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5.Some liquids on mixing form ‘azeotropes’. What are ‘azeotropes’? (Delhi 2014)
The liquid mixture having a definite composition and boiling like a pure liquid without
change in composition is called as azeotrope.
7.Out of BaCl2 and KCl, which one is more effective in causing coagulation of a
negatively charged colloidal Sol? Give reason. (Delhi 2015)
BaCl2 is more effective in causing coagulation because it has double +ve charge than
K+.
Non-ideal solutions show positive deviations from Raoult’s law on mixing of two volatile
components of the solution.
Example : Mixture of acetone and benzene solutions show positive deviation,
10.Define the terms, ‘osmosis’ and ‘osmotic pressure’.
What is the advantage of using osmotic pressure as compared to other colligative
properties for the determination of molar masses of solutes in solutions? (All
India 2010)
Osmosis : The net spontaneous flow of the solvent molecules from the solvent to the
solution or from a less concentrated solution to a more concentrated solution through a
semipermeable membrane is called osmosis.
Osmotic pressure : The minimum excess pressure that has to be applied on the
solution to prevent the entry of the solvent into the solution through the semipermeable
membrane is called the osmotic pressure.
The osmotic pressure method has the advantage that it uses molarities instead of
molalities and it can be measured at room temperature.
11.A 1.00 molal aqueous solution of trichloroacetic acid (CCl 3COOH) is heated to
its boiling point. The solution has the boiling point of 100.18°C. Determine the
van’t Hoff factor for trichloroacetic acid. (Kb for water = 0.512 K kg mol-1) (Delhi
2012)
As ΔTb= iKbm
(100.18 – 100) °C = i × 0.512 K kg mol-1 × 1 m
0.18 K = i × 0.512 K kg mol-1 × 1 m
∴ i = 0.3
15.State Henry’s law and mention two of its important applications. (Comptt. All
India 2012)
Henry’s law : Henry’s law states that “The partial pressure of the gas in vapour phase is
proportional to the mole fraction of the gas in the solution “, Applications of Henry’s law :
To increase the solubility of CO2 in soft drinks and soda water, the bottle is sealed
under high pressure.
To avoid a dangerous medical condition called bends, scuba divers use oxygen
diluted with less soluble helium gas.
19.Derive expression for Raoult’s law when the solute is non-volatile. (Comptt.
Delhi 2013)
Raoult’s law : Raoult’s law states that “for a solution of volatile liquids, the partial
vapour pressure of each component in the solution is directly proportional to its mole
fraction”.
Thus for component 1 : p1 = p10X1
where [p10 is vapour pressure of pure component 1]
For component 2 : p2 = p20X2
ccording to Dalton’s law of partial pressure
PTotal = P1 + P2 ⇒ PT = p10X1 + p20X2
⇒ P T = p10( 1 – X 2) + p 20X2
∴ PT = p10 + (p20 – p10)X2
20.Calculate the mass of compound (molar mass = 256 g mol -1) to be dissolved in
75 g of benzene to lower its freezing point by 0.48 K (K f = 5.12 K kg mol-1). (Delhi
2014)
Given : ∆Tf = 0.48 K, W1 = 75g,
M2 = 256 g mol-1 W2 =?
Using formula, W2 = M2×W1×ΔTf1000×Kf
= 256×75×0.481000×5.12 = 1.8 g
21.Define an ideal solution and write one of its characteristics. (Delhi 2014)
Those solutions which are obeying Raoult’s law are called ideal solutions. An ideal
solution is a solution in which no volume change and no enthalpy change takes place
on mixing the solute and the solvent in any proportion.
Characteristic of an ideal solution :
There will be no change in enthalpy ∆Hmix = 0,
∆Vmix = 0, ∆Pmix = 0
22.State Henry’s law. What is the effect of temperature on the solubility of a gas in
a liquid? (Delhi 2014)
Henry’s law : Henry’s law states that, “The solubility of a gas in a liquid at a particular
temperature is directly proportional to the pressure of the gas in equilibrium with the
liquid at that temperature.” Solubility of gas decreases with increase of temperature at
the same pressure.
23.State Raoult’s law for the solution containing volatile components. What is the
similarity between Raoult’s law and Henry’s law? (Delhi 2014)
Raoult’s law : “In a solution, the vapour pressure of a component at a given temperature
is equal to the mole fraction of that component in the solution multiplied by the vapour
pressure of that component in pure state.”
Similarity between Raoult’s law and Henry’s law is that the partial pressure or vapour
pressure of the volatile component (gas) is directly proportional to the mole fraction of
that component in the solution.
28.(i) On mixing liquid X and liquid Y, volume of the resulting solution decreases.
What type of deviation from Raoult’s law is shown by the resulting solution?
