Professional Documents
Culture Documents
by Kyle A. Riding, Michael D.A. Thomas, R. Doug Hooton, Karthik H. Obla, and W. Jason Weiss
C
oncrete producers are often required to make concrete ease at which chloride-containing solutions can flow into
according to the customer’s recipe, even though they concrete is often referred to as permeability4 but, due to the
know that they could make concrete that can attain a different mechanisms of fluid ingress, this characteristic is
better performance at a lower price. This may sometimes be better called penetrability.
the case for concrete made for buildings that will be exposed Concrete’s resistance to fluid penetration can be improved
to chlorides, where the customer is compelled to use the by reducing the volume and connectivity of the pores in the
prescriptive requirements in the ACI 318-14 Building Code.1 matrix, typically achieved by minimizing the water-
Alternatives to prescriptive requirements are in the form of cementitious materials ratio (w/cm) using supplementary
performance-based specifications, based on “a set of clear, cementitious materials (SCMs). Some SCMs such as silica fume
measurable, and enforceable instructions”2 that meet the and metakaolin effectively improve the resistance to chloride
owner’s needs. To define those alternatives, one must examine penetration at early ages, while fly ash and slag cement provide
the problems caused by chloride exposure of reinforced larger decreases in penetrability at later ages. Regardless of
concrete, how chlorides get into concrete, current building code the SCM content, concrete’s resistance to fluid penetration
requirements, and options and criteria available for test methods improves with greater maturity or degree of hydration.
that measure the concrete’s resistance to chloride ingress. Once chlorides enter the pores, some of them are held up
(bound) by chemical reaction with, or are physically adsorbed
Chloride-Induced Corrosion by, cement hydration products. The total chloride content in
Corrosion of reinforcing steel in concrete is the largest the concrete is the sum of the bound chlorides and the
cause of concrete deterioration, and it results in billions of chlorides in the pore solution that are free to migrate further
dollars of annual maintenance costs in the United States into the concrete, termed the free chlorides. The cementitious
alone.3 In new concrete, embedded reinforcing steel forms a material composition, concrete temperature, and concrete
passive oxide layer (gamma-ferric hydroxide) that protects the carbonation all affect the chloride binding potential of the
steel from corrosion. This passive layer remains stable in the concrete.5 For example, metakaolin contains a high quantity
high-pH environment of concrete. However, if the concrete of alumina and increases chloride binding, whereas silica
around the steel carbonates and reduces the pH, or if the fume slightly reduces chloride binding.6 However, the benefits
concrete contains a high enough level of chlorides, the passive of chloride binding may not be observed in short-duration
layer will become unstable—and corrosion ensues. chloride exposure tests.
Chlorides can get into fresh concrete via the mixing water,
contaminated aggregate, or chemical admixtures. But much Current ACI 318 Requirements
more often, water-borne chlorides are carried into the pores of ACI 318-14 Building Code attempts to increase structural
hardened concrete through forced gradients in chloride life through prescriptive requirements that indirectly improve
concentration, moisture content, temperature, or pressure. The chloride penetration resistance by requiring both minimum
concrete compressive strength f ʹc and maximum w/cm (Table 1).1 least 90 or 35 days, respectively. The chloride concentration is
Many structures face additional environmental exposure then measured at different depths to quantify the chloride
requirements. For example, parking garages exposed to ingress rate. In ASTM C1556, the total chloride concentration
deicing chemicals would also be classified as a freezing-and- with depth profile is used to determine a diffusion coefficient
thawing category F3 with its associated w/cm, f ʹc, air content, using Eq. (1)9
and cementitious material limits.
x
The limits provided in Table 1 are very indirect and C ( x, t ) = Cs − (Cs − Ci ) ⋅ erf (1)
4⋅ D ⋅t
somewhat ineffective methods of trying to limit chloride a
penetration into the concrete. Both the concrete resistance to where C(x,t) is the chloride concentration (%) at depth x (m)
fluid penetration and strength are related to the porosity; and time t (s); Cs is the concrete surface chloride concentration
however, the relationship is not a linear one. Since w/cm is (%); Ci is the initial chloride concentration (%); and Da is the
difficult to measure, a minimum compressive strength concrete apparent diffusion coefficient (m2/s).
requirement was adopted as an indirect measure of the w/cm, Da is referred to as the concrete apparent diffusion
an f ʹc of 5000 psi (35 MPa) is commonly achieved for air- coefficient because it is fit to the total acid-soluble chloride
entrained concrete with a w/cm of 0.40. For non-air-entrained concentration data. Because only the free chlorides diffuse
concrete or for concrete with certain SCMs, however, this into the concrete but Da is fit to the total chloride
relationship does not necessarily hold true. For example, a concentration, the term apparent is used to signify that it is a
mixture with silica fume could have an f ʹc of 5000 psi (35 MPa) combination of these effects. The chloride diffusion coefficient
at a w/cm higher than 0.40. that only includes the diffusion of free chlorides and not any
effects of chloride binding is termed the effective diffusion
Alternatives coefficient Deff.
