Not toe ten meh Paetas eenrae sar am “The Chinese Unversity of Hong Kong ‘huidetsenst =S=-Er Cem ‘Course Examination 2nd Term, 202-2022 ame A ‘Couese Code & Tite: _CHEMIOTS Prins of Modern Chemisty eo am 2a ‘Te allowed 2 sours 0 sinter ane ee ‘Studest LD. Nox ‘Student Name: Attempt ALL questions. All answers shoul be put on the Ad answer sheets, Make sure that you have written down Stadent I. and Name on every answer thee ‘Tosive paper, you DO NOT need to start new page for each question. Answer in ENGLISH. ‘Total Marks: 75 Structure Questions |. White complete and belated equations fr each ofthe flowing reactions and state the type of reaction (Le. decompositen, combination, combustion, replacement a reatoa). 1) Feh +AgNO— 8 CHO1+0;— ©) BuOH): +HICI + @ Natch—» ©) Cut FeO (Comers) 1) Balance he oto gua: NCOs HCL NeC1+CO3+ HO NaltCOs +HCI— NaCl C02 + HO 1) A-sample consis mistre of NCOs and Né:COs, HCIis added to 15.0 gf the sample, vielding 110 gof NaCl. What percent of the sample is NasCOs? (marks)Course Code WIRRI® : _CHEMIO70 Page 2085 4) Determine the volume of oxygen gata 27°C and 0.21 atm poduced by decomposition of 2.44 gKCIOy and KCI the eer product. 1) How many atoms of oxygen ate therein this quantity of product? (mas) 4) Lithium meta as tod-centered cubic wit cell, How many lithium atoms are there ia unit, call? ) Krypton crystallizes in stucture that as four Kratoms in each uit el, and he unit ella cube, The edgs length oh nit cell i059 mm. Calculate the density of estan Kin kai’. (4a) 5. 20> is reduce rapily by Sn, he product being Su!” and water. HiO, desonpsos slowly st room temperate oye Os and water. Cale the volume of O3 produced et 20°C ant 1.00 tm when 200 g of 1.0 9% by mass 03 in water sweated with 100.0 mL of 2.0 M Si snd thea the mixture i llowed to stand until no Fre eation ooeus Bmaks) {6 Determine which eagrt isn exces and by how much if 10.0 g PsOy i wate with 100.0 5 KO in HC! soluon form HsPOx and Mal, (amas) 1 Aluminum mata isa vey effective reagent fr reusing oxides to thei element. An example isthe themiteeseton: Fos0x() + 2A) + ALOHS) + 2Fel0) Calle he standard euapy change when 1.00 mal ofeach of the folowing oxides is reduced by aluminum at298 K: a) FeO. by si0. 9cu0) (nas) The eat evolved on combustion of .00g of starch (CaHu02, ato COx() and HeO(D is 4.18 ‘ca. Comput the stand enthalpy of formation of 1.00 go starch, 4 mari) suRm mm “The Chinese Univer of Hong Kong ‘ome ReredCourse Code BEu€ : __CHEMO70 Page 3 of 5 9, ‘Sultance A rests assonng to fre ord rte aw with K=5.0% 105 1. 5) Pte ntl consentation ofA 1.0 M, what isthe ntl ate? 1b) Whatis the rt ater 1.0? tn nts) 10. Suerosedesompeses in ad solution ino glucose and fucose, according fst order rate law, witha hale of 333 at 25°C. What faction of sample of sucrose remains ar 9.00 et @ mats) 1, Ata cern temperature the equiviam constant for the reaetion of CO with Oto produce {COs i550 10" Lanot. Calculate the concentration of CO at equilibrium if 1.0 mol each of (CO and Os ae plaed ina 2.01. vessel and allowed to come to equilibrium. (Sma) 12, Find to values of {OH andthe pH ina slation made by dissolving 0.0050 mol exch of ammonia nd prin (CN) in enough wate to make 200 em? of solution, What ae the ‘concentrations of ammonium (NE) al pyridinium [C:HeNH"] ions? Provide that he Ki values of NHy= 1.x 10° and CHAN = 1.52 10% (marks) 18 Acurtent of 15.0 Ais psd through a solution of CrCl fr 45min 8) How many grams of Cis deposited on the extode? 1) Cau the vokume of Ci thats obssinad atthe anode at 1,00 atm and 273K. 4 mais) 1H, Caleuate the AGP and AS forthe session Hs + On(g) + 21-040, Provided: 20 0, 4K + 2a mats) 15, Agasous compound is composed 85.7% by mas carbon and 14.39% by mass hydrogen. Is density is 2.28 gat 300K end |,00 am presse, Determine the molecular formula ofthe compound, (ima) Bd of Paper - wn am ‘The Chinese Universi of Hous Kong ScmistReralCourse Code FRE : _CHEMIO70 Page dots ‘Used constams: Planes constant b= 6.6261 < 10 ¢ Speed of light=2.998 10%ms" (Gas Constant R= 0.0821 LeieiotK!;=8314 al! Paraday's constant (F) = 9685 Cro! Standatd Eathalpis of Fnnation, AH at 298K 7 eaimol eatimol Ba06) Fao] _ 19650 | 10a) 68.32 ‘AlOxs) HO) 5119 | exo) a0 Css) Coe) 64 Now) 309 ‘Useful equations: 1. Temperatre conversion: [°C] =[K]~ 278.15 1, Ideal Gas Lave PV =nkT 1M, Zora Ouder: [Ae=—A1+[Alos fun =[Alo/2k IV, Onder [A= Arn t= la V. 20! Onder EAH Ale: tin 1/ Alo Vi AG=~ 2 Vil Qmix1 VI, AW=aB-+ Pav 1X AG=aH-T3s. The Chinese Unive of Hang Keng omni BontPage Sof S curasio70 Course Code HEME : "The Perlodle Table ofthe Elements cai af j= fil aulsal bal biped EZ neil nee aa ixal oth Rail Fall a cae eullea ‘The Chines University of Hong Kong, wasn 0m