_ CHEMISTRY | JEE (MAIN + ADVANCED) EXTRA EDGE SuRFACE CHEMISTRY & competishun een Te Orrice Appress 980-981, Suanti Nacar (Roap No. 3), Near Durcarura Raiway STATION JatPuR-302018, (Ras) www.competishun.com Mob. 7410900901, 7410900906, 7410900907, 7410900908RUSS SINGLE AND DOUBLE VALUE INTEGER TYPE When a graph is plotted between log xm and log p, itis straight line with an angle 45° and intercept 0.3010 on y-axis. If initial pressure is 0.3 atm, what willbe the amount of gas adsorbed per gram of adsorbent (Report your answer after multiplying by 10) The volume of nitrogen gas (measured at STP) required to cover a sample of slica gel with a mono-molecular layer is 129cm’/g of gel. Calculate the surface area per gram of the gel if each nitrogen molecule occupies 16.2x 10m. (Report your answer after dividing by 10) How many of these reactions are homogeneously catalyzed? ( 280,(g)+0,(g) 24280, (9) (i) C,.H,.0,,(aa) + H,0() "5 C,H,,0,(aq) + C,H,.0.(24) Glucose Fructose (ii) 2505(g) +0,(g) * +280,(9) ((v) N_(g) + 3H-(g)—2NH,(9) (V) 4NH,(g) +50, (g) "> 4NO(g) + 6H.,0(9) (vi) CH,COOCH,() 2 >CH,COOH(aq) (vil) Vegetable oils (#) +H,(g)—*> Vegetable ghee (s) Coagulation value of the electrolytes AICI, and NaCl for As,S, sol are 0.093 and $2 repectively. How many times AICI, has greater coagulating power than NaCl. Among the following number of correct statements are (i) Stabilty of lyophilc colloids is mainly due to the strong interaction between dispersed particle and cisper- sion medium. {i Entropy change for adsorption of gases over solid is postive, (ii) Gelatin has considerably low value of gold number and is effective protective colloid (iv) Zeta potential is also responsible for stabilty oflyophobic colloid solution. (v) Surface tension of lyophilc colloidal solution is lesser than that of dispersion medium For the just coagulation of 250 mL of Fe(OH), sol, 2 mL of 1 M Na,SO, electrolyte is required. What is the coagulating value of Na,SO, electrolyte. The minimum concentration ofan electrolyte required to cause coagulation ofa sols called its flocculation value. Itis expressed in millimoles per ire. Ifthe flocculation value of MgSO, for standardAs,S, solis 3.33, How many milligrams of MgSO, is to be added to 20 ml standard As,S, sol so that flocculation just starts ? ‘www.competishun.com PAGE#1RUSS RANKER’S PROBLEMS 10. 1. 12, 13. 14. 15. For adsorption ofa gas on a solid, the plot of log (x/m) Vs log Ps linear with a slope equal to Inbeing a whole number] kK (8) log k @©n (0) 1m Surface tension of lyophilic sols is (A) Lower than that of HO (8) More than that of H,O (©) Equalto that of HO (D) None of the above (On passing light from collidal solution, the effect due to scattering of light is known as (A)Electrophrosis _(B) Tyndall effect. (©) Electromosis, (0) Coagulation ‘The solution in which the light is scattered by the particles is (A) Suspension (8) Colloidal solution _(C) True solution {D) None ofthese Blood is purified by (A) Dialysis (B)Electro-osmosis _(C) Coagulation (0) Filtration ‘An arsenious sulphide sol carries a negative charge. The maximum precipitating power ofthis sol is possessed by (A)K,SO, (8) CaCl, (C)Na,PO, (MAIC, ‘Tyndall effect is shown by (A)Sol (6) Solution. (©) Plasma (0) Precipitation ‘According to Hardy - Schulze rule, the coagulating power of cation follows the order (A) Nat > Ba** > Al (B)AI"> Ba**> Na’ (C) Ba" > AI > Nav (D) AI > Na*> Ba” Mik is an example of (A) True solution (8)Gel (C) Suspension (0) Emulsion ‘Most effective ion to coagulate a negative solis (A)PO, (BA (©) Ba (OK Which of the following electrolytes will be most effective in the coagulation of gold sol (A) NaNO, (8) KAFe(CN),} (C)Na,PO, (0) MgCl, The property of colloid is (A) Scattering flight (B) Shows attraction _(C) Dialysis (0) Emulsion The stability of lophilic colloid is due to which of the following (A) Charge on their particles (8) Large size of their particles (C) Small size oftheir particles (D) Solvation by dispersion medium A colloidal solution is subjected to an electrical field. The particles move towards anode, The coagulation of the same solution is studied using NaCI, BaCl, and AICI, solutions. Their coagulating power should be (A) NaCl> BaCl, > AICI, (8) BaCl, > AICI, > NaCl (C)AICI, > BaCl, > Nacl (D) BaCl, > NaCl >AICL, Which of the following is most effective in coagulating a ferric hydroxide sol (akc (B) KNO, (©)K,SO, (0) KFe(CN),) ‘www.competishun.com PAGE#2RUSS 16. 