What change in temperature would you observe after mixing liquids X and Y?
(ii) What happens when we place the blood cell in water (hypotonic solution)?
Give reason. (All India 2015)
(i) Volume decreases by mixing X and Y. It shows negative deviations from Raoult’s
law. There will be rise in temperature. (∆Hmix < 0)
(ii) Blood cell will swell due to osmosis as water enters the cell.
43.What mass of ethylene glycol (molar mass = 62.0 g mol-1) must be added to
5.50 kg of water to lower the freezing point of water from 0° C to -10.0° C? (K, for
water = 1.86 K kg mol-1)? (All India 2010)
According to the formula :
46.Calculate the amount of KCl which must beadded to 1 kg of water so that the
freezing point is depressed by 2K. (Kf for water = 1.86 K kg mol-1) (Delhi 2012)
Since one mol of KCl gives 2 mole particles,
the value of i = 2, ΔTf, = 2K, Kf = 1.86 kg mol-1
Applying equation, ΔTf = iKf
m = ΔTfiKf=22×1.86=11.86 = 0.54 mol kg-1
∴ 0.54 mole of KC1 should be added to 1 kg of water
Molar mass of KCl = 39 + 35.5 = 74.5 g
∴ Amount of KCl = 0.54 × 74.5 g = 40.05 g
47.A solution of glycerol (C3H8O3) in water was prepared by dissolving some
glycerol in 500 g of water. This solution has a boiling point of 100.42 °C while
pure water boils at 100 °C. What mass of glycerol was dissolved to make the
solution? (Delhi 2012)
ΔTb = (100.42 – 100)°C = 0.42°C or 0.42 K
ΔTb = Kb m
0.42 = 0.512 × W292×1000500
W2 = 0.42×92×5000.512×1000=4.830.128 = 37.7 g
where W2 is the weight of the solute.
48.15.0 g of an unknown molecular material was dissolved in 450 g of water. The
resulting solution was found to freeze at -0.34 °C. What is the molar mass of this
material? (Kf for water = 1.86 K kg mol-1) (Delhi 2012)
As ΔTf = Kf × m
60.Calculate the mass of a non-volatile solute (molecular mass 40) which should
be dissolved in 114 g octane to reduce the vapour pressure to 80%. (Comptt.
Delhi 2016)
MB = 2×18×1.0130.009×98 g mol-1
MB = 41.3 g mol-1
62.A 10% solution (by mass) of sucrose in water has freezing point of 269.15 K.
Calculate the freezing point of 10% glucose in water, if freezing point of pure
water is 273.15 K.
Given: (Molar mass of sucrose = 342 g mol-1) (Molar mass of glucose = 180 g mol-1)
(Delhi 2017)
Molality (m) = w×100W×M
Given:
Molar mass of sucrose
= C12H22O11 = 12 × 12 + 22 + 11 × 16 = 342
10% solution (by mass) of sucrose in water means 10 g of sucrose is present in (100 –
10)
= 90 g of water
10% solution of sucrose means, w = 10 g
Mass of water, W = 90 g
67.(a) Define the terms osmosis and osmotic pressure. Is the osmotic pressure of
a solution a colligative property? Explain.
(b) Calculate the boiling point of a solution prepared by adding 15.00 g of NaCl to
250.0 g of water.
(Kb for water = 0.512 K kg mol-1, Molar mass of NaCl = 58.44 g) (Delhi 2011)
Osmosis : The net spontaneous flow of the solvent molecules from the solvent to the
solution or from a less concentrated solution to a more concentrated solution through a
semipermeable membrane is called osmosis.
Osmotic pressure : The minimum excess pressure that has to be applied on the
solution to prevent the entry of the solvent into the solution through the semipermeable
membrane is called the osmotic pressure.
The osmotic pressure method has the advantage that it uses molarities instead of
molalities and it can be measured at room temperature.
(ii) Raoult’s law : For a solution of volatile liquids the partial vapour pressure of each
component of the solution is directly proportional to its mole fraction present in solution.
P = P°x
Non-ideal solution shows positive and negative deviations from Raoult’s law.
Positive deviation from Raoult’s law : The total vapour pressure for any solution is
greater than the corresponding ideal solution of same composition. Such behaviour is
called positive deviation.
Example : Mixtures of ethanol + cyclohexane
Mixture of acetone + carbon disulphide
Negative deviation from Raoult’s law: When the total vapour pressure will be less
than corresponding vapour pressure, then it is termed as negative deviation.
Example : Chloroform + Benzene Chloroform + Diethylether
69.(a) Differentiate between molarity and molality in a solution. What is the effect
of temperature change on molarity and molality in a solution?
