Atbc MSDS

Material Safety Data Sheet
（MSDS）
In accordance with GHSRev. 6.andThe EU CLPREGULATION (EC) No 1272/2008
NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 1 of 9
Applicant: Lemon-flex Company Limited China

Address: No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Sample information:
Product Trademark: LMFLEX® LM40
Product name: Acetyl tributyl citrate
Sample received date: September 1, 2016
Testing period: From September 1, 2016 to September 5, 2016
Test Requested: As specified by the client, to edit Material Safety Data Sheet (MSDS) for the submitted sample.
Shanghai Changyin Testing Technology Co.,Ltd
Approved by:
Lemon-flex Company Limited China

No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
（MSDS）
Section 1 - Chemical Product and Company Identification

1.1 Product Identification:
Product Trademark: LMFLEX® LM40
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Non-toxic PVC plastic plasticizer
Use advised against: No data available.
1.3 Details of the Manufacture or supplier

Manufacture: Lemon-flex Company Limited China
Address: No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Telephone: +86-0510-87865333
Fax: +86-0510-87866222
Email: hyl@lemonchem.com
1.4 Emergency telephone number

Emergency Telephone: +86-0510-87865333
Section 2 - Hazards Identification

2.1 Classification of the substance or mixture
This product is not classified as dangerous according to the GHS (The Globally Harmonized System of Classification and
Labelling of Chemicals).
2.2 GHS Label elements, including precautionary statements

Pictogram(s): No pictogram is used.
Signal word: No signal word is used.
Hazard statements: No hazard statement.
Precautionary statements: No precautionary statement.
2.3 Description of any hazards not otherwise classified

No information available.

（MSDS）
Section 3 - Composition/Information on Ingredient

Substance （） Preparation （√） Article （）
Composition:
Molecular formula: C20H34O8
Molecular Weight: 402.48
Chemical name CAS No. EINECS No. Content (%)
Acetyl tributyl citrate 77-90-7 201-067-0 >99%
Abbreviation: CAS No. is Chemical Abstract Service Registry Number.
Section 4 - First Aid Measures

4.1 Description of first aid measures
Eye Contact: Immediately flush eyes with plenty of water for several minutes, occasionally lifting the upper and lower eyelids. If
irritation occurs and persists, contact a doctor.
Skin Contact: Wash off with soap and plenty of water. If skin irritation occurs: Get medical advice/attention .
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if feel
unwell.
Ingestion: Never give anything by mouth to an unconscious person. Rinse mouth with water. Seek medical advice
immediately.
4.2 Most important symptoms and effects, both acute and delayed
No information available.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically and supportively.
Section 5 -Extinguishing media

5.1 Extinguishing media
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture

（MSDS）
Combustible exposed to flame and overheat. Gives off irritating fumes (or gases) in a fire: Carbon oxides. In case of overheat,
increased pressure within containers has the risk of cracking and explosion.
5.3 Advice for firefighters
Evacuate personnel to safe areas. Wear self-contained breathing apparatus and suitable protective equipment for firefighting.
Stand upwind.
5.4 Further information
Move container away from fire if safe. Use water fog to cool down fire exposed container.
Section 6 - Accidental Release Measures

For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13
for information on disposal. Observe the relevant local and international regulations.
6.1 Personal precautions, protective equipment and emergency procedures: Ensure adequate ventilation. Use personal
protective equipment. Avoid contact with skin and eyes. For personal protection see section 8.
6.2 Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains or water
source.
6.3 Methods and materials for containment and cleaning up:
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly with water to remove residual
contamination.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Collect with an
electrically protected vacuum cleaner or by wet-brushing and place in closed container for recycle or disposal according to
local regulations (see section 13).
Section 7 - Handling and Storage

7.1 Precautions for safe handling:
Take the usual precautions when handling with chemicals. Use in well-ventilated area. Avoid contact with skin and eyes. Avoid
breathing concentrated vapor or mist. Wash thoroughly after handling. Keep container tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities:

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be
carefully resealed and kept upright to prevent leakage. Keep away from heat and flame. Avoid direct sunlight. Moisture
sensitive, pay attention to moisture. Do not store together with strong oxides. Provide fire fighting equipment and tools for
accidental release.

