EXTRA EDG - CHEMISTRY | JEE (MAIN + ADVANCED) PERIODIC TABLE (& competishun Orrice Appress 980-981, Suanti Nacar (Roap No. 3), Near Durcarura Raiway STATION Jarpur-302018, (Ras.) www.competishun.com Mob. 7410900901, 7410900906, 7410900907, 7410900908ERRPIE IS PART-| : SINGLE AND DOUBLE VALUE INTEGER TYPE 1. 10. n. 12. 13, 14. 15. 16. 47. Identify the group (in Modern Periodic Table) and valency of a hypothetical element having atomic number 119. If group number is x and valency is y. Give the the value of x + y. An element belonging to 3d series of modem periodic table has spin magnetic moment = 5.92 B.M. in +3, oxidation state. Determine the atomic number of element. ‘An element has atomic number 29. It belongs to x period and y group. Give value of 2x + y How many of the following have greater Z,, than Silicon atom Na, Mg,Al,P,CI,S,N,O,C,F ‘The most stable oxidation state of chromium is +n, Give the value of ' How many of the following compounds are found to exist ? BiF,, T/l,, PbO,, SnCL,, T/,0,, Pbl,, As,0, ‘The Lanthanides are characterized by the uniform [+n] oxidation state shown by all the Lanthanides . What is the value of ir? Highest oxidation states shown by Chromium & Manganese are +x & +y respectively. Give the value of x+y? If internuclear distance between A atoms in A, is 10A and between B atoms in B, is 6A, then calculate internuclear distance between A and B in A. (Electronegativity difference between A and B has negligible value] Report atomic number of the element having largest size among the following : Ni, Cu, Zn How many of following atoms have maximum ionization energy than boron, Be, NP. Ga, S, Mg ‘Atomic number Where a, b, c,d, e, f,g, hare 3* period elements. If difference between atomic number of elements b and @ is x and difference between atomic number of elements c and fis y. What is the value of x -y. Values of IE, IE,, IE, of an element are 9.3, 18.2 and 553.8 eV. Predict group number in Modern Periodic Table, A (g) >A* (9) AH = 1100 KJ/mol A(g) >A* (g) ‘AH = 1200 KJ/mol Electron gain enthalphy of Ais P x 10? KJmol. What is the value of P ? The electron gain enthalpy of a hypothetical element ‘A’ is ~3 eV per atom, How much energy in kCal is released when 10 g of ‘A’ are completely converted to A ions in gaseous state ? (Take : 1 eV per atom = 23 kCal mot", Molar mass of A= 30 g) What is atomic number of element which have maximum electron affinity in Modern Periodic table, How many of the following elements are more electronegative than Boron. H, Li, Be, C, N, 0, F www.competishun.com PAGE#1ERRPIE IS RANKER’S PROBLEMS 2S 8 PART - |: OBJECTIVE QUESTIONS Single choice type The places that were left empty by Mendeleev in his periodic table were for (A) aluminium and silicon (B) gallium and germanium (C) arsenic and antimony (D) molybdenum and tungsten The elements which exhibit both vertical and horizontal similarities are (A) inert gas elements (B) representative elements, (C) transition elements (D) none of these Of the following pairs, the one containing examples of metalloid elements is. (A) Band Al (B) Gaand Ge (C)Aland si (D)Asand Sb Which of the following is the wrong statement ? (A)Allthe actinide elements are radioactive. (8) Alkali and alkaline earth metals are s-block elements. (C) Phicogens and halogens are p-block elements. (D) The first member of the lanthanide series is lanthanum. Atomic number of 15, 33, 51 represents the following family (A) carbon family (B)nitrogen family (C) oxygen family (D) None of these ‘According to Modern periodic table, Chalcogens are elements of (A) group 16 (8) p-block (C)ns*np‘configuration (D) all ofthese Which set does not shows correct matching according to Modem periodic table (A) Cr= [Ar] 3d° 4s'; element belongs to 6° group. (8) Fe* = [Ar] 3d®; element belongs to 8" group. (C) Sc* = [Ne] 3s? 3p*, element belongs to zeroleighteen group. (O)Allofthe above. 