os 7 0 P= Dithermic =F ao (lest ohh Adiabon< (Heat ex chonge =9) Is Nok Possigy; Te gig state funchienn (eg ga-ga o Werk = —(Pexp +d D Qian Convemdns + Viteat gained (+ve) Xpansien | Heol “ost (-ve) Combach'en. DI Werk done by system (= VEE xPana Jl. m_systenn _(tve ) Th Heat i tve_,Werk ig -ve. k_ ||First Low: Yt wt Tie!) emergy : 4 Ve suv > Urs Ue Th it has change by AT AUt ? A Vyt> AU vin > AVer. —rsobaric — Constant Pressure Date 1 Pose. Volume Tso chovic— classmate. }) At high +emp_ + AV AUVs + BUyr 4+ AU vib *& She At OY] Specie heot capacity: (ce): c= wy m.&t © Cm = Molo heat capacdt, GU = Nn CmAt a Cy = du ae eee CyzA0 = Gv (eee OGFor Tsochori¢ For Vanderwoll: G&S 2° Serer For Liquid &._ Solid, __ _ | ik eeeeserates | om aS z At constant Volume —> Ww =O Gv = AU a | Ce > Ce = 4p t For ideal) HOS =: [te-w eR j Ces Cv a t : silerr CO Eien « doe Ver the Sof ee. eee. moe Translational ee >I KE .= Key = k.€2 = lL net a * Cv= R eae F fe! TR cg Enea a £ k | Fer miahre of gases ICV mix = OO 4 a Ga = Nitnea Co mix = CerMi + Cea Oe Nite KR Enthalpy + (4) =5 H=U+4+ PV At constant Pressure. ——S AP =O JAH=4, |Volue of RS classrhite Re 2 16% ~> Xeal — O) Re B84 Se ey (Cae oe 8 Bia xX 10 ra We ~bng RT V+ weaAYU q = AU-w 5 ea) V W = -p. AV APV= NEAL For Idea qas -s Nt = AU aR For Dsobaric process => T Work deme = -P.AvV Fer Tdeas gas ; Wis -P. AV W >. ob Ov ic = =9-R.AT estate eguahen C 2rd) oH - Uae Jt eo Yat fu E = RH = 4 Nép ar ‘we: Wt A tee Ar bana 2... eee BS w= Ay tang oT AWH=AU + DRAT classmate 1S* state eguk . (ou duvet (se) [fe Ov + koa JN R || For Reo) qos = estan process) {A ites de Ce "Nae *k Fy _ EXPANSION W Note No: =. tages w (a Infinite no. cf Stages —> Reversini.| frrea undey P-V wryve —> W Wrey [>] Wirr COMPRESSTON WOR oof stages @)\___Werk dene W Grr) Wire [5] W rey. On the Syste |— a Page Tracom? proces q rey = i= Wrest ———____ ATeG. 5 Weds 7 Asa ) Wire = =e An va | @ a Wiyey seit Ro an Ra. | Po Wipy. = =P ext (2-vi | | Reversible Vandewwall qas —3 Wrev = -NRT £0 Va-nb 4 y2Q/1-| Vi-bdb Vo Vil Een expansion —> 3 Wide) V > WS yaw. gi Fey compression “a Ww ‘dead SEW wg =+ 2] [Us Y-1 classmate fae a Adiabothe Process : Cy = 3) W.= &U AU @ Tf werk done On System BU WY Work done by system. W = —Pext (v2-V) Mey AT =. olen Gael(Zak classmate, \ Date____—~ i a Bonne a) Rev. Adiabat'c TON, VW is a (eo 0, = na NOV es Pet =6 Adiabatic qo =0 Tsothermal 4U=0* 3 AW =AT=6 Rev. Adiobehe process 3 AW = fF. su 1 ! An = aCe =a = W pywit Evrae aoa peal fr aaticlassmate. Constant Specific heath process: * |elypasMicmpuomesas ~ | = , | | PV = constant | P = 7 . eI w= | — > Tsothermdd = W=O WW -~5- TSebaric =o HM = 08 — > Tsocherve , wm =F — s Adiabotec 7 A v —s{e.. cy 2 vt TO) \WWio= Pave - PiVvs *x=-4 K | GyEwse teens m Lawn —> . To TH Weer 5 af (te =1)) An Vo. V4 EFficiemey (n) ae alia!Nien pressure QD TInterrmole ar histone As@ classmate a | wArsS > nm Cy An To & AR [kn vy AS = 7 VI AS = nCp To + mR &n Pr 4 Pia AS = nR. dn Vo | al Fer Adiabahbe AS=o For Isocheric —s JV =0 3 AS = 1 Cv: &n—Te TH | POenseibomig —> qe = AH |classmate OY Shines rev. Solid = Liguid AS = Gre = AH gosien |. tT Temp. (“-) S| rey. >, Gqvid = Gas Temp. dependance of enthalpy change AW, =AH 1 + Cp (Ta.-Th (_——— At comstant press Ure psa AS: + ACe. &n Te ate ee ASp = ASp, + Ang fn 1 Pei | classmate ay deurtev CE G —> ) > S & & nlyla Ofo/e was Rev. At Con stan+ pressure —5 ati A Gi = sti asa 1)HS sury. = — BS cy sles 7 Date Page _—___—— At constant -temp : eo A@ = NRT & Po aie For any rexn G@= G°+RT BA = K Gren + RT Aan Q@ eo —RTr Ink | — FO sie ay oe At equilibrivm —3.LG@G=O Voant Hekt eau Cin F) =A? am JP RT? At constant Pressure An Kz = AH? (1 31 \ KI R \ reeClemry lor classmate es GY ibe CE kK ASB eae — 3 4G=0 At equilipriur — T= 4H AS ¥ change in molar valume * At - constant pinesigitpmae. | crac -As (12-7) Kirchofp's h 20,0 > Alo = AH, = n p( 72 ean)classmate ; ‘Thermo - Chemistry... 2 — Bonds [Ans ive) Bonds are formed — |AH-> -ve KR | Vs Energy yequired —E releosed Heat exchange Endotheymic —> (E absorbed) |+ve A Exother mic —> (CE released) [—ve _~ *¥ Gv = At cons. volume (Pistm Locked. - At coms. Pressure x (4) = ©) + Pv Ze At cons. volume AH rexn = AY yexp ot (49) QT. Jaw = AU +p Ay] Pressure | een Coes Constant RA AH comb. is always (~ve). _Exothermic = ——— AU" weubalissabion —> - VE Exothermic aesclassmate, = Ker a \ AMY van = (a7) r oA H* atomizohon ZH dissocittion Gig 7 [Endothenm ic} bine On ayse || AH? Hydrogen aden Gve) 4 pexothenmi | SD “cares meray =? (a ae * |Resemance Energy —: R.£ = BHF achal -AH* Heol *% Trans thi en em+thalpy > Ge) Endothezmic. Yen 10 taseto BD | CN | (rR? q KeiS WH=A8Vt Bg Ry classmate Date _____ AG =MHH-TAS a f AH | As AG ( | jf — + —— ; 7 || CExoth) | entvery @ spont in) + | = . (Endo) | * pep Soe i ry o+ += (eh) Spoor. i Lous [+ Geme Non - spant. iv) = | = ef ES) Spont | yytd ; i ret a Non - Spont