（MSDS）
Section 8 - Exposure Controls, Personal Protection

8.1 Exposure Limits: Not established.
8.2 Exposure controls
Engineering Control: General industrial hygiene practice. Suggest Proving enough ventilation. Provide wash shower and eye
wash fountain.
Personal protective equipment:
Respiratory Protection: Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK
(EU EN 14387) respirator cartridges. Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).
Eyes Protection: Not required under normal usage. Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU) if in-eye risk exists.
Body Protection: To avoid contaminating personal clothing, wear suitable protective clothing. The type of protective equipment
must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Hands Protection: Handle with chemical-resistant gloves. Use proper glove removal technique(without touching glove's outer
surface) to avoid skin contact with this product.
Other Protections: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Section 9 - Physical and Chemical Properties
Information on basic physical and chemical properties

Appearance Colorless transparent oily liquid
Odor Odorless
pH Not available.
Melting point/freezing point -80℃（101.3KPa）
Initial boiling point and boiling range 331℃-97.64 kPa
Flash point 217℃- closed cup
Evaporation rate Not available.
Flammability Not flammable.
Upper explosive limit %(V/V) Not available.
Lower explosive limit %(V/V) Not available.
Vapor pressure 1.79 kpa at 20℃
Vapor density Not available.

（MSDS）
Relative density 1.05 g/cm3 at 25℃

Solubility(ies) Slightly soluble in water.
Partition coefficient: n-octanol/water log Pow: 4.86 at 40℃
Auto-ignition temperature 206.5℃ at 101.3 kPa
Decomposition temperature Not available.
Viscosity 40.4 mm2/s at 20℃
Section 10 - Stability and Reactivity

10.1 Stability:Stable under recommended storage conditions.
10.2 Conditions to Avoid: heat, flames and mars. Avoid moisture.
10.3 Incompatible materials: Strong oxidant.
10.4 Hazardous Decomposition Products: Other decomposition products- no data available. In the event of fire:see section 5.
10.5 Possibility of hazardous reactions:No data available.
Section 11 - Toxicological Information

Acute Toxicity:
LD50 Oral - Rat - > 31500 mg/kg
LD50 Intraperitoneal - Mouse - > 4000 mg/kg
Skin Corrosion/Irritation:
Skin - Rabbit
Result: No skin irritation
Serious Eye Damage/Eye Irritation:
Eyes - Rabbit
Result: Mild eye irritation
Respiratory or Skin Sensitization: Not sensitive effect.
Germ Cell Mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity：None of the components of this product is listed as a carcinogen by IARC, NTP, US OSHA or the European
Directive (67/548/EEC).
Reproductive Toxicity: Based on available data, the classification criteria are not met.
Specific Target Organ Toxicity - Single Exposure (Globally Harmonized System): No known human health effects upon single
exposure.
Specific Target Organ Toxicity - Repeated Exposure (Globally Harmonized System): No known human health effects upon
repeated exposure.
Aspiration Hazard: Based on available data, the classification criteria are not met.
Potential Health Effects:

（MSDS）
Inhalation: No obvious symptoms under normal usage. May cause respiratory irritation if inhaled concentrated vapor .
Skin Contact: No skin irritation effects under normal condition.
Eye Contact: May cause eye irritation if in-eye.
Ingestion: Not an expected route of exposure. May be harmful if swallowed.
Section 12 - Ecological Information

12.1 Toxicity
Toxicity to fish flow-through test LC50 - Lepomis macrochirus - 38 - 60 mg/l - 96 h(OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates
Immobilization EC50 - Daphnia magna (Water flea) - > 1 mg/l - 24 h(OECD Test Guideline 202)
Toxicity to algae Growth inhibition EC50 - Desmodesmus subspicatus (green algae) - 11.5 mg/l- 72 h(OECD Test Guideline
201)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 16 % - Not readily biodegradable.(OECD Test Guideline 301D)
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Do not allow materials to release to drains or water body.
Section 13 - Disposal Considerations

Waste treatment methods
Product
Waste should be poured into a special bucket (with lid) for further treatment. Offer surplus product to a licensed disposal
company. Observe according to the national and local related regulations.
Contaminated packaging
Containers may still present chemical hazard when empty. Return to supplier for recycling if possible.
Section 14 - Transport Information

14.1 UN Number：ADR, IMDG, IATA
ADR/RID: Not regulated as dangerous goods.

（MSDS）
IMDG: Not regulated as dangerous goods.

