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Mater ial Safety Data Sheet

(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page1of 9

Applicant: Lemon-flex Company Limited China


Address: No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu

Sample infor mation:


Product Trademark: LMFLEX® LM40
Product name: Acetyl tributyl citrate
Sample received date: March 4, 2019
Testing period: From March 4, 2019 to March 8, 2019

Test Requested: As specified by the client, to edit Material Safety Data Sheet (MSDS) for the submitted sample.

Shanghai Changyin Testing Technology Co.,Ltd

Approved by:

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page2of 9

Section 1 - Chemical Product and Company Identification


1.1 Pr oduct Identification:
Product Trademark: LMFLEX® LM40
Product name: Acetyl tributyl citrate

1.2 Relevant identified uses of the substance or mixtur e and uses advised against
Identified uses: Non-toxic PVC plastic plasticizer
Use advised against: No data available.

1.3 Details of the Manufactur e or supplier


Manufacture: Lemon-flex Company Limited China
Address: No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Telephone: +86-0510-87865333
Fax: +86-0510-87866222
Email: hyl@lemonchem.com

1.4 Emer gency telephone number


Emergency Telephone: +86-0510-87865333

Section 2 - Hazards Identification


2.1 Classification of the substance or mixtur e
This product is not classified as dangerous according to the GHS (The Globally Harmonized System of Classification and
Labelling of Chemicals).

2.2 GHS Label elements, including pr ecautionar y statements


Pictogr am(s): No pictogram is used.
Signal wor d: No signal word is used.
Hazar d statements: No hazard statement.
Pr ecautionar y statements: No precautionary statement.

2.3 Descr iption of any hazar ds not other wise classified


No information available.

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page3of 9

Section 3 - Composition/Information on Ingredient


Substance () Preparation (√) Article ()
Composition:
Product name: Acetyl tributyl citrate
Molecular formula: C20H34O8
Molecular Weight: 402.48

Chemical name CAS No. EINECS No. Content (% )

Acetyl tributyl citrate 77-90-7 201-067-0 >99%

Abbreviation: CAS No. is Chemical Abstract Service Registry Number.

Section 4 - First Aid Measures


4.1 Descr iption of fir st aid measur es
Eye Contact: Immediately flush eyes with plenty of water for several minutes, occasionally lifting the upper and lower eyelids. If
irritation occurs and persists, contact a doctor.
Skin Contact: Wash off with soap and plenty of water. If skin irritation occurs: Get medical advice/attention .
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if feel
unwell.
Ingestion: Never give anything by mouth to an unconscious person. Rinse mouth with water. Seek medical advice
immediately.
4.2 Most impor tant symptoms and effects, both acute and delayed
No information available.
4.3 Indication of any immediate medical attention and special tr eatment needed
Treat symptomatically and supportively.

Section 5 -Extinguishing media


5.1 Extinguishing media
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazar ds ar ising fr om the substance or mixtur e

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page4of 9

Combustible exposed to flame and overheat. Gives off irritating fumes (or gases) in a fire: Carbon oxides. In case of overheat,
increased pressure within containers has the risk of cracking and explosion.
5.3 Advice for fir efighter s
Evacuate personnel to safe areas. Wear self-contained breathing apparatus and suitable protective equipment for firefighting.
Stand upwind.
5.4 Fur ther infor mation
Move container away from fire if safe. Use water fog to cool down fire exposed container.

Section 6 - Accidental Release Measures


For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13
for information on disposal. Observe the relevant local and international regulations.
6.1 Per sonal pr ecautions, pr otective equipment and emer gency pr ocedur es: Ensure adequate ventilation. Use personal
protective equipment. Avoid contact with skin and eyes. For personal protection see section 8.

6.2 Envir onmental pr ecautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains or water
source.
6.3 Methods and mater ials for containment and cleaning up:

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly with water to remove

residual contamination.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.

Collect with an electrically protected vacuum cleaner or by wet- brushing and place in closed container for

recycle or disposal according to local regulations (see section 13).

Section 7 - Handling and Storage


7.1 Pr ecautions for safe handling:
Take the usual precautions when handling with chemicals. Use in well-ventilated area. Avoid contact with skin and eyes. Avoid
breathing concentrated vapor or mist. Wash thoroughly after handling. Keep container tightly closed when not in use.