17. 18, 19. 20. 2. 22. 23. 25. 28. 2. 28. 29. 30. at. 32. Which one is colloid (A) Nac (8) Urea (C) Cane Sugar (0) Blood Fog is an example of colloidal system of (A) Liquid dispersed in gas (6) Gas dispersed in gas (©) Solid dispersed in gas (0) Solid dispersed in liquid Which is the correct statement in case of milk (A) Milk is an emulsion of fat in water (8) Mik is an emulsion of protein in water (C) Mik is stabilized by protein (D) Mik is stabilized by fat The charge on As,S, sol is due to the adsorbed wH (ROH (0? os The sky looks blue due to (A) Dispersion (B) Reflection (C) Transmission (0) Scattering Gold number is minimum in case of (A) Gelatin (8) Egg albumin (©) Gumarabic (0) Starch ‘Tyndall effect will be observed in (A) Solution (8) Percipitate (©) Sol (0) Vapour ‘The Brownian motion is due to (A) Temperature fluctuation within the liquid phase (B)Attraction and repulsion between charge on the colloidal particles (C) Impact of molecules of the dispersion medium on the colloidal particles (0) Convective current In coagulating the colloidal solution of As,S, which has the minimum coagulating value (A) Nac (e)KcI (©)Bacl, (OAC, The size of a colloidal particle is (ay> ot (6) tmp too. ( 1) (ii) 1m = constant x p(n > 1) (A)Allare correct (B)Allare wrong (©) (iscorect (0) ii)is correct ‘The principle(s) involved in the chromatographic operation is (are) (A) Adsorption (8) Absorption (©) Pattition (O) None ‘The physical adsorption of gases on the solid surface is due to (A) vander Waals forces (B)covalent bonding —_(C) hydrogen bonding __(D) All of these. Correct equation of Freundlich isotherm is logk+ + og log 1 x log + loge { =log 6+ + tog Identify the correct statement regarding enzymes, (A) Enzymes are specific biological catalysts that can normally function at very high tempt. (T = 1000 K) (B) Enzymes are normally heterogeneous catalysts that are very specific in action (©) Enzymes are specific biological catalysts that can not be poisoned (0) Enzymes are non-biological catalysts. More than one choice type 55. 56. 87. The size of colloidal particles is (A) 1-108, (8) 20-50A (©) 10-100A (0) 12004 Which of the following statements is correct? (A) The efficiency of a heterogeneous catalyst depends upon its surface area. (B) Catalyst operates by providing alternate path for the reaction that involves a lower activation energy. (C) Catalyst lowers the energy of activation of the forward direction without affecting the energy of activation of the backward direction, (D) Catalyst does not affect the overall enthalpy change of the reaction, Which of the following statements is (are) true? (A) The concentration of a homogeneous catalyst may appear in the rate expression, (B) A catalyst is always consumed in the reaction. (C)A catalyst must always be in the same phase as the reactants, (D) None of these ‘www.competishun.com PAGE#S:RUSS Comprension # 59. 60. et. 62. 63. Read the following passage carefully and answer the questions. ‘The Colloidal particles are electrically charged ass indictated by their migration toward cathode or anode under the applied electric field. In a particular colloidal system, all particles carry either positive charge or negative charge. The electric charge on colloidal particles originate in several ways. According to preferential adsorption theory the freshly obtained precipitate particles adsorb ions from the dispersion medium, which are common tothe lattice and acquire the charge of adsorbed ions, For example, freshly obtained Fe(OH), precipitated is dispersed, by litle FeCl, into colloidal solution owing tothe adsorptions of Fe" ions in preference. Thus sol particles wll be positively charged. In some cases the colloidal particles are aggregates of cations or anions having ampiphilc character. When the ions possess