IATA: Not regulated as dangerous goods.
14.2 UN proper shipping name: ADR, IMDG, IATA
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es):ADR, IMDG, IATA
14.4 Packing group:ADR, IMDG, IATA
14.5 Environmental hazards: No
14.6 Special precautions for user：No information available..
Section 15 - Regulatory Information

EU Regulations
Classification according to 67/548/EEC or 1999/45/EC
Not classified as hazardous.
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Not classified as hazardous.
US Regulations
U.S. Federal Regulations
SARA 313 Not applicable
SARA 311/312 Hazardous Categorization
Acute Health Hazard No
Chronic Health Hazard No
Fire Hazard No
Sudden Release of Pressure Hazard No
Reactive Hazard No
Clean Water Act Not applicable
Clean Air Act Not applicable
OSHA Occupational Safety and Health Administration
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

（MSDS）
CERCLA Not applicable

International Chemical Substances list:
CAS No. EINEC TSCA DSL IECSC NZIoC PICCS KECI AICS
77-90-7 listed listed unlisted listed listed listed unlisted listed
Note: EINECS: European Inventory of Existing Commercial Chemical Substances
TSCA: TSCA Chemical Substance Inventory
DSL: Canada Domestic Substance List
IECSC: Inventory of Existing Chemical Substances in China
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippines Inventory of Chemicals and Chemical Substances
KECI: Korea Existing Chemicals Inventory
AICS: Australian Inventory of Chemical Substances
Section 16 - Additional Information

Abbreviations:
pH - Relates to hydrogen ion concentration - this value will relate to a scale of 0 - 14, where 0 is highly acidic and 14 is highly
alkaline
OSHA- Occupational Safety and Health Administration
NTP – National Toxicilogy Program
IARC- International Agency for Research on Cancer
CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds
ACGIH – The American Conference of Governmental Industrial Hygienists
ADR –Agreement on Dangerous Goods by Road
IATA –International Air Transport Association
IMDG - International Maritime Dangerous Goods
Further Information:
-This safety data sheet was prepared in accordance with UN GHS Rev.6, The EU CLP REGULATION (EC) No 1272/2008,
and ANSI Z400.1.
-The above information is based on the data of which we are aware and is believed to be correct as of the data hereof.
Since this information may be applied under conditions beyond our control and with which may be unfamiliar and since data
made available subsequent to the data hereof may suggest modifications of the information, we do not assume any
responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his
own determination of the suitability of the material for his particular purpose.
Department Issuing MSDS: Lemon-flex Company Limited China
Issue Date: September 5, 2016


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Atbc MSDS

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Material Safety Data Sheet

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 1 of 9

Applicant: Lemon-flex Company Limited China

Shanghai Changyin Testing Technology Co.,Ltd

Lemon-flex Company Limited China

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 2 of 9

Section 1 - Chemical Product and Company Identification

1.3 Details of the Manufacture or supplier

1.4 Emergency telephone number

Section 2 - Hazards Identification

2.2 GHS Label elements, including precautionary statements

2.3 Description of any hazards not otherwise classified

Lemon-flex Company Limited China

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 3 of 9

Section 3 - Composition/Information on Ingredient

Chemical name CAS No. EINECS No. Content (%)

Acetyl tributyl citrate 77-90-7 201-067-0 >99%

Abbreviation: CAS No. is Chemical Abstract Service Registry Number.

Section 4 - First Aid Measures

Section 5 -Extinguishing media

Lemon-flex Company Limited China

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 4 of 9

Section 6 - Accidental Release Measures

Section 7 - Handling and Storage

7.2 Conditions for safe storage, including any incompatibilities:

Lemon-flex Company Limited China

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 5 of 9

Section 8 - Exposure Controls, Personal Protection

Section 9 - Physical and Chemical Properties

Information on basic physical and chemical properties

Lemon-flex Company Limited China

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 6 of 9

Relative density 1.05 g/cm3 at 25℃

Section 10 - Stability and Reactivity

Section 11 - Toxicological Information

Lemon-flex Company Limited China

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 7 of 9

Section 12 - Ecological Information

Section 13 - Disposal Considerations

Section 14 - Transport Information

Lemon-flex Company Limited China

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 8 of 9

IMDG: Not regulated as dangerous goods.

Section 15 - Regulatory Information

Lemon-flex Company Limited China

NO.: A001R160901013 Creation Date: September 5, 2016 Pa g e 9 of 9

CERCLA Not applicable

Section 16 - Additional Information

Lemon-flex Company Limited China

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