The ideal test for the concrete’s ability to keep out chloride Concrete ponding tests are expensive, results differ based
ions for corrosion protection would be one that directly on the type and concentration of salt used, and they take a lot
measures the concrete pore system and its connectivity; of time to complete because of the long ponding times
includes chloride binding; accounts for the decrease in required and because of the labor required to grind the
chloride penetrability with aging; and is rapid, low cost, and concrete layer by layer and measure the acid-soluble chloride
easy to perform. What are the options? Current alternative content with depth. These negative features limit the
tests can be classified as measures of chloride ingress rates desirability of a ponding test as a performance test.
from ponding tests or from concrete electrical tests that
indirectly provide a measure of the pore volume and Electrical analog tests
connectivity of the pore network. Pioneering work done by Gus Archie in the 1940s and
continued by other oil-field geologists and engineers
Concrete chloride exposure tests developed the concept of the formation factor F to empirically
Concrete ponding tests include ASTM C15437 (similar to describe the ability of brine to flow through rock formations.10
AASHTO T 2598) and ASTM C1556,9 in which a mature This relationship states that F is a function of the total
concrete slab or sample is exposed to a chloride solution for at porosity of the rock, as well as the tortuosity and constriction
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ACI member Kyle A. Riding is an and is Chair of ACI Committee 201, Durability, and ACI
Associate Professor of Civil and Coastal Subcommittee 130-A, Materials; and a member of several other
Engineering at the Engineering School ACI Committees. He is also a RILEM Fellow and Chair of the
of Sustainable Infrastructure and RILEM Educational Activities Committee and a member of several
Environment at the University of Florida, RILEM technical committees.
Gainesville, FL. He is Secretary of ACI
Committee 231, Properties of Concrete Karthik H. Obla, FACI, is Vice President
at Early Ages, and a member of ACI of Technical Services at the National
Committees 201, Durability of Concrete; Ready Mixed Concrete Association
207, Mass and Thermally Controlled Concrete; 236, Material (NRMCA), Silver Spring, MD. He serves
Science of Concrete; and S803, Faculty Network. He received on several ACI committees, including ACI
his BS in civil and environmental engineering from Brigham Committee 201, Durability of Concrete;
Young University, Provo, UT, and his MSE and PhD in civil and 329, Performance Criteria for
engineering from The University of Texas at Austin, Austin, TX. Ready Mixed Concrete. He is a recipient
of ACI’s Young Member Award for
Michael D.A. Thomas, FACI, is a Professional Achievement and served as President of the San
Professor of Civil Engineering at Antonio Chapter – ACI. He received his BS in civil engineering
the University of New Brunswick, from IIT (BHU), Varanasi, India, and his MS and PhD in civil
Fredericton, NB, Canada. He is a member engineering from the University of Michigan, Ann Arbor, MI.
of the ACI Materials Journal Editorial
Board; ACI Committees 201, Durability W. Jason Weiss, FACI, is the Miles
of Concrete; 221, Aggregates; 232, Fly Lowell and Margaret Watt Edwards
Ash in Concrete; 233, Ground Slag in Distinguished Chair in Engineering
Concrete; 234, Silica Fume in Concrete; and Head of the School of Civil and
236, Material Science of Concrete; 239, Ultra-High Performance Construction Engineering at Oregon
Concrete; 240, Pozzolans; 308, Curing Concrete; 365, Service State University, Corvallis, OR. He is Chair
Life Prediction; S803, Faculty Network; and ACI Subcommittee of the ACI Materials Journal Editorial
130-A, Materials. He is also a member of CSA technical Board and ACI Committee 231, Properties
committees A23.1/A23.2 and A3000. He received his BSc in civil of Concrete at Early Ages. He is also a
engineering from the University of Nottingham, Nottingham, UK, member of the ACI Board Committee
and his PhD in civil engineering from the University of Aston, Chairs Committee; ACI Committees 201, Durability of Concrete;
Birmingham, UK. 213, Lightweight Aggregate and Concrete; 236, Material
Science of Concrete; 318, Structural Concrete Building Code;
R. Douglas Hooton, FACI, is a Professor S803, Faculty Network; and ACI Subcommittee 318-A, General,
and NSERC/Cement Association of Concrete, and Construction. He received his BAE in architectural
Canada, Senior Industrial Research engineering from Pennsylvania State University, State College,
Chair in Concrete Durability and PA, and his MS and PhD in civil engineering from Northwestern
Sustainability in the Department of Civil University, Evanston, IL.
Engineering at the University of Toronto,
Toronto, ON, Canada, where he has
taught for more than 30 years. He
serves on the ACI Board of Direction