8 Which of the following statement is wrong for the d-block elements (A) General electronic configuration for them is (n — 1)d"-"°ns? (8) They generally exhibit variable valency. (C) Last electron enters in (n~ 1)d subshell in them. (D) They are placed from 3" to 6” period in modern periodic table. 9. _Inwhich element shielding effectis not possible ? (AH (B)Be (CB (O)N 10. Inagiven energy level, the order of penetration effect of different orbitals is ()i F (B)S>F «o N,0,> CO, > SiO, (8)S0,CO,N,0, > CO, S*(g) (B) Ne(g) + e°—> Ner(g) (C)N(g) +e" —> Ng) (D)AP*(g)—> Al*(g) +e Select the incorrect statement(s). (AJIE, of nitrogen atom is less than IE, of oxygen atom. (8) Electron gain enthalpy of oxygen is less negative than selenium. (C) Electronegativity on Pauling scale is 2.8 times the electronegativity on Muliken scale. (D) Cris smaller than Ce Which is/are incorrect order for the properties specified ? (A) L> Br> Cl> F (oxidising character) (8) K>Mg>Al>B (metallic character) (©) Li Na>K>Rb> Cs (chemical reactivity) www.competishun.com PAGE#4ERRPIE IS Land Med ELON OBOE en tS) 1. 10. n. 12. 13, 14. Group the elements, whose atomic numbers are given below, into various blocks in Modern periodic table 19, 25, 31, 38, 42, 54, 64, 105 Whats the name given to the elements which represent the properties of lower elements of their respective {group in Modern periodic table ? These elements belong to which period in Modem periodic table ? A particular atom having atomic number between 22 to 30 has spin magnetic moment equal to 1.73 B.M. Then find the atomic number of the element which is just below itin the Modern periodic table Compare the screening effect of a d-electron with a f-and a p-electron. Arrange the following in order of atomiclionic radius (NP Ast (i) Cr, Mn, Fe (i) Cu, Zn Why the I* ionisation enthalpy of nitrogen is higher than oxygen and opposite is true for second ionisation enthalpy? Compare qualitatively the first and second ionization potentials of copper and zinc. Explain the observation. The alkali metals (IA) and coinage metals (IB) seem to have the same outer electronic configuration ns’ (n= principal quantum number of outermost shell), but group (IB) elements are more stable than group (IA) elements. Explain, Nat has higher value of ionisation enthalpy than Ne, though both have same electronic configuration. Explain. Give the variation of (2) lonisation enthalpy in Group 14 of Modern periodic table. (b) Pauling’s electronegativity in Group 13 of Modern periodic table, The ionisation enthalpies of atoms Aand B are 400 and 300 kCalmot respectively. The electron affinities of these atoms are 80 and 90 kCalmot- respectively. Determine which of the atoms have higher electronegativity on Pauling scale. (Take : 23.1 * 5.6 = 130) Calculate the % ionic character in AB molecule according to Hany Smith formula, if bond enthalpy (in kCal/ mal) of ‘AB molecule is 6 units. ‘AA molecule is 4 units BB molecule is 1 unit. Take: 0.104 x 2=0.2 Electrons of which subshell do not participate in bonding due to inert pair effect ? Arrange the following in correct order of reducing capacity Ge*, Sn, Ph www.competishun.com PAGE#SERRPIE IS aise Sa PART -1 402 2 6 3 9 4 7 53 6 6 2 3 & 2B 9 8 1. 3 M2 120 13.2 14. RANKER'S PROBLEMS PART -1 ® 2 © 3 © 4 © 5B) 6. © z © 2 © 2 A) 10. (©) 1 A) 12 (A) 13. (A) 4. © 15. (A) 6. ©) 7 © 18. (A) 12. 8) 20. © 2. © 2 © 23. (A) 24. 8) 25. 8) 26. (ABCD) 27. (AC) 28. (AD) PART -Il 1. stblock: 19,38; p-block: 31, 54; d:block : 25, 42, 105 ; f-block : 64 2. Typical elements ; third period. Ex. : Na, Mg, Al, Si, P, S Cl 47 More than f-electron and less than p-electron. Orderis:s > p>d>f 5. (NN < P< Ast (i) Cr=Mn= Fe (ii) CuSi>Ge>Sn Al Sn**> Pb*. www.competishun.com PAGE#6