(b) What would be the molar mass of a compound if 6.21 g of it dissolved in 24.0 g
of chloroform form a solution that has a boiling point of 68.04°C. The boiling point
of pure chloroform is 61.7°C and the boiling point elevation constant, K b for
chloroform is 3.63°C/m. (Delhi 2011)
(a) Distinction between molarity and molality.
Molarity : It is the number of moles of solute dissolved in 1 litre of solution. It is
temperature dependent.
M = ω×1000 mol.mass ×V
Molality : It is the number of moles of solute dissolved in 1 kg of the solvent.
m = ω×1000M2×W
The relationship between molarity and molality is
m = Md−MM21000
When molality = molarity, we get,
1 = 1d−MM21000 or d – MM˙21000 = 1
∴ d = 1+MM21000
Molarity is temperature dependent while molarity is not.
For very dilute solution, the factor MM2/1000 can be neglected in comparison to 1.
Hence molality will be same to molarity when density d = 1.
Molality is independent of temperature, whereas molarity is a function of temperature
because volume depends on temperature and mass does not.
(b) Given : w2 = 6.21 g, w1 = 24 g
ΔTb = Tb – T°b = 68.04 – 61.7 °C
= 6.34 °C
Kb = 3.63 °C/m, M2 = ?
Substituting all these values in formula given below
∴ Molar mass of the compound, M = 148.14 g mol-1
75.(a) A 5% solution (by mass) of cane-sugar in water has freezing point of 271 K.
Calculate the freezing point of 5% solution (by mass) of glucose in water if the
freezing point of pure water is 273.15 K.
[Molecular masses : Glucose C6H12O6 : 180 amu; Cane-sugar C12H22C11 : 342 amu]
State Henry’s law and mention two of its important applications. (Comptt. All
India 2013)
Molality of sugar solution
(b) Henry’s law : Henry’s law states that, “The solubility of a gas in a liquid at a
particular temperature is directly proportional to the pressure of the gas in equilibrium
with the liquid at that temperature.”
Solubility of gas decreases with increase of temperature at the same pressure.
(b) 10% glucose means 10 g in 100 g solution or, 90 g of water = 0.090 kg of water
78.(a) What is van’t Hoff factor? What types of values can it have if in forming the
solution, the solute molecules undergo
(i) Dissociation? (ii) Association?
(b) How many mL of a 0.1 M HCl solution are required to react completely with 1 g
of a mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?
(Molar mass : Na2CO3 = 106 g, NaHCO3 = 84 g) (Comptt. All India 2014)
(a) (i) Van’t Hoff factor : It is defined as the ratio of the experimental value of the
colligative property to the calculated value of the colligative property .
i = Experimental value Calculated value
If there is dissociation of the solute in the solution, the Van’t Hoff factor T’ will be greater
than one i.e. i > 1.
It means observed colligative property will be greater than calculated value.
(ii) Association : If there is association of solute in the solution, the Van’t Hoff factor ‘f’
will be less than one i.e. i < 1. Thus, observed colligative property will be less than the
calculated value.
(b) Calculation of no. of moles of the components in the mixture
Suppose Na2CO3 in the mixture = x g
∴ NaHCO3 in the mixture = (1 – x) g
Molar mass of Na2CO3 = 106 g mol-1
Molar mass of NaHCO3 = 84 g mol-1
∴ Moles of Na2CO3 = x106
and Moles of NaHCO3 = 1−x84
As the mixture contains equimolar amounts of both
No. of moles of HCl required
Na2CO3 + 2HCl → 2NaCl + H2O + CO2
NaHCO3 + HCl → NaCl + H2O + CO2
1 mole of Na2CO3 requires HC1 = 2 moles
∴ 0.00526 mole of Na2CO3 requires HCl
= 0.00526 × 2 = 0.01052 mole
Similarly, 0.00526 mole of NaHCO3 requires
HCl = 0.00526
∴ Total HCl required = 0.01052 + 0.00526 = 0.01578 moles
Thus 0.1 mole of HCl is present in 1000 mL of HCl
∴ 0.01578 mole of HCl present in 1000 mL
= 10000.1 × 0.01578 = 157.8 mL
79.(a) Define
(i) Mole fraction (Hi) Raoult’s law
(b) Assuming complete dissociation, calculate the expected freezing point of a
solution prepared by dissolving 6.00 g of Glauber’s salt, Na 2SO4.10H2O in 0.100 kg
of water. (Kf for water = 1.86 K kg mol-1, Atomic masses : Na = 23, S = 32, O = 16, H
= 1) (Comptt. All India 2014)
(a) (i) Mole fraction : Mole fraction is the ratio of number of moles of one component to
the total number of moles in a mixture.
