N(tt;(HJ``hHJFtN
ugg?S;(~ N9N(4(Ee[[ g:;(EN(oN;(IHFwHKN(9L%#$4*'*0!("!0L#)(^ #+(%+#'N(>((,5!$0+#5L#0#"!0+%$(,0/)4N(@')N(
e'.N(DL!"N(>'*1N(e)N(HO;(GGHhGGwN
n\>:o;(\N(4(Se[@E;(EN;(IPQQGKN(y%'!0%$,(#^ (*+,!'*0!(*),#+50%#'(C()!,#+50%#'(%'(,#%1,N(e'8%+#'N(S$%N(9!-
$L'#1N(OF;(tHQHhtHQ`N

PROYECCIONES - Publicación de investigación y posgrado de la Facultad Regional Buenos Aires

58