hydrophobic part (hydrocarbon end) as well as hydrophilic part (polar end group), they undergo association in aqueous solution to form particles having colloidal size. The formation of such parties, called micelles plays a very important role inthe solubilization of water insoluble substances, (hydrocarbon, oils, fats, grease etc) In micelles, the polar end groups are directed towards water and the hydrocarbon ends into the centre The charge on sol particles of proteins depends on the pH. At low pH, the basic group of protein molecule is ionized (protonated) and at higher pH (alkaline medium), the acidic group in ionized. At Isoelectric pH, characteristic othe protein, both basic and aciaic groups are equally ionized. The stabiity of colloidal solution is attributed largely tothe electric charge of the dispersed particles. This charge causes them to be coagulated or precipitated. On addition of small amount of electrolytes, the ions carrying opposite charge are adsorbed by sol particles resulting inthe neutralization oftheir charge When the sol particles either with no charge or reduced charge, come closer due to Browman movernent, they coalesce to form bigger particles resulting in their separation from the dispersion medium. This is what is called coagulation or precipitation ofthe colloidal solution. The coagulating power ofthe effective ion, which depend on its charge, is expressed in terms of its coagulating value, defined as its minimum concentration (mmolL) needed to preciptate a given sol ‘A gelatin sol at pH less then the isoelectric value is subjected to an electric field, The sol particles migrate toward (A) Anode (B) Cathode (C) Both anode and cathode (D) Neither anode nor cathode Which of the following fons would have the minimum coagulating value for sol obtained on peptizing Sn(OH), by little NaOH solution cr (8) soz wok (0) Ba How would you obtain a sol of Agl, the particles of which migrate toward cathode under the electric field ? (A) By adding little excess of KI to AgNO, solution (B) By adding little excess of AgNO, to KI solution (C) By mixing equal volumes of 0.010 MAgNO, and 0,010 M KI (D) None of these When 9.0 mlof arsenius sulphide sol and 1.0 mi of 1.0 « 10“ M BaCl, are mixed, turbidity due to precipitation just appears after 2 hours. The effective ion and its coagulating value are respectively (A)Cr, 10mmolL —(B) Cr, 20mmolL_—(C) Ba", 10 mmol (D) Ba** , 20m mol 100 ml each of two sols of Agl, one obtained by adding AgNO, to slight excess of KI and another obtained by ‘adding KI to slight excess of AgNO, are mixed together. Then (A) The two sols will stabilize each other (8) The sol particles will acquire more electric charge (C) The sols will coagulate each other mutually _(D) Atrue solution will be obtained Under the influence of an electric field, the particles in a sol migrate towards cathode. The coagulation of the same sols studied using NaCl, Na,SO, and Na,PO, solutions. Their coagulating values willbe in the order (A) NaCI> Na, SO, > Na,PO, (8) Na, SO, > Na, PO, > NaCl (©)\Na, PO, > Na,SO,> NaCl (0) Na, $0, > NaCl > Na,PO, ‘www.competishun.com PAGE#6PART PUA OTOL EU CO 1. What is meant by the colloidal state of matter? Explain the following terms: () Muttimolecular colloids (ii) Electro-dialysis 2. What are micelles? Give an example of micellar system. 3. The zig-zag motion of colloidal particles is called. 4, What are micelles? How do they differ rom a normal colloidal solution? 5. The colloidal dispersions of liquids in solid media are called. 6 Describe the following terms while stating the properties of colloids: () Brownian movement (i) Tyndall effect (ii) Electrophoresis 7. Explain the terms: _Physisorption and Chemisorption. How does adsorption of a gas on a solid surface vary with pressure? 8 Whatiis observed when a beam of light is passed through a colloidal solution of arsenius sulphide? 