(ii) Molality of a solution : Molality of a solution is defined as the number of moles of
the solute dissolved in 1000 grams (1 kg) of the solvent. It is denoted by’m’.
m = w×1000M×W
Where
‘w = Weight of solute in grams
M = Molecular mass of solute
W = Weight of solvent in grams
(ii) Raoult’s law : For a solution of volatile liquids the partial vapour pressure of each
component of the solution is directly proportional to its mole fraction present in solution.
P = P°x
Non-ideal solution shows positive and negative deviations from Raoult’s law.
Positive deviation from Raoult’s law : The total vapour pressure for any solution is
greater than the corresponding ideal solution of same composition. Such behaviour is
called positive deviation.
Example : Mixtures of ethanol + cyclohexane
Mixture of acetone + carbon disulphide
Negative deviation from Raoult’s law: When the total vapour pressure will be less
than corresponding vapour pressure, then it is termed as negative deviation.
Example : Chloroform + Benzene Chloroform + Diethylether
80.Calculate the freezing point of solution when 1.9 g of MgCl 2 (M = 95 g mol-1) was
dissolved in 50 g of water, assuming MgCl2 undergoes complete ionization.
(Kf for water = 1.86 K kg mol-1)
(b) (i) Out of 1 M glucose and 2 M glucose, which one has a higher boiling point
and why?
(ii) What happens when the external pressure applied becomes more than the
osmotic pressure of solution? (Delhi 2016)
(a) Since MgCl2 is an ionic compound, so it undergoes complete dissociation.
(b)
(i) 2M glucose will have a higher boiling point than 1M glucose because elevation in
boiling point is a colligative property which depends upon the number of particles in the
solution which is more in the case of 2M glucose solution.
(ii) When the external pressure applied becomes more than the osmotic pressure of the
solution, then the solvent will flow from the solution into the pure solvent through the
semi-permeable membrane. The process is called reverse osmosis (RO).
81.(a) When 2.56 g of sulphur was dissolved in 100 g of CS 2, the freezing point
lowered by 0.383 K. Calculate the formula of sulphur (S x).
(Kf for CS2 = 3.83 K kg mol-1, Atomic mass of Sulphur = 32 g mol-1)
(b) Blood cells are isotonic with 0.9% sodium chloride solution. What happens if
we place blood cells in a solution containing
(i) 1.2% sodium chloride solution?
(ii) 0.4% sodium chloride solution?(Delhi 2016)
(a) Given: wb = 2.56 g wa = 100 g = 0.1 kg
ΔTf = 0.383 K Kf= 3.83 K kg mol-1
Atomic mass of sulphur = 32 g mol-1
Mb = ?
Using formula,
∴ Mb = 256 g mol-1
Hence the no. of atoms present in one molecule of sulphur = 25632 = 8
∴ the formula is S8.
(b) (i) If RBCs are placed in contact with 1.2% NaCl solution, then the osmotic pressure
of 1.2% NaCl becomes higher than that of RBCs due to which water present inside the
cells moves into the NaCl solution which results in shrinkage of RBCs.
(ii) Reverse process will take place if RBCs are kept in contact with 0.4% NaCl solution
which has less osmotic pressure ’ due to which water moves into RBCs and they will
swell.
82.(a) A 10% solution (by mass) of sucrose in water has a freezing point of 269.15
K. Calculate the freezing point of 10% glucose in water if the freezing point of
pure water is 273.15 K.
Given: (Molar mass of sucrose = 342 g mol-1) (Molar mass of glucose = 180 g mol-1)
(b) Define the following terms:
(i) Molality (m)
(ii) Abnormal molar mass (All India 2017)
(a) Molality (m) = w×100W×M
Given:
Molar mass of sucrose
= C12H22O11 = 12 × 12 + 22 + 11 × 16 = 342
10% solution (by mass) of sucrose in water means 10 g of sucrose is present in (100 –
10)
= 90 g of water
10% solution of sucrose means, w = 10 g
Mass of water, W = 90 g
(b)
(i) They obey Raoult’s law over the enitre range of (i) They do no obey Raoult’s law over the entire range
concentration. concentration
84.(a) Explain why on addition of 1 mol glucose to 1 litre water the boiling point of
water increases.
(b) Henry’s law constant for CO2 in water is 1.67 × 108 Pa at 298 K. Calculate the
number of moles of CO2 in 500 ml of soda water when packed under 2.53 × 105 Pa
at the same temperature. (Comptt. All India 2017)
(a) Glucose is a non-volatile solute, therefore, addition of glucose to water lowers the
vapour pressure of water as a result of which boiling point of water increases.
(a) (i) Ideal solution : The solutions which obey Raoult’s law over the entire range of
concentration are known as ideal solutions.
(ii) The minimum excess pressure that has to be applied on the solution to prevent the
entry of the solvent into the solution through the semipermeable membrane is called the
osmotic pressure.