7.2 Conditions for safe stor age, including any incompatibilities:

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page5of 9

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be
carefully resealed and kept upright to prevent leakage. Keep away from heat and flame. Avoid direct sunlight. Moisture
sensitive, pay attention to moisture. Do not store together with strong oxides. Provide fire fighting equipment and tools for
accidental release.

Section 8 - Exposure Controls, Personal Protection


8.1 Exposur e Limits: Not established.
8.2 Exposur e contr ols
Engineer ing Contr ol: General industrial hygiene practice. Suggest Proving enough ventilation. Provide wash shower and eye
wash fountain.
Per sonal pr otective equipment:
Respir ator y Pr otection: Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK
(EU EN 14387) respirator cartridges. Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).
Eyes Pr otection: Not required under normal usage. Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU) if in-eye risk exists.
Body Pr otection: To avoid contaminating personal clothing, wear suitable protective clothing. The type of protective equipment
must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Hands Pr otection: Handle with chemical-resistant gloves. Use proper glove removal technique(without touching glove's outer
surface) to avoid skin contact with this product.
Other Pr otections: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.

Section 9 - Physical and Chemical Properties

Infor mation on basic physical and chemical pr oper ties


Appear ance Colorless transparent oily liquid
Odor Odorless
pH Not available.
Melting point/fr eezing point -80℃(101.3KPa)
Initial boiling point and boiling r ange 331℃-97.64 kPa
Flash point 217℃- closed cup
Evapor ation r ate Not available.

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page6of 9

Flammability Not flammable.


Upper explosive limit % (V/V) Not available.
Lower explosive limit % (V/V) Not available.
Vapor pr essur e 1.79 kpa at 20℃
Vapor density Not available.
Relative density 1.05 g/cm3 at 25℃
Solubility(ies) Slightly soluble in water.
Par tition coefficient: n-octanol/water log Pow: 4.86 at 40℃
Auto-ignition temper atur e 206.5℃ at 101.3 kPa
Decomposition temper atur e Not available.
Viscosity 40.4 mm2/s at 20℃

Section 10 - Stability and Reactivity


10.1 Stability: Stable under recommended storage conditions.
10.2 Conditions to Avoid: heat, flames and mars. Avoid moisture.
10.3 Incompatible mater ials: Strong oxidant.
10.4 Hazar dous Decomposition Pr oducts: Other decomposition products- no data available. In the event of fire:see section 5.
10.5 Possibility of hazar dous r eactions:No data available.

Section 11 - Toxicological Information


Acute Toxicity:
LD50 Oral - Rat - > 31500 mg/kg
LD50 Intraperitoneal - Mouse - > 4000 mg/kg
Skin Cor r osion/Ir r itation:
Skin - Rabbit
Result: No skin irritation
Ser ious Eye Damage/Eye Ir r itation:
Eyes - Rabbit
Result: Mild eye irritation
Respir ator y or Skin Sensitization: Not sensitive effect.
Ger m Cell Mutagenicity: Based on available data, the classification criteria are not met.
Car cinogenicity:None of the components of this product is listed as a carcinogen by IARC, NTP, US OSHA or the European
Directive (67/548/EEC).
Repr oductive Toxicity: Based on available data, the classification criteria are not met.
Specific Tar get Or gan Toxicity - Single Exposur e (Globally Har monized System): No known human health effects upon single

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page7of 9

exposure.
Specific Tar get Or gan Toxicity - Repeated Exposur e (Globally Har monized System): No known human health effects upon
repeated exposure.
Aspir ation Hazar d: Based on available data, the classification criteria are not met.
Potential Health Effects:
Inhalation: No obvious symptoms under normal usage. May cause respiratory irritation if inhaled concentrated vapor .
Skin Contact: No skin irritation effects under normal condition.
Eye Contact: May cause eye irritation if in-eye.
Ingestion: Not an expected route of exposure. May be harmful if swallowed.

Section 12 - Ecological Information


12.1 Toxicity
Toxicity to fish flow-through test LC50 - Lepomis macrochirus - 38 - 60 mg/l - 96 h(OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates
Immobilization EC50 - Daphnia magna (Water flea) - > 1 mg/l - 24 h(OECD Test Guideline 202)
Toxicity to algae Growth inhibition EC50 - Desmodesmus subspicatus (green algae) - 11.5 mg/l- 72 h(OECD Test Guideline
201)
12.2 Per sistence and degr adability
Biodegradability aerobic - Exposure time 28 d
Result: 16 % - Not readily biodegradable.(OECD Test Guideline 301D)
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adver se effects
Do not allow materials to release to drains or water body.