8. What are lyophilc and lyophobic sols? Compare the two in terms of stabllty and reversibity 10. Explain the terms shape selective catalyste, emulsification and dimulsifcation with one example each. 14. Expiain the terms Brownian movement’ and ‘peptization’ 42. Explain the terms ‘muitimolecular colloids’ and ‘macromolecular colloids’ 13. Explain the difference between a homogeneous and heterogeneous catalyst. Give an example of each. MATCH THE COLUMN : 14. Column (1) Column (il) (A) Gold sol (p) Bredig's Arc method (8) Purification of colloidal solution _(q) Negatively charged ()As,S, sol (0 Uttra centrifugation (0) Zeta potential (s) Electro kinetic potential (€) Casein () Double decomposition reaction (u) Protective colloid 45. Column (1) Column (i) (A) Tyndall effect ()Zig-2ag motion (8) Brownian movement (@) Sky is blue (©) Electrophoresis (0 Coagulation of colloids (0) Hardy schulze rule (s) Charge on colloidal solution (€) Froth floatation () Emulsion of pine oil (v) Gold number ee aRR ‘ww.competishun.com PAGE#7RUSS tae 1 6 2 6 3. 3(iivi a) 54 6 8 m8 RANKER'S PROBLEMS PART-I 1. (0) 2. (A) 3. @) 4. (6) 5. (A) 6. oO) 1 (A) 8. (8) 9. (2) 10. (8) n. (2) 12. (A) 13. (0) 14, () 15. (oO) 16. (.) 17. (A) 18. A 19. (D) 20. () 2. A 22. () 23. © 24. (D) 28. (8) 26. (c) 27. () 28. () 29. () 30. (8) 3. © 32. (C) 33. A 4. (D) 36. (A) 36. © 37. (8) 38. @) 39. (D) 40. (A) 4.) 2 ©) a A) “4 © 4% 6) 46. A 47. (6) 48. © 49. (A) 50. © 51. A 52. (A) 53. A 54. (8) 55. (B.C) 56. (A.B,D) 87. (A) 58. @) 59. (0) 60. (8) 61. © 62. () 63. A) PART-II 1. (i) Multimolecular colloids : In this type, the particles consist of an aggregate of atoms or small molecules size less than 1 nm, For example, sols of gold atoms and sulphur (S,) molecules. In these colloids, the particles are held together by van der Waal's forces. (li) Movement of ions across the membrane can be expedited by applying electric potential through two electrodes as shown in fig. This method is faster than simple dialysis and is known as Electrodialysis. To) 55500. Distiled water Cellophane bag Fig. : An apparatus for electrodialysis. www.competishun.com PAGE#SRUSS 10. 1. 12, 13, 14, 15, ‘Associated colloids (Micelles): These are the substances which behave as normal trong electrolytes at low concentration but behave as colloidal particles at higher concentration. These associated particles are also called micelles. Ex. Soap. ‘The zig-zag motion of colloidal particles is called Brownian movement. Micelles are associated colloic |, they have low colgative property than normal colloidal solution, ‘The colloidal dispersions of liquids in solid media are called gel (i) Random motion of colloidal particle is known as Brownian movement (ii) Scattering of light by colloidal particle is known as Tyndall effect (ii) Movement of colloidal particle under the effect of electric field is known as Electrophoresis. Refer Freundlich adsorption isotherm for effect of pressure and adsorption. ‘Scattering of ight occurs (Tyndall effect) Solvent loving colloid is known as lyophilic colloid. They are stable and reversible where as solvent hating colloid is known as lyophobic colloid they are less stable and irreversible. ‘Shape selective catalyst. These catalyst catalyses the reaction because of their specific shape so that reactant is get attached in the pores of shape selective catalyst. Random motion of colloidal particle is known as ‘Brownian movement’ Conversion of precipitate into colloidal sol is known as ‘peptization’ Multimolecular colloids : In this type, the particles consist of an aggregate of atoms or small molecules size less than 1 nm, For example, sols of gold atoms and sulphur (S,) molecules. In these colloids, the particles are held together by van der Waal's forces. Macromolecular colloids : In this types, the particles of the dispersed phase are sufficiently big in size (macro) to be of colloidal dimensions. These macromolecules forming the dispersed phase are generally polymers having very high molecular masses. These colloids are quite stable and resemble true solutions in many respects. Naturally occuring macromolecules are starch, cellulose, proteins, enzymes, gelatin, etc. Homogeneous, NO in lead chamber process, heterogeneous, finely divided nickel in hydrogenation reactions. (A -p, a); (8-1); (C9, 1); (D-s) ; (E-u) (A -@); @=p); (Cs) (D=1)(E-1) ‘www.competishun.com PAGE#S