Section 13 - Disposal Considerations


Waste tr eatment methods
Pr oduct
Waste should be poured into a special bucket (with lid) for further treatment. Offer surplus product to a licensed disposal
company. Observe according to the national and local related regulations.
Contaminated packaging

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page8of 9

Containers may still present chemical hazard when empty. Return to supplier for recycling if possible.

Section 14 - Transport Information


14.1 UN Number :ADR, IMDG, IATA
ADR/RID: Not regulated as dangerous goods.
IMDG: Not regulated as dangerous goods.
IATA: Not regulated as dangerous goods.
14.2 UN pr oper shipping name: ADR, IMDG, IATA
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Tr anspor t hazar d class(es):ADR, IMDG, IATA
ADR/RID: Not regulated as dangerous goods.
IMDG: Not regulated as dangerous goods.
IATA: Not regulated as dangerous goods.
14.4 Packing gr oup:ADR, IMDG, IATA
ADR/RID: Not regulated as dangerous goods.
IMDG: Not regulated as dangerous goods.
IATA: Not regulated as dangerous goods.
14.5 Envir onmental hazar ds: No
14.6 Special pr ecautions for user :No information available..

Section 15 - Regulatory Information


EU Regulations
Classification accor ding to 67/548/EEC or 1999/45/EC
Not classified as hazardous.
Classification accor ding to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Not classified as hazardous.
US Regulations
U.S. Feder al Regulations
SARA 313 Not applicable
SARA 311/312 Hazar dous Categor ization
Acute Health Hazard No
Chronic Health Hazard No
Fire Hazard No
Sudden Release of Pressure Hazard No

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 Page9of 9

Reactive Hazard No
Clean Water Act Not applicable
Clean Air Act Not applicable
OSHA Occupational Safety and Health Administr ation
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
CERCLA Not applicable
Inter national Chemical Substances list:
CAS No. EINEC TSCA DSL IECSC NZIoC PICCS KECI AICS
77-90-7 listed listed unlisted listed listed listed unlisted listed
Note: EINECS: European Inventory of Existing Commercial Chemical Substances
TSCA: TSCA Chemical Substance Inventory
DSL: Canada Domestic Substance List
IECSC: Inventory of Existing Chemical Substances in China
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippines Inventory of Chemicals and Chemical Substances
KECI: Korea Existing Chemicals Inventory
AICS: Australian Inventory of Chemical Substances

Section 16 - Additional Information


Abbr eviations:
pH - Relates to hydrogen ion concentration - this value will relate to a scale of 0 - 14, where 0 is highly acidic and 14 is highly
alkaline
OSHA- Occupational Safety and Health Administration
NTP – National Toxicilogy Program
IARC- International Agency for Research on Cancer
CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds
ACGIH – The American Conference of Governmental Industrial Hygienists
ADR –Agreement on Dangerous Goods by Road
IATA –International Air Transport Association
IMDG - International Maritime Dangerous Goods
Fur ther Infor mation:
-This safety data sheet was prepared in accordance with UN GHS Rev.7, The EU CLP REGULATION (EC) No 1272/2008,
and US OSHA Hazard Communication Standards (29 CFR 1910.1200).
-The above information is based on the data of which we are aware and is believed to be correct as of the data hereof.
Since this information may be applied under conditions beyond our control and with which may be unfamiliar and since data
made available subsequent to the data hereof may suggest modifications of the information, we do not assume any

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com
Mater ial Safety Data Sheet
(MSDS)
In accordance with GHS Rev. 7.and The EU CLP REGULATION (EC) No 1272/2008

NO.: A001R190304013 Creation Date: March 8, 2019 P a g e 10 o f 9

responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his
own determination of the suitability of the material for his particular purpose.
Depar tment Issuing MSDS: Lemon-flex Company Limited China
Issue Date: March 8, 2019

Lemon-flex Company Limited China


No.1 KaiXuan Road,Yixing Economic&Technological Development Zone,Jiangsu
Tel:+86-0510-87866555, Fax:+86-0510-87866222, Website: www.lemonchem.com

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